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Development of osmotic heat engine using temperature phase transition materials as working fluid

Research Project

Project/Area Number 17K14851
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Properties in chemical engineering process/Transfer operation/Unit operation
Research InstitutionNihon University (2018)
Kobe University (2017)

Principal Investigator

TAKAHASHI Tomoki  日本大学, 生産工学部, 助教 (80535518)

Project Period (FY) 2017-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2018: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2017: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywordsオスモティックヒートエンジン / 浸透圧発電 / 温度相転移材料 / 正浸透膜 / 駆動溶液 / 正浸透法 / 低品位排熱
Outline of Final Research Achievements

In an industrial field and power plant, most of the low-grade heat are unused, and their thermal energy is huge quantities. Therefore power generation with low-grade heat is necessary. We focused on the osmotic heat engine (OHE). OHE is the pressure retard osmosis which generates power from osmotic pressure difference between solutions combined with thermal regeneration. In this study, LCST-type phase transition materials which is separated into dense phase and dilute phase by heating were used. We established the method to predict power generating performance of OHE and investigated it. We also simulated the power generating performances by changing the various parameters such as membrane characteristics. Consequently, the simulation provided a better knowledge for not only membrane characteristics, but also characteristics of LCST-type materials. Moreover, power generating performance of OHE and binary power generation in case of using same heat source were compared.

Academic Significance and Societal Importance of the Research Achievements

日本国内の発電所や工場における排熱の合計は年間1兆kWhとも言われており、これは日本の年間総発電量とほぼ同じである。さらに、環太平洋火山帯に位置する日本の地熱発電ポテンシャルは53~120℃の温度域だけでも年間7兆kWh以上の膨大な地熱資源量を誇る。これらの膨大な未利用熱エネルギーから高効率で電力を生み出すことが出来れば、日本のエネルギー安定供給の実現に貢献するものと考えられる。加えて、本研究により開発される高性能なDSは、正浸透膜法を用いた省エネ型水処理技術への応用展開も可能であり、市場規模110兆円(2025年)と言われている水処理産業へ及ぼす経済的波及効果も期待される。

Report

(3 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Research-status Report
  • Research Products

    (20 results)

All 2019 2018 2017

All Journal Article (4 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 4 results,  Open Access: 3 results) Presentation (16 results) (of which Int'l Joint Research: 3 results)

  • [Journal Article] Development of thermoresponsive star oligomers with a glycerol backbone as the draw solute in forward osmosis process2019

    • Author(s)
      A. Inada, K. Yumiya, T. Takahashi, K. Kumagai, Y. Hashizume, H. Matsuyama
    • Journal Title

      Journal of Membrane Science

      Volume: 574 Pages: 147-153

    • DOI

      10.1016/j.memsci.2018.12.067

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Fundamental investigation of osmolality, thermo-responsive phase diagram, and waterdrawing ability of ionic-liquid-based draw solution for forward osmosis membrane process2019

    • Author(s)
      E. Kamio, A. Takenaka, T. Takahashi, H. Matsuyama
    • Journal Title

      Journal of Membrane Science

      Volume: 570-571 Pages: 93-102

    • DOI

      10.1016/j.memsci.2018.10.004

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Development of high-flux and robust reinforced aliphatic polyketone thin-film composite membranes for osmotic power generation: The role of reinforcing materials2018

    • Author(s)
      Y. Sun, L. Cheng, T. Shintani, Y. Tanaka, T. Takahashi, T. Itai, S. Wang, L.F. Fang, H. Matsuyama
    • Journal Title

      Industrial & Engineering Chemistry Research

      Volume: 57 Issue: 40 Pages: 13528-13538

    • DOI

      10.1021/acs.iecr.8b03392

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Fundamental Study on Pressure-retarded Osmosis Using Ultrafiltration Membranes and Polymer Draw Solution2017

    • Author(s)
      T. Takahashi, M. Yasukawa, H. Matsuyama
    • Journal Title

      Bull. Soc. Sea Water Sci., Jpn.

      Volume: 71(6) Pages: 346-347

    • NAID

      130007494802

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Presentation] 温度応答性モルフォリン誘導体の相分離性評価と正浸透法への応用2019

    • Author(s)
      稲田飛鳥, 高橋智輝, 熊谷和夫, 松山秀人
    • Organizer
      化学工学会第84年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 駆動溶液に用いる温度応答性を付与した多分岐ポリマーの開発2018

    • Author(s)
      弓矢健一郎, 稲田飛鳥, 高橋智輝, 橋爪陽子, 松山秀人
    • Organizer
      日本膜学会第40年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 温度/二酸化炭素応答性を示すデンドリマー型正浸透駆動溶質の分子設計および機能制御2018

    • Author(s)
      高橋智輝, 西森塩穂美, 浜田豊三, 松山秀人
    • Organizer
      日本海水学会第69年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 正浸透プロセスに向けたグリセロール骨格を有する温度応答性ドロー溶質の開発2018

    • Author(s)
      弓矢健一郎, 稲田飛鳥, 高橋智輝, 橋爪陽子, 松山秀人
    • Organizer
      第7回JACI/GSCシンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] Development and evaluation of thermal/CO2 dual responsive dendrimers as draw solute for forward osmosis2018

    • Author(s)
      Asuka INADA, Shihomi NISHIMORI, Tomoki TAKAHASHI, Toyozo HAMADA, Hideto MATSUYAMA
    • Organizer
      the 11th conference of the Aseanian Membrane Society (AMS11)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Development of novel fabric reinforced aliphatic polyketone-based thin-film composite membranes for osmotic power generation2018

    • Author(s)
      Yuchen SUN, Liang Cheng, Takuji Shintani, Yasuhiro Tanaka, Tomoki Takahashi, Takuya Itai, Shengyao Wang, Lifeng Fang, Hideto Matsuyama
    • Organizer
      the 11th conference of the Aseanian Membrane Society (AMS11)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Development of polyamide thin-film composite membrane using novel porous support for organic solvent treatment2018

    • Author(s)
      Takuji SHINTANI, Yuki NAKAGAWA, Tomoki TAKAHASHI, Keizo NAKAGAWA, Hideto MATSUYAMA, Tomohisa YOSHIOKA
    • Organizer
      the 11th conference of the Aseanian Membrane Society (AMS11)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 正浸透膜プロセスに用いる温度相転移物質の会合挙動が浸透圧に及ぼす影響2018

    • Author(s)
      栗栖宏樹, 高橋智輝, 吉岡朋久, 神尾英治, 稲田飛鳥, 松山秀人
    • Organizer
      化学工学会第50回秋季大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 温度応答性ポリグリセロール誘導体を用いた駆動溶液の開発2018

    • Author(s)
      弓矢健一郎, 稲田飛鳥, 高橋智輝, 橋爪陽子, 松山秀人
    • Organizer
      化学工学会第50回秋季大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 正浸透膜法の駆動溶液に用いる温度応答性イオン液体の会合挙動に関する検討2018

    • Author(s)
      栗栖宏樹, 高橋智輝, 吉岡朋久, 松山秀人
    • Organizer
      第5回海水・生活・化学連携シンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] 温度/二酸化炭素二重応答性デンドリマーの開発と正浸透膜法への応用2018

    • Author(s)
      高橋智輝、西森塩穂美、浜田豊三、松山秀人
    • Organizer
      第5回海水・生活・化学連携シンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] 正浸透法における駆動溶液に用いる最適な温度応答性イオン液体の創製と評価2018

    • Author(s)
      稲田飛鳥, 栗栖宏樹, 神尾英治, 高橋智輝, 松山秀人
    • Organizer
      膜シンポジウム2018
    • Related Report
      2018 Annual Research Report
  • [Presentation] 正浸透法利用を指向した温度/二酸化炭素二重応答性デンドリマーの開発2018

    • Author(s)
      高橋智輝、西森塩穂美、浜田豊三、松山秀人
    • Organizer
      第28回日本MRS年次大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 閉鎖型浸透圧発電の連続運転に向けた基礎的検討2017

    • Author(s)
      板井 拓也, 高橋 智輝, 松山 秀人
    • Organizer
      化学工学会第49回秋季大会
    • Related Report
      2017 Research-status Report
  • [Presentation] 三成分系温度相転移を利用した閉鎖型浸透圧発電2017

    • Author(s)
      板井 拓也, 高橋 智輝, 松山 秀人
    • Organizer
      膜シンポジウム2017
    • Related Report
      2017 Research-status Report
  • [Presentation] LCST型相転移材料を作用媒体とするオスモティックヒートエンジンの発電ポテンシャル評価2017

    • Author(s)
      板井 拓也, 高橋 智輝, 松山 秀人
    • Organizer
      化学工学会第83年会
    • Related Report
      2017 Research-status Report

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Published: 2017-04-28   Modified: 2020-03-30  

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