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Development of nano-porous membranes and study on the influence of water vapour

Research Project

Project/Area Number 17K06893
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Properties in chemical engineering process/Transfer operation/Unit operation
Research InstitutionYamaguchi University

Principal Investigator

Kumakiri Izumi  山口大学, 大学院創成科学研究科, 教授 (20618805)

Project Period (FY) 2017-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2019: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2018: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2017: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywords膜 / ガス分離 / 液分離 / 膜分離 / 炭素膜 / 二酸化炭素 / 水蒸気 / 無機ナノ多孔質膜 / 水素 / 炭素 / 反応・分離工学 / ナノ材料
Outline of Final Research Achievements

Carbon membranes were synthesized on ceramic supports using tannin and phenol resin as the precursor. Combination of ion-additives and low-temperature calcination improved the hydrogen selectivity maintaining the flux. Membranes prepared with a tannin containing precursor showed high CO2/N2 selectivity. Membranes showed hydrophilic properties. Their micro-pores were plugged by the humidity in the air. Both heat and vacuum were required to remove adsorbed water from the pores. Membrane synthesis was tried with more general facilities: instead of using induction heating oven and ceramic fibers (φ3mm, 30mm length), a standard electric furnace with nitrogen atmosphere and ceramic tubes (φ12mm, 100mm length).

Academic Significance and Societal Importance of the Research Achievements

従来の蒸留法や吸着法に比べて、省エネルギーで環境調和型の膜は、新しい分離プロセスとして期待されている。さらに、反応と分離を複合化した次世代の化学反応器としての利用も盛んに検討され始めている。このような新しい用途で使用できる膜として炭素膜の合成条件などを検討し、水素や二酸化炭素分離性を向上した。汎用的な設備で製膜できることも示した。これらの結果は、分離や合成プロセスの省エネ化や膜合成の大型化に貢献できる。

Report

(5 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Research-status Report
  • 2018 Research-status Report
  • 2017 Research-status Report
  • Research Products

    (8 results)

All 2020 2018 Other

All Int'l Joint Research (2 results) Journal Article (2 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 2 results) Presentation (3 results) (of which Int'l Joint Research: 2 results) Book (1 results)

  • [Int'l Joint Research] ノルウェー工科大学(ノルウェー)

    • Related Report
      2019 Research-status Report
  • [Int'l Joint Research] NTNU大学(ノルウェー)

    • Related Report
      2018 Research-status Report
  • [Journal Article] Conceptual process design and simulation of membrane systems for integrated natural gas dehydration and sweetening2020

    • Author(s)
      He Xuezhong、Kumakiri Izumi、Hillestad Magne
    • Journal Title

      Separation and Purification Technology

      Volume: 247 Pages: 116993-116993

    • DOI

      10.1016/j.seppur.2020.116993

    • Related Report
      2019 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Influence of Iron Additive on the Hydrogen Separation Properties of Carbon Molecular Sieve Membranes2018

    • Author(s)
      Kumakiri I.、Tamura K.、Sasaki Y.、Tanaka K.、Kita H.
    • Journal Title

      Industrial & Engineering Chemistry Research

      Volume: 57 Issue: 15 Pages: 5370-5377

    • DOI

      10.1021/acs.iecr.7b05265

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Presentation] リグニンを前駆体とする炭素膜の浸透気化性能に与える合成条件の影響2020

    • Author(s)
      矢野 達士, 熊切 泉, 野中 寛
    • Organizer
      化学工学会広島大会2020
    • Related Report
      2020 Annual Research Report
  • [Presentation] Development of carbon membranes for concentrating fermented alcoholic solutions2020

    • Author(s)
      T. Yano, I. Kumakiri
    • Organizer
      The 17th Young Scientist Seminar
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Enhanced selectivity of carbon molecular sieve membranes by an addition of iron compounds to the precursor2018

    • Author(s)
      I. Kumakiri, K. Tamura, Y. Sasaki, K. Tanaka, H. Kita
    • Organizer
      EuroMembrane 2018, Valencia
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Book] Carbon Membrane Technology: Fundamentals and Applications2020

    • Author(s)
      He, Xuezhong,, Izumi Kumakiri, eds.
    • Total Pages
      184
    • Publisher
      CRC Press
    • ISBN
      9781138333376
    • Related Report
      2020 Annual Research Report

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Published: 2017-04-28   Modified: 2022-01-27  

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