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Study on functional materials and ways of their functional enhancement from viewpoint of sub-nanosheet magnets

Research Project

Project/Area Number 17K06788
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Inorganic materials/Physical properties
Research InstitutionKyoto University (2019)
Tokyo University of Agriculture and Technology (2017-2018)

Principal Investigator

Ohta Hiroto  京都大学, 工学研究科, 講師 (60546985)

Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2019: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2018: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2017: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywords層状化合物 / 遍歴強磁性 / サブナノシート磁石 / 磁性材料 / 遍歴電子強磁性 / 遍歴電子磁性 / 固相反応法 / 溶液反応法 / 金属物性 / 強相関電子系 / 強相関エレクトロニクス / 磁性
Outline of Final Research Achievements

In this project, I have focused on the magnetic layers with a thickness as large as a few atoms in the layered itinerant magnets, and for this "sub-nano sheet magnet" I have investigated its common nature and physical properties caused by interaction between this sheet and intermediate layer blocks. As results, in a layered antiferromagnetic compound EuCo2P2, partial Ni-substitution for Co is found to induce ferromagnetic ordering instead of the antiferromagnetic one, and also in this ferromagnetic phase new antiferromagnetic ordering was found, which is similar antiferromagnetic phase seen in LnCoPnO. Thus, Ni-substituted EuCo2P2 is locating near the three phase boundaries of Eu valences, tetragonal structural, and magnetic phases, so this system can be controlled by several factors such as magnetic filed and pressure. Also, this system is expected to show novel phases because of such triple degrees of freedom.

Academic Significance and Societal Importance of the Research Achievements

本研究では層状遍歴電子磁性体における厚さが数原子分の磁性層に着目し、その性質やこの磁石層に関係した物質の機能の付加と既存の機能性物質に対する機能向上を目標として実施した。これは、これまで個別論として実施されてきた層状化合物の研究を統一的・系統的にまとめる意義があり、この方向で今後も研究分野として発展していくと期待できる。また、機能性材料の探索の指針につながる研究であり、実用的な観点から社会的な意義があると考えている。

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Research-status Report
  • 2017 Research-status Report
  • Research Products

    (14 results)

All 2020 2019 2018 2017 Other

All Journal Article (5 results) (of which Peer Reviewed: 5 results) Presentation (8 results) (of which Int'l Joint Research: 1 results) Remarks (1 results)

  • [Journal Article] Study on Magnetism and Electronic Structure of New Layered Compound Sr3Sc2O5Co2As2 with Body-Centered Crystal Structure2019

    • Author(s)
      Hiroto Ohta, Atsushi Suzuki, Hiroko Aruga Katori
    • Journal Title

      Journal of the Physical Society of Japan

      Volume: 88 Issue: 5 Pages: 054714-054714

    • DOI

      10.7566/jpsj.88.054714

    • NAID

      40021885932

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Magnetic Study on Y2M3Co9P7 (M: Transition Metals) with Cation-Ordered Zr2Fe12P7-Type Structure2019

    • Author(s)
      Yusuke Kato, Hiroto Ohta, Hiroko Aruga Katori
    • Journal Title

      Solid State Phenomena

      Volume: 289 Pages: 164-169

    • DOI

      10.4028/www.scientific.net/ssp.289.164

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Study of Magnetism and Electronic Structures of Compounds with CoAs Layers2018

    • Author(s)
      Hiroto OHTA, Atsushi SUZUKI, Daisuke NOGUCHI, Atsushi ODA, Takuya IINUMA and Hiroko ARUGA KATORI
    • Journal Title

      J. Jpn. Soc. Powder Powder Metallurgy

      Volume: 65 Pages: 261-264

    • NAID

      130007383431

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Magnetism and Electronic States of X2Co12P7 (X = Ti, Zr and Hf)2018

    • Author(s)
      Yusuke KATO, Hiroto OHTA and Hiroko ARUGA KATORI
    • Journal Title

      J. Jpn. Soc. Powder Powder Metallurgy

      Volume: 65 Pages: 274-278

    • NAID

      130007383435

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Disappearance of the Itinerant Electronic Ferromagnetism in Layered Compound Sr2VO3CoAs due to Self-Electron-Doping Effect2018

    • Author(s)
      Hiroto Ohta, Daisuke Noguchi, and Hiroko Aruga Katori
    • Journal Title

      Journal of the Physical Society of Japan

      Volume: 87 Issue: 9 Pages: 094711-094711

    • DOI

      10.7566/jpsj.87.094711

    • NAID

      210000134962

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Presentation] サイト秩序型Zr2Fe12P7型化合物Y2Tmpy3Tmtet9P7 (Tmpy, Tmtet: 遷移金属) の合成と磁性2020

    • Author(s)
      太田寛人、須賀隆裕、加藤優典、和氣剛、田畑吉計、香取浩子、中村裕之
    • Organizer
      日本物理学会 第75回年次大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Eu(Co1-xNix)2P2のucT及びcT構造における磁性2020

    • Author(s)
      中村頼人、太田寛人、原口祐哉、香取浩子、中村仁
    • Organizer
      日本物理学会 第75回年次大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 遍歴電子強磁性体X2Co12P7 (X-Zr, Hf) のFe置換効果と磁性の研究2019

    • Author(s)
      太田寛人、中村真一、加藤優典、原口祐哉、香取浩子、勝藤拓郎
    • Organizer
      日本物理学会 2019年秋季大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 遍歴電子強磁性体Y2Co12P7の電子状態と磁性の研究2019

    • Author(s)
      太田寛人、加藤優典、原口祐哉、香取浩子
    • Organizer
      日本物理学会 2019年秋季大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] EuCo2P2のNi置換による磁性の研究2019

    • Author(s)
      中村頼人、太田寛人、原口祐哉、香取浩子、中村仁
    • Organizer
      日本物理学会 2019年秋季大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 遍歴電子強磁性体 Y2(FexCo1-x)12P7 の 57Fe メスバウアー分光による磁気秩序状態の研究2019

    • Author(s)
      太田寛人、中村真一、加藤優典、香取浩子、勝藤拓郎
    • Organizer
      日本物理学会 第74回年次大会
    • Related Report
      2018 Research-status Report
  • [Presentation] 遍歴電子強磁性体 Y2(Fe,Co)12P7 のメスバウアー分光による構造と磁性の研究2018

    • Author(s)
      太田寛人、中村真一、加藤優典、香取浩子、勝藤拓郎
    • Organizer
      日本物理学会 2018年秋季大会
    • Related Report
      2018 Research-status Report
  • [Presentation] Study of magnetism and electronic structures of compounds with CoAs layers2017

    • Author(s)
      Hiroto Ohta, Atsushi Suzuki, Daisuke Noguchi, Atsushi Oda, Takuya Iinuma, Hiroko Aruga Katori
    • Organizer
      International Conference on Powder and Powder Metallurgy ~60th Annibersary~
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Remarks] 研究成果

    • URL

      http://web.tuat.ac.jp/~katori/researchoutcome.html

    • Related Report
      2018 Research-status Report 2017 Research-status Report

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Published: 2017-04-28   Modified: 2021-02-19  

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