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Metaloxide films deposited by a nonequilibrium 2D plasma in a liquid phase and their application to ye-sensitized solar cell

Research Project

Project/Area Number 17K06817
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Composite materials/Surface and interface engineering
Research InstitutionShizuoka University

Principal Investigator

Okuya Masayuki  静岡大学, 工学部, 准教授 (00293605)

Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2019: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2018: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2017: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Keywords非平衡二次元プラズマ / 誘電体バリア放電 / 薄膜 / 色素増感太陽電池 / 沿面放電 / 液中プラズマ / 太陽電池モジュール
Outline of Final Research Achievements

A non-equilibrium two-dimensional plasma was induced in a small cavity between an insulating electrode and a glass substrate by introducing a gas in a liquid phase. A pre-sintered porous-TiO2/FTO double layered glass substrate was set below the electrode for discharge to face each other in the Titaniumtetraisopropoxide solution. The oxidization process was promoted with irradiating a plasma to the precursor spread on a glass substrate by a capillarity.
After the plasma treatment, the surface of the TiO2 layer was found to be porous with the particle size of 10 to 20 nm, which is almost comparable to a typical dye-sensitized solar cell. The conversion efficiency reached as high as 3.7 % for the cell prepared under N2/O2 mixture gas. We found that the active plasma species originated from N2 gas played an important role in the oxidation and crystallization in the film formation to enhance the necking process between TiO2 particles.

Academic Significance and Societal Importance of the Research Achievements

一般的なプラズマを利用した製膜では、基板に対し高エネルギープラズマへの耐抗性・耐熱性が要求され、汎用的な低融点基板への適用が難しい。さらに、マスキングやレジストといった追加処理が要求される。一方、液相からの化学的手法による低温製膜やパターニングにおいて、バルクの液相中では均一分散している修飾子であっても、溶媒を除去する過程で基板からの影響を強く受ける。
本研究では独自に開発した大気圧非平衡平面プラズマによる製膜技術を発展させ、液相中の微小空洞へのプラズマ閉じ込め効果を利用した新規製膜技術の確立、およびその応用を目的とする新たな研究である。

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Research-status Report
  • 2017 Research-status Report
  • Research Products

    (50 results)

All 2020 2019 2018 2017 Other

All Int'l Joint Research (4 results) Journal Article (8 results) (of which Int'l Joint Research: 8 results,  Peer Reviewed: 8 results) Presentation (34 results) (of which Int'l Joint Research: 6 results) Book (2 results) Remarks (2 results)

  • [Int'l Joint Research] ブダペスト経済工科大(ハンガリー)

    • Related Report
      2018 Research-status Report
  • [Int'l Joint Research] ペラデニア大(スリランカ)

    • Related Report
      2018 Research-status Report
  • [Int'l Joint Research] ブダペスト経済工科大(ハンガリー)

    • Related Report
      2017 Research-status Report
  • [Int'l Joint Research] ペラデニア大(スリランカ)

    • Related Report
      2017 Research-status Report
  • [Journal Article] Spray Angle Dependence for the Growth of Terrace-truncated Nanocone Structure of Gallium-doped Zinc Oxide by Advanced Spray Pyrolysis Deposition Technique2020

    • Author(s)
      Attanayake Sameera、Okuya Masayuki、Murakami Kenji
    • Journal Title

      International Journal of Technology

      Volume: 11 Issue: 1 Pages: 81-81

    • DOI

      10.14716/ijtech.v11i1.3068

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Complete coverage of perovskite materials over ZnO Nanorods with Multiwalled Carbon Nanotubes (MWCNTs) as Hole Transport Material (HTM)2020

    • Author(s)
      Bramantyo Albertus、Poespawati Nji Raden、Udhiarto Arief、Murakami Kenji、Okuya Masayuki
    • Journal Title

      IOP Conference Series: Materials Science and Engineering

      Volume: 715 Issue: 1 Pages: 012057-012057

    • DOI

      10.1088/1757-899x/715/1/012057

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Growth of Zinc Oxide Nanorods with the Thickness of Less than or Equal to 1?μm through Zinc Acetate or Zinc Nitrate for Perovskite Solar Cell Applications2019

    • Author(s)
      Bramantyo Albertus、Murakami Kenji、Okuya Masayuki、Udhiarto Arief、Poespawati Nji Raden
    • Journal Title

      Journal of Engineering

      Volume: 2019 Pages: 1-9

    • DOI

      10.1155/2019/2793853

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Synthesis and characterization of Al-doped ZnO terrace-truncated nanocone structure by the advanced spray pyrolysis deposition technique2019

    • Author(s)
      Attanayake Sameera、Okuya Masayuki、Murakami Kenji
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 58 Issue: 8 Pages: 080904-080904

    • DOI

      10.7567/1347-4065/ab2e8a

    • NAID

      120006708968

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Morphological and Structural Study of Vertically Aligned Zinc Oxide Nanorods Grown on Spin Coated Seed Layers2019

    • Author(s)
      Bramantyo Albertus、Murakami Kenji、Okuya Masayuki、Udhiarto Arief、Poespawati Nji Raden
    • Journal Title

      International Journal of Technology

      Volume: 10 Issue: 1 Pages: 147-147

    • DOI

      10.14716/ijtech.v10i1.2012

    • Related Report
      2019 Annual Research Report 2018 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] TiO2/TNO homojunction introduced in a dye-sensitized solar cell with a novel TNO transparent conductive oxide film2018

    • Author(s)
      Okuya Masayuki、Sato Jun、Endo Takeshi、Iwaki Ryo、Takemura Shuichiro、Muramoto Ryosuke、Nagygyorgy Viola、Madarasz Janos、Nakao Shoichiro、Yamada Naoomi、Sakai Enju、Hitosugi Taro、Hasegawa Tetsuya
    • Journal Title

      Journal of the American Ceramic Society

      Volume: 101 Issue: 11 Pages: 5071-5079

    • DOI

      10.1111/jace.15751

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] TiO2/TNO homojunction introduced in a dye-sensitized solar cell with a novel TNO transparent conductive oxide film2018

    • Author(s)
      Masayuki Okuya, Jun Sato, Takeshi Endo, Ryo Iwaki, Shuichiro Takemura, Ryosuke Muramoto, Viola Nagygyourgy, Janos Madarasz, Shoichiro Nakao, Naoomi Yamada, Enju Sakai, Taro Hitosugi,Tetsuya Hasegawa
    • Journal Title

      Journal of the American Ceramic Society

      Volume: 印刷中

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Structural characterizations of organic-based materials with extensive mechanoluminescence properties2017

    • Author(s)
      Ranasinghe R.A.D.M.、Tanaka Yasutaka、Okuya Masayuki、Shimomura Masaru、Murakami Kenji
    • Journal Title

      Journal of Luminescence

      Volume: 190 Pages: 413-423

    • DOI

      10.1016/j.jlumin.2017.05.073

    • NAID

      120006644919

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] マイクロ波加熱法によるITO透明導電膜の作製と色素増感太陽電池への応用2020

    • Author(s)
      内藤貫太、鈴木康介、奥谷昌之
    • Organizer
      第67回応用物理学会春季学術講演会
    • Related Report
      2019 Annual Research Report
  • [Presentation] ITO微粒子層の導入による高ヘイズFTO膜の作製と色素増感太陽電池への応用2020

    • Author(s)
      久保田祐紳、山下佑海、奥谷昌之
    • Organizer
      第67回応用物理学会春季学術講演会
    • Related Report
      2019 Annual Research Report
  • [Presentation] TiO2 thin films prepared with a non-equilibrium two-dimensional plasma induced under various atmospheres2019

    • Author(s)
      Shinji Mayumi、Minato Sawamura、Junpei Sagisaka、Ryosuke Okumura、Yuki Masuda、Masayuki Okuya
    • Organizer
      29th Annual Meeting of MRS-J
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Fabrication of porous-TiO2 layers with a non-equilibrium two-dimensional plasma and their application to dye sensitized solar cells2019

    • Author(s)
      Shinji Mayumi、Minato Sawamura、Junpei Sagisaka、Ryosuke Okumura、Yuki Masuda、Masayuki Okuya
    • Organizer
      29th Annual Meeting of MRS-J
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Porous-TiO2 layers prepared by a microwave heating technique and their application to dye-sensitized solar cells with a high-haze FTO film2019

    • Author(s)
      Kosuke Suzuki、Kanta Naito、Ayato Iketani、Masayuki Okuya
    • Organizer
      29th Annual Meeting of MRS-J
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] High-haze FTO transparent conductive oxide film with a SnO2 nano-particle layer for dye-sensitized solar cells2019

    • Author(s)
      Yumi Yamashita、Yoshinobu Kubota、Jun Sato、Masayuki Okuya
    • Organizer
      29th Annual Meeting of MRS-J
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 非平衡プラズマの活性種の検討による多孔質TiO2層の作製と色素増感太陽電池への応用2019

    • Author(s)
      眞弓慎司、澤村南斗、鷺坂潤平、奥村亮祐、奥谷昌之
    • Organizer
      2019年 第80回応用物理学会秋季学術講演会
    • Related Report
      2019 Annual Research Report
  • [Presentation] TiO2膜の作製における非平衡二次元プラズマの活性種の検討2019

    • Author(s)
      眞弓慎司、澤村南斗、鷺坂潤平、奥村亮祐、奥谷昌之
    • Organizer
      2019年 第80回応用物理学会秋季学術講演会
    • Related Report
      2019 Annual Research Report
  • [Presentation] マイクロ波加熱法により作製された色素増感太陽電池におけるFTO透明導電膜のヘイズ率の影響2019

    • Author(s)
      鈴木康介、内藤貫太、池谷綾斗、奥谷昌之
    • Organizer
      2019年 第80回応用物理学会秋季学術講演会
    • Related Report
      2019 Annual Research Report
  • [Presentation] SnO2微粒子層の粒径制御による高へイズFTO膜の作製と色素増感太陽電池の高効率化2019

    • Author(s)
      山下佑海、久保田祐紳、佐藤純、奥谷昌之
    • Organizer
      2019年 第80回応用物理学会秋季学術講演会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 非平衡二次元プラズマによる多孔質TiO2層の作製と色素増感太陽電池への応用2019

    • Author(s)
      眞弓慎司, 奥村亮祐, 鷺坂潤平, 奥谷昌之
    • Organizer
      日本セラミックス協会 第31回秋季シンポジウム
    • Related Report
      2018 Research-status Report
  • [Presentation] 積層型FTO膜の導入による色素増感太陽電池の高効率化2019

    • Author(s)
      山下佑海, 佐藤純, 采女敬史, 奥谷昌之
    • Organizer
      日本セラミックス協会 第31回秋季シンポジウム
    • Related Report
      2018 Research-status Report
  • [Presentation] マイクロ波加熱による多孔質TiO2層の粒成長制御と色素増感太陽電池への応用2019

    • Author(s)
      鈴木康介, 池谷綾斗, 奥谷昌之
    • Organizer
      日本セラミックス協会 第31回秋季シンポジウム
    • Related Report
      2018 Research-status Report
  • [Presentation] マイクロ波による急速加熱を利用した色素増感太陽電池の作製2018

    • Author(s)
      鈴木康介, 池谷綾斗, 奥谷昌之
    • Organizer
      第66回応用物理学会春季学術講演会
    • Related Report
      2018 Research-status Report
  • [Presentation] SnO2微粒子光散乱層導入によるFTO膜のヘイズ率制御と色素増感太陽電池の高効率化2018

    • Author(s)
      山下佑海, 佐藤純, 奥谷昌之
    • Organizer
      第66回応用物理学会春季学術講演会
    • Related Report
      2018 Research-status Report
  • [Presentation] 非平衡液中プラズマを利用した新規製膜装置の開発とTiO2膜の作製2018

    • Author(s)
      眞弓慎司, 鷺坂潤平, 奥村亮祐,奥谷昌之
    • Organizer
      第66回応用物理学会春季学術講演会
    • Related Report
      2018 Research-status Report
  • [Presentation] ハイブリッド加熱によるTiO2/FTO積層膜の作製と色素増感太陽電池への応用2018

    • Author(s)
      池谷綾斗,鈴木康介,青山貴裕,奥谷昌之
    • Organizer
      第12回日本電磁波エネルギー応用学会シンポジウム
    • Related Report
      2018 Research-status Report
  • [Presentation] 非平衡液中プラズマを利用したTiO2膜の作製2018

    • Author(s)
      鷺坂潤平,眞弓慎司,奥村亮祐,奥谷昌之
    • Organizer
      第49回 中部化学関係学協会支部連合秋季大会
    • Related Report
      2018 Research-status Report
  • [Presentation] 非平衡二次元プラズマを利用した多孔質TiO2層の作製と色素増感太陽電池への応用2018

    • Author(s)
      眞弓慎司, 鷺坂潤平, 奥村亮祐, 奥谷昌之
    • Organizer
      第49回 中部化学関係学協会支部連合秋季大会
    • Related Report
      2018 Research-status Report
  • [Presentation] マイクロ波照射下の誘電損失を利用した色素増感太陽電池の作製2018

    • Author(s)
      鈴木康介, 池谷綾斗, 奥谷昌之
    • Organizer
      第49回 中部化学関係学協会支部連合秋季大会
    • Related Report
      2018 Research-status Report
  • [Presentation] 高へイズFTO透明導電膜の作製と色素増感太陽電池の高効率化2018

    • Author(s)
      山下佑海, 佐藤純, 奥谷昌之
    • Organizer
      第49回 中部化学関係学協会支部連合秋季大会
    • Related Report
      2018 Research-status Report
  • [Presentation] Synthesis and Characterization of Ga Doped ZnO 1-D Nanostructures by Using Advanced Spray Pyrolysis Deposition Technique at Different Spraying Angles2018

    • Author(s)
      A.M.S.L.B. Attanayake, Masayuki Okuya and Kenji Murakami
    • Organizer
      The 79th JSAP Autumn Meeting 2018
    • Related Report
      2018 Research-status Report
  • [Presentation] 誘電体バリア放電を利用した多孔質TiO2層の作製と色素増感太陽電池への応用2018

    • Author(s)
      眞弓慎司, 奥村亮祐, 鷺坂潤平, 奥谷昌之
    • Organizer
      2018年 第79回応用物理学会秋季学術講演会
    • Related Report
      2018 Research-status Report
  • [Presentation] 積層型FTO膜におけるヘイズ率の制御と色素増感太陽電池への応用2017

    • Author(s)
      采女 敬史, 佐藤 純, 奥谷 昌之
    • Organizer
      第65回応用物理学会春季学術講演会
    • Related Report
      2017 Research-status Report
  • [Presentation] Formation and Characterization of Ga Doped ZnO 1-D Nanostructures by Using Advanced Spray Pyrolysis Deposition Technique2017

    • Author(s)
      Sameera Attanayake, Masayuki Okuya, Kenji Murakami
    • Organizer
      第65回応用物理学会春季学術講演会
    • Related Report
      2017 Research-status Report
  • [Presentation] Perovskite-type solar cell based on ZnO Nanorods Array: Current-Voltage (I-V) Characteristics2017

    • Author(s)
      Albertus Bramantyo, Masayuki Okuya, Kenji Murakami, Nji Raden Poespawati, Arief Udhiarto
    • Organizer
      第65回応用物理学会春季学術講演会
    • Related Report
      2017 Research-status Report
  • [Presentation] Optimization of a photovoltaic performance in a dye-sensitized solar cell (DSSC) by tuning a sheet resistance in FTO layer2017

    • Author(s)
      Jun Sato, Keishi Uneme, Takeshi Endo and Masayuki Okuya
    • Organizer
      27th Annual Meeting of MRS-J
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] TiO2 film prepared with a non-equilibrium plasma induced in in a liquid phase2017

    • Author(s)
      Ryosuke Okumura, Junpei Sagisaka, Yuki Masuda and Masayuki Okuya
    • Organizer
      27th Annual Meeting of MRS-J
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] 赤外・マイクロ波ハイブリッド加熱による色素増感太陽電池の作製2017

    • Author(s)
      池谷 綾斗 、青山貴裕、 ヴィオラナジャージ 、ヤーノシュマダラス、 奥谷昌之
    • Organizer
      第11回日本電磁波エネルギー応用学会シンポジウム
    • Related Report
      2017 Research-status Report
  • [Presentation] 界面抵抗制御による色素増感太陽電池の最適化2017

    • Author(s)
      佐藤 純, 遠藤 剛, 奥谷 昌之
    • Organizer
      日本セラミックス協会 第30回秋季シンポジウム
    • Related Report
      2017 Research-status Report
  • [Presentation] 非平衡液中プラズマを用いたTiO2膜の作製2017

    • Author(s)
      奥村 亮祐, 鷺坂 潤平, 堀水 懸登,増田 優貴, 奥谷 昌之
    • Organizer
      日本セラミックス協会 第30回秋季シンポジウム
    • Related Report
      2017 Research-status Report
  • [Presentation] 赤外・マイクロ波ハイブリッド加熱による多孔質TiO2層の焼成と色素増感太陽電池への応用2017

    • Author(s)
      池谷 綾斗, 青山 貴裕, Viola Nagygyörgy, János Madarász, 奥谷 昌之
    • Organizer
      第78回応用物理学会 秋季学術講演会
    • Related Report
      2017 Research-status Report
  • [Presentation] 液中非平衡プラズマを利用したTiO2膜の作製2017

    • Author(s)
      奥村 亮祐, 鷺坂 潤平, 増田 優貴, 奥谷 昌之
    • Organizer
      第78回応用物理学会 秋季学術講演会
    • Related Report
      2017 Research-status Report
  • [Presentation] Perovskite-type solar cell base on ZnO Nanorods Array: the effect of molar ratio of PbI2 to MAI on formation of Perovskite Layer2017

    • Author(s)
      Albertus Bramantyo, Kenji Murakami, Masayuki Okuya, Nji Raden Poespawati, Arief Udhiarto
    • Organizer
      第78回応用物理学会 秋季学術講演会
    • Related Report
      2017 Research-status Report
  • [Book] 次世代の太陽電池・太陽光発電 -その発電効率向上,用途と市場の可能性-2018

    • Author(s)
      豊島安健, 近藤道雄, 中田仗祐, 村田正義 , 小林光, 小林悠輝, 傍島靖, 富永姫香, 吉野賢二, 岡本保, 高本達也, 伊﨑昌伸, 都甲薫, 山口真史, 荒木秀明, 末益崇, 櫛屋勝巳, 大島隆治, 丸本一弘, 奥谷昌之, 他46名
    • Total Pages
      556
    • Publisher
      技術情報協会
    • ISBN
      9784861047077
    • Related Report
      2018 Research-status Report
  • [Book] 次世代の太陽電池・太陽光発電 -その発電効率向上 用途と市場の可能性-2018

    • Author(s)
      奥谷昌之(分担著)
    • Total Pages
      556
    • Publisher
      技術情報協会
    • ISBN
      9784861047077
    • Related Report
      2017 Research-status Report
  • [Remarks] 静岡大学奥谷研究室ホームページ

    • URL

      http://okuyalab.sakura.ne.jp/

    • Related Report
      2019 Annual Research Report
  • [Remarks] 静岡大学奥谷研究室

    • URL

      http://okuyalab.sakura.ne.jp/

    • Related Report
      2018 Research-status Report 2017 Research-status Report

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Published: 2017-04-28   Modified: 2021-02-19  

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