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Systematic understanding and application of chemical etching of compound semiconductors

Research Project

Project/Area Number 17K06866
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Material processing/Microstructural control engineering
Research InstitutionKogakuin University

Principal Investigator

Asoh Hidetaka  工学院大学, 先進工学部, 教授 (80338277)

Co-Investigator(Kenkyū-buntansha) 橋本 英樹  工学院大学, 先進工学部, 助教 (60579556)
Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2019: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2018: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2017: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywords化合物半導体 / 湿式エッチング
Outline of Final Research Achievements

III-V compound semiconductors have attracted attention as next-generation materials and potential alternatives to silicon-based semiconductors. Nanostructures with ordered periodicity and/or high aspect ratio are considered to be important element in various applications including optical and optoelectronic devices. In this study, GaAs nanopillar arrays were successfully fabricated by metal-assisted chemical etching using Au nanodot arrays. The nanodot arrays were formed on substrates by vacuum deposition through a porous alumina mask with an ordered array of openings. By using an etchant with a high acid concentration and low oxidant concentration at a relatively low temperature, the area surrounding the Au/GaAs interface could be etched selectively. Under the optimum conditions, Au-capped GaAs nanopillar arrays were formed with an ordered periodicity of 100 nm and pillar heights of 50 nm.

Academic Significance and Societal Importance of the Research Achievements

湿式プロセスによる半導体基板の微細加工は研究者人口も少なく,未開拓な研究課題が多い。本研究は半導体の中でも,GaAsなどのⅢ-Ⅴ族化合物半導体に対し,特に湿式プロセスによりナノ構造を高度に制御するという取り組みである。次世代を担うナノ素材とナノプロセス技術の開発という観点からも,今日の社会的要請に応える研究課題と言える。シリコン基板に比べ,GaAs基板の製造コストが高く,普及するまでには技術課題が多く存在するが,次世代,次々世代デバイスへの応用可能性を秘めた魅力的な材料であり,基礎研究を通じて情報を蓄積・整理し,研究基盤を整備しておく意義は大きい。

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Research-status Report
  • 2017 Research-status Report
  • Research Products

    (8 results)

All 2019 2018 2017

All Journal Article (2 results) (of which Peer Reviewed: 2 results,  Open Access: 1 results) Presentation (6 results) (of which Int'l Joint Research: 2 results,  Invited: 1 results)

  • [Journal Article] Ⅲ-Ⅴ族化合物半導体のアノードエッチング2018

    • Author(s)
      阿相英孝,小野幸子
    • Journal Title

      表面技術

      Volume: 69 Pages: 633-636

    • NAID

      130007657348

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Au-Capped GaAs Nanopillar Arrays Fabricated by Metal-Assisted Chemical Etching2017

    • Author(s)
      Asoh Hidetaka、Imai Ryota、Hashimoto Hideki
    • Journal Title

      Nanoscale Research Letters

      Volume: 12 Issue: 1 Pages: 444-444

    • DOI

      10.1186/s11671-017-2219-1

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Open Access
  • [Presentation] シリコンの化学エッチングに対する炭素系触媒の影響2019

    • Author(s)
      関戸大智,川澄諒,橋本英樹,阿相英孝
    • Organizer
      表面技術協会金属のアノード酸化皮膜の機能化部会 第36回ARSコンファレンス
    • Related Report
      2019 Annual Research Report
  • [Presentation] 貴金属の代替としてカーボン材料を触媒としたシリコンの化学エッチング2019

    • Author(s)
      関戸大智,川澄諒,橋本英樹,阿相英孝
    • Organizer
      日本化学会第9回CSJ化学フェスタ
    • Related Report
      2019 Annual Research Report
  • [Presentation] アノードエッチングを用いた化合物半導体の微細加工2018

    • Author(s)
      阿相英孝
    • Organizer
      金属のアノード酸化皮膜の機能化部会第100回例会
    • Related Report
      2018 Research-status Report
    • Invited
  • [Presentation] Chemical Etching of GaAs using Au Nanodots as a Catalyst2017

    • Author(s)
      R. Imai, H. Hashimoto and H. Asoh
    • Organizer
      The 16th International Symposium on Advanced Technology (ISAT-16)
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Metal-Assisted Chemical Etching of GaAs Using Au Nanodots2017

    • Author(s)
      R. Imai, H. Hashimoto and H. Asoh
    • Organizer
      232nd Meeting of the Electrochemical Society
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] HF-KMnO4混合液を用いたGaAsの金属触媒エッチング2017

    • Author(s)
      今井涼太,橋本英樹,阿相英孝
    • Organizer
      金属のアノード酸化皮膜の機能化部会 第34回ARSコンファレンス
    • Related Report
      2017 Research-status Report

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Published: 2017-04-28   Modified: 2021-02-19  

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