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Molecular Interaction Analysis for Understanding Perfluoroalkyl Compound-Specific Properties

Research Project

Project/Area Number 17K14502
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Analytical chemistry
Research InstitutionKyoto University

Principal Investigator

Shimoaka Takafumi  京都大学, 化学研究所, 助教 (40609921)

Project Period (FY) 2017-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2019: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2018: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2017: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywords有機フッ素材料 / パーフルオロアルキル化合物 / 赤外分光法 / ラマン分光法 / アトロプ異性 / 分子配向 / SDA理論 / ダイポールインタラクティブ / 赤外外部反射(ER)法 / 表面モード / パーフルオロアルカン / 有機フッ素化合物 / 赤外外部反射法 / 表面圧-表面積曲線 / ラマン光学活性(ROA) / フッ素化学 / パーフルオロアルキル鎖 / ラマン分光イメージング法 / ねじれ構造 / アトロプ異性体 / ガス吸着 / 凝集ダイナミクス
Outline of Final Research Achievements

In this project, we studied the intermolecular interactions between perfluoroalkyl (Rf) compounds and heterogeneous molecules. As a representative result, we found a characteristic property of liquid perfluoroalkanes on the water surface: those remain on the water surface for a long time. This result indicates that perfluoroalkane molecules have a good affinity at the air-water interface, although Rf compounds are known to have a low affinity to water in general. This property does not appear in non-fluorinated organic solvents. As a result, the specific character of perfluoroalkanes on the water surface is surely attributed to the molecular interactive force derived from the large dipole.

Academic Significance and Societal Importance of the Research Achievements

本課題では,パーフルオロアルキル(Rf)化合物が水面上で示す特徴的な性質を見出した.これは,Rf基間の相互作用が双極子支配であり,非フッ素系の化合物とは全く異なることを意味する.Rf化合物と水の界面でみられる親和性は,燃料電池のキーデバイスであるプロトン電導膜の性能の理解において重要であり,より高い性能を目指した材料開発に指針を与える成果といえる.

Report

(5 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Research-status Report
  • 2018 Research-status Report
  • 2017 Research-status Report
  • Research Products

    (97 results)

All 2021 2020 2019 2018 2017 Other

All Journal Article (29 results) (of which Int'l Joint Research: 3 results,  Peer Reviewed: 29 results,  Open Access: 7 results) Presentation (63 results) (of which Int'l Joint Research: 6 results,  Invited: 7 results) Remarks (5 results)

  • [Journal Article] Monitoring of Crystallization Process in Solution-Processed Pentacene Thin Films by Chemical Conversion Reactions2021

    • Author(s)
      Shioya Nobutaka、Fujiwara Ryoi、Tomita Kazutaka、Shimoaka Takafumi、Okudaira Koji K.、Yoshida Hiroyuki、Koganezawa Tomoyuki、Hasegawa Takeshi
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 125 Issue: 4 Pages: 2437-2445

    • DOI

      10.1021/acs.jpcc.0c10431

    • NAID

      120006954892

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Controlling the concentration gradient in sequentially deposited bilayer organic solar cells via rubbing and annealing2020

    • Author(s)
      Abdul Aziz Mohd Zaidan、Higashimine Koichi、Shioya Nobutaka、Shimoaka Takafumi、Hasegawa Takeshi、Sakai Heisuke、Vohra Varun、Murata Hideyuki
    • Journal Title

      RSC Advances

      Volume: 10 Issue: 61 Pages: 37529-37537

    • DOI

      10.1039/d0ra05991a

    • NAID

      120006893986

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Quantitative Anisotropic Analysis of Molecular Orientation in Amorphous N2O at 6 K by Infrared Multiple-Angle Incidence Resolution Spectrometry2020

    • Author(s)
      Hama T., Ishibashi A., Kouchi A., Watanabe N., Shioya N., Shimoaka T., Hasegawa T.
    • Journal Title

      The Journal of Physical Chemistry Letters

      Volume: 11 Issue: 18 Pages: 7857-7866

    • DOI

      10.1021/acs.jpclett.0c01585

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] In vivo characterization of the structures of films of a fatty acid and an alcohol adsorbed on the skin surface2020

    • Author(s)
      Hama T., Kouchi A., Watanabe N., Shioya N., Shimoaka T., Hasegawa T.
    • Journal Title

      Biophysical Chemistry

      Volume: 266 Pages: 106459-106459

    • DOI

      10.1016/j.bpc.2020.106459

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hidden thin-film phase of dinaphthothienothiophene revealed by high-resolution X-ray diffraction2020

    • Author(s)
      Shioya Nobutaka、Eda Kazuo、Shimoaka Takafumi、Hasegawa Takeshi
    • Journal Title

      Applied Physics Express

      Volume: 13 Issue: 9 Pages: 095505-095505

    • DOI

      10.35848/1882-0786/abb061

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mechanistic Study of Silane Alcoholysis Reaction with Self-Assembled Monolayer-Functionalized Gold Nanoparticle Catalysts2020

    • Author(s)
      K. Isozaki, T. Taguchi, K. Ishibashi, T. Shimoaka, W. Kurashige, Y. Negishi, T. Hasegawa, M. Nakamura, K. Miki
    • Journal Title

      Catalysts

      Volume: 10 Issue: 8 Pages: 908-908

    • DOI

      10.3390/catal10080908

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Infrared active surface modes found in thin films of perfluoroalkanes reveal the dipole?dipole interaction and surface morphology2020

    • Author(s)
      Fukumi Aki、Shimoaka Takafumi、Shioya Nobutaka、Nagai Naoto、Hasegawa Takeshi
    • Journal Title

      The Journal of Chemical Physics

      Volume: 153 Issue: 4 Pages: 044703-044703

    • DOI

      10.1063/5.0012910

    • NAID

      120006878503

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Supramolecular double-stranded Archimedean spirals and concentric toroids2020

    • Author(s)
      Sasaki Norihiko、Mabesoone Mathijs F. J.、Kikkawa Jun、Fukui Tomoya、Shioya Nobutaka、Shimoaka Takafumi、Hasegawa Takeshi、Takagi Hideaki、Haruki Rie、Shimizu Nobutaka、Adachi Shin-ichi、Meijer E. W.、Takeuchi Masayuki、Sugiyasu Kazunori
    • Journal Title

      Nature Communications

      Volume: 11 Issue: 1 Pages: 3578-3578

    • DOI

      10.1038/s41467-020-17356-5

    • NAID

      120006888025

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Simultaneous Analysis of Molecular Orientation and Quantity Change of Constituents in a Thin Film Using pMAIRS2020

    • Author(s)
      Shioya Nobutaka、Fujiwara Ryoi、Tomita Kazutaka、Shimoaka Takafumi、Hasegawa Takeshi
    • Journal Title

      The Journal of Physical Chemistry A

      Volume: 124 Issue: 13 Pages: 2714-2720

    • DOI

      10.1021/acs.jpca.0c00111

    • Related Report
      2020 Annual Research Report 2019 Research-status Report
    • Peer Reviewed
  • [Journal Article] pMAIRS Analysis on Chain-End Functionalization of Densely Grafted, Concentrated Polymer Brushes2019

    • Author(s)
      Sakakibara Keita、Nishiumi Kosuke、Shimoaka Takafumi、Hasegawa Takeshi、Tsujii Yoshinobu
    • Journal Title

      Macromolecules

      Volume: 52 Issue: 17 Pages: 6673-6682

    • DOI

      10.1021/acs.macromol.9b01149

    • Related Report
      2019 Research-status Report
    • Peer Reviewed
  • [Journal Article] Second Generation of Multiple-Angle Incidence Resolution Spectrometry2019

    • Author(s)
      Shioya Nobutaka、Tomita Kazutaka、Shimoaka Takafumi、Hasegawa Takeshi
    • Journal Title

      The Journal of Physical Chemistry A

      Volume: 123 Issue: 32 Pages: 7177-7183

    • DOI

      10.1021/acs.jpca.9b05316

    • NAID

      120006712784

    • Related Report
      2019 Research-status Report
    • Peer Reviewed
  • [Journal Article] Two-Dimensional Film Growth of Zinc Tetraphenylporphyrin with the Aid of Solvent Coordination2019

    • Author(s)
      Tomita Kazutaka、Shioya Nobutaka、Shimoaka Takafumi、Eda Kazuo、Hasegawa Takeshi
    • Journal Title

      Bulletin of the Chemical Society of Japan

      Volume: 92 Issue: 8 Pages: 1335-1340

    • DOI

      10.1246/bcsj.20190100

    • NAID

      130007689988

    • Related Report
      2019 Research-status Report
    • Peer Reviewed
  • [Journal Article] Probing the Molecular Structure and Orientation of the Leaf Surface of Brassica oleracea L. by Polarization Modulation-Infrared Reflection-Absorption Spectroscopy2019

    • Author(s)
      T. Hama, K. Seki, A. Ishibashi, A. Miyazaki, A. Kouchi, N. Watanabe, T. Shimoaka, T. Hasegawa
    • Journal Title

      Plant Cell Physiology

      Volume: 60 Issue: 7 Pages: 1567-1580

    • DOI

      10.1093/pcp/pcz063

    • Related Report
      2019 Research-status Report 2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Raman Optical Activity on a Solid Sample: Identification of Atropisomers of Perfluoroalkyl Chains Having a Helical Conformation and No Chiral Center2019

    • Author(s)
      Shimoaka Takafumi、Sonoyama Masashi、Amii Hideki、Takagi Toshiyuki、Kanamori Toshiyuki、Hasegawa Takeshi
    • Journal Title

      The Journal of Physical Chemistry A

      Volume: 123 Issue: 18 Pages: 3985-3991

    • DOI

      10.1021/acs.jpca.8b11613

    • Related Report
      2019 Research-status Report 2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Rational Method of Monitoring Molecular Transformations on Metal-Oxide Nanowire Surfaces2019

    • Author(s)
      C. Wang, T. Hosomi, K. Nagashima, T. Takahashi, G. Zhang, M. Kanai, H. Zeng, W. Mizukami, N. Shioya, T. Shimoaka, Y. Aoki, J. Terao, T. Hasegawa and T. Yanagida
    • Journal Title

      Nano Lett.

      Volume: 19 Issue: 4 Pages: 2443-2449

    • DOI

      10.1021/acs.nanolett.8b05180

    • Related Report
      2019 Research-status Report 2018 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Fluorous Property of a Short Perfluoroalkyl-Containing Compound Realized by Self-Assembled Monolayer Technique on a Silicon Substrate2019

    • Author(s)
      Kise Ryuma、Fukumi Aki、Shioya Nobutaka、Shimoaka Takafumi、Sonoyama Masashi、Amii Hideki、Takagi Toshiyuki、Kanamori Toshiyuki、Eda Kazuo、Hasegawa Takeshi
    • Journal Title

      Bulletin of the Chemical Society of Japan

      Volume: 92 Issue: 4 Pages: 785-789

    • DOI

      10.1246/bcsj.20180356

    • NAID

      130007632600

    • Related Report
      2019 Research-status Report 2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] 振動分光法により読み解く有機フッ素化合物の分子集合構造2019

    • Author(s)
      下赤卓史
    • Journal Title

      分光研究

      Volume: 68 Pages: 189-198

    • NAID

      40022161334

    • Related Report
      2019 Research-status Report
    • Peer Reviewed
  • [Journal Article] Molecular Orientation Change in Naphthalene Diimide Thin Films Induced by Removal of Thermally Cleavable Substituents2019

    • Author(s)
      Nakamura Tomoya、Shioya Nobutaka、Shimoaka Takafumi、Nishikubo Ryosuke、Hasegawa Takeshi、Saeki Akinori、Murata Yasujiro、Murdey Richard、Wakamiya Atsushi
    • Journal Title

      Chemistry of Materials

      Volume: 31 Issue: 5 Pages: 1729-1737

    • DOI

      10.1021/acs.chemmater.8b05237

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Alternative Face-on Thin Film Structure of Pentacene2019

    • Author(s)
      Shioya Nobutaka、Murdey Richard、Nakao Kazuto、Yoshida Hiroyuki、Koganezawa Tomoyuki、Eda Kazuo、Shimoaka Takafumi、Hasegawa Takeshi
    • Journal Title

      Scientific Reports

      Volume: 9 Issue: 1 Pages: 579-579

    • DOI

      10.1038/s41598-018-37166-6

    • NAID

      120006551753

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Structure control of a zinc tetraphenylporphyrin thin film by vapor annealing using fluorine containing solvent2018

    • Author(s)
      Tomita Kazutaka、Shioya Nobutaka、Kise Ryuma、Shimoaka Takafumi、Yoshida Hiroyuki、Koganezawa Tomoyuki、Eda Kazuo、Hasegawa Takeshi
    • Journal Title

      Thin Solid Films

      Volume: 665 Pages: 85-90

    • DOI

      10.1016/j.tsf.2018.09.015

    • NAID

      120006531253

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Molecular Aggregation of Perfluoroalkyl Groups Can Win the Hydrogen Bonding between Amides2018

    • Author(s)
      Shimoaka, Takafumi; Ukai, Hironori; Kurishima, Kana; Takei, Koutaro; Yamada, Norihiro; Hasegawa, Takeshi
    • Journal Title

      J. Phys. Chem. C

      Volume: 122 Issue: 38 Pages: 22018-22023

    • DOI

      10.1021/acs.jpcc.8b07435

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Amyloid-β fibrils assembled on ganglioside-enriched membranes contain both parallel β-sheets and turns2018

    • Author(s)
      Matsubara Teruhiko、Yasumori Hanaki、Ito Koichiro、Shimoaka Takafumi、Hasegawa Takeshi、Sato Toshinori
    • Journal Title

      Journal of Biological Chemistry

      Volume: 293 Issue: 36 Pages: 14146-14154

    • DOI

      10.1074/jbc.ra118.002787

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Robust Surface Plasmon Resonance Chips for Repetitive and Accurate Analysis of Lignin?Peptide Interactions2018

    • Author(s)
      Isozaki Katsuhiro、Shimoaka Takafumi、Oshiro Satoshi、Yamaguchi Asako、Pincella Francesca、Ueno Ryo、Hasegawa Takeshi、Watanabe Takashi、Takaya Hikaru、Nakamura Masaharu
    • Journal Title

      ACS Omega

      Volume: 3 Issue: 7 Pages: 7483-7493

    • DOI

      10.1021/acsomega.8b01161

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Isolation of the simplest hydrated acid2017

    • Author(s)
      Zhang Rui、Murata Michihisa、Wakamiya Atsushi、Shimoaka Takafumi、Hasegawa Takeshi、Murata Yasujiro
    • Journal Title

      Science Advances

      Volume: 3 Issue: 4 Pages: 1602833-1602833

    • DOI

      10.1126/sciadv.1602833

    • NAID

      120006223603

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Optimal Experimental Condition of IR pMAIRS Calibrated by Using an Optically Isotropic Thin Film Exhibiting the Berreman Effect2017

    • Author(s)
      Nobutaka Shioya, Shingo Norimoto, Naoki Izumi, Miyako Hada, Takafumi Shimoaka, Takeshi Hasegawa
    • Journal Title

      Appl. Spectrosc.

      Volume: 印刷中 Issue: 5 Pages: 901-910

    • DOI

      10.1177/0003702816658673

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Accurate Molecular Orientation Analysis Using Infrared pMAIRS Considering the Refractive Index of the Thin Film Sample2017

    • Author(s)
      Nobutaka Shioya, Takafumi Shimoaka, Richard Murdey, Takeshi Hasegawa
    • Journal Title

      Appl. Spectrosc.

      Volume: 印刷中 Issue: 6 Pages: 1242-1248

    • DOI

      10.1177/0003702816676492

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Controlling Mechanism of Molecular Orientation of Poly(3-alkylthiophene) in a Thin Film Revealed by Using pMAIRS2017

    • Author(s)
      Shioya Nobutaka、Shimoaka Takafumi、Eda Kazuo、Hasegawa Takeshi
    • Journal Title

      Macromolecules

      Volume: 50 Issue: 13 Pages: 5090-5097

    • DOI

      10.1021/acs.macromol.7b00826

    • NAID

      120006325171

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Study of Perfluoroalkyl Chain-Specific Band Shift in Infrared Spectra on the Chain Length2017

    • Author(s)
      Shimoaka Takafumi、Sonoyama Masashi、Amii Hideki、Takagi Toshiyuki、Kanamori Toshiyuki、Hasegawa Takeshi
    • Journal Title

      The Journal of Physical Chemistry A

      Volume: 121 Issue: 44 Pages: 8425-8431

    • DOI

      10.1021/acs.jpca.7b08940

    • NAID

      120006364087

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] In Situ Nondestructive Analysis of Kalanchoe pinnata Leaf Surface Structure by Polarization-Modulation Infrared Reflection?Absorption Spectroscopy2017

    • Author(s)
      Hama Tetsuya、Kouchi Akira、Watanabe Naoki、Enami Shinichi、Shimoaka Takafumi、Hasegawa Takeshi
    • Journal Title

      The Journal of Physical Chemistry B

      Volume: 121 Issue: 49 Pages: 11124-11131

    • DOI

      10.1021/acs.jpcb.7b09173

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Open Access
  • [Presentation] 振動分光法で読み解くパーフルオロアルキル化合物の分子集合構造2021

    • Author(s)
      下赤 卓史
    • Organizer
      第2回群馬大学 F-マテリアルプロジェクト研究会
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] ポルフィリン誘導体の中心金属との配位結合を利用した分子配列制御法の確立: pMAIRS法とGIXD法による解析2021

    • Author(s)
      冨田 和孝,塩谷 暢貴,下赤 卓史,長谷川 健
    • Organizer
      日本化学会 第101春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 直鎖アルカンが薄膜中で特異的に示す偶奇効果の消失2021

    • Author(s)
      吉田 茉莉子,塩谷 暢貴,藤井 正道,下赤 卓史,長谷川 健
    • Organizer
      日本化学会 第101春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] ラマン分光法によるパーフルオロアルカン微結晶表面の分子配向解析2021

    • Author(s)
      大槻 眞士,下赤 卓史,塩谷 暢貴,長谷川 健
    • Organizer
      日本化学会 第101春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 気―水界面において特異な集合構造を形成するπ-ゲル化剤薄膜の分子配向解析2021

    • Author(s)
      山口 悠太,下赤 卓史,塩谷 暢貴,AJAYAGHOSH Ayyappanpillai,森 泰蔵,有賀 克彦,長谷川 健
    • Organizer
      日本化学会 第101春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 直鎖アルカンが基板界面で特異的に示す偶奇効果の消失2020

    • Author(s)
      吉田 茉莉子,塩谷 暢貴,藤井 正道,下赤 卓史,長谷川 健
    • Organizer
      2020年度 関西薄膜・表面物理セミナー
    • Related Report
      2020 Annual Research Report
  • [Presentation] テトラフェニルポルフィリン塗布膜の結晶多形制御2020

    • Author(s)
      冨田 和孝,塩谷 暢貴,下赤 卓史,長谷川 健
    • Organizer
      第49回結晶成長国内会議(JCCG-49)
    • Related Report
      2020 Annual Research Report
  • [Presentation] 赤外分光法によるπ-ゲル化剤薄膜の分子配向解析2020

    • Author(s)
      山口 悠太,下赤 卓史,塩谷 暢貴,AJAYAGHOSH Ayyappanpillai,森 泰蔵,有賀 克彦,長谷川 健
    • Organizer
      2020年度 日本分光学会年次講演会
    • Related Report
      2020 Annual Research Report
  • [Presentation] ポルフィリン誘導体の分子間配位結合を利用した分子配向制御: pMAIRS法とGIXD法による構造解析2020

    • Author(s)
      冨田 和孝,塩谷 暢貴,下赤 卓史,長谷川 健
    • Organizer
      2020年度 日本分光学会年次講演会
    • Related Report
      2020 Annual Research Report
  • [Presentation] パーフルオロアルカンが示す表面モードと表面モルフォロジー解析2020

    • Author(s)
      福海 紅希,下赤 卓史,塩谷 暢貴,永井 直人,長谷川 健
    • Organizer
      2020年度 日本分光学会年次講演会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 直鎖アルカンが薄膜中で示す偶奇効果の消失2020

    • Author(s)
      吉田 茉莉子,塩谷 暢貴,藤井 正道,下赤 卓史,長谷川 健
    • Organizer
      2020年度 日本分光学会年次講演会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 赤外分光法による水表面に特異的に残存するパーフルオロアルカンの解析2020

    • Author(s)
      下赤 卓史,福海 紅希,塩谷 暢貴,長谷川 健
    • Organizer
      2020年度 日本分光学会年次講演会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 二次元的な水素結合網とパーフルオロアルキル鎖の凝集力の気水界面単分子膜での競合2020

    • Author(s)
      藤本 洸介,下赤 卓史,塩谷 暢貴,山田 哲弘,長谷川 健
    • Organizer
      第71回コロイドおよび界面化学討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 直鎖アルカンが薄膜中で示す偶奇効果:赤外pMAIRS法による解析2020

    • Author(s)
      吉田 茉莉子,塩谷 暢貴,藤井 正道,下赤 卓史,長谷川 健
    • Organizer
      第81回応用物理学会秋季学術講演会
    • Related Report
      2020 Annual Research Report
  • [Presentation] DNTT前駆体の薄膜に特有な構造転換反応の研究2020

    • Author(s)
      藤井 正道,塩谷 暢貴,冨田 和孝,下赤 卓史,長谷川 健
    • Organizer
      第81回応用物理学会秋季学術講演会
    • Related Report
      2020 Annual Research Report
  • [Presentation] ポルフィリン誘導体の分子間配位結合を利用した分子配向制御2020

    • Author(s)
      冨田 和孝,塩谷 暢貴,下赤 卓史,長谷川 健
    • Organizer
      第81回応用物理学会秋季学術講演会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 高分解能X線回折によるDNTT薄膜相の発見2020

    • Author(s)
      塩谷 暢貴,下赤 卓史,長谷川 健
    • Organizer
      第81回応用物理学会秋季学術講演会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 赤外分光法による気水界面におけるπ-ゲル化剤の分子配向解析2020

    • Author(s)
      山口悠太,下赤卓史,塩谷暢貴,AJAYAGHOSH Ayyappanpillai,森泰蔵,有賀克彦,長谷川健
    • Organizer
      日本化学会 第100春季年会
    • Related Report
      2019 Research-status Report
  • [Presentation] Controlling Technique of Molecular Arrangement of Porphyrin Derivatives in a Thin Film Using Intermolecular Interaction Studied by the pMAIRS and GIXD Techniques2020

    • Author(s)
      Kazutaka Tomita, Nobutaka Shioya, Takafumi Shimoaka, Takeshi Hasegawa
    • Organizer
      日本化学会 第100春季年会
    • Related Report
      2019 Research-status Report
  • [Presentation] 相転移温度から分子の対称性および剛直性の情報を読み解く2020

    • Author(s)
      下赤卓史,長谷川健
    • Organizer
      日本化学会 第100春季年会
    • Related Report
      2019 Research-status Report
  • [Presentation] 膜厚に依存するDNTTの分子パッキング構造の解明2020

    • Author(s)
      塩谷暢貴,下赤卓史,長谷川健
    • Organizer
      第67回応用物理学会春季学術講演会
    • Related Report
      2019 Research-status Report
  • [Presentation] DNTT前駆体の立体異性が前駆体の結晶化およびDNTTへの転化反応に及ぼす影響2020

    • Author(s)
      藤井正道,塩谷暢貴,藤原龍以,冨田和孝,下赤卓史,長谷川健
    • Organizer
      第67回応用物理学会春季学術講演会
    • Related Report
      2019 Research-status Report
  • [Presentation] ポルフィリン誘導体の官能基および中心金属に依存する分子凝集構造の統一的理解2020

    • Author(s)
      冨田和孝,塩谷暢貴,下赤卓史,長谷川健
    • Organizer
      第67回応用物理学会春季学術講演会
    • Related Report
      2019 Research-status Report
  • [Presentation] pMAIRS法を用いたDNTT前駆体薄膜の熱転化反応の解析2019

    • Author(s)
      藤井正道,塩谷暢貴,藤原龍以,冨田和孝,下赤卓史,長谷川健
    • Organizer
      第29回日本MRS年次大会
    • Related Report
      2019 Research-status Report
  • [Presentation] 基板表面特性がペンタセン前駆体薄膜の熱転化反応に及ぼす影響2019

    • Author(s)
      藤原龍以,塩谷暢貴,冨田和孝,下赤卓史,長谷川健
    • Organizer
      第29回日本MRS年次大会
    • Related Report
      2019 Research-status Report
  • [Presentation] 気水界面に吸着したπ-ゲル化剤の分子配向解析2019

    • Author(s)
      山口悠太,下赤卓史,塩谷暢貴,AJAYAGHOSH Ayyappanpillai,森泰蔵,有賀克彦,長谷川健
    • Organizer
      第29回日本MRS年次大会
    • Related Report
      2019 Research-status Report
  • [Presentation] パーフルオロアルカン分子が水表面で示す特殊な分子間相互作用2019

    • Author(s)
      福海紅希,下赤卓史,塩谷暢貴,長谷川健
    • Organizer
      第29回日本MRS年次大会
    • Related Report
      2019 Research-status Report
  • [Presentation] 分子間相互作用を利用したポルフィリン誘導体薄膜の分子配列制御2019

    • Author(s)
      冨田和孝,塩谷暢貴,下赤卓史,長谷川健
    • Organizer
      第29回日本MRS年次大会
    • Related Report
      2019 Research-status Report
  • [Presentation] 相転移温度から読み解く有機フッ素化合物の分子論的な特徴2019

    • Author(s)
      下赤卓史,長谷川健
    • Organizer
      第42回フッ素化学討論会
    • Related Report
      2019 Research-status Report
  • [Presentation] 界面で起こるパーフルオロアルカンの特殊な分子間相互作用2019

    • Author(s)
      福海紅希,下赤卓史,塩谷暢貴,長谷川健
    • Organizer
      第42回フッ素化学討論会
    • Related Report
      2019 Research-status Report
  • [Presentation] 融点に影響を与える分子構造因子2019

    • Author(s)
      下赤卓史,長谷川健
    • Organizer
      第42回溶液化学シンポジウム
    • Related Report
      2019 Research-status Report
  • [Presentation] ポルフィリン誘導体の分子間相互作用に基づく薄膜中の分子配列制御2019

    • Author(s)
      冨田和孝,塩谷暢貴,下赤卓史,長谷川健
    • Organizer
      第80回応用物理学会秋季学術講演会
    • Related Report
      2019 Research-status Report
  • [Presentation] ペンタセンの酸化がペンタセン前駆体の熱転化反応中の薄膜成長へ及ぼす影響2019

    • Author(s)
      藤原龍以,塩谷暢貴,冨田和孝,下赤卓史,長谷川健
    • Organizer
      第80回応用物理学会秋季学術講演会
    • Related Report
      2019 Research-status Report
  • [Presentation] 低分子有機半導体のface-on配向を実現する製膜条件の最適化2019

    • Author(s)
      塩谷暢貴,下赤卓史,長谷川健
    • Organizer
      第80回応用物理学会秋季学術講演会
    • Related Report
      2019 Research-status Report
  • [Presentation] DNTT前駆体の立体異性が薄膜中の構造転換反応に及ぼす影響2019

    • Author(s)
      藤井正道,塩谷暢貴,藤原龍以,冨田和孝,下赤卓史,長谷川健
    • Organizer
      第80回応用物理学会秋季学術講演会
    • Related Report
      2019 Research-status Report
  • [Presentation] プロトン伝導膜中の吸着水および有機フッ素鎖の役割に関する振動分光学的研究2019

    • Author(s)
      下赤卓史
    • Organizer
      日本分析化学会第68年会
    • Related Report
      2019 Research-status Report
    • Invited
  • [Presentation] pMAIRS-CLS法によるペンタセン前駆体の薄膜中における熱転化反応の定量的解析2019

    • Author(s)
      藤原龍以,塩谷暢貴,冨田和孝,下赤卓史,長谷川健
    • Organizer
      第14回有機デバイス・物性院生研究会
    • Related Report
      2019 Research-status Report
  • [Presentation] 湿式薄膜中で のポルフィリン誘導体 の結晶多型制御2019

    • Author(s)
      冨田和孝,塩谷暢貴,下赤卓史,長谷川健
    • Organizer
      第14回有機デバイス・物性院生研究会
    • Related Report
      2019 Research-status Report
  • [Presentation] MAIRS and Chemometrics: Quantitative Pursue of Chemical Reaction in a Thin Film2019

    • Author(s)
      Takeshi Hasegawa, Ryoi Fujiwara, Nobutaka Shioya, Takafumi Shimoaka
    • Organizer
      10th International Conference on Advanced Vibrational Spectroscopy (ICAVS10)
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Understanding Polymorphism of Tetraphenylporphyrin in a Solution Processed Film Using GIXD and pMAIRS Techniques2019

    • Author(s)
      Kazutaka Tomita, Nobutaka Shioya, Takafumi Shimoaka, Takeshi Hasegawa
    • Organizer
      10th International Conference on Advanced Vibrational Spectroscopy (ICAVS10)
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Raman optical activity specifically found on solid samples of perfluoroalkyl compounds having helical conformation and no chiral center2019

    • Author(s)
      Takafumi Shimoaka, Masashi Sonoyama, Hideki Amii, Toshiyuki Takagi, Toshiyuki Kanamori, Takeshi Hasegawa
    • Organizer
      10th International Conference on Advanced Vibrational Spectroscopy (ICAVS10)
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] 第2世代MAIRS(MAIRS2)の基礎と応用2019

    • Author(s)
      塩谷暢貴,下赤卓史,長谷川健
    • Organizer
      サーモフィッシャーサイエンティフィック FT-IR・ラマンユーザーズフォーラム2019
    • Related Report
      2019 Research-status Report
  • [Presentation] ポルフィリン誘導体が薄膜中で示すポリモルフィズムの解明2019

    • Author(s)
      冨田和孝,塩谷暢貴,下赤卓史,長谷川健
    • Organizer
      サーモフィッシャーサイエンティフィック FT-IR・ラマンユーザーズフォーラム2019
    • Related Report
      2019 Research-status Report
  • [Presentation] 水面と一体化するフッ素系溶媒:赤外外部反射法による解析2019

    • Author(s)
      福海紅希,下赤卓史,塩谷暢貴,長谷川健
    • Organizer
      サーモフィッシャーサイエンティフィック FT-IR・ラマンユーザーズフォーラム2019
    • Related Report
      2019 Research-status Report
  • [Presentation] pMAIRS-CLS法によるペンタセン前駆体の薄膜中における熱転化反応の定量的解析2019

    • Author(s)
      藤原龍以,塩谷暢貴,冨田和孝,下赤卓史,長谷川健
    • Organizer
      サーモフィッシャーサイエンティフィック FT-IR・ラマンユーザーズフォーラム2019
    • Related Report
      2019 Research-status Report
  • [Presentation] 固体試料表面の高感度ラマン光学活性解析2019

    • Author(s)
      下赤卓史,長谷川健
    • Organizer
      サーモフィッシャーサイエンティフィック FT-IR・ラマンユーザーズフォーラム2019
    • Related Report
      2019 Research-status Report
  • [Presentation] 有機半導体薄膜の分子配向を決める製膜因子の分光学的検討2019

    • Author(s)
      塩谷暢貴,下赤卓史,長谷川健
    • Organizer
      令和元年度日本分光学会年次講演会
    • Related Report
      2019 Research-status Report
  • [Presentation] pMAIRS法を利用した薄膜中の化学種定量2019

    • Author(s)
      藤原龍以,塩谷暢貴,冨田和孝,下赤卓史,長谷川健
    • Organizer
      令和元年度日本分光学会年次講演会
    • Related Report
      2019 Research-status Report
  • [Presentation] pMAIRS法とGIXD法を用いたポルフィリン誘導体が塗布膜中で示すポリモルフィズムの解明2019

    • Author(s)
      冨田和孝,塩谷暢貴,下赤卓史,長谷川健
    • Organizer
      令和元年度日本分光学会年次講演会
    • Related Report
      2019 Research-status Report
  • [Presentation] 有機フッ素化合物の分子集合構造を読み解く振動分光法の開拓2019

    • Author(s)
      下赤卓史
    • Organizer
      令和元年度日本分光学会年次講演会
    • Related Report
      2019 Research-status Report
    • Invited
  • [Presentation] Optical and Structural Anisotropy in Pentacene Thin Films Revealed by pMAIRS2019

    • Author(s)
      Nobutaka Shioya, Takafumi Shimoaka, Takeshi Hasegawa
    • Organizer
      2019 MRS Spring Meeting
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] パーフルオロアルキル鎖を有する両親媒性分子の凝集支配因子の赤外分光法による検討2018

    • Author(s)
      下赤卓史,鵜飼裕紀,山田哲弘,長谷川健
    • Organizer
      平成30年度 日本分光学会年次講演会
    • Related Report
      2018 Research-status Report
  • [Presentation] ラマン分光イメージング法による固体試料表面の光学異性体の識別2018

    • Author(s)
      下赤卓史,長谷川健
    • Organizer
      サーモフィッシャーサイエンティフィック FT-IR・ラマンユーザーズフォーラム2018
    • Related Report
      2018 Research-status Report
  • [Presentation] パーフルオロアルキル鎖特有のねじれ構造に起因するアトロプ異性体のラマン分光イメージング法による識別2018

    • Author(s)
      下赤卓史,園山正史,網井秀樹,高木俊之,金森敏幸,長谷川健
    • Organizer
      日本分析化学会 第67年会
    • Related Report
      2018 Research-status Report
  • [Presentation] 赤外分光法で読み解く機能性有機薄膜の分子配向2018

    • Author(s)
      下赤卓史
    • Organizer
      膜工学サロン
    • Related Report
      2018 Research-status Report
    • Invited
  • [Presentation] パーフルオロアルキル鎖のねじれ構造に起因するアトロプ異性のラマン分光法による識別2018

    • Author(s)
      下赤卓史,園山正史,網井秀樹,高木俊之,金森敏幸,長谷川健
    • Organizer
      第41回フッ素化学討論会
    • Related Report
      2018 Research-status Report
  • [Presentation] 固体試料のROA解析:パーフルオロアルキル化合物のアトロプ異性の識別をめざして2018

    • Author(s)
      下赤卓史
    • Organizer
      先端的レーザー分光の若手シンポジウム
    • Related Report
      2018 Research-status Report
    • Invited
  • [Presentation] 相転移温度から読み解く有機フッ素化合物特有の分子論的性質2018

    • Author(s)
      日本化学会第99春季年会
    • Organizer
      下赤卓史,長谷川健
    • Related Report
      2018 Research-status Report
  • [Presentation] パーフルオロアルキル鎖のCF伸縮振動バンドが赤外スペクトルに示す特異な鎖長依存性の解明2017

    • Author(s)
      下赤卓史,長谷川健
    • Organizer
      日本分光学会年次講演会
    • Related Report
      2017 Research-status Report
  • [Presentation] Unusual band shift specifically found for the CF stretching vibration on the chain length of a perfluoroalkyl group2017

    • Author(s)
      Takafumi Shimoaka, Masashi Sonoyama, Hideki Amii, Toshiyuki Takagi, Toshiyuki Kanamori, Takeshi Hasegawa
    • Organizer
      ICAVS9
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Quantitative Molecular Orientation Analysis in Organic Semiconductor Thin Films Having a Rough Surface by pMAIRS2017

    • Author(s)
      Takafumi Shimoaka, Nobutaka Shioya, Miyako Hada and Takeshi Hasegawa
    • Organizer
      SciX 2017
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] パーフルオロアルキル鎖の分子凝集力は水素結合をしのぐか?2017

    • Author(s)
      下赤卓史,鵜飼裕紀,山田哲弘,長谷川健
    • Organizer
      第40回フッ素化学討論会
    • Related Report
      2017 Research-status Report
  • [Presentation] ラマン分光法によるパーフルオロアルキル鎖のねじれ構造解析2017

    • Author(s)
      下赤卓史,園山正史,網井秀樹,高木俊之,金森敏幸,長谷川健
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Research-status Report
  • [Remarks] 研究室ホームページ

    • URL

      http://www.scl.kyoto-u.ac.jp/~yoeki/

    • Related Report
      2020 Annual Research Report
  • [Remarks] 所属研究室HP

    • URL

      https://www.scl.kyoto-u.ac.jp/~yoeki/

    • Related Report
      2019 Research-status Report
  • [Remarks] 所属研究室facebook

    • URL

      https://www.facebook.com/thinfilms

    • Related Report
      2019 Research-status Report
  • [Remarks] 研究室ホームページ

    • URL

      https://www.scl.kyoto-u.ac.jp/~yoeki/

    • Related Report
      2018 Research-status Report
  • [Remarks] 京都大学化学研究所 分子環境解析化学領域

    • URL

      http://www.scl.kyoto-u.ac.jp/~yoeki/

    • Related Report
      2017 Research-status Report

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Published: 2017-04-28   Modified: 2022-01-27  

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