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Development of Cooperative Catalysis for Active Organometallic Species and Application for Diversity-Oriented Synthesis

Research Project

Project/Area Number 17K08206
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Chemical pharmacy
Research InstitutionOsaka University (2019-2020)
Tokyo University of Science (2017-2018)

Principal Investigator

Yutaka Saga  大阪大学, 工学研究科, 助教 (20785521)

Project Period (FY) 2017-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2019: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2018: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2017: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Keywords不活性C-H結合 / 光触媒 / 金属錯体 / 電気化学 / CO2活性化 / 複核亜鉛錯体 / 光レドックス触媒 / 多機能触媒 / 不活性C-H結合活性化反応 / 超分子化学 / 亜鉛クラスター / 有機化学
Outline of Final Research Achievements

We have succeeded to develop three metal-complex-based catalyst systems that enable difficult chemical conversions starting from unreactive organic molecules, especially with unactivated chemical bonds. 1. We developed a new dinuclear Zn complex bearing photoredox moiety and metal moiety and achieved the direct oxidation reactions of unactivated benzylic C-H bonds, under mild conditions, such as room temperature, visible light irradiation and aerobic conditions. 2. We demonstrate that a metal-based photocatalytic system with newly identified acyl donors achieves the first photocatalytic intermolecular hydroacylation with unactivated alkenes, without the intermediacy of acyl radicals, under room temperature and visible-light irradiation conditions. 3. We achieved the electrochemical hydrocarboxylation of simple alkenes under CO2 atmosphere in the presence of a pentanuclear metal complex developed by our group.

Academic Significance and Societal Importance of the Research Achievements

アルカン・アルケン類は石油資源から入手容易であるが、安定な化学結合を有しその化学変換は困難である。我々は本研究において、そのような低反応性有機化合物、また活性化が困難である不活性化学結合からの高難度変換を実現する、3つの新規金属錯体触媒系の開発に成功した。一般に本化学変換には、高温条件や紫外線照射などの過酷条件を必要としていた。我々は、金属触媒と光エネルギーもしくは電気エネルギーを組み合わせた独自の触媒系を開発することで、室温、可視光照射などの温和条件における化学変換を達成した。加えて、今回構築される化合物群は有用医薬候補としての要請に合致しており、医薬リードの迅速供給につながりうると考える。

Report

(5 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Research-status Report
  • 2018 Research-status Report
  • 2017 Research-status Report
  • Research Products

    (67 results)

All 2021 2020 2019 2018 2017

All Journal Article (11 results) (of which Int'l Joint Research: 3 results,  Peer Reviewed: 10 results,  Open Access: 10 results) Presentation (55 results) (of which Int'l Joint Research: 9 results,  Invited: 2 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Development of Metallosupramolecular Phosphatases Based on Combinatorial Self-Assembly of Metal Complexes and Organic Building Blocks for Catalytic Hydrolysis of Phosphate Monoesters2021

    • Author(s)
      S. Aoki, A. B. Rahman, Y. Hisamatsu, Y. Miyazawa, M. Zulkefeli, Y. Saga, T. Tanaka
    • Journal Title

      Results in Chemistry (a joint special issue with Inorganica Chimica Acta)

      Volume: 3 Pages: 100133-100133

    • DOI

      10.1016/j.rechem.2021.100133

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] 多段階光励起で「酸化」触媒を超「還元」触媒へ!2021

    • Author(s)
      嵯峨 裕
    • Journal Title

      化学

      Volume: 76 Pages: 64-65

    • Related Report
      2020 Annual Research Report
  • [Journal Article] Photocatalytic redox-neutral hydroxyalkylation of N-heteroaromatics with aldehydes2020

    • Author(s)
      Fuse Hiromu、Nakao Hiroyasu、Saga Yutaka、Fukatsu Arisa、Kondo Mio、Masaoka Shigeyuki、Mitsunuma Harunobu、Kanai Motomu
    • Journal Title

      Chemical Science

      Volume: 11 Issue: 44 Pages: 12206-12211

    • DOI

      10.1039/d0sc04114a

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Rational Synthetic Strategy for Heterometallic Multinuclear Complexes2020

    • Author(s)
      Hitoshi Izu, Mio Kondo, Yutaka Saga, Hikaru Iwami, Shigeyuki Masaoka
    • Journal Title

      Chem. Lett.

      Volume: 49 Issue: 2 Pages: 125-125

    • DOI

      10.1246/cl.190815

    • NAID

      130007795180

    • Related Report
      2019 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] One-Pot Synthesis of Cyclic Oligosaccharides by the Polyglycosylation of Monothioglycosides2020

    • Author(s)
      Hidetoshi Someya, Takehito Seki, Gota Ishigami, Taiki Itoh, Yutaka Saga, Yasuyuki Yamada, Shin Aoki
    • Journal Title

      Carbohydrate Research

      Volume: 487 Pages: 107888-107888

    • DOI

      10.1016/j.carres.2019.107888

    • Related Report
      2019 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Effect of metal ion substitution on the catalytic activity of a pentanuclear metal complex2020

    • Author(s)
      Takuya Akai, Mio Kondo, Sze Koon Lee, Hitoshi Izu, Takafumi Enomoto, Masaya Okamura, Yutaka Saga, Shigeyuki Masaoka
    • Journal Title

      Dalton Trans

      Volume: 49 Issue: 5 Pages: 1384-1387

    • DOI

      10.1039/c9dt04684d

    • Related Report
      2019 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Catalytic Hydrolysis of Phosphate Monoester by Supramolecular Complexes Formed by the Self-Assembly of a Hydrophobic Bis(Zn2+-cyclen) Complex, Copper, and Barbital Units That Are Functionalized with Amino Acids in a Two-Phase Solvent System2019

    • Author(s)
      Yuya Miyazawa, Akib Bin Rahaman, Yutaka Saga, Hiroki Imafuku, Yosuke Hisamatsu, Shin Aoki
    • Journal Title

      Micromachines

      Volume: 10 Issue: 7 Pages: 452-452

    • DOI

      10.3390/mi10070452

    • Related Report
      2019 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Evaluation of Zn2+ Coordination Structures in Chiral Zn2+ Complexes Based on Shape Measurement Factors: Relationships between Catalytic Activity and the Coordination Structure2019

    • Author(s)
      Shin Aoki, Chiharu Kikuchi, Yuichi Kitagawa, Yasuchika Hasegawa, Syotaro Sonoike, Yutaka Saga, Miho Hatanaka
    • Journal Title

      Eur. J. Org. Chem.

      Volume: 44 Issue: 44 Pages: 4740-4751

    • DOI

      10.1002/ejic.201900934

    • Related Report
      2019 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Catalytic Hydrolysis of Phosphate Monoester by Supramolecular Phosphatases Formed from a Monoalkylated Dizinc(II) Complex, Cyclic Diimide Units, and Copper(II) in Two-Phase Solvent System2019

    • Author(s)
      Rahman Akib Bin、Imafuku Hiroki、Miyazawa Yuya、Kafle Ananda、Sakai Hideki、Saga Yutaka、Aoki Shin
    • Journal Title

      Inorganic Chemistry

      Volume: 58 Issue: 9 Pages: 5603-5616

    • DOI

      10.1021/acs.inorgchem.8b03586

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Stereoselective aldol reactions of dihydroxyacetone derivatives catalyzed by chiral Zn2+ complexes2019

    • Author(s)
      Yasuda Masato、Saga Yutaka、Tokunaga Takuya、Itoh Susumu、Aoki Shin
    • Journal Title

      Tetrahedron

      Volume: 75 Issue: 6 Pages: 757-777

    • DOI

      10.1016/j.tet.2018.12.060

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] セリウム光触媒/アルコールHAT触媒による不活性アルカンガスの官能基化2019

    • Author(s)
      嵯峨 裕
    • Journal Title

      Farumashia

      Volume: 55 Issue: 4 Pages: 342-342

    • DOI

      10.14894/faruawpsj.55.4_342

    • NAID

      130007621927

    • ISSN
      0014-8601, 2189-7026
    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Open Access
  • [Presentation] 光触媒を用いたN-ヘテロ芳香環のヒドロキシアルキル化2021

    • Author(s)
      中尾 裕康、布施 拡、嵯峨 裕、深津 亜里沙、近藤 美欧、正岡 重行、三ツ沼 治信、金井 求
    • Organizer
      日本薬学会第141年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 光触媒を用いたN-ヘテロ芳香環のヒドロキシアルキル化2021

    • Author(s)
      布施 拡、中尾 裕康、嵯峨 裕、深津 亜里紗、近藤 美欧、正岡 重行、三ツ沼 治信、金井 求
    • Organizer
      日本化学会第101春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Control over Catalytic Activity of a Multinuclear Metal Complex Using an Encapsulated Hydrogen Ion2021

    • Author(s)
      Misa Tomoda, Yutaka Saga, Mio Kondo, Shigeyuki Masaoka
    • Organizer
      日本化学会第101春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Photochemical CO2 Reduction and Formic Acid Dehydrogenation Promoted by a Pentanuclear Cobalt Complex2021

    • Author(s)
      Takuya Akai, Yutaka Saga, Mio Kondo, Shigeyuki Masaoka
    • Organizer
      日本化学会第101春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] ニッケル 5核錯体を用いた二酸化炭素雰囲気下における電気化学的有機分子変換反応の開発2021

    • Author(s)
      山口 希海・帯刀 隼人・赤井 拓哉・嵯峨 裕・近藤 美欧・正岡 重行
    • Organizer
      日本化学会第101春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Rhパドルホイール錯体を基盤とするフレームワーク材料の構築2021

    • Author(s)
      奥田 佳那子・石見 輝・藤澤 信樹・嵯峨 裕・近藤 美欧・正岡 重行
    • Organizer
      日本化学会第101春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] イリジウム触媒による光駆動型ヒドロアシル化反応の開発2021

    • Author(s)
      中山 雄介・嵯峨 裕・近藤 美欧・正岡 重行
    • Organizer
      日本化学会第101春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 銅ポルフィリン錯体を用いた電気化学的な小分子変換反応2021

    • Author(s)
      鹿島日菜・小杉健斗・嵯峨裕・近藤美欧・正岡重行
    • Organizer
      日本化学会第101春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] ピレン基を有する金属ポルフィリン錯体の合成とフレームワーク構築2021

    • Author(s)
      赤塚 千春・小杉 健斗・石見 輝・田崎 雅大・岡部 佑紀・嵯峨 裕・近藤 美欧・正岡 重行
    • Organizer
      日本化学会第101春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] N-ヘテロサイクリックカルベン配位子を有する新規機能統合型Ru錯体の開発2021

    • Author(s)
      渡部 太登・中山 雄介・嵯峨 裕・近藤 美欧・正岡 重行
    • Organizer
      日本化学会第101春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Rh二核錯体から構築される置換活性サイト内在型フレームワークを用いたC-H挿入反応2021

    • Author(s)
      藤澤 信樹・石見 輝・伊東貴宏・可知 真美・嵯峨 裕・近藤 美欧・正岡 重行
    • Organizer
      日本化学会第101春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Design and Synthesis of Metallosupramolecular Catalysts Formed by the Self-Assembly of Functionalized Building Blocks to Mimic Natural Enzymes2021

    • Author(s)
      Shin Aoki, Akib Bin Rahman, Hirokazu Okamoto, Yuya Miyazawa, and Yutaka Saga
    • Organizer
      5th International Conference on Catalysis and Chemical Engineering (CCE-2021)
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 鉄五核錯体を触媒とする有機化合物の酸化反応2020

    • Author(s)
      帯刀隼人、岡村将也、松田美帆、嵯峨 裕、 近藤美欧、相田冬樹、正岡重行
    • Organizer
      錯体化学会第70回討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Pentanuclear Cobalt Complex that Catalyzes CO2 Reduction and HCOOH Dehydrogenation2020

    • Author(s)
      Takuya AKAI, Yutaka SAGA, Mio KONDO, Shigeyuki MASAOKA
    • Organizer
      錯体化学会第70回討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Rh二核錯体から構築される置換活性サイト内在型フレームワークの反応性2020

    • Author(s)
      藤澤信樹・石見 輝・可知真美・藤澤真由・ 嵯峨 裕・近藤美欧・正岡重行
    • Organizer
      錯体化学会第70回討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 機能統合型Ru錯体を用いた光駆動型触媒的有機分子変換法の開発2020

    • Author(s)
      中山雄介・嵯峨 裕・近藤美欧・正岡重行
    • Organizer
      錯体化学会第70回討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 異種金属五核錯体が示す特異な電子移動反応の機構解明2020

    • Author(s)
      赤塚 千春・伊豆 仁・友田 美紗・赤井 拓哉・嵯峨 裕・近藤 美欧・正岡 重行
    • Organizer
      錯体化学会第70回討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Synthesis and Properties of Iron Porphyrin Complexes with Proton Responsive Sites for CO2 reduction2020

    • Author(s)
      Kento KOSUGI, Yutaka SAGA, Mio KONDO, Shigeyuki MASAOKA
    • Organizer
      錯体化学会第70回討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 異種金属5核錯体の示す特異な水素イオンの放出/包接挙動2020

    • Author(s)
      友田美紗・伊豆 仁・岡村将也・嵯峨 裕・ 近藤美欧・正岡重行
    • Organizer
      錯体化学会第70回討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] One-Pot Synthesis of Cyclic Oligosaccharides by the Polyglycosylation of Monothioglycosides(モノチオ糖のポリグリコシル化反応による環状オリゴ糖のワンポット合成)2020

    • Author(s)
      染谷 英寿、関 健仁、石上 剛太、嵯峨 裕、山田 泰之、青木 伸
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Research-status Report
  • [Presentation] コバルト五核金属錯体を用いた電気および光化学的CO2還元2020

    • Author(s)
      赤井 拓哉・LEE Sze Koon・伊豆 仁・榎本 孝文・岡村 将也・嵯峨 裕・近藤 美欧・正岡 重行
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Research-status Report
  • [Presentation] Ar-ArF相互作用部位を有するRu三核錯体の合成と自己集積化2020

    • Author(s)
      冨安 瞭・石見 輝・藤澤 真由・嵯峨 裕・近藤 美欧・正岡 重行
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Research-status Report
  • [Presentation] 光捕集能と基質活性化能を併せ持つRu錯体を用いた光駆動型有機分子変換反応の開発2020

    • Author(s)
      中山 雄介・嵯峨 裕・近藤 美欧・正岡 重行
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Research-status Report
  • [Presentation] On-demand installation of metal ions into multinuclear metal complexes for precise control over their redox behaviors2020

    • Author(s)
      IZU, Hitoshi; OKAMURA, Masaya; LEE, Sze Koon; TOMODA, Misa; AKAI, Takuya; PRANEETH, Vijayendran; KAWATA, Satoshi; SAGA, Yutaka; KONDO, Mio; MASAOKA, Shigeyuk
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Research-status Report
  • [Presentation] プロトン応答性部位を有する鉄ポルフィリン錯体の合成と性質2020

    • Author(s)
      小杉 健斗・嵯峨 裕・近藤 美欧・正岡 重行
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Research-status Report
  • [Presentation] 鉄五核錯体を触媒とするオレフィンの酸化反応2020

    • Author(s)
      帯刀 隼人・岡村 将也・松田 美帆・嵯峨 裕・近藤 美欧・相田 冬樹・正岡 重行
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Research-status Report
  • [Presentation] Rh二核錯体から構築される置換活性サイト内在型フレームワークの反応性2020

    • Author(s)
      藤澤 信樹・石見 輝・可知 真美・藤澤 真由・嵯峨 裕・近藤 美欧・正岡 重行
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Research-status Report
  • [Presentation] 異種金属5核錯体の示す特異的プロトン包摂挙動2020

    • Author(s)
      友田 美紗・伊豆 仁・金池 真理・岡村 将也・嵯峨 裕・近藤 美欧・正岡 重行
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Research-status Report
  • [Presentation] アルキル化された二核亜鉛錯体とバルビタールユニット、銅イオンの自己集積体による触媒的リン酸モノエステル加水分解2019

    • Author(s)
      青木 伸、Akib Bin Rahman、宮澤 有哉、今福 浩輝、Ananda Kafle、酒井 秀樹、嵯峨 裕
    • Organizer
      第17回ホスト-ゲスト・超分子化学シンポジウム
    • Related Report
      2019 Research-status Report 2018 Research-status Report
  • [Presentation] Design and Synthesis of Chiral Zn2+ Complexes Mimicking Class II Aldolases for Catalytic Asymmetric Aldol Reactions2019

    • Author(s)
      Shin Aoki, Masato Yasuda, Chiharu Kikuchi, Yutaka Saga, Yuichi Kitagawa, Yasuchika Hasegawa, Miho Hatanaka
    • Organizer
      15th International Symposium of Applied Biological Chemixstry (ISABC15)
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Design, Synthesis, and Phosphatase Activities of Supramolecular Complexes Inspired by an Active Center of Alkaline Phosphatase2019

    • Author(s)
      Yuya Miyazawa, Yutaka Saga, Akib Bin Rahman, Hiroki Imafuku, Shin Aoki
    • Organizer
      錯体化学会第69回討論会
    • Related Report
      2019 Research-status Report
  • [Presentation] 二核亜鉛錯体を触媒とする光化学的ベンジル位酸素酸化反応2019

    • Author(s)
      嵯峨 裕、幸内 貴耶、佐藤 亨平、黒田 玲子、田所 誠、正岡 重行、青木 伸
    • Organizer
      錯体化学会第69回討論会
    • Related Report
      2019 Research-status Report
  • [Presentation] Design and Synthesis of Tetrakis(Zn2+-cyclen) Complex Bridged with an Alkyl Chain for the Contruction of Supramolecular Phsophatase by Self-Assembly with Barbital and Copper(II)2019

    • Author(s)
      Yuka Kobayashi, Akib Bin Rahman, Yuya Miyazawa, Yutaka Saga, and Shin Aoki
    • Organizer
      7th Asian Congress on Coordination Chemistry (ACCC7)
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Synthesis of Linear and Cyclic Oligosaccharides by Glycosylation of Monothioglycosides2019

    • Author(s)
      Hidehisa Someya, Takehito Seki, Gota Ishigami, Taiki Itoh, Yutaka Saga, and Shin Aoki
    • Organizer
      18th Asian Chemical Congress (18ACC) and 20th General Assembly of the Federation of Asian Chemical Societies
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] One-pot Synthesis of Cyclic Oligosaccharides by Glycosylation of Monothioglycosides2019

    • Author(s)
      Takehito Seki, Hidehisa Someya, Gota Ishigami, Taiki Itoh, Yutaka Saga, and Shin Aoki
    • Organizer
      18th Asian Chemical Congress (18ACC) and 20th General Assembly of the Federation of Asian Chemical Societies
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Design & Synthesis of Supramolecular Phosphatases Based on Self-Assembly of Molecular Building Blocks & Mechanistic Study by Means of Imaging of Reaction Mixtures2019

    • Author(s)
      Akib Bin Rahman, Yuya Miyazawa, Ananda Kafle, Hideki Sakai, Yutaka Saga, and Shin Aoki
    • Organizer
      東京理科大学総合研究院イメージングフロンティアセンターシンポジウム
    • Related Report
      2019 Research-status Report
  • [Presentation] 東京理科大学薬学部生命創薬科学科―早稲田塾スーパーメディカルサイエンスプログラムの12年2019

    • Author(s)
      青木 伸、深井 文雄、秋本 和憲、羽田 紀康、久松 洋介、伊豫田 拓也、嵯峨 裕、藤井 裕子、関口 真世、李 ミン宰, 石井 彩華, 杉田 萌々子, 小林 由佳、多森 翔馬
    • Organizer
      日本薬学会第139年会
    • Related Report
      2018 Research-status Report
  • [Presentation] アミノ酸で修飾したバルビタール誘導体・二核亜鉛錯体・銅イオンの自己集積型超分子の設計、合成とphosphatase活性2019

    • Author(s)
      宮澤 有哉、Akib Bin Rahman、今福 浩輝、嵯峨 裕、青木 伸
    • Organizer
      日本薬学会第139年会
    • Related Report
      2018 Research-status Report
  • [Presentation] Development of Supramolecular Complexes by Combinatorial Assembly of Functionalized Zinc(II) Complexes, Building Blocks & Metals2018

    • Author(s)
      Shin Aoki, Akib Bin Rahman, Hiroki Imafuku, Yuya Miyazawa, Yuka Kobayashi, Yutaka Saga
    • Organizer
      International Congress on Pure & Applied Chemistry Langkawi (ICPAC Langkawi 2018)
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Design and Synthesis of Supramolecular Phosphatases Mimicking an Active Center of Alkaline Phosphatase2018

    • Author(s)
      Yuya Miyazawa, Akib Bin Rahman, Hiroki Imafuku, Yutaka Saga, Shin Aoki
    • Organizer
      43rd International Conference on Coordination Chemistry (ICCC2018)
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] 立体選択的アルドール反応を触媒する人工キラル亜鉛錯体の配位構造と反応機構の解析2018

    • Author(s)
      園池 昇太郎、菊地 千陽、畑中 美穂、北川 裕一、長谷川 靖哉、嵯峨裕 、青木 伸
    • Organizer
      第62回日本薬学会関東支部大会
    • Related Report
      2018 Research-status Report
  • [Presentation] 二核亜鉛錯体、バルビタール誘導体、銅イオンの自己集積型超分子によるリン酸加水分解と、官能基の導入および添加金属イオンの影響2018

    • Author(s)
      今福 浩輝、Akib Bin Rahman、宮澤 有哉、嵯峨 裕、青木 伸
    • Organizer
      第62回日本薬学会関東支部大会
    • Related Report
      2018 Research-status Report
  • [Presentation] Catalytic Hydrolysis of Phosphate Monoester by Supramolecular Phosphatase Formed from Monoalkylated Dizinc(II) Complex, Diimide Units & Copper(II) in Two-Phase Solvent System2018

    • Author(s)
      Akib Bin Rahman, Hiroki Imafuku, Yuya Miyazawa, Yutaka Saga, Shin Aoki
    • Organizer
      第16回ホストゲスト・超分子化学シンポジウム
    • Related Report
      2018 Research-status Report
  • [Presentation] Catalytic Hydrolysis of Phosphate Monoester by Supramolecular Phosphatase Fomred by Complexation of Monoalkylated Dizinc(II) Complex, Dimide Units & Copper(II)2018

    • Author(s)
      Akib Bin Rahman, Hiroki Imafuku, Yuya Miyazawa, Yutaka Saga, Shin Aoki
    • Organizer
      6th International Postgraduate Conference on Pharmaceutical Sciences 2018 (iPoPS2018)
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] 新規二核亜鉛錯体、イミド誘導体、銅から成る自己集積的多核銅錯体の構築と反応活性2018

    • Author(s)
      嵯峨 裕、宮澤 有哉、青木 伸
    • Organizer
      第16回ホストゲスト・超分子化学シンポジウム
    • Related Report
      2018 Research-status Report
  • [Presentation] 新規二核亜鉛錯体とバルビタール、銅から成る自己集積的多核銅錯体の構築と反応活性2018

    • Author(s)
      嵯峨 裕、宮澤 有哉、青木 伸
    • Organizer
      日本薬学会第138年会
    • Related Report
      2018 Research-status Report
  • [Presentation] リン酸-Zn(Ⅱ)配位結合を利用するロタキサン型分子シャトルの設計と合成2018

    • Author(s)
      関根 禎亮、嵯峨 裕、青木 伸
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2018 Research-status Report
  • [Presentation] Design and Synthesis of Molecular Shuttles Driven by Phosphate-Zn(Ⅱ) Coordination2018

    • Author(s)
      Yoshiyuki Sekine, Yutaka Saga, Shin Aoki
    • Organizer
      6th International Postgraduate Conference on Pharmaceutical Sciences 2018 (iPoPS2018)
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Design and Synthesis of Molecular Shuttles Driven by Phosphate-Zn(Ⅱ) Coordination2018

    • Author(s)
      SEKINE, Yoshiaki.; Saga, Yutaka.; AOKI, Shin.
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Research-status Report
  • [Presentation] Development and Cnstruction of Polynuclear Cu Complexes Comprising with New Binuclear Zn Complexes, Barbital and Cu2018

    • Author(s)
      嵯峨 裕、宮澤有哉、青木伸
    • Organizer
      日本薬学会第138年会
    • Related Report
      2017 Research-status Report
  • [Presentation] 新規二核亜鉛錯体、イミド誘導体、銅から成る自己集積的多核銅錯体の構築と反応活性2018

    • Author(s)
      嵯峨 裕、宮澤 有哉、青木 伸
    • Organizer
      第16回ホストゲスト超分子化学シンポジウム
    • Related Report
      2017 Research-status Report
  • [Presentation] Catalytic Hydrolysis of Phosphate Monoester by Supramolecular Phosphatase Formed from Monoalkylated Dizinc(II) Complex, Diimide Units & Copper(II) in Two-Phase Solvent System2018

    • Author(s)
      Akib Bin Rahman, Hiroki Imafuku, Yuya Miyazawa, Yutaka Saga, Shin Aoki
    • Organizer
      第16回ホストゲスト超分子化学シンポジウム
    • Related Report
      2017 Research-status Report
  • [Presentation] ハイブリッド触媒系を用いた有機分子からの水素放出反応の開発2017

    • Author(s)
      布施拡、小島正寛、加藤将太、嵯峨裕、金井求
    • Organizer
      第6回JACI/GSCシンポジウム
    • Related Report
      2017 Research-status Report
  • [Presentation] Design and Synthesis of Supramolecular Phosphatase Based on Self Assembly of Monoalkylated Dizinc(II) Complexes, Diimide Units & Copper(II) for catalyticHydrolysis of Phosphate Monostar2017

    • Author(s)
      Akib Bin RAHMAN, Hiroki IMAFUKU, Yosuke HISAMATSU, Yuya MIYAZAWA, Yutaka SAGA, Shin AOKI
    • Organizer
      The 67th Japan Society of Coordination Chemistry Symposium
    • Related Report
      2017 Research-status Report
  • [Presentation] Ternary Hybrid Catalysis Enabling Room-Temperature Hydrogen Gas Release from Organic Molecules2017

    • Author(s)
      Yutaka Saga
    • Organizer
      分子研研究会-Cutting-Edge Researches in Coordination Chemistry and Photochemistry-
    • Related Report
      2017 Research-status Report
    • Invited
  • [Patent(Industrial Property Rights)] 有機化合物の酸化物の製造方法2021

    • Inventor(s)
      相田 冬樹、正岡 重行、嵯峨 裕、帯刀 隼人
    • Industrial Property Rights Holder
      相田 冬樹、正岡 重行、嵯峨 裕、帯刀 隼人
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2021-033374
    • Filing Date
      2021
    • Related Report
      2020 Annual Research Report

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Published: 2017-04-28   Modified: 2022-01-27  

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