• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Elucidation of Mechanisms of Hydrogen Co-deposition and Hydrogen-Induced Phenomena in Electrochemical Deposition

Research Project

Project/Area Number 17K06864
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Material processing/Microstructural control engineering
Research InstitutionUniversity of Hyogo

Principal Investigator

Naoki Fukumuro  兵庫県立大学, 工学研究科, 准教授 (10347528)

Co-Investigator(Kenkyū-buntansha) 八重 真治  兵庫県立大学, 工学研究科, 教授 (00239716)
Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2019: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2018: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2017: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywordsめっき / 水素 / 空孔 / 金属原子拡散 / 水素脆化 / 水素化物 / 昇温脱離スペクトル / 電子顕微鏡 / 拡散 / 透過電子顕微鏡
Outline of Final Research Achievements

In this study, the mechanisms of hydrogen co-deposition and hydrogen-induced phenomena in electro and electroless deposited metal films were investigated using thermal desorption spectroscopy, X-ray diffraction, and transmission electron microscopy. In the electrodeposited Pt and Pd films with high hydrogen concentrations, hydrogen-induced superabundant vacancies were formed and the enhancement of metal atom diffusion such as low-temperature grain growth was observed. A large amount of co-deposited hydrogen in the electroless Ni-P/Au films improved the wettability of lead-free solders for electronic packaging. We succeeded in the electrochemical synthesis of superstoichiometric hydride PdHx (1 < x ≦ 2) and analyzed its crystal structure. These results are extremely significant in the study of metal-hydrogen system and are expected to be used in various applications.

Academic Significance and Societal Importance of the Research Achievements

本研究では、PtおよびPd電析膜について水素共析によって生成した超多量空孔が、格子収縮や低温粒成長等の顕著な水素誘起現象を引き起こすことを明らかにした。また、電解チャージと無電解めっきによってこれまで得られていない超化学量論的水素化物PdHx(1 < x ≦2)の合成に成功した。これらは金属-水素系の研究において非常に重要な成果であり、学術的意義が大きい。電子部品の基板実装において、無電解Ni-P/Auめっき膜中の水素がはんだ濡れ性の向上に寄与することを見出し、企業からのめっき膜中の水素の分析依頼と技術相談に応じ、水素の問題の解決に貢献したことは社会的意義が大きい。

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Research-status Report
  • 2017 Research-status Report
  • Research Products

    (47 results)

All 2020 2019 2018 2017 Other

All Journal Article (7 results) (of which Peer Reviewed: 7 results,  Open Access: 1 results,  Acknowledgement Compliant: 1 results) Presentation (39 results) (of which Int'l Joint Research: 8 results,  Invited: 1 results) Remarks (1 results)

  • [Journal Article] Superstoichiometric hydride PdHx≦2 formed by electrochemical synthesis: Dissolution as molecular H2 proposed2020

    • Author(s)
      N. Fukumuro, Y. Fukai, H. Sugimoto, Y. Ishii, H. Saitoh, S. Yae
    • Journal Title

      J. Alloy. Comp.

      Volume: 825 Pages: 153830-153830

    • DOI

      10.1016/j.jallcom.2020.153830

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Behavior of Hydrogen in Electrolessly Deposited Ni/Au and Ni/Pd/Au Films2019

    • Author(s)
      小田幸典,相良優作,福室直樹 ,八重真治
    • Journal Title

      Journal of The Surface Finishing Society of Japan

      Volume: 70 Issue: 3 Pages: 163-167

    • DOI

      10.4139/sfj.70.163

    • NAID

      130007606828

    • ISSN
      0915-1869, 1884-3409
    • Year and Date
      2019-03-01
    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Influence of Hydrogen in Electrolessly Deposited Ni-P/Au Films on Solder Wettability2018

    • Author(s)
      小田幸典,相良優作,福室直樹 ,八重真治
    • Journal Title

      Journal of The Surface Finishing Society of Japan

      Volume: 69 Issue: 9 Pages: 415-417

    • DOI

      10.4139/sfj.69.415

    • NAID

      130007605830

    • ISSN
      0915-1869, 1884-3409
    • Year and Date
      2018-09-01
    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Hydrogen in Electrolessly Deposited Pure Pd and Pd-P Films2018

    • Author(s)
      小田幸典, 福室直樹, 八重真治
    • Journal Title

      Journal of The Surface Finishing Society of Japan

      Volume: 69 Issue: 7 Pages: 308-309

    • DOI

      10.4139/sfj.69.308

    • NAID

      130007541924

    • ISSN
      0915-1869, 1884-3409
    • Year and Date
      2018-07-01
    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Intermetallic Compound Growth between Electroless Nickel/Electroless Palladium/Immersion Gold Surface Finish and Sn-3.5Ag or Sn-3.0Ag-0.5Cu Solder2018

    • Author(s)
      Y. Oda, N. Fukumuro, S. Yae
    • Journal Title

      Journal of Electronic Materials

      Volume: 47 Issue: 4 Pages: 2507-2511

    • DOI

      10.1007/s11664-018-6067-2

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Electroless Nickel–Phosphorus Plating under High Pressure2018

    • Author(s)
      信吉裕太, 山本拓司, 前田光治, 福室直樹, 八重真治
    • Journal Title

      KAGAKU KOGAKU RONBUNSHU

      Volume: 44 Issue: 1 Pages: 35-38

    • DOI

      10.1252/kakoronbunshu.44.35

    • NAID

      130006316106

    • ISSN
      0386-216X, 1349-9203
    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Influence of Hydrogen Adsorption on Electrodeposition of Platinum from Chloro Complex Solution2017

    • Author(s)
      Ayano Yokoyama, Shinya Karatsu, Mai Sumikawa, Naoki Fukumuro, and Shinji Yae
    • Journal Title

      ECS Transactions

      Volume: 75(52) Issue: 52 Pages: 55-60

    • DOI

      10.1149/07552.0055ecst

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] 無電解Ni/Pd/Auめっき膜中の水素がはんだ濡れ性に及ぼす影響2020

    • Author(s)
      相良優作, 小田幸典, 福室直樹, 八重真治
    • Organizer
      表面技術協会第141回講演大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 電気化学的手法によって合成した超化学量論的水素化物 PdHx≦2の結晶構造2020

    • Author(s)
      福室直樹, 深井 有, 杉本秀彦, 石井 靖, 齋藤寛之, 八重真治
    • Organizer
      日本金属学会2020年春期(第166回)講演大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 超化学量論的水素化物PdHx≦2の電気化学合成2020

    • Author(s)
      橋本倫也, 福室直樹, 深井 有, 八重真治
    • Organizer
      日本金属学会2020年春期(第166回)講演大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Influence of Hydrogen on Room-Temperature Grain Growth of Electrodeposited Cu Films2019

    • Author(s)
      N. Fukumuro, Y. Fukai, S. Yae
    • Organizer
      2nd Nucleation and Growth Research Conference (NGRC2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Hydrogen generation and nickel electrodeposition under high hydrostatic pressure2019

    • Author(s)
      T. Nishimoto, N. Fukumuro, T. Yamamoto, K. Maeda, M. Moritoki, S. Yae
    • Organizer
      2nd Nucleation and Growth Research Conference (NGRC2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Analysis of Hydrogen in Electroless Nickel/Electroless Palladium/Immersion Gold Multilayer Films Using Thermal Desorption Spectroscopy2019

    • Author(s)
      Y. Sagara, Y. Oda, Y. Matsumura, N. Fukumuro, S. Yae
    • Organizer
      2nd Nucleation and Growth Research Conference (NGRC2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] めっきにおける水素共析と水素誘起現象の解析2019

    • Author(s)
      八重真治, 福室直樹
    • Organizer
      2019年 関西表面技術シンポジウム
    • Related Report
      2019 Annual Research Report
  • [Presentation] 無電解Ni/Pd/Auめっき膜中の水素とはんだ濡れ性との関係2019

    • Author(s)
      相良優作, 小田幸典, 松村祐亮, 福室直樹, 八重真治
    • Organizer
      第83回半導体・集積回路技術シンポジウム
    • Related Report
      2019 Annual Research Report
  • [Presentation] 昇温脱離スペクトルによる無電解Pdめっき膜中水素の全量分析2019

    • Author(s)
      松村祐亮, 相良優作, 小田幸典, 福室直樹, 八重真治
    • Organizer
      表面技術協会第140回講演大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 塩化物浴からの白金電析膜の共析水素と構造への影響2019

    • Author(s)
      木下剛志, 福室直樹, 八重真治
    • Organizer
      日本金属学会2019年秋季(第165回)講演大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] ジニトロスルファト白金(II)酸水溶液を用いる白金電析における水素共析2019

    • Author(s)
      前田 凌, 木下剛志, 福室直樹, 八重真治
    • Organizer
      第21回関西表面技術フォーラム
    • Related Report
      2019 Annual Research Report
  • [Presentation] めっきにおける水素誘起超多量空孔の生成とその影響2019

    • Author(s)
      福室直樹, 深井 有, 八重真治
    • Organizer
      2018年度 日本金属学会 水素誘起超多量空孔(SAV)研究発表会
    • Related Report
      2018 Research-status Report
  • [Presentation] 無電解Ni/AuおよびNi/Pd/Auめっきの膜中水素とはんだ濡れ性との関係2019

    • Author(s)
      相良優作,小田幸典,松村祐亮,福室直樹,八重真治
    • Organizer
      表面技術協会第139回講演大会
    • Related Report
      2018 Research-status Report
  • [Presentation] 無電解Ni-P/Pd/Auめっき膜中の水素の挙動とはんだ接合への影響2019

    • Author(s)
      福室直樹,小田幸典,相良優作,八重真治
    • Organizer
      日本金属学会2019年春期(第164回)講演大会
    • Related Report
      2018 Research-status Report
  • [Presentation] 電析時の圧力がニッケル膜中の水素量に及ぼす影響2019

    • Author(s)
      西本孝宣, 阿部晃平, 福室直樹, 松本 歩, 山本拓司, 前田光治, 八重真治
    • Organizer
      電気化学会第87回大会
    • Related Report
      2018 Research-status Report
  • [Presentation] 無電解Ni\Au積層めっき膜中の水素が電子部品の接合に及ぼす影響2019

    • Author(s)
      相良優作,小田幸典,松村祐亮,福室直樹,八重真治
    • Organizer
      電気化学会第87回大会
    • Related Report
      2018 Research-status Report
  • [Presentation] Hydrogen-Induced Structural Changes in Electrodeposited Metal Films2018

    • Author(s)
      N. Fukumuro, Y. Fukai, A. Matsumoto, S. Yae
    • Organizer
      22nd Topical Meeting of the International Society of Electrochemistry
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Analysis of Hydrogen Adsorption and Incorporation during Electrodeposition of Platinum Films2018

    • Author(s)
      T. Kinoshita, A. Yokoyama, A. Matsumoto, N. Fukumuro, S. Yae
    • Organizer
      22nd Topical Meeting of the International Society of Electrochemistry
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Kinetic Modelling of Electroless Nickel-Phosphorus Plating under High Pressure2018

    • Author(s)
      H. Yokohama, M. Tayakout-Fayolle, N. Fukumuro, S. Yae, K. Itoh, K. Maeda, T. Yamamoto
    • Organizer
      8th Pacific Basin Conference on Adsorption Science and Technology
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Atomistic State of Absorbed Hydrogen in Electrodeposited Platinum Films2018

    • Author(s)
      T. Kinoshita, A. Yokoyama, A. Matsumoto, N. Fukumuro, S. Yae
    • Organizer
      2018 ECS and SMEQ Joint International Meeting (AiMES 2018)
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] 高静水圧下でのニッケル電析と水素発生2018

    • Author(s)
      西本孝宣, 阿部晃平, 福室直樹, 松本 歩, 山本拓司, 前田光治, 八重真治
    • Organizer
      第7回JACI/GSCシンポジウム
    • Related Report
      2018 Research-status Report
  • [Presentation] めっきにおける水素共析と水素誘起現象の解析2018

    • Author(s)
      八重真治、福室直樹
    • Organizer
      2018年関西表面技術シンポジウム
    • Related Report
      2018 Research-status Report
  • [Presentation] 塩化物錯体溶液から電析した白金膜中の共析水素の存在状態2018

    • Author(s)
      木下剛志, 福室直樹, 八重真治
    • Organizer
      第80回マテリアルズ・テーラリング研究会
    • Related Report
      2018 Research-status Report
  • [Presentation] 無電解パラジウムめっき膜中の水素2018

    • Author(s)
      相良優作,小田幸典,福室直樹,八重真治
    • Organizer
      第28回マイクロエレクトロニクスシンポジウム秋季大会(MES2018)
    • Related Report
      2018 Research-status Report
  • [Presentation] 無電解 Ni/Pd/Au めっき膜中の水素2018

    • Author(s)
      相良優作 ,小田幸典 ,福室直樹 ,八重真治
    • Organizer
      表面技術協会第138回講演大会
    • Related Report
      2018 Research-status Report
  • [Presentation] 無電解Ni-P/Auめっき膜のはんだ濡れ性に及 ぼす膜中水素の影響2018

    • Author(s)
      小田幸典 ,相良優作,福室直樹 ,八重真治
    • Organizer
      表面技術協会第138回講演大会
    • Related Report
      2018 Research-status Report
  • [Presentation] 高静水圧下での電気化学測定2018

    • Author(s)
      西本孝宣、阿部晃平、福室直樹、山本卓司、前田光治、八重真治
    • Organizer
      2018年電気化学秋季大会
    • Related Report
      2018 Research-status Report
  • [Presentation] 高静水圧下で電析したニッケルの膜中水素2018

    • Author(s)
      阿部晃平,西本孝宣,福室直樹,山本拓司,前田光治,八重真治
    • Organizer
      2018年第3回関西電気化学研究会
    • Related Report
      2018 Research-status Report
  • [Presentation] 電子部品の接合に影響する無電解Ni/AuおよびNi/Pd/Auめっき膜中の水素2018

    • Author(s)
      相良優作,小田幸典,松村祐亮,福室直樹,八重真治
    • Organizer
      2018年第3回関西電気化学研究会
    • Related Report
      2018 Research-status Report
  • [Presentation] 白金電析中の水素吸着と共量関係2018

    • Author(s)
      横山綾乃, 木下剛志, 松本 歩, 福室直樹, 八重真治
    • Organizer
      表面技術協会第137回講演大会
    • Related Report
      2017 Research-status Report
  • [Presentation] 白金電析膜に共析した水素の存在状態 -電析条件による変化-2018

    • Author(s)
      木下剛志、横山綾乃、松本 歩、福室直樹、八重真治
    • Organizer
      日本金属学会第162回講演大会
    • Related Report
      2017 Research-status Report
  • [Presentation] 無電解パラジウムめっき膜中の水素の存在状態2018

    • Author(s)
      福室直樹、小田幸典、横山綾乃、角川 舞、森 優輔、松本 歩、八重 真治
    • Organizer
      日本金属学会第162回講演大会
    • Related Report
      2017 Research-status Report
  • [Presentation] パラジウム電析のEQCM測定と析出膜中水素の測定2018

    • Author(s)
      角川 舞、福室直樹、八重真治
    • Organizer
      電気化学会第85回大会
    • Related Report
      2017 Research-status Report
  • [Presentation] 金属電析における水素共析と水素誘起現象2017

    • Author(s)
      福室直樹
    • Organizer
      日本真空学会関西支部&日本表面科学会関西支部合同セミナー2017
    • Related Report
      2017 Research-status Report
    • Invited
  • [Presentation] 白金めっき時の水素の吸着と吸蔵2017

    • Author(s)
      横山綾乃、木下剛志、福室直樹、八重真治
    • Organizer
      第77回マテリアルズ・テーラリング研究会
    • Related Report
      2017 Research-status Report
  • [Presentation] Influence of Adsorption of Hydrogen on Its Incorporation during Electrodeposition of Platinum2017

    • Author(s)
      S. Yae, A. Yokoyama, N. Fukumuro
    • Organizer
      68th Annual Meeting of the International Society of Electrochemistry
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] 無電解Ni/Pd/Auの厚膜パラジウム条件下でのはんだ接合合金層の解析2017

    • Author(s)
      小田幸典, 福室直樹,八重真治
    • Organizer
      表面技術協会第136回講演大会
    • Related Report
      2017 Research-status Report
  • [Presentation] 高圧力下における無電解ニッケル‐リンめっきの反応機構2017

    • Author(s)
      横濱大空, Tayakout-Fayolle M&eacute;laz, 福室直樹, 八重真治, 伊藤和宏, 前田光治, 山本拓司
    • Organizer
      化学工学会第49回秋季大会
    • Related Report
      2017 Research-status Report
  • [Presentation] 白金電析時の水素共析に及ぼす吸着水素の影響2017

    • Author(s)
      横山綾乃, 木下剛志, 福室直樹, 八重真治
    • Organizer
      第19回関西表面技術フォーラム
    • Related Report
      2017 Research-status Report
  • [Remarks] 兵庫県立大学大学院工学研究科 化学工学専攻 表面エネルギー化学研究グループ

    • URL

      http://www.eng.u-hyogo.ac.jp/group/group39/

    • Related Report
      2019 Annual Research Report 2018 Research-status Report 2017 Research-status Report

URL: 

Published: 2017-04-28   Modified: 2021-02-19  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi