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Development of thermoelectric materials by novel electric-current sintering method for achieving both fine crystal grains and crystal orientation

Research Project

Project/Area Number 17K06861
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Material processing/Microstructural control engineering
Research InstitutionShimane University

Principal Investigator

Kitagawa Hiroyuki  島根大学, 学術研究院理工学系, 准教授 (00325044)

Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2019: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2018: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2017: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Keywords焼結 / 結晶・組織制御 / 熱電材料 / 粉末冶金
Outline of Final Research Achievements

Pulse-current sintering under cyclic uniaxial pressure was applied to Bi0.4Sb1.6Te3, which is a typical p-type thermoelectric material. The crystal alignment and grain size were remarkably changed by applying the cyclic uniaxial pressure and textures were controllable by the sintering temperature, holding time and uniaxial pressure patterns. As a result of preparation of sintered materials having the various microstructures, the texture dependence of thermoelectric properties could be shown. Furthermore, it was also confirmed that the texture and thermoelectric properties of n-type Bi2Te2.7Se0.3 could be controlled by this method as well as the p-type Bi0.4Sb1.6Te3.

Academic Significance and Societal Importance of the Research Achievements

本研究で対象としたBi2Te3系材料は、室温付近で動作する高性能熱電材料として知られる一方、その製造プロセスに関する研究は現在も多数行われている。本研究はユニークな材料製造プロセスを提案するとともに、組織と熱電特性の関係を示した。得られた知見が今後のBi2Te3系材料設計指針の一助となることが期待される。

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Research-status Report
  • 2017 Research-status Report
  • Research Products

    (11 results)

All 2020 2019 2018 2017

All Journal Article (3 results) (of which Peer Reviewed: 2 results) Presentation (8 results) (of which Int'l Joint Research: 2 results)

  • [Journal Article] Effect of Cyclic Uniaxial Pressure in Pulse-Current Sintering on Microstructure of Bi2Te3-Based Thermoelectric Materials2020

    • Author(s)
      Ayako Suzuki, Hiroyuki Kitagawa, Kazuaki Hirayama, Anh Hoang Pham, Shigekazu Morito, Takao Etoh, Kotaro Kikuchi
    • Journal Title

      Journal of Electronic Materials

      Volume: 49 Issue: 5 Pages: 2832-2837

    • DOI

      10.1007/s11664-019-07867-3

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 周期的一軸圧力下でのパルス通電焼結によるn型Bi2Te3系熱電材料の組織制御2018

    • Author(s)
      北川 裕之, 井戸 翔太, 鈴木 絢子, 菊池 光太郎
    • Journal Title

      セラミックス

      Volume: 53 Pages: 622-624

    • Related Report
      2018 Research-status Report
  • [Journal Article] Microstructure Control of Bi0.4Sb1.6Te3 Thermoelectric Material by Pulse-Current Sintering under Cyclic Uniaxial Pressure2018

    • Author(s)
      Ayako Suzuki, Hiroyuki Kitagawa, Shota Ido, Anh Hoang Pham, Shigekazu Morito, Takao Etoh, Kotaro Kikuchi
    • Journal Title

      Journal of Alloys and Compounds

      Volume: 742 Pages: 240-247

    • DOI

      10.1016/j.jallcom.2018.01.269

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Presentation] Effect of Cyclic Uniaxial Pressure in Pulse-Current Sintering on the Microstructure of Bi2Te3-based Thermoelectric Materials2019

    • Author(s)
      Ayako Suzuki, Hiroyuki Kitagawa, Kazuaki Hirayama, Anh Hoang Pham, Shigekazu Morito, Takao Etoh, Kotaro Kikuchi
    • Organizer
      The 38th International Conference on Thermoelectrics
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] p型Bi2Te3系材料の微細組織へ及ぼすパルス通電焼結における周期的圧力の効果2019

    • Author(s)
      鈴木 絢子,北川 裕之,平山 一章, Anh Hoang Pham,森戸 茂一,衛藤 孝男,菊池 光太郎
    • Organizer
      第16回 日本熱電学会学術講演会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 周期的一軸圧力下でのパルス通電焼結により作製したClドープn型Bi2Te3系材料の熱電特性2018

    • Author(s)
      鈴木 絢子,北川 裕之,Anh Hoang Pham,森戸 茂一,衛藤 孝男,菊池 光太郎
    • Organizer
      粉体粉末冶金協会 平成30年度秋季大会(第122回講演大会)
    • Related Report
      2018 Research-status Report
  • [Presentation] p型Bi2Te3系材料の組織制御による熱電特性の変化2018

    • Author(s)
      鈴木 絢子,北川 裕之,Anh Hoang Pham,森戸 茂一,衛藤 孝男,菊池 光太郎
    • Organizer
      第15回 日本熱電学会学術講演会
    • Related Report
      2018 Research-status Report
  • [Presentation] 周期的一軸圧力下でのパルス通電焼結によるBi2Te3系熱電材料の組織に及ぼす焼結保持時間の影響2017

    • Author(s)
      北川 裕之
    • Organizer
      第22回通電焼結研究会
    • Related Report
      2017 Research-status Report
  • [Presentation] Microstructure and Thermoelectric Properties of Bi0.4Sb1.6Te3 prepared by Pulse-Current Sintering under Cyclic Uniaxial Pressure2017

    • Author(s)
      Ayako Suzuki, Hiroyuki Kitagawa, Shota Ido, Anh Hoang Pham, Shigekazu Morito, Takao Etoh, Kotaro Kikuchi
    • Organizer
      JSPM International Conference on Powder and Powder Metallurgy ~60th Anniversary~
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Bi0.4Sb1.6Te3の結晶配向・結晶粒径制御と熱電特性2017

    • Author(s)
      鈴木 絢子,北川 裕之,井戸 翔太,Anh Hoang Pham,森戸 茂一,衛藤 孝男,菊池 光太郎
    • Organizer
      第14回 日本熱電学会学術講演会
    • Related Report
      2017 Research-status Report
  • [Presentation] 周期的一軸圧力下でのパルス通電焼結によるBi0.4Sb1.6Te3の微細構造制御2017

    • Author(s)
      鈴木 絢子,北川 裕之,井戸 翔太,Anh Hoang Pham,森戸 茂一,衛藤 孝男,菊池 光太郎
    • Organizer
      日本金属学会 2017年秋期大会
    • Related Report
      2017 Research-status Report

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Published: 2017-04-28   Modified: 2021-02-19  

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