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Construction of Nanospace with Accumulated Labile Coordination Sites and Specific Molecular Conversion

Research Project

Project/Area Number 17K14455
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Inorganic chemistry
Research InstitutionUniversity of Tsukuba

Principal Investigator

Nakamura Takashi  筑波大学, 数理物質系, 助教 (90734103)

Project Period (FY) 2017-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2018: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2017: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywords超分子化学 / 錯体化学 / 大環状化合物 / イミン結合 / 配位結合 / パラジウム / 亜鉛 / 銀 / 超分子 / 錯体 / 合成化学 / 反応場 / 配位サイト
Outline of Final Research Achievements

In this project, the synthesis of multinuclear complexes possessing the nanospace with orderly accumulated labile coordination sites has been realized. The three major achievements are as follows. (1) Synthesis of Pd-hexapap, a macrocyclic hexanuclear palladium complex with accumulated labile coordination sites in the cavity, and the analysis of its twisted shape. (2) Synthesis of a novel tripodal ligand and its metal complex, which serves as a building block for the construction of supramolecular complexes with inwardly accumulated coordination sites. (3) Synthesis of a heterometallic hexanuclear zinc-silver complex and a double-decker dodecanuclear zinc complex utilizing a triangular macrocyclic ligand.

Academic Significance and Societal Importance of the Research Achievements

反応性が高い配位サイトを維持した状態で複数の金属を一定間隔で配列させ、それらを制御することはチャレンジングな課題である。本研究では、置換活性な配位サイトをもつキレート錯体ユニットを共有結合によって複数連結する設計指針により、外部の分子が結合可能な配位サイトが内向きに集積したナノ空間をもつ多核金属錯体の合成を達成した。本研究で合成された錯体は、多点での配位結合により分子を内孔に捕捉・集積できる構造的特徴をもつため、単核錯体では実現できない選択的な触媒反応への展開が可能である。また、その環状骨格を生かした特異的な分子認識ホストや化学センサーへの応用が期待される。

Report

(3 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Research-status Report
  • Research Products

    (64 results)

All 2019 2018 2017 Other

All Journal Article (9 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 9 results,  Open Access: 1 results) Presentation (52 results) (of which Int'l Joint Research: 16 results,  Invited: 4 results) Remarks (3 results)

  • [Journal Article] Polychromatic Photoluminescence of Polymorph Boron Dipyrromethene Crystals and Heterostructures2019

    • Author(s)
      Aswin Asaithambi, Daichi Okada, Gunther Prinz, Hiroyasu Sato, Akinori Saeki, Takashi Nakamura, Tatsuya Nabeshima, Yohei Yamamoto, Axel Lorke*
    • Journal Title

      J. Phys. Chem. C

      Volume: 123 Issue: 8 Pages: 5061-5066

    • DOI

      10.1021/acs.jpcc.8b09202

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Heterodinuclear Group 13 Element Complexes of N4O6-Type Dipyrrin with an Unsymmetrical Twisted Structure2019

    • Author(s)
      Makoto Saikawa, Takumu Noda, Ryota Matsuoka, Takashi Nakamura, and Tatsuya Nabeshima
    • Journal Title

      European Journal of Inorganic Chemistry

      Volume: 2019 Issue: 6 Pages: 766-769

    • DOI

      10.1002/ejic.201801062

    • NAID

      120007128210

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A twisted macrocyclic hexanuclear palladium complex with internal bulky coordinating ligands2019

    • Author(s)
      Akira Nagai, Takashi Nakamura, and Tatsuya Nabeshima
    • Journal Title

      Chemical Communications

      Volume: 55 Issue: 17 Pages: 2421-2424

    • DOI

      10.1039/c8cc09643k

    • NAID

      120007128043

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of per(5-N-carboxamide-5-dehydroxylmethyl)-β-cyclodextrins and their selective recognition ability utilizing multiple hydrogen bonds2019

    • Author(s)
      Takashi Nakamura, Sota Yonemura,and Tatsuya Nabeshima
    • Journal Title

      Chemical Communications

      Volume: 55 Issue: 27 Pages: 3872-3875

    • DOI

      10.1039/c9cc00517j

    • NAID

      120007127947

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Unique Optical Properties of Selenophenyl BODIPYs and Their Linear Oligomers2018

    • Author(s)
      Taguchi Daisuke、Nakamura Takashi、Horiuchi Hiroaki、Saikawa Makoto、Nabeshima Tatsuya
    • Journal Title

      The Journal of Organic Chemistry

      Volume: in press Issue: 9 Pages: 5331-5337

    • DOI

      10.1021/acs.joc.8b00782

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and chiroptical properties of phenanthrene-fused N2O-type BODIPYs2018

    • Author(s)
      Yuki Gobo, Ryota Matsuoka, Yusuke Chiba, Takashi Nakamura, and Tatsuya Nabeshima
    • Journal Title

      Tetrahedron Letters

      Volume: 59 Issue: 47 Pages: 4149-4152

    • DOI

      10.1016/j.tetlet.2018.10.003

    • NAID

      120007128440

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Uniquely folded shapes, photophysical properties, and recognition abilities of macrocyclic BODIPY oligomers2018

    • Author(s)
      Tomohiro Hojo, Takashi Nakamura, Ryota Matsuoka, and Tatsuya Nabeshima
    • Journal Title

      Heteroatom Chemistry

      Volume: 29 Issue: 5-6

    • DOI

      10.1002/hc.21470

    • NAID

      120007128180

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Molecular recognition by multiple metal coordination inside wavy-stacked macrocycles2017

    • Author(s)
      Takashi Nakamura, Yuya Kaneko, Eiji Nishibori, Tatsuya Nabeshima
    • Journal Title

      Nature Communications

      Volume: 8 Issue: 1 Pages: 129-129

    • DOI

      10.1038/s41467-017-00076-8

    • NAID

      120007134542

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] 多点での配位結合によって分子を捕捉する超分子錯体2017

    • Author(s)
      中村 貴志
    • Journal Title

      Bulletin of Japan Society of Coordination Chemistry

      Volume: 70 Pages: 39-42

    • NAID

      40021485015

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Presentation] Precise synthesis and functions of macrocyclic oligomers with unique structure2019

    • Author(s)
      Takashi Nakamura
    • Organizer
      日本化学会第99回春季年会(2019)
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] サロフを壁面に持つベルト状大環状分子によるフラーレン包接2019

    • Author(s)
      佃真之介・中村貴志・鍋島達弥
    • Organizer
      日本化学会第99回春季年会(2019)
    • Related Report
      2018 Annual Research Report
  • [Presentation] 大環状ジピリン多量体およびそのBODIPY誘導体の分子認識能2019

    • Author(s)
      北條智大・松岡亮太・中村貴志・鍋島達弥
    • Organizer
      日本化学会第99回春季年会(2019)
    • Related Report
      2018 Annual Research Report
  • [Presentation] 7つのビピリジル基をもつシクロデキストリン誘導体の金属錯形成による単一異性体の生成2019

    • Author(s)
      米村颯太・中村貴志・鍋島達弥
    • Organizer
      日本化学会第99回春季年会(2019)
    • Related Report
      2018 Annual Research Report
  • [Presentation] 2,2´-ビピリジンを導入した三角形大環状配位子および配位サイトを精密集積した多核錯体の合成2018

    • Author(s)
      中村貴志・川島侑人・鍋島達弥
    • Organizer
      第16回ホスト-ゲスト・超分子化学シンポジウム(SHGSC2018)
    • Related Report
      2018 Annual Research Report
  • [Presentation] ユニークにねじれた大環状骨格を有するパラジウム六核錯体の合成2018

    • Author(s)
      永井瑛・中村貴志・鍋島達弥
    • Organizer
      第16回ホスト-ゲスト・超分子化学シンポジウム(SHGSC2018)
    • Related Report
      2018 Annual Research Report
  • [Presentation] アミド基を集積したβシクロデキストリン誘導体の特異な構造とアニオン認識能2018

    • Author(s)
      米村颯太・中村貴志・鍋島達弥
    • Organizer
      第16回ホスト-ゲスト・超分子化学シンポジウム(SHGSC2018)
    • Related Report
      2018 Annual Research Report
  • [Presentation] Synthesis and Unique Optical Properties of Thiophenyl and Selenophenyl BODIPYs2018

    • Author(s)
      Tatsuya Nabeshima, Daisuke Taguchi, Makoto Saikawa, Sousuke Saino, Takashi Nakamura, Hiroaki Horiuchi
    • Organizer
      28th International Symposium on the Organic Chemistry of Sulfur(ISOCS-28)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] アミドシクロデキストリン誘導体の合成とその非対称化された空孔における多点水素結合による分子認識能2018

    • Author(s)
      中村貴志・米村颯太・鍋島達弥
    • Organizer
      第29回基礎有機化学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 大環状サロフベルト錯体の合成と不飽和脂肪酸の位置選択的エポキシ化2018

    • Author(s)
      佃真之介・中村貴志・鍋島達弥
    • Organizer
      第12回バイオ関連化学シンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] アミド基を多数導入したβ-シクロデキストリン誘導体によるアニオンの非対称的な認識2018

    • Author(s)
      米村颯太・中村貴志・鍋島達弥
    • Organizer
      第12回バイオ関連化学シンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] 多色発光を示すBODIPYマイクロ結晶と光学ヘテロ構造の形成2018

    • Author(s)
      岡田大地・Asaithambi Aswin・Prinz Gunther ・佐藤寛泰・佐伯昭紀・中村貴志・鍋島達弥・Lorke Axel・山本洋平
    • Organizer
      第67回高分子討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 多色発光を示すBODIPYマイクロ結晶と光学ヘテロ構造の作成2018

    • Author(s)
      岡田大地・Vijai Aswin・Prinz Gunther・佐藤寛泰・佐伯昭紀・中村貴志・鍋島達弥・Lorke Axel・山本洋平
    • Organizer
      第79回応用物理学会秋季学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Synthesis of macrocyclic saloph-belt ligands from a bifunctional monomer and function of their Mn complexes2018

    • Author(s)
      Shinnosuke Tsukuda, Takashi Nakamura, Tatsuya Nabeshima
    • Organizer
      Tsukuba Global Science Week (TGSW) 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis and uniquely twisted shape of a macrocyclic hexanuclear palladium complex with labile coordination sites in its inner cavity2018

    • Author(s)
      Akira Nagai, Takashi Nakamura, Tatsuya Nabeshima
    • Organizer
      Tsukuba Global Science Week (TGSW) 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis of supramolecular cages based on Schiff-base formation using a tris(2-pyridylmethyl)amine derivative2018

    • Author(s)
      Takuma Kawashima, Takashi Nakamura, Tatsuya Nabeshima
    • Organizer
      Tsukuba Global Science Week (TGSW) 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Selective Anion Recognition by Multiple Hydrogen Bonds with Amide Groups Accumulated on β-Cyclodextrin2018

    • Author(s)
      Sota Yonemura, Takashi Nakamura, Tatsuya Nabeshima
    • Organizer
      Tsukuba Global Science Week (TGSW) 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 両官能性単量体を用いた大環状サロフベルト配位子の合成およびそのMn錯体の機能2018

    • Author(s)
      佃真之介・中村貴志・鍋島達弥
    • Organizer
      第8回CSJ化学フェスタ2018
    • Related Report
      2018 Annual Research Report
  • [Presentation] 内孔に配位部位を持つ大環状六核パラジウム錯体の合成とそのねじれ形状2018

    • Author(s)
      永井瑛・中村貴志・鍋島達弥
    • Organizer
      第8回CSJ化学フェスタ2018
    • Related Report
      2018 Annual Research Report
  • [Presentation] 動的共有結合を用いたトリス(2-ピリジルメチル)アミン部位を頂点とする超分子ケージの構築2018

    • Author(s)
      川島拓馬・中村貴志・鍋島達弥
    • Organizer
      第8回CSJ化学フェスタ2018
    • Related Report
      2018 Annual Research Report
  • [Presentation] アミド基を非対称に配置したシクロデキストリン誘導体の多数の水素結合による選択的ゲスト認識2018

    • Author(s)
      米村颯太・中村貴志・鍋島達弥
    • Organizer
      第8回CSJ化学フェスタ2018
    • Related Report
      2018 Annual Research Report
  • [Presentation] Construction of Elaborate Giant Molecules via Coordination-driven Desymmetrization Self-assembly2018

    • Author(s)
      Takashi Nakamura
    • Organizer
      The 2nd International Symposium on Coordination Asymmetry
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] A large macrocycle that binds molecules by multipoint metal-ligand coordination2018

    • Author(s)
      Takashi Nakamura, Yuya Kaneko, Tatsuya Nabeshima
    • Organizer
      2018 Joint Symposium on Energy Materials Science and Technology
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Studies on Size-Selective Synthesis of Macrocycles with Amphiphilic Chains2018

    • Author(s)
      Akira Nagai, Takashi Nakamura, Tatsuya Nabeshima
    • Organizer
      2018 Joint Symposium on Energy Materials Science and Technology
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Beta-Cyclodextrin Derivatives with 7 Amide Groups and Its Unique Structure2018

    • Author(s)
      Sota Yonemura, Takashi Nakamura, Tatsuya Nabeshima
    • Organizer
      2018 Joint Symposium on Energy Materials Science and Technology
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Multinuclear Zinc Complex that Accumulates Labile Coordination Sites in an Orderly Fashion2018

    • Author(s)
      Yuto Kawashima, Takashi Nakamura, Tatsuya Nabeshima
    • Organizer
      2018 Joint Symposium on Energy Materials Science and Technology
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] A Macrocyclic Saloph-Belt Ligand and Its Manganese Complex2018

    • Author(s)
      Shinnosuke Tsukuda, Takashi Nakamura, Tatsuya Nabeshima
    • Organizer
      2018 Joint Symposium on Energy Materials Science and Technology
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Synthesis of Multinuclear Macrocyclic Complexes that Orderly Assemble Labile Coordination Sites and Its Supramolecular Structure2018

    • Author(s)
      Takashi Nakamura, Yuto Kawashima, Yuya Kaneko, Tatsuya Nabeshima
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Research-status Report
  • [Presentation] 内孔に配位サイトをもつ大環状六核パラジウム錯体の合成および分子結合によるその構造変化2018

    • Author(s)
      永井 瑛、中村 貴志、鍋島 達弥
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Research-status Report
  • [Presentation] 大環状サロフベルト錯体の合成と機能2018

    • Author(s)
      佃 真之介、中村 貴志、鍋島 達弥
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Research-status Report
  • [Presentation] 7つのアミド基をもつシクロデキストリン誘導体の合成および水素結合によるその特異な分子構造2018

    • Author(s)
      米村 颯太、中村 貴志、鍋島 達弥
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Research-status Report
  • [Presentation] Wavy-stacked macrocyclic hexanuclear complex that captures guest molecules via multipoint coordination2017

    • Author(s)
      Takashi Nakamura, Yuya Kaneko, Eiji Nishibori, Tatsuya Nabeshima
    • Organizer
      The 6th Asian Conference on Coordination Chemistry (ACCC6)
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Chiral supramolecules constructed from helical metal complexes2017

    • Author(s)
      Takashi Nakamura, Hikaru Kimura, Tatsuya Nabeshima
    • Organizer
      Chirality 2017; ISCD-29
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Synthesis and Functions of Expanded Macrocyclic Dipyrrin Complexes2017

    • Author(s)
      Tomohiro Hojo, Takashi Nakamura, Ryota Matsuoka, Tatsuya Nabeshima
    • Organizer
      Tsukuba Global Science Week 2017 (TGSW2017)
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Synthesis and Properties of Heteronuclear Dipyrrin Complexes with a Figure-of-8 Structure2017

    • Author(s)
      Takumu Noda, Makoto Saikawa, Ryota Matsuoka, Takashi Nakamura, Tatsuya Nabeshima
    • Organizer
      Tsukuba Global Science Week 2017 (TGSW2017)
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Selective Synthesis of Amphiphilic Macrocyclic Ligands and Their Complexes Utilizing Reversibility of Imine Bonds2017

    • Author(s)
      Akira Nagai, Takashi Nakamura, Tatsuya Nabeshima
    • Organizer
      Tsukuba Global Science Week 2017 (TGSW2017)
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] 超分子システムの精密構築と機能開拓2017

    • Author(s)
      中村 貴志
    • Organizer
      第17回機能性分子シンポジウム(2017大饗シンポジウム)
    • Related Report
      2017 Research-status Report
    • Invited
  • [Presentation] 特異な構造を有する大環状BODIPY多量体の合成と性質2017

    • Author(s)
      北條 智大、松岡 亮太、中村 貴志、鍋島 達弥
    • Organizer
      第74回 有機合成化学協会関東支部シンポジウム
    • Related Report
      2017 Research-status Report
  • [Presentation] カルコゲノフェンを含むBODIPY類の合成と性質2017

    • Author(s)
      田口 大介、中村 貴志、鍋島 達弥
    • Organizer
      第44回有機典型元素化学討論会
    • Related Report
      2017 Research-status Report
  • [Presentation] N2O型非対称ジピリンの合成と性質2017

    • Author(s)
      牛坊 勇貴、松岡 亮太、中村 貴志、鍋島 達弥
    • Organizer
      第47回 複素環化学討論会
    • Related Report
      2017 Research-status Report
  • [Presentation] シッフ塩基形成による巨大正四面体型ケージ分子の合成2017

    • Author(s)
      武藤 圭汰、松岡 亮太、中村 貴志、鍋島 達弥
    • Organizer
      第7回 CSJ化学フェスタ2017
    • Related Report
      2017 Research-status Report
  • [Presentation] 大きな空孔を有する大環状ジピリン錯体の合成と機能2017

    • Author(s)
      北條 智大、松岡 亮太、中村 貴志、鍋島 達弥
    • Organizer
      第7回 CSJ化学フェスタ2017
    • Related Report
      2017 Research-status Report
  • [Presentation] 8の字型不斉構造をもつ環状ジピリン錯体の合成と性質2017

    • Author(s)
      野田 卓夢、齊川 誠、松岡 亮太、中村 貴志、鍋島 達弥
    • Organizer
      第7回 CSJ化学フェスタ2017
    • Related Report
      2017 Research-status Report
  • [Presentation] 両親媒性環状多量体の選択的合成と性質2017

    • Author(s)
      永井 瑛、中村 貴志、鍋島 達弥
    • Organizer
      第7回 CSJ化学フェスタ2017
    • Related Report
      2017 Research-status Report
  • [Presentation] 2,2´-ビピリジンを導入したトリサレン錯体による金属原子の置換活性部位の秩序的な集積2017

    • Author(s)
      川島 侑人、中村 貴志、鍋島 達弥
    • Organizer
      第7回 CSJ化学フェスタ2017
    • Related Report
      2017 Research-status Report
  • [Presentation] 非対称な平面性BODIPYの合成と光学特性2017

    • Author(s)
      牛坊 勇貴、松岡 亮太、中村 貴志、鍋島 達弥
    • Organizer
      第7回 CSJ化学フェスタ2017
    • Related Report
      2017 Research-status Report
  • [Presentation] Triangular Multinuclear Zinc Complex that Inwardly Accumulates Labile Coordination Sites and Its Supramolecular Structure2017

    • Author(s)
      Yuto Kawashima, Takashi Nakamura, Tatsuya Nabeshima
    • Organizer
      錯体化学会第67回討論会
    • Related Report
      2017 Research-status Report
  • [Presentation] ねじれた不斉構造を持つ環状ジピリン錯体の合成と性質2017

    • Author(s)
      野田 卓夢、齊川 誠、中村 貴志、松岡 亮太、鍋島 達弥
    • Organizer
      第28回基礎有機化学討論会
    • Related Report
      2017 Research-status Report
  • [Presentation] シッフ塩基形成による自己集積を利用した正四面体型ケージ分子の合成と機能2017

    • Author(s)
      武藤 圭汰、松岡 亮太、中村 貴志、鍋島 達弥
    • Organizer
      第28回基礎有機化学討論会
    • Related Report
      2017 Research-status Report
  • [Presentation] 複数のシッフ塩基をもつ両親媒性環状多量体配位子の合成と性質2017

    • Author(s)
      永井 瑛、中村 貴志、鍋島 達弥
    • Organizer
      第15回ホスト-ゲスト・超分子化学シンポジウム
    • Related Report
      2017 Research-status Report
  • [Presentation] 大きな空孔を有する大環状ジピリン誘導体の合成と機能2017

    • Author(s)
      北條 智大、中村 貴志、松岡 亮太、鍋島 達弥
    • Organizer
      第15回ホスト-ゲスト・超分子化学シンポジウム
    • Related Report
      2017 Research-status Report
  • [Presentation] 三重らせん錯体の自己集積による巨大正四面体型ホモキラル超分子の合成2017

    • Author(s)
      武藤 圭汰、中村 貴志、松岡 亮太、鍋島 達弥
    • Organizer
      第15回ホスト-ゲスト・超分子化学シンポジウム
    • Related Report
      2017 Research-status Report
  • [Remarks] 筑波大学 数理物質系 化学域 超分子化学研究室

    • URL

      http://www.chem.tsukuba.ac.jp/nabesima/

    • Related Report
      2018 Annual Research Report 2017 Research-status Report
  • [Remarks] 筑波大学|お知らせ・情報|注目の研究|多数の金属で分子を捕まえる大環状分子を開発

    • URL

      http://www.tsukuba.ac.jp/attention-research/p201707251900.html

    • Related Report
      2017 Research-status Report
  • [Remarks] SPring-8 Web Site|多数の金属で分子を捕まえる大環状分子を開発(プレスリリース)

    • URL

      http://www.spring8.or.jp/ja/news_publications/press_release/2017/170725_1/

    • Related Report
      2017 Research-status Report

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Published: 2017-04-28   Modified: 2020-03-30  

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