| Budget Amount *help |
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2019: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2018: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2017: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
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| Outline of Final Research Achievements |
We investigated the development of substitution reaction of vinyl C-H bond of alkenes by utilizing the property that strong Lewis acid and weak base having suitable bulkiness are in dissociation equilibrium. As a result, we achieved electrophilic borylation and Friedel-Crafts acylation of alkenes. We also expanded the applicability of the carboxylation to substrates having coordinating functional groups by the choice of the combination of Lewis acid/base and substrate designing. Furthermore, we could obtain the promising knowledge about Friedel-Crafts alkylation and catalytic Friedel-Crafts acylation.
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