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Creation of polymer network materials utilizing intercalation properties of layered inorganic compounds

Research Project

Project/Area Number 17K14537
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Polymer/Textile materials
Research InstitutionUtsunomiya University

Principal Investigator

Tamesue Shingo  宇都宮大学, 工学部, 助教 (10611767)

Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2019: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2018: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2017: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Keywordsヒドロゲル / 高分子ゲル / 自己修復ゲル / 接着 / ソフトマテリアル / 機能性材料 / 自己修復 / インターカレーション / ゲル材料 / 高分子 / 超分子 / ネットワーク材料 / 高分子構造・物性 / 高分子合成 / 複合材料・物性 / 超分子化学 / 生体材料
Outline of Final Research Achievements

Layered inorganic compounds are formed from multiple stacked inorganic layers. Many of them have unique functions, e.g. 'intercalation', via which layered inorganic compounds entrap various guest compounds into their layers. In this research, we developed some adhesive hydrogel systems using this 'intercalation' properties of layered inorganic compounds. Furthermore, we developed an adhesive hydrogel system which adheres various hydrogel materials via in-situ synthesis of linear polymers inside hydrogel networks applying these adhesive systems using intercalations.

Academic Significance and Societal Importance of the Research Achievements

コンニャクなどの水を大量に含んだ高分子、低分子からなるヒドロゲル材料は、柔軟性と弾力、そして水を大量に含むことから人工筋肉、人工軟骨などへの利用が期待されている。しかし、体内でヒドロゲルを体内で利用するためには簡便かつ強度の高く、汎用性の高いヒドロゲル同士、ヒドロゲルと生体組織間の接着手法の開発が必要である。本研究では、層状無機化合物のインターカレーションという内部に物質を取り込む性質を用いて簡便かつ強固にヒドロゲル材料の接着に成功した。そして高分子ゲルネットワークの構造を変化させ、接着強度などの比較を行い、より最適なヒドロゲル材料の構造を明らかにした。

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Research-status Report
  • 2017 Research-status Report
  • Research Products

    (19 results)

All 2020 2019 2018 2017

All Journal Article (4 results) (of which Peer Reviewed: 4 results) Presentation (12 results) (of which Int'l Joint Research: 1 results,  Invited: 3 results) Book (3 results)

  • [Journal Article] Sewing Hydrogels: Adhesion of Hydrogels Utilizing in Situ Polymerization of Linear Polymers inside Gel Networks2019

    • Author(s)
      Tamesue Shingo、Endo Takuo、Ueno Yuma、Tsurumaki Fumiya
    • Journal Title

      Macromolecules

      Volume: 52 Issue: 15 Pages: 5690-5697

    • DOI

      10.1021/acs.macromol.9b01084

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Adhesive Hydrogel System Based on the Intercalation of Anionic Substituents into Layered Double Hydroxides2018

    • Author(s)
      Tamesue Shingo、Yasuda Kento、Endo Takuo
    • Journal Title

      ACS Applied Materials & Interfaces

      Volume: 10 Issue: 35 Pages: 29925-29932

    • DOI

      10.1021/acsami.8b09136

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Reversing Redox Responsiveness of Hydrogels due to Supramolecular Interactions by Utilizing Double-Network Structures2018

    • Author(s)
      Tamesue Shingo、Noguchi Shingo、Kimura Yuko、Endo Takuo
    • Journal Title

      ACS Applied Materials & Interfaces

      Volume: 10 Issue: 32 Pages: 27381-27390

    • DOI

      10.1021/acsami.8b10001

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Logic gate aggregation of poly(N-isopropylacrylamide) nanogels with catechol substituents that respond to body heat2018

    • Author(s)
      Tamesue Shingo、Abe Shinji、Endo Takuo、Yamauchi Takeshi
    • Journal Title

      Polymer Journal

      Volume: 印刷中 Issue: 7 Pages: 503-510

    • DOI

      10.1038/s41428-018-0042-x

    • NAID

      40021575847

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Presentation] ゲル内でのその場重合によるヒドロゲルの接着2020

    • Author(s)
      為末真吾
    • Organizer
      第100回日本化学会春季年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] トリチオカルボネート形成によるオルガノゲルの接着とその機能2020

    • Author(s)
      上野佑真, 大庭亨, 為末真吾
    • Organizer
      第100回日本化学会春季年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] インターカレーションを利用した高強度超分子ゲルの作製2020

    • Author(s)
      寺井孟, 大庭亨, 為末真吾
    • Organizer
      第100回日本化学会春季年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 層状無機化合物のインターカレーションを利用した塩存在下でも自己修復するゲルの開発2020

    • Author(s)
      齋藤佑槙, 大庭亨, 為末真吾
    • Organizer
      第100回日本化学会春季年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] チオール-エン反応によって機能を事後修飾可能な多分化能ゲル2020

    • Author(s)
      弦巻史哉, 大庭亨, 為末真吾
    • Organizer
      第100回日本化学会春季年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 直鎖状高分子を用いた縫合によるヒドロゲル間の接着2019

    • Author(s)
      為末真吾
    • Organizer
      第99回日本化学会春季年会
    • Related Report
      2019 Annual Research Report 2018 Research-status Report
  • [Presentation] Adhesive Hydrogel Systems Utilizing Supramolecular Interactions and Macromolecular Structures2019

    • Author(s)
      Shingo Tamesue
    • Organizer
      APSMR 2019 Annual Meeting
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Adhering hydrogel systems utilizing in-situ polymerization of linear polymers inside gel networks2019

    • Author(s)
      Shingo Tamesue
    • Organizer
      第29回MRS-J年次大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Adhesive Hydrogel Systems Based On Intercalation Properties of Layered Inorganic Compounds.2018

    • Author(s)
      為末真吾
    • Organizer
      第28回MRS-J年次大会
    • Related Report
      2018 Research-status Report
  • [Presentation] Adhesive Hydrogel Systems Utilizing various interactions2018

    • Author(s)
      為末真吾
    • Organizer
      KSIEC2018
    • Related Report
      2018 Research-status Report
    • Invited
  • [Presentation] Adhesion between hydrogel materials utilizing various interactions.2017

    • Author(s)
      為末真吾
    • Organizer
      第27回日本MRS年次大会
    • Related Report
      2017 Research-status Report
    • Invited
  • [Presentation] 直鎖状高分子のin situ重合を用いた生体組織とヒドロゲルの接着2017

    • Author(s)
      為末真吾、遠藤拓生
    • Organizer
      第98回日本化学会春季年会
    • Related Report
      2017 Research-status Report
  • [Book] 自己修復材料:自己組織化、形状記憶材料の開発と応用事例「物質内への超分子結合の組込みによる自己修復マテリアルの開発」2020

    • Author(s)
      為末真吾
    • Total Pages
      446
    • Publisher
      技術情報協会出版社
    • ISBN
      9784861047817
    • Related Report
      2019 Annual Research Report
  • [Book] 次世代のポリマー・高分子開発、新しい用途展開と将来展望2019

    • Author(s)
      為末真吾
    • Total Pages
      608
    • Publisher
      技術情報協会
    • ISBN
      9784861047381
    • Related Report
      2018 Research-status Report
  • [Book] A Novel Grafting of Polymers onto the Surface of Graphene Oxide2017

    • Author(s)
      Norio Tsubokawa, Takeshi Yamauchi, Kazuhiro Fujiki and Shingo Tamesue
    • Total Pages
      25
    • Publisher
      InTech
    • Related Report
      2017 Research-status Report

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Published: 2017-04-28   Modified: 2021-02-19  

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