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Fabrication of High-performance Metal-air Secondary Battery using Functionalized Nano-carbon

Research Project

Project/Area Number 17K07034
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Energy engineering
Research InstitutionKindai University

Principal Investigator

Yuasa Masayoshi  近畿大学, 産業理工学部, 准教授 (50404075)

Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2019: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2018: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2017: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Keywords大容量蓄電池 / ナノカーボン / 酸素還元反応 / 酸素発生反応 / 金属空気電池 / 酸素還元活性 / 酸素発生活性 / 電気自動車 / 低消費電力・高エネルギー密度 / ナノ材料 / 触媒・化学プロセス / 無機工業化学
Outline of Final Research Achievements

Electrode materials that have high stability against anodic polarization and high activity toward oxygen reduction reaction (discharge reaction) and oxygen evolution reaction (charge reaction) are required for improving the performance of metal-air batteries. In this study, we focused on graphene as an electrode material of metal-air batteries. The mechanochemical method was investigated as the synthesis method of graphene. As the result, multi-layered graphenes were successfully obtained by mechanochemical reaction using planetary ball mills. The graphene synthesized by the mechanochemical reaction showed higher oxygen reduction and evolution activity than the chemically exfoliated graphene. The oxygen evolution activity of the graphene synthesized by the mechanochemical reaction was improved by doping nitrogen and sulfur. Moreover, it was found that the graphene synthesized by the mechanochemical reaction has high activity toward the glucose oxidation.

Academic Significance and Societal Importance of the Research Achievements

本研究では、ボールミル粉砕(硬質ボールと固体試料を円筒形の容器中で回転させることで試料をすりつぶす材料粉砕方法)を利用したグラフェン(炭素で構成されたシート状の微粒子)の合成を検討した。本研究で得られたグラフェンは、金属空気電池の充電反応に対して安定で、かつ、高い充放電活性を有することを見出した。金属空気電池は、リチウムイオン電池を凌ぐ高い放電容量を実現しうる電池であるが、充電反応の際に構成材料が分解すること、そして材料の反応活性が低いことが課題であった。本研究で得られた材料は、上述の金属空気電池の課題の解決に資する有望な材料である。

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Research-status Report
  • 2017 Research-status Report
  • Research Products

    (11 results)

All 2019 2018 2017

All Journal Article (1 results) (of which Peer Reviewed: 1 results) Presentation (10 results) (of which Int'l Joint Research: 3 results,  Invited: 2 results)

  • [Journal Article] Oxygen reduction/evolution activity of air electrodes using nitrogen-doped and perovskite-type oxide loaded reduced graphene oxides2019

    • Author(s)
      Masayoshi Yuasa, Yuko Suenaga, Ryushin Nakamura,Kenta Abe, Shunsuke Watanabe
    • Journal Title

      Journal of Applied Electrochemistry

      Volume: 166 Issue: 10 Pages: 1055-1067

    • DOI

      10.1007/s10800-019-01350-x

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Presentation] Exploration of bi-functional electrode materials for oxygen reduction and oxygen Evolution2019

    • Author(s)
      Masayoshi Yuasa, Miu Tanaka, Mamia Yoshida, Masayo Shimizu
    • Organizer
      Materials Research Meeting (MRM2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] メカノケミカル法により合成したナノカーボンの酸素還元発生特性2019

    • Author(s)
      田中 未有, 清水 雅代, 湯浅 雅賀
    • Organizer
      2019年電気化学秋季大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 遷移金属複合酸化物を用いた非酵素型グルコース酸化電極2019

    • Author(s)
      柴山紘輝, 瀧宮悠佑, 湯浅雅賀
    • Organizer
      第56回化学関連支部合同九州大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Exploration of electrode materials for bi-functional air electrode2018

    • Author(s)
      湯浅雅賀
    • Organizer
      Second International Zn-Air Battery Workshop
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] メカノケミカル法による異種元素ドープグラフェンの合成と空気極への応用2018

    • Author(s)
      田中未有, 吉田眞実愛, 湯浅雅賀
    • Organizer
      第55回化学関連支部合同九州大会
    • Related Report
      2018 Research-status Report
  • [Presentation] SnO2ーグラフェン複合体を用いた半導体ガスセンサ2018

    • Author(s)
      平野一弥, 田中未有, 安部雄希, 湯浅雅賀
    • Organizer
      第55回化学関連支部合同九州大会
    • Related Report
      2018 Research-status Report
  • [Presentation] 金属空気電池用空気極の二元機能化と高性能化2018

    • Author(s)
      湯浅雅賀
    • Organizer
      第28回日本MRS年次大会
    • Related Report
      2018 Research-status Report
    • Invited
  • [Presentation] メカノケミカル法により合成した異種元素ドープ多層グラフェンの金属空気二次電池用空気極への応用2018

    • Author(s)
      田中 未有、吉田 眞美愛、湯浅 雅賀
    • Organizer
      第28回日本MRS年次大会
    • Related Report
      2018 Research-status Report
  • [Presentation] Exploration of electrode materials for bi-functional air electrode2018

    • Author(s)
      湯浅雅賀, 末永侑子, 阿部賢太, 渡邉俊介, 吉田眞美愛
    • Organizer
      Second International Zn-Air Battery Workshop
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] 還元型酸化グラフェン空気極の酸素還元・発生特性2017

    • Author(s)
      湯浅雅賀,阿部賢太, 末永侑子, 渡邉俊介
    • Organizer
      2017年電気化学秋季大会
    • Related Report
      2017 Research-status Report

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Published: 2017-04-28   Modified: 2021-02-19  

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