• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Development of the active base metal nanocluster catalyst by using an interfacial structure

Research Project

Project/Area Number 17K06912
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Catalyst/Resource chemical process
Research InstitutionChiba University

Principal Investigator

Ichikuni Nobuyuki  千葉大学, 大学院工学研究院, 教授 (40261937)

Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2019: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2018: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2017: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Keywordsナノクラスター / XAFS / 卑金属元素 / 酸化ニッケル触媒 / 酸化マンガン触媒 / コロイド / 担体界面構造 / アルコール酸化反応 / 担体界面アシスト触媒作用 / 酸化鉄触媒 / 酸化コバルト触媒 / 触媒・化学プロセス / 触媒調製化学
Outline of Final Research Achievements

Base metal, such as nickel and manganese, nanocluster (NC) catalyst was prepared and applied to the catalytic reaction. The cooperative reaction mechanism between NiO-NC and support was found that the OH group was dissociated at NiO-NC and the H at CH was extracted at activated carbon surface. In the case of MnOx-NC, the particle size as well as the valence of manganese affected the 1-phenylethanol oxidation reaction. The smaller size MnOx-NC easily desorbed surface oxygen, and hence, redox cycle did not proceed well. It is expected that the regeneration of lattice oxygen lead to obtain more amount of acetophenone. To develop the effective base metal catalyst, the control of both size and valence is important.

Academic Significance and Societal Importance of the Research Achievements

ニッケルを微細化し活性炭に固定することで,ニッケルのみならず活性炭の機能を協奏的に発現させ活性の高い触媒を創出することに成功した。また,酸化還元という反応過程に着目し,ナノサイズ化した酸化マンガンを用いた場合は,粒子サイズだけでなく,マンガン種の価数を制御することが触媒機能発現に重要であることを見出した。これらは持続可能社会の実現に向けて,卑金属元素を利用したアルコール酸化反応の高機能化に向けた手法の確立につながるものである。

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Research-status Report
  • 2017 Research-status Report
  • Research Products

    (42 results)

All 2020 2019 2018 2017 Other

All Int'l Joint Research (3 results) Journal Article (8 results) (of which Int'l Joint Research: 3 results,  Peer Reviewed: 8 results,  Open Access: 4 results) Presentation (31 results) (of which Int'l Joint Research: 12 results,  Invited: 2 results)

  • [Int'l Joint Research] Universite catholique de Louvain(ベルギー)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] Universite de Bourgogne(フランス)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] Universite catholique de Louvain(ベルギー)

    • Related Report
      2018 Research-status Report
  • [Journal Article] The catalytic oxidation of 1-phenylethanol over SiO2 supported manganese oxide nanocluster prepared by PVP stabilized colloidal Mn as precursor2020

    • Author(s)
      Nakamura, Kyoko; Ichikuni, Nobuyuki; Hara, Takayoshi; Kojima, Takashi; Shimazu, Shogo
    • Journal Title

      Catalysis Today

      Volume: - Pages: 250-254

    • DOI

      10.1016/j.cattod.2019.10.020

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enhancement of Oxidative Dehydrogenation of Alcohols by Utilizing Hydrotalcite as Support of NiO Nanocluster Catalyst2019

    • Author(s)
      Sasaki Takuro、Ichikuni Nobuyuki、Hara Takayoshi、Shimazu Shogo
    • Journal Title

      Chemistry Letters

      Volume: 48 Issue: 4 Pages: 374-377

    • DOI

      10.1246/cl.181040

    • NAID

      130007624441

    • ISSN
      0366-7022, 1348-0715
    • Year and Date
      2019-04-05
    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Electron Population and Water Splitting Activity Controlled by Strontium Cations Doped in KTaO3 Photocatalysts2019

    • Author(s)
      Sudrajat Hanggara、Dhakal Dikshya、Kitta Mitsunori、Sasaki Takuro、Ozawa Akiyo、Babel Sandhya、Yoshida Tomoko、Ichikuni Nobuyuki、Onishi Hiroshi
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 123 Issue: 30 Pages: 18387-18397

    • DOI

      10.1021/acs.jpcc.9b03640

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Development of Supported NiO Nanocluster for Aerobic Oxidation of 1-Phenylethanol and Elucidation of Reaction Mechanism via X-ray Analysis2019

    • Author(s)
      Sasaki Takuro、Devred Francois、Eloy Pierre、Gaigneaux Eric M.、Hara Takayoshi、Shimazu Shogo、Ichikuni Nobuyuki
    • Journal Title

      Bulletin of the Chemical Society of Japan

      Volume: 92 Issue: 4 Pages: 840-846

    • DOI

      10.1246/bcsj.20180387

    • NAID

      130007632623

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] The atomic-scale structure of LaCrO3-NaTaO3 solid solution photocatalysts with enhanced electron population2019

    • Author(s)
      Sudrajat Hanggara、Zhou Yizhong、Sasaki Takuro、Ichikuni Nobuyuki、Onishi Hiroshi
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: 21 Issue: 9 Pages: 5148-5157

    • DOI

      10.1039/c8cp07688j

    • NAID

      120006604669

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Photoexcited Electrons Driven by Doping Concentration Gradient: Flux-Prepared NaTaO3 Photocatalysts Doped with Strontium Cations2018

    • Author(s)
      An Longjie、Kitta Mitsunori、Iwase Akihide、Kudo Akihiko、Ichikuni Nobuyuki、Onishi Hiroshi
    • Journal Title

      ACS Catalysis

      Volume: 8 Issue: 10 Pages: 9334-9341

    • DOI

      10.1021/acscatal.8b02437

    • NAID

      120006536968

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Local Environment of Strontium Cations Activating NaTaO3 Photocatalysts2018

    • Author(s)
      Longjie An, Takuro Sasaki, Peter G. Weidler, Christof Woell, Nobuyuki Ichikuni, Hiroshi Onishi
    • Journal Title

      ACS Catalysis

      Volume: 8 Issue: 2 Pages: 880-885

    • DOI

      10.1021/acscatal.7b03567

    • NAID

      120006469058

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Study on the promoting effect of nickel silicate for 1-phenylethanol oxidation on supported NiO nanocluster catalysts2018

    • Author(s)
      Sasaki, Takuro; Ichikuni, Nobuyuki; Hara, Takayoshi; Shimazu, Shogo
    • Journal Title

      Catalysis Today

      Volume: 307 Pages: 29-34

    • DOI

      10.1016/j.cattod.2017.05.076

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Presentation] 酸性官能基を導入した活性炭を担体とする鉄酸化物ナノクラスター触媒の構築2020

    • Author(s)
      田野文也,一國伸之,原孝佳,島津省吾
    • Organizer
      第125回触媒討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] マンガン酸化物ナノクラスター触媒の1-フェニルエタノール酸化反応における担体効果2020

    • Author(s)
      中村恭子,Pierre Eloy, Francois Devred, Eric Gaigneaux, 原孝佳,島津省吾,一國伸之
    • Organizer
      第125回触媒討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Preparation of manganese oxide nanocluster on SiO2 by using PVP stabilized colloidal Mn precursor2019

    • Author(s)
      Kyoko Nakamura, Nobuyuki Ichikuni, Takayoshi Hara, Shogo Shimazu
    • Organizer
      The 17th Korea-Japan Symposium on Catalysis
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] XAFS study on the supported Fe oxide nanocluster catalyst for benzyl alcohol oxidation reaction2019

    • Author(s)
      Nobuyuki Ichikuni, Hiroyuki Oide, Takayoshi Hara, Shogo Shimazu
    • Organizer
      French Conference on Catalysis (FCCat2)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] LaとCrをダブルドープしたNaTaO3光触媒のXAFSによる構造解析2019

    • Author(s)
      一國伸之,Sudrajat Hanggara,周以重,佐々木拓朗,大西洋
    • Organizer
      第22回XAFS討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] シリカ担持Taカーバイド触媒のカーバイド化過程におけるCoの添加効果に関する研究2019

    • Author(s)
      井村貴洸,COMBEMALE, Lionel,原孝佳,島津省吾,一國伸之
    • Organizer
      第124回触媒討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] CoOxナノクラスター調製時の前駆体の違いがベンジルアルコール酸化反応へ与える影響2019

    • Author(s)
      中山大雅,一國伸之,原孝佳,島津省吾
    • Organizer
      第9回CSJ化学フェスタ2019
    • Related Report
      2019 Annual Research Report
  • [Presentation] アルミナ担持NiOナノクラスター触媒のベンジルアルコール酸化反応中の構造変化に関する研究2019

    • Author(s)
      柴野浩,一國伸之,原孝佳,島津省吾
    • Organizer
      第9回CSJ化学フェスタ2019
    • Related Report
      2019 Annual Research Report
  • [Presentation] PVA保護Niコロイドを用いたシリカ担持Niナノクラスターの水性ガスシフト反応への応用とXAFSによる構造解析2019

    • Author(s)
      西村学,一國伸之,原孝佳,島津省吾
    • Organizer
      第9回CSJ化学フェスタ2019
    • Related Report
      2019 Annual Research Report
  • [Presentation] Development of Base Metal Nanocluster Catalysts for Liquid Phase Aerobic Oxidation of Alcohol2019

    • Author(s)
      Nobuyuki Ichikuni, Takuro Sasaki, Takayoshi Hara, Shogo Shimazu
    • Organizer
      International Symposium on Spectro-Microscopy of Functional Materials and Interfaces
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Preparation of SiO2-supported Ni nanoparticle catalyst for water gas shift reaction and XAFS analysis2019

    • Author(s)
      Manabu Nishimura, Nobuyuki Ichikuni, Takayoshi Hara, Shogo Shimazu
    • Organizer
      International Symposium on Spectro-Microscopy of Functional Materials and Interfaces
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Enhancing the population of photoexcited electrons in NaTaO3 via codoping with lanthanum and manganese2019

    • Author(s)
      Hanggara SUDRAJAT, Takuro SASAKI, Nobuyuki ICHIKUNI, Hiroshi ONISHI
    • Organizer
      第123回触媒討論会
    • Related Report
      2018 Research-status Report
  • [Presentation] PVA保護Niコロイドを用いたシリカ担持Niナノクラスター触媒の調製と水性ガスシフト反応への応用2019

    • Author(s)
      西村学,一國伸之,原孝佳,島津省吾
    • Organizer
      第123回触媒討論会
    • Related Report
      2018 Research-status Report
  • [Presentation] アルミナ担持酸化ニッケルナノクラスター触媒の調製とベンジルアルコール酸化反応活性に関する研究2019

    • Author(s)
      柴野浩,一國伸之,原孝佳,島津省吾
    • Organizer
      第123回触媒討論会
    • Related Report
      2018 Research-status Report
  • [Presentation] PVP保護コロイドを用いたCoOxナノクラスターの焼成がベンジルアルコール酸化反応に与える影響2019

    • Author(s)
      中山大雅,一國伸之,原孝佳,島津省吾
    • Organizer
      第123回触媒討論会
    • Related Report
      2018 Research-status Report
  • [Presentation] REPARATION OF COLLOID-DERIVED IRON OXIDE NANOCLUSTER CATALYST AND APPLICATION FOR OXIDATION OF BENZYL ALCOHOL2018

    • Author(s)
      Nobuyuki Ichikuni, Hiroyuki Oide, Takayoshi Hara, Shogo Shimazu
    • Organizer
      PREPA12
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Structural analysis of iron oxide nanocluster catalyst and its application to benzyl alcohol oxidation reaction2018

    • Author(s)
      Nobuyuki ICHIKUNI, Hiroyuki OIDE, Takayoshi HARA, Shogo SHIMAZU
    • Organizer
      The 17th International Conference on X-ray Absorption Fine Structure
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Study on the effect of the interfacial structure of supported NiO nanocluster catalysts to 1-phenylethanol oxidation reaction2018

    • Author(s)
      Takuro SASAKI, Nobuyuki ICHIKUNI, Takayoshi HARA, Shogo SHIMAZU
    • Organizer
      The 17th International Conference on X-ray Absorption Fine Structure
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Unravelling structural properties of NaTaO3-LaCrO3 solid solution photocatalysts2018

    • Author(s)
      Hanggara SUDRAJAT, Yizhong ZHOU, Takuro SASAKI, Nobuyuki ICHIKUNI, Hiroshi ONISHI
    • Organizer
      TOCAT8
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] LaとFeをドープしたNaTaO3光触媒のドープサイトに関する研究2018

    • Author(s)
      一國伸之,Sudrajat Hanggara,佐々木拓朗,大西洋
    • Organizer
      第21回XAFS討論会
    • Related Report
      2018 Research-status Report
  • [Presentation] アルコール酸化反応に有効な酸化ニッケルナノクラスターの活性起源に関する研究2018

    • Author(s)
      佐々木拓朗,一國伸之,原孝佳,島津省吾
    • Organizer
      第21回XAFS討論会
    • Related Report
      2018 Research-status Report
  • [Presentation] PVP保護ニッケルコロイドを用いた1-フェニルエタノール酸化反応に有効な酸化ニッケルナノクラスターの開発2018

    • Author(s)
      佐々木拓朗,一國伸之,原孝佳,島津省吾
    • Organizer
      第122回触媒討論会
    • Related Report
      2018 Research-status Report
  • [Presentation] Double doping of NaTaO3 photocatalyst with La and Fe for visible light sensitization2018

    • Author(s)
      Hanggara SUDRAJAT,佐々木拓朗,一國伸之,大西洋
    • Organizer
      第122回触媒討論会
    • Related Report
      2018 Research-status Report
  • [Presentation] アルコキシドを保護基とした酸化コバルトナノクラスター触媒の調製とXAFSによる構造解析2017

    • Author(s)
      佐々木直人,一國伸之,原孝佳,島津省吾
    • Organizer
      第20回XAFS討論会
    • Related Report
      2017 Research-status Report
  • [Presentation] 1-フェニルエタノール酸化反応に有効な担持NiOナノクラスター触媒の表面化学種の解析2017

    • Author(s)
      佐々木拓朗,一國伸之,原孝佳,島津省吾
    • Organizer
      第20回XAFS討論会
    • Related Report
      2017 Research-status Report
  • [Presentation] Characterization of Ni nanocluster on silica support derived from PVP-stabilized Ni colloid and its application to water gas shift reaction2017

    • Author(s)
      Nobuyuki ICHIKUNI, Yuya TAKEISHI, Takayoshi HARA, Shogo SHIMAZU
    • Organizer
      19th International Sol-Gel Conference
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Construction of a clean process with colloid derived NiO nanocluster catalysts for oxidation of 1-phenylethanol2017

    • Author(s)
      Takuro SASAKI, Nobuyuki ICHIKUNI, Takayoshi HARA, Shogo SHIMAZU
    • Organizer
      19th International Sol-Gel Conference
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] ベンジルアルコールの選択酸化反応に有効な担持酸化鉄ナノクラスター触媒の調製2017

    • Author(s)
      生出裕幸,一國伸之,原孝佳,島津省吾
    • Organizer
      第120回触媒討論会
    • Related Report
      2017 Research-status Report
  • [Presentation] Preparation of iron oxide nanocluster catalyst and application for selective oxidation of benzyl alcohol2017

    • Author(s)
      Hiroyuki Oide, Nobuyuki Ichikuni, Takayoshi Hara, Shogo Shimazu
    • Organizer
      International Symposium on Novel Energy Nanomaterials, Catalysts and Surfaces for Future Earth
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] NaTaO3 Photocatalysts Doped with Alkaline Earth Metals: Simultaneous Doping of A site and B site in Perovskite-Structured Lattice2017

    • Author(s)
      Longjie An, Tomoya Fujiwara, Mitsunori Kitta, Takuro Sasaki, Yoshihiro Ebisu, Naohisa Happo, Koji Kimura, Nobuyuki Ichikuni, Kouichi Hayashi, Hiroshi Onishi
    • Organizer
      International Symposium on Novel Energy Nanomaterials, Catalysts and Surfaces for Future Earth
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] 卑金属ナノクラスター触媒によるベンジルアルコール酸化反応2017

    • Author(s)
      一國伸之
    • Organizer
      第9回岩澤コンファレンス2017「サステイナブル社会のための最先端触媒化学・表面科学」
    • Related Report
      2017 Research-status Report
    • Invited

URL: 

Published: 2017-04-28   Modified: 2021-02-19  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi