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Development of Mesoporous Single-Crystalline Oxide Electrodes with High Electroconductivity and Durability

Research Project

Project/Area Number 17K06803
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Inorganic materials/Physical properties
Research InstitutionYokohama National University

Principal Investigator

Kuroda Yoshiyuki  横浜国立大学, 大学院工学研究院, 准教授 (50638640)

Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2019: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2018: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2017: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Keywords多孔質材料 / ナノシート / 導電性酸化物 / 固体高分子形燃料電池 / アルカリ水電解 / 多孔体 / 電極触媒 / 酸素還元 / 酸素発生 / メソ多孔体 / 電極材料 / 鋳型合成法
Outline of Final Research Achievements

Hydrogen has attracted much attention for the efficient use of renewable energy without emission of CO2. Water electrolysis converting electricity to hydrogen and polymer electrolyte fuel cell converting hydrogen to electricity have problems about durability of electrodes which degrade by corrosion, dissolution, and/or delamination due to frequent power fluctuation and/or start/stop operation. In this research, novel materials, such as porous conductive metal oxides and hybrid nanosheets were developed as highly durable electrode materials. These new technologies will contribute to cost reduction of hydrogen energy in our society.

Academic Significance and Societal Importance of the Research Achievements

地球温暖化の進行を食い止めるためには、CO2を排出しないクリーンな再生可能エネルギーの利用が必須である。再生可能エネルギー(太陽光、風力、水力、地熱など)は発電時間や発電場所が限られており、水素等の貯蔵、輸送に敵した形で取り扱う必要がある。本研究の成果は、水素利用、水素製造の装置の高寿命化に貢献する技術であり、将来社会において水素エネルギーを利用する際のコスト低減に寄与すると期待される。

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Research-status Report
  • 2017 Research-status Report
  • Research Products

    (30 results)

All 2020 2019 2018 2017 Other

All Int'l Joint Research (2 results) Journal Article (4 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 4 results) Presentation (22 results) (of which Int'l Joint Research: 9 results,  Invited: 5 results) Patent(Industrial Property Rights) (2 results) (of which Overseas: 1 results)

  • [Int'l Joint Research] Universite de Poitiers(フランス)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] クイーンズ大学(カナダ)

    • Related Report
      2018 Research-status Report
  • [Journal Article] Selective Covalent Modification of Layered Double Hydroxide Nanoparticles with Tripodal Ligands on Outer and Interlayer Surfaces2020

    • Author(s)
      Muramatsu Keisuke、Hayashi Shiori、Kuroda Yoshiyuki、Oka Yuya、Wada Hiroaki、Shimojima Atsushi、Kuroda Kazuyuki
    • Journal Title

      Inorganic Chemistry

      Volume: 59 Issue: 9 Pages: 6110-6119

    • DOI

      10.1021/acs.inorgchem.0c00192

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Templated Synthesis of Carbon-Free Mesoporous Magnéli-Phase Titanium Suboxide2019

    • Author(s)
      Yoshiyuki Kuroda, Hikaru Igarashi, Takaaki Nagai, Teko W. Napporn, Koichi Matsuzawa, Shigenori Mitsushima, Ken-ichiro Ota, Akimitsu Ishihara
    • Journal Title

      Electrocatalysis

      Volume: 10 Issue: 5 Pages: 459-465

    • DOI

      10.1007/s12678-019-00544-3

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Self-repairing hybrid nanosheet anode catalysts for alkaline water electrolysis connected with fluctuating renewable energy2019

    • Author(s)
      Kuroda Yoshiyuki、Nishimoto Takeshi、Mitsushima Shigenori
    • Journal Title

      Electrochimica Acta

      Volume: 323 Pages: 134812-134812

    • DOI

      10.1016/j.electacta.2019.134812

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] In situ synthesis of magnesium hydroxides modified with tripodal ligands in an organic medium2018

    • Author(s)
      Keisuke Muramatsu, Yoshiyuki Kuroda, Hiroaki Wada, Atsushi Shimojima, Kazuyuki Kuroda
    • Journal Title

      Dalton Transactions

      Volume: 47 Issue: 9 Pages: 3074-3083

    • DOI

      10.1039/c7dt03699j

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Presentation] アルカリ水電解用自己修復アノード触媒の構造2019

    • Author(s)
      黒田義之, 西本武史, 光島重徳
    • Organizer
      2019年電気化学会秋季大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Development of Highly Stable Oxide-Based Electrocatalysts for Polymer Electrolyte Fuel Cells and Water Electrolyzers Toward Applications of Green Hydrogen2019

    • Author(s)
      Yoshiyuki Kuroda, Takaaki Nagai, Koichi Matsuzawa, Shigenori Mitsushima, Ken-ichiro Ota, Akimitsu Ishihara
    • Organizer
      IUMRS-ICA2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Self-repairing catalyst for highly durable anode catalysts of alkaline water electrolysis2019

    • Author(s)
      Yoshiyuki Kuroda, Takeshi Nishimoto, Shigenori Mitsushima
    • Organizer
      ECS Canadian Section 2019 Fall Symposium
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] ハイブリッドナノシート触媒を用いたアルカリ水電解の運転条件の検討2019

    • Author(s)
      西本武史, 黒田義之, 光島重徳
    • Organizer
      電気化学会第86回大会
    • Related Report
      2018 Research-status Report
  • [Presentation] PEFC用カソード担体としてのマクロポーラスNb-Ti4O7の合成と電気化学的評価2019

    • Author(s)
      梶間博隆, 黒田義之, 松澤幸一, 石原顕光, 光島重徳
    • Organizer
      電気化学会第86回大会
    • Related Report
      2018 Research-status Report
  • [Presentation] 酸性電解質中でのチタン酸ナノシートの酸素還元触媒能2019

    • Author(s)
      中島督晴, 石原顕光, 光島重徳, 黒田義之
    • Organizer
      電気化学会第86回大会
    • Related Report
      2018 Research-status Report
  • [Presentation] テンプレート法による導電性チタニアナノ構造体の合成2018

    • Author(s)
      梶間博隆, 黒田義之, 松澤幸一, 石原顕光, 光島重徳
    • Organizer
      第28回電極材料研究会
    • Related Report
      2018 Research-status Report
  • [Presentation] Preparation of Highly Durable Electrocatalyst for Alkaline Water Electrolysis via Self-Assembly of Hybrid Cobalt Hydroxide Nanosheets2018

    • Author(s)
      Yoshiyuki Kuroda, Shigenori Mitsushima
    • Organizer
      International Symposium on Electrocatalysis
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] ハイブリッド水酸化コバルトナノシートを用いたアルカリ水電解用自己組織化触媒2018

    • Author(s)
      黒田義之, 光島重徳
    • Organizer
      第62回粘土科学討論会
    • Related Report
      2018 Research-status Report
  • [Presentation] Self-Assembled Anode Catalysts with Excellent Durability for Alkaline Water Electrolysis Using Novel Hybrid Cobalt Hydroxide Nanosheets2018

    • Author(s)
      Yoshiyuki Kuroda Shigenori Mitsushima
    • Organizer
      AiMES2018
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] 水酸化コバルトナノシートを用いた自己組織化OER触媒の検討2018

    • Author(s)
      西本武史, 黒田義之, 光島重徳
    • Organizer
      第42回電解技術討論会
    • Related Report
      2018 Research-status Report
  • [Presentation] Self-Assembling Electrocatalyst for Alkaline Water Electrolysis2018

    • Author(s)
      Yoshiyuki Kuroda, Takeshi Nishimoto, Shigenori Mitsushima
    • Organizer
      2nd International Workshop on Phase Interfaces for Highly Efficient Energy Utilization -For dramatic advancement of energy utilization efficiency-
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Synthetic Chemistry of Metal Hydroxides and Their Applications2018

    • Author(s)
      Yoshiyuki Kuroda
    • Organizer
      Fourth Joint Workshop on Electrocatalysis, Materials Science and Analytical Chemistry of Nickel-Based Materials
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] 層状複水酸化物の自己組織化による固体塩基触媒のナノ構造制御 ~層状金属水酸化物の構造 機能制御法の開拓~2018

    • Author(s)
      黒田義之
    • Organizer
      2018年度フロンティア材料研究所学術賞受賞記念講演会・若手教員講演会
    • Related Report
      2018 Research-status Report
    • Invited
  • [Presentation] Formation of turbostratic brucite and its nanosheets by reversible modification with dipodal ligands2017

    • Author(s)
      Keisuke Muramatsu, Yoshiyuki Kuroda, Atsushi Shimojima, Hiroaki Wada, Kazuyuki Kuroda
    • Organizer
      The 16th International Clay Conference
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Direct synthesis of colloidal interlayer-modified layered double hydroxides using tripodal ligands2017

    • Author(s)
      Yoshiyuki Kuroda, Shiori Hayashi, Yuya Oka, Atsushi Shimojima, Hiroaki Wada, Kazuyuki Kuroda
    • Organizer
      The 16th International Clay Conference
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Design of Silica Superstructures by Assembly of Silica Nanospheres2017

    • Author(s)
      Yoshiyuki Kuroda, Hiroaki Wada, Atsushi Shimojima, Kazuyuki Kuroda
    • Organizer
      IUMRS-ICAM2017
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] 層状複水酸化物の溶解再析出及び再構築過程における三脚型配位子の効果2017

    • Author(s)
      黒田義之, 岡佑弥, 安田忠央, 小市竜之, 和田宏明, 下嶋敦, 黒田一幸
    • Organizer
      第61回粘土科学討論会
    • Related Report
      2017 Research-status Report
  • [Presentation] 遷移金属含有層状複水酸化物の三脚型配位子による層間修飾2017

    • Author(s)
      林志桜里, 岡佑弥, 黒田義之, 和田宏明, 下嶋敦, 黒田一幸
    • Organizer
      第61回粘土科学討論会
    • Related Report
      2017 Research-status Report
  • [Presentation] 二脚型配位子の修飾・脱離による剥離可能なブルーサイトの合成2017

    • Author(s)
      村松佳祐, 黒田義之, 和田宏明, 下嶋敦, 黒田一幸
    • Organizer
      第61回粘土科学討論会
    • Related Report
      2017 Research-status Report
  • [Presentation] PEFC用導電性酸化物担体に向けたメソポーラスNbドープTiO2の合成2017

    • Author(s)
      黒田義之, 島崎佑太, 北原真樹, 梶間博敬, 松澤幸一, 石原顕光, 和田宏明, 下嶋敦, 黒田一幸, 光島重徳
    • Organizer
      2017年電気化学秋季大会
    • Related Report
      2017 Research-status Report
  • [Presentation] 三脚型配位子による層状腹水酸化物の層間修飾2017

    • Author(s)
      林志桜里, 岡佑弥, 黒田義之, 下嶋敦, 和田宏明, 黒田一幸
    • Organizer
      第7回CSJ化学フェスタ
    • Related Report
      2017 Research-status Report
  • [Patent(Industrial Property Rights)] アルカリ水電解アノード2019

    • Inventor(s)
      黒田義之, 光島重徳, 西本武
    • Industrial Property Rights Holder
      横浜国立大学, デノラ・ペルメレック株式会社
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2019-045008
    • Filing Date
      2019
    • Related Report
      2019 Annual Research Report
  • [Patent(Industrial Property Rights)] アルカリ水電解アノード2019

    • Inventor(s)
      黒田義之, 光島重徳, 西本武史
    • Industrial Property Rights Holder
      横浜国立大学、デノラ・ペルメレック株式会社
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2019-045008
    • Filing Date
      2019
    • Related Report
      2018 Research-status Report
    • Overseas

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Published: 2017-04-28   Modified: 2021-02-19  

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