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High temperature strengthening design based on growth mechanism of grain boundary carbides in high-Cr ferritic heat-resistant steels

Research Project

Project/Area Number 17K06839
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Structural/Functional materials
Research InstitutionKyushu University

Principal Investigator

Mitsuhara Masatoshi  九州大学, 総合理工学研究院, 准教授 (10514218)

Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2019: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2018: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2017: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywords高Crフェライト系耐熱鋼 / クリープ変形 / 強化機構 / ラスマルテンサイト / 炭化物 / 結晶粒界 / 電子顕微鏡 / 結晶方位解析 / M23C6炭化物 / フェライト系耐熱鋼 / クリープ / 粒界上炭化物制御
Outline of Final Research Achievements

In order to development the controlling method of large-angle grain boundary carbides for high temperature strengthening in high-Cr ferritic heat-resistant steel, this study aimed to reveal the origin of the grain boundary character dependence on the formation and growth of the carbides. The growth behaviors of carbides under aging with/without loading were investigated, and it was clarified that the crystallographic relationship between the carbides and matrix phase (BCC-Fe) influenced on the growth behavior. In addition, we investigated the diffusion behavior of Cr, which is the main element of the carbides, and showed that the diffusion behavior on large-angle grain boundaries was not affected by segregation elements or grain boundary rotation angles.

Academic Significance and Societal Importance of the Research Achievements

次世代火力発電プラントの実用化検討が進められている最中にあって、耐熱鋼・耐熱合金への社会ニーズや研究開発意欲は高い水準で維持されており、それら耐熱材料の性能向上は大きな社会的意義を持つ。本研究課題は、高Crフェライト鋼のクリープ強度の根幹を支える組織因子でありながらその役割を曖昧にされてきた粒界上炭化物の本質を理解し制御する新たな試みの一環で進められたものであり、中でも、大角粒界上での炭化物成長メカニズムを明らかにしたことは学術的な意義と発展性において高い価値を持つと考えられる。

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Research-status Report
  • 2017 Research-status Report
  • Research Products

    (12 results)

All 2020 2019 2018

All Presentation (12 results) (of which Int'l Joint Research: 3 results,  Invited: 7 results)

  • [Presentation] Growth behavior of intergranular carbides in martensitic heat-resistant steel2020

    • Author(s)
      M. Mitsuhara, S. Yamasaki, R. Arakane, H. Nakashima, K. Nomura, K. Kubushiro
    • Organizer
      日本金属学会2020年春期(第167回)講演大会シンポジウム, International workshop of young researchers for steel metallurgy
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 高温変形の教科書的理解2019

    • Author(s)
      光原昌寿
    • Organizer
      日本鉄鋼協会秋季講演大会シンポジウム
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] フェライト系耐熱鋼の実用ひずみ速度域でのクリープ変形2019

    • Author(s)
      山﨑重人、光原昌寿、中島英治
    • Organizer
      日本鉄鋼協会秋季講演大会シンポジウム
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] Growth behavior of M23C6 carbides in high-Cr ferritic heat-resistant steels2019

    • Author(s)
      M. Mitsuhara, S. Yamasaki, R. Arakane, R. Takao, H. Nakashima
    • Organizer
      EPRI-123 HiMAT International Conference on Advances in High Temperature Materials
    • Related Report
      2019 Annual Research Report 2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Creep behavior of ferritic heat resistant steel added with nitrogen2019

    • Author(s)
      S. Yamasaki, M. Mitsuhara, H. Nakashima
    • Organizer
      EPRI-123 HiMAT International Conference on Advances in High Temperature Materials
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] マルテンサイト系耐熱鋼の高温強度に関する金相学的解釈2019

    • Author(s)
      光原昌寿
    • Organizer
      日本鉄鋼協会中国四国支部第134回金属物性研究会
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] 窒素含有フェライト系耐熱鋼の創製とその特性2018

    • Author(s)
      光原昌寿
    • Organizer
      平成30年度 日本金属学会・日本鉄鋼協会 九州支部 秋季講演会
    • Related Report
      2018 Research-status Report
    • Invited
  • [Presentation] BCC系耐熱鋼における高温強度と組織の考え方2018

    • Author(s)
      光原昌寿
    • Organizer
      日本金属学会「鉄鋼メタラジー研究グループ」第2回若手勉強会
    • Related Report
      2018 Research-status Report
    • Invited
  • [Presentation] 窒素添加新規フェライト系耐熱鋼の組織とクリープ特性2018

    • Author(s)
      光原昌寿、山﨑重人、中島英治
    • Organizer
      日本鉄鋼協会176回秋季講演大会 シンポジム「高温材料の高強度化」
    • Related Report
      2018 Research-status Report
    • Invited
  • [Presentation] 焼きならし処理のみを施したGr.91鋼における静的時効中のM23C6炭化物成長挙動2018

    • Author(s)
      荒金遼河、山﨑重人、光原昌寿、中島英治、澤田浩太、木村一弘
    • Organizer
      日本鉄鋼協会176回秋季講演大会
    • Related Report
      2018 Research-status Report
  • [Presentation] 高Crフェライト系耐熱鋼溶接熱影響部再現組織への前焼き戻し処理の影響2018

    • Author(s)
      佐々木王城、山﨑重人、光原昌寿、中島英治、澤田浩太、久布白圭司
    • Organizer
      日本鉄鋼協会176回秋季講演大会
    • Related Report
      2018 Research-status Report
  • [Presentation] 金属材料における転位の3次元観察技術2018

    • Author(s)
      光原昌寿
    • Organizer
      日本顕微鏡学会第61回シンポジウム
    • Related Report
      2018 Research-status Report
    • Invited

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Published: 2017-04-28   Modified: 2021-02-19  

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