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What is the new technology "chemical doping and three-dimensional structure" that realizes high mobility characteristics in OFETs?

Research Project

Project/Area Number 17K06361
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Electronic materials/Electric materials
Research InstitutionNagaoka National College of Technology

Principal Investigator

MINAGAWA MASAHIRO  長岡工業高等専門学校, 電子制御工学科, 准教授 (20584684)

Co-Investigator(Kenkyū-buntansha) 新保 一成  新潟大学, 自然科学系, 教授 (80272855)
Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2019: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2018: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2017: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Keywords有機トランジスタ / 酸化銀電極 / ウェットプロセス / コンタクト抵抗の低減 / OFET / 銀電極 / コンタクト抵抗 / AgOx電極 / コンタクト抵抗低減 / OFET / 電子・電気材料
Outline of Final Research Achievements

In this study, we attempted to develop an OFET that can observe a large output current by realizing a transistor with chemical doping and having a three-dimensional step structure. However, it was more difficult than expected to stably fabricate OFETs on a substrate with a step structure, therefore, we developed a bottom contact OFET in which silver oxide layer was inserted on the S-D electrode surfaces.
As a result, it has been clarified that good transfer characteristics can be obtained even with a wide-gap organic semiconductor layer that was previously inoperable.
Furthermore, it has been found that the transfer characteristics can be significantly improved and the contact resistance can be dramatically reduced by inserting silver oxide layer even in the bottom contact type OFET in which the electrode are prepared by the solution process.

Academic Significance and Societal Importance of the Research Achievements

この本研究成果によれば,両キャリア輸送性を持つワイドギャップ有機半導体材料が一種類あれば,電極表面の処理方法を変えることによりホールまたは電子を選択的に注入できるようになるため,pチャネル形またはnチャネル形OFETを作製することが可能となる。これは,1種類の有機半導体でC-MOSインバータを実現できることを示し,フレキシブルLSIの実現を大きく後押しする。その結果,シート状フレキシブル圧力センサの大面積化が可能となり,例えば義手や義足への触覚機能の実装など国民のクオリティ・オブ・ライフの向上に大きく貢献できる。

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Research-status Report
  • 2017 Research-status Report
  • Research Products

    (19 results)

All 2020 2019 2018 2017 Other

All Int'l Joint Research (5 results) Journal Article (6 results) (of which Int'l Joint Research: 5 results,  Peer Reviewed: 6 results,  Open Access: 4 results) Presentation (8 results) (of which Int'l Joint Research: 4 results)

  • [Int'l Joint Research] Center for Advancing Electronics Dresden/Technische Universitat Dresden(ドイツ)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] Department of Chemical Engineering/Stanford University,(米国)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] ドレスデン工科大学(ドイツ)

    • Related Report
      2018 Research-status Report
  • [Int'l Joint Research] Stanford University/Department of Chemical Engineering(米国)

    • Related Report
      2017 Research-status Report
  • [Int'l Joint Research] Technische Universität Dresden/Center for Advanced Electronics Dresden(Germany)

    • Related Report
      2017 Research-status Report
  • [Journal Article] Understanding the metal-oxides induced reduction of the contact resistance in organic transistors2020

    • Author(s)
      Donnha Shabnam、Minagawa Masahiro、Blawid Stefan、Claus Martin
    • Journal Title

      Solid-State Electronics

      Volume: 163 Pages: 107676-107676

    • DOI

      10.1016/j.sse.2019.107676

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Characteristics of 9,10-diphenylanthracene field-effect transistors obtained by exposing the silver electrodes to oxidative conditions2019

    • Author(s)
      Minagawa Masahiro、Sone Shinnosuke、Kobayashi Kanta、Claus Martin、Shinbo Kazunari
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 58 Issue: SB Pages: SBBG10-SBBG10

    • DOI

      10.7567/1347-4065/aafd8c

    • NAID

      210000135379

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Improvement of organic field-effect transistor characteristics via oxidation treatment of Ag nano-ink electrode surfaces2019

    • Author(s)
      Minagawa Masahiro、Kobayashi Kanta、Sone Shinnosuke、Shinbo Kazunari
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 59 Issue: SC Pages: SCCA03-SCCA03

    • DOI

      10.7567/1347-4065/ab48cb

    • NAID

      210000157212

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Characteristics of 9,10-diphenylanthracene field-effect transistors obtained by exposing the silver electrodes to oxidative conditions2019

    • Author(s)
      M. Minagawa, S. Sone, K. Kobayashi, M. Claus and K. Shinbo,
    • Journal Title

      Jpn. J. Appl. Phys

      Volume: 58

    • NAID

      210000135379

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Experimental analysis of dark frame growth mechanism in organic light-emitting diodes2018

    • Author(s)
      Minagawa Masahiro、Tanabe Takuma、Kondo Eiki、Kamimura Kenji、Kimura Munehiro
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 57 Issue: 2S2 Pages: 02CA10-02CA10

    • DOI

      10.7567/jjap.57.02ca10

    • NAID

      210000148647

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Reducing the contact resistance in bottom-contact-type organic field-effect transitors using an AgO x interface layer2017

    • Author(s)
      Minagawa Masahiro、Kim Yeongin、Claus Martin、Bao Zhenan
    • Journal Title

      Applied Physics Express

      Volume: 10 Issue: 9 Pages: 091601-091601

    • DOI

      10.7567/apex.10.091601

    • NAID

      210000135959

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] Improvement of OFET characteristics due to oxidation treatment of silver nano-ink electrode surfaces2019

    • Author(s)
      Kanta Kobayashi, Shinnosuke Sone, Kazunari Shinbo, Masahiro Minagawa
    • Organizer
      The 7th International Symposium on Organic and Inorganic Electronic Materials and Related Nanotechnologies
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ウェットプロセスで作製したOFET における 銀ナノインク電極表面酸化処理の効果2019

    • Author(s)
      曽根 森之介,小林 幹太 ,皆川 正寛,新保 一成
    • Organizer
      第80回応用物理学会秋季学術講演会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 酸化処理した銀電極を持つOFETの作製と評価2019

    • Author(s)
      酒井 龍一,曽根 森之介,小林 幹太,皆川 正寛
    • Organizer
      第29回電気学会東京支部新潟支所研究発表会
    • Related Report
      2019 Annual Research Report
  • [Presentation] mprovement of characteristics in 9,10-diphenylanthracene field-effect transistors due to using oxidized silver electrodes2018

    • Author(s)
      S. Sone, K. Kobayashi, M. Minagawa
    • Organizer
      International Conference on Organic Materials for Electronics and Photonics
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Characteristics of 9,10-Diphenylanthracene Field-Effect Transistors Obtained by Using Oxidization-Treated Silver Electrodes2018

    • Author(s)
      S. Sone, K. Kobayashi, M. Minagawa
    • Organizer
      Characteristics of 9,10-Diphenylanthracene Field-Effect Transistors Obtained by Using Oxidization-Treated Silver Electrodes”, International Conference on Solid State Devices and Materials
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] 銀ナノインク電極の表面酸化処理によるOFETの特性改善2018

    • Author(s)
      小林 幹太,曽根 森之介,皆川 正寛,新保 一成
    • Organizer
      第79回応用物理学会秋季学術講演会
    • Related Report
      2018 Research-status Report
  • [Presentation] Experimental Analysis of Pixel-Shrinkage in Organic Light-Emitting Diodes2017

    • Author(s)
      T. Tanabe, E. Kondo, M. Kimura, M. Minagawa
    • Organizer
      The 6th International Symposium on Organic and Inorganic Electronic Materials and Related Nanotechnologies (EM-NANO 2017)
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] 小林 幹太, 曽根 森之介, 皆川 正寛,Zhenan Bao2017

    • Author(s)
      酸化銀キャリア注入層を持つOFETの作製と評価
    • Organizer
      第78回応用物理学会秋季学術講演会
    • Related Report
      2017 Research-status Report

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Published: 2017-04-28   Modified: 2022-02-21  

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