• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Development of an Organic Transistor-Based Chemical Sensor Using a Molecular Recognizable Polythiophene Material

Research Project

Project/Area Number 17K14489
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Polymer chemistry
Research InstitutionNational Institute of Advanced Industrial Science and Technology (2018)
The University of Tokyo (2017)

Principal Investigator

Minamiki Tsukuru  国立研究開発法人産業技術総合研究所, 生命工学領域, 研究員 (40793980)

Project Period (FY) 2017-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2018: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2017: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywords機能性高分子 / ポリチオフェン / 分子認識 / 高分子トランジスタ / 電解質ゲート / 電気二重層キャパシタ
Outline of Final Research Achievements

Polymer thin-film transistors (TFTs) are among the most fascinating electronic devices because of their attractive properties, such as mechanical flexibility and easy solution-processability. However, the development of electrical sensor devices on the basis of molecular-recognizable polythiophenes for chemical sensing is still in its early stage although many optical chemosensors have been reported. With that in mind, we have designed and fabricated an electrolyte-gated TFT based on a carboxy-attached polythiophene material for chemical sensing applications. As a result, the fabricated polymer device was used to successfully detect biogenic amines in water.

Academic Significance and Societal Importance of the Research Achievements

高分子半導体を用いた従来のトランジスタデバイスに関する研究は,有機ELと組み合わせた次世代ディスプレイ開発に注力されてきたが,それだけでは高分子半導体材料のポテンシャルを十分に引き出せてはいなかった。本研究を通じ,有機トランジスタ構造に基づく化学センサデバイスが実現可能であることが示され,高分子半導体(=ポリチオフェン)の新たな魅力を見出すことができた。本研究で得られた知見は,今後のトランジスタ型化学センサ開発のみならず,分子認識化学や高分子化学,表面科学,有機デバイス工学の多岐に渡る関連研究分野の発展に大きく寄与し得るものと期待できる。

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Research-status Report
  • Products Report
  • Research Products

    (29 results)

All 2019 2018 2017 Other

All Journal Article (12 results) (of which Peer Reviewed: 10 results,  Open Access: 6 results) Presentation (12 results) (of which Int'l Joint Research: 2 results,  Invited: 2 results) Book (1 results) Remarks (3 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] An Organic FET with an Aluminum Oxide Extended Gate for pH Sensing2019

    • Author(s)
      Tsukuru Minamiki, Tomohito Sekine, Michio Aiko, Shiwei Su, Tsuyoshi Minami
    • Journal Title

      Sensors and Materials

      Volume: 31 Issue: 1 Pages: 99

    • DOI

      10.18494/SAM.2019.2082

    • ISSN
      0914-4935, 2435-0869
    • Year and Date
      2019-01-15
    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Fabrication of a Flexible Biosensor Based on an Organic Field-effect Transistor for Lactate Detection2019

    • Author(s)
      Tsukuru Minamiki, Shizuo Tokito, Tsuyoshi Minami
    • Journal Title

      Analytical Sciences

      Volume: 35 Issue: 1 Pages: 103-106

    • DOI

      10.2116/analsci.18SDN02

    • NAID

      130007554963

    • ISSN
      0910-6340, 1348-2246
    • Year and Date
      2019-01-10
    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Potentiometric detection of biogenic amines utilizing affinity on a 4-mercaptobenzoic acid monolayer2019

    • Author(s)
      Minamiki Tsukuru、Kurita Ryoji
    • Journal Title

      Analytical Methods

      Volume: 11 Issue: 9 Pages: 1155-1158

    • DOI

      10.1039/c8ay02616e

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Development of Enzymatic Sensors Based on Extended-gate-type Organic Field-effect Transistors2018

    • Author(s)
      Tsuyoshi Minami, Tsukuru Minamiki, Yui Sasaki
    • Journal Title

      Electrochemistry

      Volume: 86 Issue: 6 Pages: 303-308

    • DOI

      10.5796/electrochemistry.18-6-E2672

    • NAID

      130007504967

    • ISSN
      1344-3542, 2186-2451
    • Year and Date
      2018-11-05
    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Development of polymer field-effect transistor-based immunoassays2018

    • Author(s)
      Tsukuru Minamiki, Yui Sasaki, Shiwei Su, Tsuyoshi Minami
    • Journal Title

      Polymer Journal

      Volume: 51 Issue: 1 Pages: 1-9

    • DOI

      10.1038/s41428-018-0112-0

    • NAID

      40021935726

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] An electrolyte-gated polythiophene transistor for the detection of biogenic amines in water2018

    • Author(s)
      Tsukuru Minamiki, Yuki Hashima, Yui Sasaki, Tsuyoshi Minami
    • Journal Title

      Chemical Communications

      Volume: 54 Issue: 50 Pages: 6907-6910

    • DOI

      10.1039/c8cc02462f

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 有機薄膜デバイスの分析化学への展開:分子認識能を付与した有機薄膜トランジスタによる化学センシング2018

    • Author(s)
      南木創, 南豪
    • Journal Title

      分析化学

      Volume: 67

    • NAID

      130007384768

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Label-Free Direct Electrical Detection of a Histidine-Rich Protein with Sub-Femtomolar Sensitivity using an Organic Field-Effect Transistor2017

    • Author(s)
      Tsukuru Minamiki, Yui Sasaki, Shizuo Tokito, Tsuyoshi Minami
    • Journal Title

      ChemistryOpen

      Volume: 6 Issue: 4 Pages: 472-475

    • DOI

      10.1002/open.201700070

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] An Organic Transistor-based Electrical Assay for Copper(II) in Water2017

    • Author(s)
      Yui Sasaki, Tsuyoshi Minami, Tsukuru Minamiki, Shizuo Tokito
    • Journal Title

      Electrochemistry

      Volume: 85 Issue: 12 Pages: 775-778

    • DOI

      10.5796/electrochemistry.85.775

    • NAID

      130006242959

    • ISSN
      1344-3542, 2186-2451
    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] A molecular self-assembled colourimetric chemosensor array for simultaneous detection of metal ions in water2017

    • Author(s)
      Yui Sasaki, Tsukuru Minamiki, Shizuo Tokito, Tsuyoshi Minami
    • Journal Title

      Chemical Communications

      Volume: 53 Issue: 49 Pages: 6561-6564

    • DOI

      10.1039/c7cc03218h

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] π共役高分子の構造制御による光学ケモセンサー及び電気化学センサーデバイスの開発2017

    • Author(s)
      南豪, 南木創
    • Journal Title

      ぶんせき

      Volume: 10 Pages: 497-500

    • Related Report
      2017 Research-status Report
  • [Journal Article] ボロン酸の化学的性質に基づいたポリマースポンジの機能化手法2017

    • Author(s)
      南木創
    • Journal Title

      ぶんせき

      Volume: 11 Pages: 553-553

    • Related Report
      2017 Research-status Report
  • [Presentation] Label-free biosensing platforms based on organic electronic devices2019

    • Author(s)
      Tsukuru Minamiki
    • Organizer
      Taiwan-Japan Joint Symposium
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] ポリチオフェン薄膜トランジスタを用いた化学センシング2018

    • Author(s)
      南木 創,佐々木 由比,南 豪
    • Organizer
      第33回 高分子学会関東支部茨城地区若手の会交流会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Modulation Effect of Threshold Voltage in Mixed-Electrolyte Gated Organic Transistors2018

    • Author(s)
      Shiwei Su, Tsukuru Minamiki, Tsuyoshi Minami
    • Organizer
      第79回応用物理学会秋季学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Control of Threshold Voltage in Electrolyte-Gated Organic Transistors by Cations2018

    • Author(s)
      Shiwei Su, Tsukuru Minamiki, Tsuyoshi Minami
    • Organizer
      2018 International Conference on Solid State Devices and Materials
    • Related Report
      2018 Annual Research Report
  • [Presentation] 有機カチオンによる電気二重層トランジスタの特性変化2018

    • Author(s)
      南木 創,蘇 セキイ,相子 美智雄,南 豪
    • Organizer
      日本分析化学会 平成30年度東日本分析化学若手交流会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Control of Threshold Voltage in Polymer Transistors by Electrolytes2018

    • Author(s)
      Tsukuru Minamiki, Michio Aiko, Tsuyoshi Minami
    • Organizer
      第67回高分子学会年次大会
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 有機カチオンによる高分子トランジスタの閾値電圧制御2018

    • Author(s)
      南木 創,蘇 セキイ,相子 美智雄,南 豪
    • Organizer
      化学とマイクロ・ナノシステム学会第37回研究会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 電解質ゲート型有機電界効果トランジスタの閾値電圧制御2018

    • Author(s)
      南木創, 相子美智雄, 南豪
    • Organizer
      第65回応用物理学会春季学術講演会
    • Related Report
      2017 Research-status Report
  • [Presentation] カルボキシ基導入ポリチオフェンを用いた電解質ゲート型トランジスタの作製とそのセンシング応用2017

    • Author(s)
      南木創, 時任静士, 南豪
    • Organizer
      第61回 高分子学会年次大会
    • Related Report
      2017 Research-status Report
  • [Presentation] 電解質ゲート高分子トランジスタ型化学センサの構築2017

    • Author(s)
      南木創, 南豪
    • Organizer
      平成29年度日本分析化学会関東支部若手交流会
    • Related Report
      2017 Research-status Report
  • [Presentation] π共役高分子の電子的摂動を活用した化学センサデバイスの構築2017

    • Author(s)
      南木創, 南豪
    • Organizer
      日本分析化学会第66年会
    • Related Report
      2017 Research-status Report
    • Invited
  • [Presentation] 化学センサを指向した電解質ゲート型高分子トランジスタ2017

    • Author(s)
      南木創, 南豪
    • Organizer
      化学とマイクロ・ナノシステム学会 第36回研究会
    • Related Report
      2017 Research-status Report
  • [Book] ウェアラブル機器の開発とマーケット・アプリケーション・法規制動向 第1章第3節「有機FET型化学センサ」2017

    • Author(s)
      南豪, 南木創, 時任静士
    • Total Pages
      9
    • Publisher
      R&D支援センター
    • ISBN
      9784905507215
    • Related Report
      2017 Research-status Report
  • [Remarks] 研究者個人HP

    • URL

      https://staff.aist.go.jp/t.minamiki/

    • Related Report
      2018 Annual Research Report
  • [Remarks] 産業技術総合研究所バイオメディカル研究部門 ナノバイオデバイス研究グループHP

    • URL

      https://unit.aist.go.jp/bmd/biomed-nbd/

    • Related Report
      2018 Annual Research Report
  • [Remarks] 東京大学生産技術研究所・南研究室

    • URL

      http://www.tminami.iis.u-tokyo.ac.jp/

    • Related Report
      2017 Research-status Report
  • [Patent(Industrial Property Rights)] 高分子複合体および発光フィルム2019

    • Inventor(s)
      南木 創, 栗田 僚二
    • Industrial Property Rights Holder
      産業技術総合研究所
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2019-139356
    • Filing Date
      2019
    • Related Report
      Products Report

URL: 

Published: 2017-04-28   Modified: 2021-07-06  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi