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Development of defect evaluation method for photoabsorption layer in compound thin film solar cells and evaluation using it

Research Project

Project/Area Number 17K06345
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Electronic materials/Electric materials
Research InstitutionGifu University

Principal Investigator

ITOH Takashi  岐阜大学, 工学部, 教授 (00223157)

Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2019: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2018: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2017: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywords太陽電池 / 光吸収 / 欠陥評価 / 半導体物性 / 光物性
Outline of Final Research Achievements

In this study, We developed a method to evaluate defects from photo-absorption for the photo-absorption layer in compound thin film solar cells using Fourier transform photocurrent spectroscopy (FTPS). We also evaluated Cu2ZnSn(S,Se)4(CZTSSe) solar cell using it. The exponential tail was observed in the photon-energy region smaller than the band gap energy of CZTSSe. The exponential tail would be related to antisite point defects of Cu and Zn. Furthermore, absorption near 1.3eV was observed through the FTPS measurement of CZTSSe solar cell under bias light irradiation. This absorption would be related to gap-state defect induced by bias light irradiation and would cause decrease of quantum efficiency in the high photon-energy region under the irradiation of white bias light.

Academic Significance and Societal Importance of the Research Achievements

薄膜太陽電池光吸収層の欠陥を太陽電池構造のまま評価である本評価技術は、高効率化合物薄膜太陽電池だけでなく、ペロブスカイト太陽電池など他の高効率薄膜太陽電池の迅速な開発に貢献できる。また、本研究ではCZTSSeのバンドギャップ内の欠陥準位に関する新たな知見が得られており、CZTSSe太陽電池の高効率化だけでなく、CZTSSeの物性理解につながる。以上の点に、学術的意義と社会的意義があると考えられる。

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Research-status Report
  • 2017 Research-status Report
  • Research Products

    (12 results)

All 2019 2018 2017

All Journal Article (2 results) (of which Peer Reviewed: 1 results) Presentation (10 results) (of which Int'l Joint Research: 3 results)

  • [Journal Article] Evaluation of Optical Absorption in Cu<inf>2</inf>ZnSn(S,Se)<inf>4</inf> Absorber Within Cell Structure by Fourier Transform Photocurrent Spectroscopy2018

    • Author(s)
      Itoh Takashi、Syazwana Abd Rahman Nur、Tanabe Kousei、Yamada Shigeru、Nonomura Shuichi、Sugimoto Kanta、Yamada Akira
    • Journal Title

      Proceedings of 2018 IEEE 7th World Conference on Photovoltaic Energy Conversion

      Volume: 1 Pages: 1889-1892

    • DOI

      10.1109/pvsc.2018.8547929

    • Related Report
      2018 Research-status Report
  • [Journal Article] Optical absorption spectra of Cu2ZnSn(S,Se)4 thin film solar cells by Fourier Transform Photocurrent Spectroscopy2018

    • Author(s)
      A.R. Nur Syazwana, K. Tanabe, S. Yamada, T. Itoh, S. Nonomura, K. Sugimoto, and A. Yamada
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 印刷中

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Presentation] 白色バイアス光照射によるCu2ZnSn(S,Se)4太陽電池の量子効率の変化2019

    • Author(s)
      Nur Syazwana Abd Rahman, 杉本寛太, 河田知輝, 山田繁, 伊藤貴司, 野々村修一, 山田明
    • Organizer
      日本学術振興会第175委員会 第16回「次世代の太陽光発電システム」シンポジウム
    • Related Report
      2019 Annual Research Report
  • [Presentation] Effect of light irradiation on quantum efficiency in Cu2ZnSn(S,Se)4 solar cells2019

    • Author(s)
      Abd Rahman Binti Nur Syazwana, Tomoki Kawata, Kanta Sugimoto, Wataru Takahoko, Takumi Nakagawa, Shigeru Yamada, Takashi Itoh, Akira Yamada
    • Organizer
      第80回応用物理学会秋季学術講演会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Internal Quantum Efficiency Spectra of Cu2ZnSn(S,Se)4 Solar Cells Measured by Fourier Transform Photocurrent Spectroscopy2019

    • Author(s)
      A. R. Nur Syazwana, T. Kawata, S. Yamada, T. Itoh, K. Sugimoto, A. Yamada
    • Organizer
      Japan Korea PV Joint Student Seminar
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Evaluation of Optical Absorption in Cu2ZnSn(S,Se)4 Absorber within Cell Structure by Fourier Transform Photocurrent Spectroscopy2018

    • Author(s)
      T. Itoh, A. R. Nur Syazwana, K. Tanabe, S. Yamada, S. Nonomura, K. Sugimoto, A. Yamada
    • Organizer
      7th World Conference on Photovoltaic Energy Conversion
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] FTPS法によるCu2ZnSn(S,Se)4光吸収層の光吸収評価における窓層厚の影響2018

    • Author(s)
      Abd Rahman Nur Syazwana,河田知輝,長田佑太,山田繁,伊藤貴司,野々村修一, 杉本寛太,山田明
    • Organizer
      日本学術振興会第175委員会 第15回「次世代の太陽光発電システム」シンポジウム
    • Related Report
      2018 Research-status Report
  • [Presentation] Cu2ZnSn(S,Se)4の光吸収スペクトルにおける指数関数裾の評価2018

    • Author(s)
      Nur Syazwana Abd Rahman,河田知輝,長田佑太, 山田繁,伊藤貴司,野々村修一,杉本寛太,山田明
    • Organizer
      第79回応用物理学会秋季学術講演会
    • Related Report
      2018 Research-status Report
  • [Presentation] Cu2ZnSn(S,Se)4におけるサブギャップ領域の光吸収評価2018

    • Author(s)
      Nur Syazwana Abd Rahman,河田知輝,長田佑太, 山田繁,伊藤貴司,野々村修一,杉本寛太,山田明
    • Organizer
      第6回応用物理学会名古屋大学スチューデントチャプター東海地区学術講演会
    • Related Report
      2018 Research-status Report
  • [Presentation] FTPS 法によるCu2ZnSn(S,Se)4 の光吸収評価2018

    • Author(s)
      Nur Syazwana Abd Rahman,田邊耕生,山田繁, 伊藤貴司,野々村修一,杉本寛太,山田明
    • Organizer
      第65回応用物理学会春季学術講演会
    • Related Report
      2017 Research-status Report
  • [Presentation] FTPS 法によるCu2ZnSn(SSe)4 薄膜太陽電池の光吸収スペクトル2017

    • Author(s)
      Nur Syazwana Abd Rahman,Norfaizah Mohd Rosli,伊藤貴司,野々村修一,杉本寛太,山田明
    • Organizer
      日本学術振興会第175委員会 第14回 「次世代の太陽光発電システム」シンポジウム
    • Related Report
      2017 Research-status Report
  • [Presentation] Optical Absorption Spectra of Cu2ZnSn(S,Se)4 Thin Film Solar Cells by Fourier Transform Photocurrent Spectroscopy2017

    • Author(s)
      A.R. Nur Syazwana, K. Tanabe, T. Itoh, S. Nonomura, K. Sugimoto, and A. Yamada
    • Organizer
      27th International photovoltaic Science and Engineering Conference
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research

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Published: 2017-04-28   Modified: 2021-02-19  

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