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Development of transparent wavelength conversion film using Ag-zeolite fluorescent nanoparticles improving solar devices

Research Project

Project/Area Number 17K18098
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Nanomaterials chemistry
Inorganic industrial materials
Research InstitutionKeio University

Principal Investigator

Iso Yoshiki  慶應義塾大学, 理工学部(矢上), 助教 (00769705)

Project Period (FY) 2017-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Fiscal Year 2018: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2017: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Keywords蛍光体 / ナノ粒子 / ゼオライト / Agクラスター / 波長変換膜 / X線照射 / 焼成 / 蛍光ナノ材料 / 波長変換 / 蛍光 / 太陽電池
Outline of Final Research Achievements

The use of transparent wavelength conversion films for converting near-ultraviolet light, which is inefficient for power generation, into visible light has been proposed as a method for improving the efficiency of solar devices. Ag zeolite fluorescent nanoparticle was focused as a wavelength conversion material. Improvement on the photoluminescence (PL) properties by the X-ray irradiation was investigated. PL intensity of the prepared Ag zeolite was enhanced by the characteristic X-ray of Pd. This may be attributed to formation of fluorescent Ag clusters in the zeolite framework. Subsequently, a transparent wavelength conversion film was prepared from the Ag zeolite and characterized. Calcination under inert gas was more effective than the X-ray irradiation for the improvement on the PL intensity of the Ag zeolite film.

Academic Significance and Societal Importance of the Research Achievements

低炭素社会の実現に向けた取り組みのひとつとして、太陽光発電の高効率化は重要な課題である。市販の太陽電池は、保護のために紫外線吸収剤が使用されており、太陽光が含有する近紫外光を発電に有効利用できていない。そこで、近紫外光を吸収して太陽電池を保護するだけでなく、さらに発電に有効な可視光に変換するような透明な波長変換膜の開発が求められる。本研究ではAgゼオライトナノ粒子に着目し、X線照射という新たな手法により蛍光特性を改善したことに加え、透明な波長変換膜の作製に成功した。新規な蛍光材料であるAgゼオライトを用いての太陽電池用波長変換膜の開発に対して、重要な知見を与える成果が得られたと言える。

Report

(3 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Research-status Report
  • Research Products

    (5 results)

All 2018 Other

All Journal Article (1 results) (of which Peer Reviewed: 1 results) Presentation (2 results) (of which Int'l Joint Research: 1 results) Remarks (2 results)

  • [Journal Article] Fluorescent Ag+-Exchanged Zeolite Nanoparticles with Improved Photoluminescence Properties via X-Ray Irradiation2018

    • Author(s)
      Taiji Kohei、Iso Yoshiki、Isobe Tetsuhiko
    • Journal Title

      Journal of Luminescence

      Volume: 196 Pages: 214-220

    • DOI

      10.1016/j.jlumin.2017.12.028

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Presentation] Influence of X-ray Irradiation on Photoluminescence Properties of Silver Ion-Exchanged FAU Zeolite Nanoparticles2018

    • Author(s)
      K. Taiji, Y. Iso, T. Isobe
    • Organizer
      International Symposium for Luminescence Materials & Applications Phosphor Safari 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] X線照射が銀ゼオライトナノ粒子の蛍光特性に与える影響(II)2018

    • Author(s)
      泰地航平、磯由樹、磯部徹彦
    • Organizer
      第79回応用物理学会秋季学術講演会
    • Related Report
      2018 Annual Research Report
  • [Remarks] 慶應義塾大学理工学部応用化学科機能材料デザイン研究室ホームページ

    • URL

      http://www.applc.keio.ac.jp/~isobe/index.html

    • Related Report
      2018 Annual Research Report
  • [Remarks] 慶應義塾大学理工学部 応用化学科 機能材料デザイン研究室

    • URL

      http://www.applc.keio.ac.jp/~isobe/

    • Related Report
      2017 Research-status Report

URL: 

Published: 2017-04-28   Modified: 2020-03-30  

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