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Photoreduction of carbon dioxide using porous glass nanocavity under ambient condition

Research Project

Project/Area Number 17K18013
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Physical chemistry
Bio-related chemistry
Research InstitutionThe University of Tokyo (2018-2022)
Osaka City University (2017)

Principal Investigator

Noji Tomoyasu  東京大学, 先端科学技術研究センター, 助教 (40452205)

Project Period (FY) 2017-04-01 – 2023-03-31
Project Status Completed (Fiscal Year 2022)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2019: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2018: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2017: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Keywords光合成 / 人工光合成 / 水素発生 / ギ酸生成 / 多孔質ガラス板 / 光化学系I / ロドプシン / エネルギー移動 / 吸収波長制御 / 量子化学計算 / フィコビリソーム / 励起エネルギー移動 / 光捕集アンテナ / 多孔質 / ガラス / ギ酸 / 光水素発生 / 嫌気 / 再生可能 / 光触媒 / デバイス / 多孔体 / 生体材料 / 再生可能エネルギー
Outline of Final Research Achievements

To realize a renewable energy society, it is necessary to develop artificial photosynthesis that converts carbon dioxide and hydrogen ions into formic acid and hydrogen as fuel sources. In this study, by introducing a photoreaction system consisting of a photosensitizer, an electron transfer agent, and an enzyme into a glass plate with pores of nm-order (porous glass plate), we have developed, clarified the mechanism of, and improved a device that can produce formic acid from carbon dioxide by creating oxygen-free nanospaces with light even under atmospheric conditions. We reported that the energy from the light-harvesting antenna to the photosystem I that is useful as a photosensitizer, occurs with 95% efficiency. To control a wavelength of absorbance of a protein, we elucidated the mechanism by which the absorption wavelength of bacteriorhodopsin, whose absorption wavelength varies in a photoreaction.

Academic Significance and Societal Importance of the Research Achievements

再生可能で持続可能なエネルギー社会の実現のため、様々な触媒を利用した人工光合成が報告されている。しかし、大気下では酸素に反応を阻害される事が、大きな問題の一つである。純度の高い二酸化炭素や不活性化ガスで酸素を除くとコストが掛かり、人工光合成を実現できない。酸素大気下で運用できるシステムの開発が必要である。このような課題に対して、これまでに申請者は、数十nm の細孔を持つガラス板(多孔質ガラス板)の中に、光反応系を導入することで、「大気下においても、酸素の無いナノ空間を光で作り、二酸化炭素をギ酸に変化する」デバイスを開発した。本研究では、その機構解明と効率改善に関する研究を行った。

Report

(7 results)
  • 2022 Annual Research Report   Final Research Report ( PDF )
  • 2021 Research-status Report
  • 2020 Research-status Report
  • 2019 Research-status Report
  • 2018 Research-status Report
  • 2017 Research-status Report
  • Research Products

    (28 results)

All 2022 2021 2020 2019 2018 2017

All Journal Article (13 results) (of which Int'l Joint Research: 4 results,  Peer Reviewed: 13 results,  Open Access: 6 results) Presentation (15 results) (of which Int'l Joint Research: 2 results,  Invited: 1 results)

  • [Journal Article] Mechanism of Absorption Wavelength Shift of Bacteriorhodopsin During Photocycle2022

    • Author(s)
      Noji Tomoyasu、Ishikita Hiroshi
    • Journal Title

      The Journal of Physical Chemistry B

      Volume: 126 Issue: 48 Pages: 9945-9955

    • DOI

      10.1021/acs.jpcb.2c04359

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Energy transfer dynamics and the mechanism of biohybrid photosynthetic antenna complexes chemically linked with artificial chromophores2022

    • Author(s)
      Yoneda Yusuke、Noji Tomoyasu、Mizutani Naoto、Kato Daiji、Kondo Masaharu、Miyasaka Hiroshi、Nagasawa Yutaka、Dewa Takehisa
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: 24 Issue: 40 Pages: 24714-24726

    • DOI

      10.1039/d2cp02465a

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Direct Energy Transfer from Allophycocyanin-Free Rod-Type CpcL-Phycobilisome to Photosystem I2021

    • Author(s)
      Tomoyasu Noji, Mai Watanabe, Takehisa Dewa, Shigeru Itoh, Masahiko Ikeuchi
    • Journal Title

      J. Phys. Chem. Lett.

      Volume: 12 Issue: 28 Pages: 6692-6697

    • DOI

      10.1021/acs.jpclett.1c01763

    • Related Report
      2021 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] A sublethal ATP11A mutation associated with neurological deterioration causes aberrant phosphatidylcholine flipping in plasma membranes2021

    • Author(s)
      Segawa Katsumori、21人、Nagata Shigekazu
    • Journal Title

      Journal of Clinical Investigation

      Volume: 131 Issue: 18 Pages: 1-17

    • DOI

      10.1172/jci148005

    • Related Report
      2021 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Mechanism of absorption wavelength shifts in anion channelrhodopsin-1 mutants2021

    • Author(s)
      Tsujimura Masaki、Noji Tomoyasu、Saito Keisuke、Kojima Keiichi、Sudo Yuki、Ishikita Hiroshi
    • Journal Title

      Biochimica et Biophysica Acta (BBA) - Bioenergetics

      Volume: 1862 Issue: 2 Pages: 148349-148349

    • DOI

      10.1016/j.bbabio.2020.148349

    • Related Report
      2020 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Photocatalytic activity of the light-harvesting complex of photosystem II (LHCII) monomer2021

    • Author(s)
      Kondo Masaharu、Matsuda Haruka、Noji Tomoyasu、Nango Mamoru、Dewa Takehisa
    • Journal Title

      Journal of Photochemistry and Photobiology A: Chemistry

      Volume: 406 Pages: 112926-112926

    • DOI

      10.1016/j.jphotochem.2020.112926

    • Related Report
      2020 Research-status Report
    • Peer Reviewed
  • [Journal Article] Design of PG-surfactants bearing polyacrylamide polymer chain to solubilize membrane proteins in a surfactant-free buffer2021

    • Author(s)
      Taro Shimamoto, Tatsuki Nakakubo, Tomoyasu Noji, Shuhei Koeda, Keisuke Kawakami, Nobuo Kamiya, Toshihisa Mizuno
    • Journal Title

      International Journal of Molecular Sciences

      Volume: 22 Issue: 4 Pages: 1524-1524

    • DOI

      10.3390/ijms22041524

    • Related Report
      2020 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Green-Sensitive, Long-Lived, Step-Functional Anion Channelrhodopsin-2 Variant as a High-Potential Neural Silencing Tool2020

    • Author(s)
      Kojima Keiichi、Miyoshi Natsuki、Shibukawa Atsushi、Chowdhury Srikanta、Tsujimura Masaki、Noji Tomoyasu、Ishikita Hiroshi、Yamanaka Akihiro、Sudo Yuki
    • Journal Title

      The Journal of Physical Chemistry Letters

      Volume: 11 Issue: 15 Pages: 6214-6218

    • DOI

      10.1021/acs.jpclett.0c01406

    • Related Report
      2020 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Vectorial Proton Transport Mechanism of RxR, a Phylogenetically Distinct and Thermally Stable Microbial Rhodopsin2020

    • Author(s)
      Kojima Keiichi、Ueta Tetsuya、Noji Tomoyasu、Saito Keisuke、Kanehara Kanae、Yoshizawa Susumu、Ishikita Hiroshi、Sudo Yuki
    • Journal Title

      Scientific Reports

      Volume: 10 Issue: 1 Pages: 1-11

    • DOI

      10.1038/s41598-019-57122-2

    • NAID

      120006884916

    • Related Report
      2019 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Synthesis and characterization of chemically-reactive solubilization surfactants for membrane proteins and preparation of membrane protein hydrogel microfibers2019

    • Author(s)
      Taniguchi Aki、Koeda Shuhei、Noji Tomoyasu、Kawakami Keisuke、Sumito Natsumi、Dewa Takehisa、Itoh Shigeru、Kamiya Nobuo、Mizuno Toshihisa
    • Journal Title

      Colloid and Interface Science Communications

      Volume: 32 Pages: 100199-100199

    • DOI

      10.1016/j.colcom.2019.100199

    • Related Report
      2019 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Anti-Stokes fluorescence from chlorophyll a2019

    • Author(s)
      Emura Hidetoshi、Noji Tomoyasu、Kondo Masaharu、Amao Yutaka、Sugisaki Mitsuru
    • Journal Title

      Journal of Physics: Conference Series

      Volume: 1220 Issue: 1 Pages: 012043-012043

    • DOI

      10.1088/1742-6596/1220/1/012043

    • Related Report
      2019 Research-status Report
    • Peer Reviewed
  • [Journal Article] Enhancement of Photocurrent by Integration of an Artificial Light-Harvesting Antenna with a Photosystem I Photovoltaic Device2019

    • Author(s)
      Takekuma Yuya、Nagakawa Haruki、Noji Tomoyasu、Kawakami Keisuke、Furukawa Rei、Nango Mamoru、Kamiya Nobuo、Nagata Morio
    • Journal Title

      ACS Applied Energy Materials

      Volume: - Issue: 6 Pages: 3986-3990

    • DOI

      10.1021/acsaem.9b00349

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Efficient hydrogen production using photosystem I enhanced by artificial light harvesting dye2019

    • Author(s)
      Nagakawa Haruki、Takeuchi Ayano、Takekuma Yuya、Noji Tomoyasu、Kawakami Keisuke、Kamiya Nobuo、Nango Mamoru、Furukawa Rei、Nagata Morio
    • Journal Title

      Photochemical & Photobiological Sciences

      Volume: 18 Issue: 2 Pages: 309-313

    • DOI

      10.1039/c8pp00426a

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] Shifting mechanism of absorption energy in intermediate states of bacteriorhodopsin2022

    • Author(s)
      Tomoyasu Noji, Hiroshi Ishikita
    • Organizer
      The 22nd Annual Meeting of the Protein Science Society of Japan
    • Related Report
      2022 Annual Research Report
  • [Presentation] バクテリオロドプシンにおける中間体の吸収波長変化の機構2021

    • Author(s)
      野地 智康, 石北 央
    • Organizer
      第28回 光合成セミナー2021
    • Related Report
      2021 Research-status Report
  • [Presentation] レチナールタンパク質の吸収波長制御機構の解明2019

    • Author(s)
      野地 智康、斉藤 圭亮、田村 宏之、石北 央
    • Organizer
      第19回東京大学生命科学シンポジウム
    • Related Report
      2019 Research-status Report
  • [Presentation] レチナールタンパク質の吸収波長制御機構の解明2019

    • Author(s)
      野地 智康、斉藤 圭亮、田村 宏之、石北 央
    • Organizer
      第46回生体分子科学討論会
    • Related Report
      2019 Research-status Report
  • [Presentation] タンパク質環境によるレチナール分子の吸収波長制御機構の解明2019

    • Author(s)
      野地 智康、斉藤 圭亮、田村 宏之、石北 央
    • Organizer
      第27回「光合成セミナー2019」
    • Related Report
      2019 Research-status Report
  • [Presentation] アニオンチャネルロドプシンの変異体の吸収波長予測方法の評価2019

    • Author(s)
      野地 智康,辻村 真樹, 小島 慧一,斉藤 圭亮, 須藤 雄気, 石北 央
    • Organizer
      「ファイバーレス光遺伝学による高次脳機能を支える本能機能の解明」 第4回ワークショップ
    • Related Report
      2019 Research-status Report
  • [Presentation] 多孔質ガラス板のナノ空間と光合成膜タンパク質を利用した人工光合成系の構築2018

    • Author(s)
      野地 智康
    • Organizer
      東京工業大学 理学院 化学系 石谷・前田研究室
    • Related Report
      2018 Research-status Report
    • Invited
  • [Presentation] 光化学系IIの蛍光量子収率の励起光量依存性、pH依存性2018

    • Author(s)
      野地 智康, 大幸 昇平, 川上 恵典, 神谷 信夫
    • Organizer
      新学術領域「革新的光-物質変換」第一回領域会議
    • Related Report
      2018 Research-status Report
  • [Presentation] 多孔質ガラス板への光化学系I/IIの3次元的固定と量子効率2018

    • Author(s)
      野地 智康, 池田 有佑, 平野 誠, 川上 恵典, 神 哲郎, 神谷 信夫
    • Organizer
      新学術領域「革新的光-物質変換」第一回領域会議
    • Related Report
      2018 Research-status Report
  • [Presentation] 光化学系IIとガラスナノ空間を利用した高効率キノン光還元系の構築2018

    • Author(s)
      野地 智康, 池田 有佑, 川上 恵典, 神 哲郎, 神谷 信夫
    • Organizer
      第16回ナノ学会
    • Related Report
      2018 Research-status Report
  • [Presentation] Function of light-driven water-splitting device immobilizing photosystem II inside porous glass plate2018

    • Author(s)
      Noji Tomoyasu, Ikeda Yusuke, Kawakami Keisuke, Jin Tetsuro, Kamiya Nobuo
    • Organizer
      植物生理学会
    • Related Report
      2017 Research-status Report
  • [Presentation] Function of light-driven water-splitting device immobilizing photosystem II inside porous glass plate2018

    • Author(s)
      Noji Tomoyasu, Ikeda Yusuke, Kawakami Keisuke, Jin Tetsuro, Kamiya Nobuo
    • Organizer
      9th OCARINA International Symposium
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] クロスリンカーを用いたcytc6/光化学系I/白金ナノ粒子複合体による光誘起水素発生2017

    • Author(s)
      平野 誠人、野地 智康、川上 恵典、神 哲郎、吉野 宏明、池内 昌彦、近藤 政晴、大岡 宏造、神谷 信夫
    • Organizer
      光合成学会
    • Related Report
      2017 Research-status Report
  • [Presentation] Light-induced hydrogen production by photosystem I-Pt nanoparticle immobilized in porous glass plate nanopores2017

    • Author(s)
      Makoto Hirano, Tomoyasu Noji, Keisuke Kawakami, Teturo Jin, Masaharu Kondo, Hirozo Oh-oka, Nobuo Kamiya
    • Organizer
      植物生理学会
    • Related Report
      2017 Research-status Report
  • [Presentation] Improvement of photosystem II activity in solution and nanopores inside porous glass2017

    • Author(s)
      Yusuke Ikeda, Tomoyasu Noji, Keisuke Kawakami, Tetsuro Jin, Nobuo Kamiya
    • Organizer
      8th OCARINA International Symposium
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research

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Published: 2017-04-28   Modified: 2024-01-30  

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