| Budget Amount *help |
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2019: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2018: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2017: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
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| Outline of Final Research Achievements |
Iptycenes,which contain triptycene as a unit structure, are expected to be utilized for development of functional organic materials. However, synthetic methods of these compounds have a lot of limitation, and therefore it is desirable to develop more convenient and efficient method. In this research, I investigated synthesis of iptycenes using ynolate-aryne triple cycloaddition which has been recently developed by our group. As a result, synthesis of pentiptycenes, heptiptycenes and noniptycenes was achieved utilizing arynes derived from triptycenes. Additionally, a novel synthetic method of triptycene using anthrones as arynophiles was established.
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