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Improvement in creep strength of over 700 C grade ferritic heat-resistant steels by control of precipitation

Research Project

Project/Area Number 17K06851
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Structural/Functional materials
Research InstitutionNational Institute for Materials Science

Principal Investigator

TODA Yoshiaki  国立研究開発法人物質・材料研究機構, 構造材料研究拠点, 主幹研究員 (60343878)

Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2019: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2018: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2017: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Keywordsクリープ / 析出 / 炭化物 / 炭素 / 窒素 / フェライト鋼 / ラーベス相 / Z相 / 窒化物 / 粒界上析出 / クリープボイド / クリープ破断寿命 / 耐熱鋼 / クリープ強度
Outline of Final Research Achievements

In order to improve in the high-temperature creep strength of new heat-resistant steels the ferritic parent phase of which is precipitation-strengthened by carbonitrides and Laves phase, the creep strength at 700 C of the steels with various carbon and nitrogen contents was investigated. 0.02 % or more of nitrogen is necessary, and the creep strength was improved with increase in the nitrogen content by the solute strengthening and precipitation of Z phase. The long-term creep strength of the steels with 0.05 % carbon content was decreased, because voids were formed at the interfaces between the parent phase and the carbide on the grain boundaries. The slopes of creep stress vs. time to rupture curves of 0.02C-0.03N steel was low, then it was found that they were optimum contents for improving in the creep strength at 700 C of the new ferritic heat-resistant steels.

Academic Significance and Societal Importance of the Research Achievements

発電・化学プラントの高温構造部材に使用されている既存の高クロムフェライト耐熱鋼の重要な析出強化因子である炭化物が、開発鋼では母相との低い整合性からクリープ破断の原因になり得ること、既存鋼では有害相とされている窒化物が、開発鋼における安定な析出強化因子であることが分かり、700℃以上のクリープ強度を向上させるための新しい耐熱材料設計指針を示すことができた。
これにより、700 ℃級先進超々臨界圧火力発電や超臨界地熱発電、次世代核融合炉、固体酸化物型燃料電池等に安価で熱的性質の優れたフェライト開発鋼を応用でき、高効率なエネルギー変換機器により、今までよりも進んだ低炭素化社会を築くことができる。

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Research-status Report
  • 2017 Research-status Report
  • Research Products

    (10 results)

All 2019 2018

All Journal Article (1 results) (of which Peer Reviewed: 1 results) Presentation (9 results) (of which Int'l Joint Research: 2 results,  Invited: 4 results)

  • [Journal Article] Improvement in Creep and Steam Oxidation Resistance of Precipitation Strengthened Ferritic Steels2019

    • Author(s)
      Y. Toda, A. Kaseya, Y.-Y. Mitarai, O. Umezawa
    • Journal Title

      Proceedings of the Joint EPRI-123HiMAT Conference on Advances in High Temperature Materials

      Volume: -

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Presentation] 教科書にないフェライト耐熱鋼のクリープ強化機構 ~析出強化型15Crフェライト耐熱鋼の開発を通して~2019

    • Author(s)
      戸田佳明
    • Organizer
      日本鉄鋼協会第3回高温材料の高強度化研究会
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] 高温構造材料設計2019

    • Author(s)
      戸田佳明
    • Organizer
      明治大学理工学部機械情報工学科 機械情報工学
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] 教科書にないフェライト耐熱鋼のクリープ強化機構2019

    • Author(s)
      戸田佳明、御手洗容子
    • Organizer
      高温材料の高強度化研究会「高温材料の高強度化II」
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] Improvement in Creep and Steam Oxidation Resistance of Precipitation Strengthened Ferritic Steels2019

    • Author(s)
      Y.Toda, A. Kaseya, Y.-Y. Mitarai, O. Umezawa
    • Organizer
      Joint EPRI-123HiMAT Conference on Advances in High Temperature Materials
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Fe-C-15Cr-W合金における金属間化合物と炭化物による析出強化2019

    • Author(s)
      戸田佳明、加瀬谷彰宏、原田直道、中村優樹、御手洗容子、梅澤修
    • Organizer
      日本学術振興会耐熱金属材料第123委員会研究会(2018年3月期)
    • Related Report
      2018 Research-status Report
  • [Presentation] 析出強化型15Cr鋼の700℃クリープ強度に及ぼす炭素・窒素添加量の影響2019

    • Author(s)
      戸田佳明、加瀬谷彰宏、御手洗容子、梅澤修
    • Organizer
      日本鉄鋼協会第177回春季講演大会
    • Related Report
      2018 Research-status Report
  • [Presentation] 高温構造材料設計2018

    • Author(s)
      戸田佳明
    • Organizer
      明治大学理工学部機械情報工学科「機械情報工学」授業
    • Related Report
      2018 Research-status Report
    • Invited
  • [Presentation] Steam Oxidation and Creep Resistant Performances of Precipitation Strengthened Ferritic Steels2018

    • Author(s)
      Y. TODA, M. AUCHI, Y. YAMABE-MITARAI
    • Organizer
      International Symposium on High-temperature Oxidation and Corrosion 2018
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] 析出強化型15Crフェライト鋼の高温クリープ強度に及ぼす炭素・窒素添加量の影響2018

    • Author(s)
      加瀬谷彰宏、中村優樹、戸田佳明、御手洗容子、梅澤修
    • Organizer
      日本鉄鋼協会第175回春季講演大会
    • Related Report
      2017 Research-status Report

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Published: 2017-04-28   Modified: 2021-02-19  

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