• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Basic studies on the gold-like color developing mechanism and the decorative applications of 3-methoxythiophene oligomers

Research Project

Project/Area Number 17K06815
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Composite materials/Surface and interface engineering
Research InstitutionChiba University

Principal Investigator

Hoshino Katsuyoshi  千葉大学, 大学院工学研究院, 教授 (50192737)

Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2019: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2018: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2017: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Keywords金属調光沢 / オリゴチオフェン / ラメラ結晶構造 / 塗布膜 / 電解重合膜 / 導電性ポリマー / 塗布膜・電解重合膜 / チオフェン / 重合体 / 金色調光沢 / スマート材料
Outline of Final Research Achievements

We previously found that the high-molecular weight oligomer of 3-methoxythiophene exhibited a gold-like luster. In this study, the effect of dopant and substituent on the optical and structural properties were firstly investigated in order to establish the basis of the gold-like color developing mechanism. The results showed that the film was colored red gold or blue gold dependent on the dopant type. The glossiness of film was also dependent on the type of dopant. The change in the substituent led to a change in the lamellar interlayer distance in the lamellar crystallites formed in the film, causing the change in the chromaticity and glossiness of the film. Secondly, the blend films of the oligomer and polyester were successfully prepared without losing the gold-like luster.

Academic Significance and Societal Importance of the Research Achievements

日常空間では、金、銀および銅色の加飾がなされている物品が多く存在する。しかしこうした塗料・インクには金属微粉末が含有されており、種々の実使用上の問題を内蔵している。これまで、金属を用いずにメダル色を実現しようといくつかの興味深い有機物質が創生されてきた。研究代表者のグループも金色あるいは銅色調高分子物質を創生し検討を行ってきた。本研究では、その高分子材料に関する様々な分析を通して、金色調光沢発現のメカニズムの検討を行い、その解明に迫ることができた。さらには、社会実装を見据えた検討により、応用に関する基盤を確立することができた。

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Research-status Report
  • 2017 Research-status Report
  • Research Products

    (33 results)

All 2020 2019 2018 2017 Other

All Journal Article (4 results) (of which Peer Reviewed: 4 results,  Open Access: 2 results) Presentation (22 results) (of which Int'l Joint Research: 5 results,  Invited: 2 results) Book (1 results) Remarks (3 results) Patent(Industrial Property Rights) (3 results)

  • [Journal Article] Effects of Dopant Type on Lustrous Film Properties of Oligo(3-methoxythiophene)2020

    • Author(s)
      土井浩敬、久保美菜子、塚田 学、星野勝義
    • Journal Title

      NIHON GAZO GAKKAISHI (Journal of the Imaging Society of Japan)

      Volume: 59 Issue: 1 Pages: 34-39

    • DOI

      10.11370/isj.59.34

    • NAID

      130007796120

    • ISSN
      1344-4425, 1880-4675
    • Year and Date
      2020-02-10
    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Effect of π-π interaction-induced secondary doping on the gold-like luster of oligo(3-methoxythiophene) cast films2019

    • Author(s)
      Yumi Takashina, Katsuyoshi Hoshino
    • Journal Title

      Polymer Journal

      Volume: 印刷中 Issue: 6 Pages: 1-9

    • DOI

      10.1038/s41428-019-0172-9

    • NAID

      40021935917

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Chemical Events in Oligo(3-methoxythiophene) Coating Solutions and Their Effect on the Goldlike Coating Film Properties2018

    • Author(s)
      Yumi Takashina, Terumasa Mitogawa, Kota Saito, Katsuyoshi Hoshino
    • Journal Title

      Langmuir

      Volume: 34 Issue: 9 Pages: 3049-3057

    • DOI

      10.1021/acs.langmuir.7b04182

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Effect of Supporting Electrolyte on the Color/Gloss Characteristics of Electropolymerized Oligo(3-methoxythiophene) Films with Gold-like Luster2018

    • Author(s)
      Dan Takamura, Katsuyoshi Hoshino
    • Journal Title

      Chemistry Letters

      Volume: 47 Issue: 4 Pages: 540-543

    • DOI

      10.1246/cl.180022

    • NAID

      130006638889

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Open Access
  • [Presentation] Effect of Polymerization Condition on the Color of Solution-Cast Metal-Like Lustrous Films of Water-Soluble 3-Methoxythiophene Oligomers2019

    • Author(s)
      Minako Tachiki, Katsuyoshi Hoshino
    • Organizer
      International Conference on Advance Imaging 2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Development of Metal-Like luster by Rubbing 3-Methoxythiophene Oligomer Powder2019

    • Author(s)
      Satoya Sugiura, Rihito Tamura, Kenta Horikoshi, Katsuyoshi Hoshino
    • Organizer
      International Conference on Advance Imaging 2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 金属調光沢膜物性に及ぼすドーパント種の影響2019

    • Author(s)
      土井 浩敬, 星野 勝義
    • Organizer
      第123回日本画像学会年次大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 金属フリー金属調光沢ポリマーブレンド塗料・塗膜 の作製と物性2019

    • Author(s)
      田村 理人、宮本 克真、塚田 学、星野 勝義
    • Organizer
      電気化学会 2019年電気化学秋季大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 金属調光沢を発現する水溶性3-メトキシチオフェン重合体塗布膜の作製とその物性2019

    • Author(s)
      立木 美奈子、田川 麗央、星野 勝義
    • Organizer
      第68回高分子討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 金属を含まない金属調光沢ポリマーブレンドの作製と物性2019

    • Author(s)
      田村 理人、宮本 克真、塚田 学、星野 勝義
    • Organizer
      第68回高分子討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 3-メトキシチオフェン重合体の金色調光沢膜物性に及ぼす重合温度の影響2019

    • Author(s)
      佐野 凌平、塚田 学、星野 勝義
    • Organizer
      画像関連学会連合会 第6回秋季大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 3-メトキシチオフェン重合体と汎用ポリマーからなる金色調光沢ブレンド塗布膜の作製と物性2019

    • Author(s)
      田村 理人、塚田 学、星野 勝義
    • Organizer
      画像関連学会連合会 第6回秋季大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 金属光沢を有する有機薄膜の色調と構造に及ぼす重合条件の影響2018

    • Author(s)
      久保美菜子、堀越健太、星野勝義
    • Organizer
      第121回日本画像学会年次大会
    • Related Report
      2018 Research-status Report
  • [Presentation] 金属調光沢を発現する水溶性3-メトキシチオフェン重合体塗布膜の作成と物性2018

    • Author(s)
      立木美奈子、星野勝義
    • Organizer
      第121回日本画像学会年次大会
    • Related Report
      2018 Research-status Report
  • [Presentation] 金属調光沢ポリマーアロイの作製と物性2018

    • Author(s)
      田村理人、宮本克真、星野勝義
    • Organizer
      第121回日本画像学会年次大会
    • Related Report
      2018 Research-status Report
  • [Presentation] 3-アルコキシチオフェンを用いた金属調光沢膜の作製と物性2018

    • Author(s)
      堀越健太、星野勝義
    • Organizer
      2018電気化学秋季大会
    • Related Report
      2018 Research-status Report
  • [Presentation] π-π相互作用により誘起される二次ドーピングがオリゴ(3-メトキシチオフェン) 塗布膜の金色調光沢に及ぼす影響2018

    • Author(s)
      高科祐美、星野勝義
    • Organizer
      第122回日本画像学会討論会
    • Related Report
      2018 Research-status Report
  • [Presentation] Structure and Association of All-Organic Gold Metallic Lustrous Films2018

    • Author(s)
      Minako Kubo, Katsuyoshi Hoshino
    • Organizer
      The 4th Asia Color Association Conference
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Preparation and Physical Properties of Metal-Like Lustrous Polymer Alloy2018

    • Author(s)
      Rihito Tamura, Katsuyoshi Hoshino
    • Organizer
      1st International Symposium of Soft Molecular Activation Research Center
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Properties of Coating liquids and films Prepared Using Lustrous Gold-like Organic Colorants2018

    • Author(s)
      Yumi Takashina, Katsuyoshi Hoshino
    • Organizer
      1st International Symposium of Soft Molecular Activation Research Center
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] 金属を使わない金属調光沢発現重合体とその塗布膜・電解重合膜の創製2018

    • Author(s)
      星野勝義
    • Organizer
      2018年電気化学秋季大会
    • Related Report
      2018 Research-status Report
    • Invited
  • [Presentation] 金属を使わない金属調光沢発現重合体とその塗布膜・電解重合膜の創製2018

    • Author(s)
      星野勝義
    • Organizer
      技術情報協会主催セミナー
    • Related Report
      2018 Research-status Report
    • Invited
  • [Presentation] 3-アルコキシチオフェンを用いた金属調光沢膜の作製と物性2017

    • Author(s)
      堀越健太、福田和男、桝飛雄真、星野勝義
    • Organizer
      Imaging Conference JAPAN 2017
    • Related Report
      2017 Research-status Report
  • [Presentation] 有機金色調色材の塗布液と塗布膜の物性2017

    • Author(s)
      高科佑美、星野勝義
    • Organizer
      第6回 JACI/GSCシンポジウム
    • Related Report
      2017 Research-status Report
  • [Presentation] 金属調光沢膜の電解合成に及ぼす支持電解質の影響2017

    • Author(s)
      高村 檀、星野 勝義
    • Organizer
      2017年電気化学秋季大会
    • Related Report
      2017 Research-status Report
  • [Presentation] チオフェン重合体膜を用いた新規金属調光沢エレクトロクロミズム2017

    • Author(s)
      寺島佳生梨、星野勝義
    • Organizer
      Imaging Conference JAPAN 2017 Fall Meeting
    • Related Report
      2017 Research-status Report
  • [Book] 理系のためのベンチャービジネス実践論2019

    • Author(s)
      星野勝義(共著)
    • Total Pages
      139
    • Publisher
      丸善
    • ISBN
      9784621303788
    • Related Report
      2018 Research-status Report
  • [Remarks] 千葉大学工学研究院星野勝義研究室ホームページ

    • URL

      http://hoshino-nanoelectrochem.tp.chiba-u.jp/

    • Related Report
      2019 Annual Research Report 2018 Research-status Report 2017 Research-status Report
  • [Remarks] 特色ある研究活動の成果

    • URL

      http://www.chiba-u.ac.jp/research/coe_gp/result/engineering/result21.html

    • Related Report
      2019 Annual Research Report
  • [Remarks] 導電性ポリマーのイノベーション

    • URL

      http://www.chiba-u.ac.jp/research/coe_gp/files/hoshino.pdf

    • Related Report
      2019 Annual Research Report
  • [Patent(Industrial Property Rights)] 塗工液および金属光沢膜2020

    • Inventor(s)
      星野、立木
    • Industrial Property Rights Holder
      星野、立木
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2020-030788
    • Filing Date
      2020
    • Related Report
      2019 Annual Research Report
  • [Patent(Industrial Property Rights)] 黒色光沢塗料、黒色光沢塗膜及び黒色光沢塗料の製造方法2017

    • Inventor(s)
      星野勝義、宮本克真
    • Industrial Property Rights Holder
      星野勝義、宮本克真
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2017-162212
    • Filing Date
      2017
    • Related Report
      2017 Research-status Report
  • [Patent(Industrial Property Rights)] 金属調光沢エレクトロクロミック表示素子及びエレクトロクロミック表示素子の製造方法2017

    • Inventor(s)
      星野勝義、寺島佳生梨
    • Industrial Property Rights Holder
      星野勝義、寺島佳生梨
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2017-227531
    • Filing Date
      2017
    • Related Report
      2017 Research-status Report

URL: 

Published: 2017-04-28   Modified: 2021-02-19  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi