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Development of emulsion-based fire suppressants containing ferrocene

Research Project

Project/Area Number 17K12987
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Social systems engineering/Safety system
Research InstitutionYokohama National University

Principal Investigator

KOSHIBA Yusuke  横浜国立大学, 大学院工学研究院, 技術専門職員 (60419273)

Project Period (FY) 2017-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2018: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2017: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywords消火剤 / 火災 / マイクロエマルション / フェロセン / プール火災 / リンフリー / 消火
Outline of Final Research Achievements

This report describes the preparation and fire-suppression efficiency of oil-in-water microemulsions containing ferrocene. In this work, oil-in-water emulsions containing 0-1000 ppm ferrocene and four surfactants (Surfynol 465, Olfin E1020, Triton X-100 (TX), and Noigen TDS-80 (NT)) were prepared. Four emulsion parameters were then characterized: emulsion stability, oil-droplet size in emulsion, flash point, and suppression ability. Emulsion stability experiments and droplet-size measurements demonstrated that the oil-in-water emulsions containing ferrocene and TX/NT were thermodynamically stable microemulsions. Suppression trials involving microemulsions containing 0-1000 ppm ferrocene and NT revealed the relationship between their fire suppression efficiency and the concentrations of ferrocene and NT, and also demonstrated that the microemulsions tested in this study have a higher ability to suppress pool fires compared with a conventional wet chemical agent.

Academic Significance and Societal Importance of the Research Achievements

【社会的意義】本研究で開発したフェロセン含有マイクロエマルションは,既存の液系消火剤である強化液よりも高性能であった.また,提案したマイクロエマルション消火剤は,イオン成分を含まないため,本研究で確認はしていないが,C 火災を含めた ABC 火災全てに対応できる可能性が高い.従って,火災による人損や物損の低減に大きく寄与できると言える.
【学術的意義】消火性能が高いマイクロエマルション消火剤は,今までに全く報告が無かった.マイクロエマルション系消火剤という新たな研究領域を創生できたため,ここに学術的貢献があったと言える.

Report

(3 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Research-status Report
  • Research Products

    (7 results)

All 2018 2017

All Journal Article (2 results) (of which Peer Reviewed: 2 results,  Open Access: 2 results) Presentation (5 results) (of which Int'l Joint Research: 2 results)

  • [Journal Article] Oil-in-water microemulsion containing ferrocene: A new fire suppressant2018

    • Author(s)
      Yusuke Koshiba, Takuya Tomita, Hideo Ohtani
    • Journal Title

      Fire Saf. J.

      Volume: 98 Pages: 82-89

    • DOI

      10.1016/j.firesaf.2018.04.005

    • NAID

      120006534533

    • Related Report
      2018 Annual Research Report 2017 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Ferrocene-Containing Emulsion-Based Fire-Extinguishing Agents2017

    • Author(s)
      Koshiba, Y., Tomita T., Ohtani H.
    • Journal Title

      Fire Science and Technology

      Volume: 36 Issue: 1 Pages: 1-9

    • DOI

      10.3210/fst.36.1

    • NAID

      130006285121

    • ISSN
      0285-9521, 1882-0492
    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Open Access
  • [Presentation] フェロセン含有マイクロエマルションの消火性能2018

    • Author(s)
      入谷,小柴,大谷
    • Organizer
      第51回安全工学研究発表会 (石川県金沢市)
    • Related Report
      2018 Annual Research Report
  • [Presentation] セルロースの熱分解に及ぼす鉄化合物の影響2018

    • Author(s)
      小柴佑介
    • Organizer
      平成30年度機器分析技術研究会 (秋田県秋田市)
    • Related Report
      2018 Annual Research Report
  • [Presentation] Combustion inhibition effects of iron compounds2017

    • Author(s)
      Haga T., Koshiba Y., Ohtani H.
    • Organizer
      Asia Pacific Symposium on Safety 2017
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Fire extinguishing capability of aqueous solutions of organic solvents2017

    • Author(s)
      Yamamoto Y., Koshiba Y., Ohtani H
    • Organizer
      Asia Pacific Symposium on Safety 2017
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] DLSおよび引火点試験器を用いたマイクロエマルション系消火剤の特性評価2017

    • Author(s)
      小柴佑介
    • Organizer
      機器分析技術研究会
    • Related Report
      2017 Research-status Report

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Published: 2017-04-28   Modified: 2020-03-30  

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