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Study on electronic and atomic structure of ZnMgTe epilayers for electrical conductivity control

Research Project

Project/Area Number 17K06354
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Electronic materials/Electric materials
Research InstitutionSaga University

Principal Investigator

Katsuhiko Saito  佐賀大学, シンクロトロン光応用研究センター, 助教 (40380795)

Project Period (FY) 2017-04-01 – 2023-03-31
Project Status Completed (Fiscal Year 2022)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2019: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2018: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2017: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Keywordsエピタキシャル成長 / 半導体 / 薄膜 / ドーピング / グリーンギャップ / 化合物半導体 / MOVPE法 / 結晶成長 / 放射光 / MOVPE / 電子・電気材料 / 結晶工学 / 半導体物性 / エピタキシャル / シンクロトロン放射光
Outline of Final Research Achievements

This study focused on ZnTe and ZnMgTe semiconductors, which are expected as novel emitting and cladding layer materials capable of covering a wide visible light range from green to blue, and as promising materials to address the "green gap" problem. We aimed to understand the factors that hindered the control of electrical conductivity in these materials, which have p-type unipolarity. By employing a combination of metal organic vapor phase epitaxy method and post-growth annealing, the activation rate of dopants was improved, and a negative correlation between carrier density and lattice constant was identified. Valuable knowledge was also acquired regarding the electronic states of ZnMgTe. Furthermore, significant insights were gained, including the impact of annealing temperature on the variation of complex acceptors.

Academic Significance and Societal Importance of the Research Achievements

ワイドギャップ半導体にみられる単極性は,デバイス応用を進める上で問題となる共通の課題である。本研究により得られた種々の基礎的知見および洞察は,純緑色発光に適したユニークな材料であるZnTeからなるLEDの高効率化と「グリーンギャップ」の克服,さらには純緑色レーザーへの道を切り開く点など,低炭素・省エネルギー社会における次世代光デバイス応用に寄与し得るものである。

Report

(7 results)
  • 2022 Annual Research Report   Final Research Report ( PDF )
  • 2021 Research-status Report
  • 2020 Research-status Report
  • 2019 Research-status Report
  • 2018 Research-status Report
  • 2017 Research-status Report
  • Research Products

    (8 results)

All 2022 2021 2020 2019 2018

All Presentation (8 results) (of which Int'l Joint Research: 2 results)

  • [Presentation] MOVPE成長Al ドープ ZnTe薄膜特性に及ぼすポストアニーリング処理温度の影響 (2)2022

    • Author(s)
      平田 翔大, 齊藤 勝彦, 田中 徹, 郭 其新
    • Organizer
      2022年応用物理学会九州支部学術講演会
    • Related Report
      2022 Annual Research Report
  • [Presentation] MOVPE成長AlドープZnTe薄膜特性に及ぼすポストアニーリング処理温度の影響2021

    • Author(s)
      澤田航哉,斉藤勝彦,田中徹,郭其新
    • Organizer
      2021年度応用物理学会九州支部学術講演会
    • Related Report
      2021 Research-status Report
  • [Presentation] GGG基板上ZnTe薄膜のMOVPE成長と評価2021

    • Author(s)
      澤田航哉, 斉藤勝彦, 田中 徹, 郭 其新
    • Organizer
      2021年度電気・情報関係学会九州支部連合大会
    • Related Report
      2021 Research-status Report
  • [Presentation] MOVPE成長Al ドープZnTe薄膜特性に及ぼす基板温度とポストアニールの効果2020

    • Author(s)
      澤田航哉,斉藤勝彦,田中徹,郭其新
    • Organizer
      2020年度応用物理学会九州支部学術講演会
    • Related Report
      2020 Research-status Report
  • [Presentation] Al,P共添加ZnTe薄膜のMOVPE成長と評価2019

    • Author(s)
      浜田樹, 斉藤勝彦, 田中徹, 郭其新
    • Organizer
      2019年度(第72回)電気・情報関係学会九州支部連合大会
    • Related Report
      2019 Research-status Report
  • [Presentation] P and Al co-doped ZnTe Epilayers Grown by MOVPE2019

    • Author(s)
      K. Saito, T. Hamada, Y. Hara, T. Tanaka, Q. Guo
    • Organizer
      The 19th International Conference on II-VI Compounds and Related Materials
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] 減圧MOVPE法による(100)GaAs基板上へのZnMgSeTe薄膜成長2018

    • Author(s)
      浜田 樹,平木 美穂,原 悠馬,斉藤 勝彦,田中 徹,郭 其新
    • Organizer
      平成30年度応用物理学会九州支部学術講演会
    • Related Report
      2018 Research-status Report
  • [Presentation] MOVPE growth of ZnMgSeTe alloys on (100) GaAs substrates2018

    • Author(s)
      Katsuhiko Saito,Yusei Matsuo, Akihiro Tomota, Tatsuki Hamada, Yuken Oishi, Tooru Tanaka,and Qixin Guo
    • Organizer
      19th International Conference on Metalorganic Vapor Phase Epitaxy
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research

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Published: 2017-04-28   Modified: 2024-01-30  

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