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Effects of interphase layer on mechanical properties of silicone rubber composite filled with nano-silica particles

Research Project

Project/Area Number 17K06053
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Materials/Mechanics of materials
Research InstitutionToyohashi University of Technology

Principal Investigator

Adachi Tadaharu  豊橋技術科学大学, 工学(系)研究科(研究院), 教授 (20184187)

Co-Investigator(Kenkyū-buntansha) 石井 陽介  豊橋技術科学大学, 工学(系)研究科(研究院), 助教 (70781706)
Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2019: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2018: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2017: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywords材料設計 / シリコーンゴム / シリカ粒子 / ナノコンポジット / 弾性係数 / 比例限界ひずみ / 破壊靭性 / ヤング率 / 中間層 / 力学的特性 / 機械材料・材料力学 / 複合材料・物性
Outline of Final Research Achievements

Effect of interphase layers formed around nano-particles on mechanical properties of silicone rubber composites filled with nano- and micro-silica particles was examined experimentally and their elastic behaviors including the effect were formulated by using a model in which the particles were distributed three-dimensionally and randomly. Considering the nano-particles with the interphase layers in the composite behaved as apparent particles, the experimental result confirmed that Lewis and Nielsen’s mixture law with the apparent volume fraction could obtain the Young’s modulus of the composite in the linear elastic region. The proportional limit strain of the composite was then formulated theoretically. The validity of the analytical limit strain was confirmed by comparison with measured results for composites filled with nano- and micro-particles.

Academic Significance and Societal Importance of the Research Achievements

本研究においてゴム材料で重要な特性のひとつである柔軟性を有する低弾性領域におけるヤング率に対する従来の複合則の適用方法を見出し,さらにヤング率の適用限界である比例限界ひずみを定式化することに成功した.この成果からナノコンポジットを含む粒子充填ゴム複合材料の材料設計を行うことを可能にした.さらに中間層を積極的に使用することで,複合材料の問題である廃棄物処理,リサイクルのために充填材の使用を低減するとともに密度の増加をも抑え,必要な複合材料の力学的特性を得ることができると考えられる.

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Research-status Report
  • 2017 Research-status Report
  • Research Products

    (5 results)

All 2020 2019 2018 2017

All Journal Article (1 results) (of which Peer Reviewed: 1 results) Presentation (4 results)

  • [Journal Article] Interphase-layer effect on deformation of silicone rubber filled with nano-silica particles2018

    • Author(s)
      Tadaharu ADACHI, Yuki YAMADA, Yosuke ISHII
    • Journal Title

      Journal of Applied Polymer Science

      Volume: 135 Issue: 8 Pages: 1-7

    • DOI

      10.1002/app.45880

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Presentation] シリコーンゴム複合材料の線形弾性挙動に及ぼすナノ粒子充填の影響2020

    • Author(s)
      野田 彩華, 足立 忠晴, 石井 陽介
    • Organizer
      第51回応力・ひずみ測定と強度評価シンポジウム
    • Related Report
      2019 Annual Research Report
  • [Presentation] 粒子充填ゴム複合材料の線形弾性領域の変形特性に及ぼす粒子充填の影響2019

    • Author(s)
      野田 彩華, 足立 忠晴, 石井 陽介
    • Organizer
      日本機械学会 M&M2019 材料力学カンファレンス
    • Related Report
      2019 Annual Research Report
  • [Presentation] シリコーンゴム複合材料の破壊に及ぼすシリカ充填効果2019

    • Author(s)
      渡邊 亮賢, 野田 彩華, 足立 忠晴, 石井 陽介
    • Organizer
      第50回応力・ひずみ測定と強度評価シンポジウム
    • Related Report
      2018 Research-status Report
  • [Presentation] エポキシ樹脂のゴム状態における粘弾性特性に及ぼすナノシリカ粒子充填効果2017

    • Author(s)
      伊賀 千尋, 足立 忠晴, 石井 陽介
    • Organizer
      第48回応力・ひずみ測定と強度評価シンポジウム
    • Related Report
      2017 Research-status Report

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Published: 2017-04-28   Modified: 2021-02-19  

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