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Development of superprotonic conductivity in plastic crystals

Research Project

Project/Area Number 17K18746
Research Category

Grant-in-Aid for Challenging Research (Exploratory)

Allocation TypeMulti-year Fund
Research Field Condensed matter physics and related fields
Research InstitutionThe University of Tokyo

Principal Investigator

Mori Hatsumi  東京大学, 物性研究所, 教授 (00334342)

Project Period (FY) 2017-06-30 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥6,500,000 (Direct Cost: ¥5,000,000、Indirect Cost: ¥1,500,000)
Fiscal Year 2019: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2018: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2017: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Keywords無水有機結晶 / 超プロトン伝導 / 柔粘性結晶 / 水素結合 / 酸ー塩基塩 / 分子運動 / 異方性 / グロッタス機構 / プロトン伝導 / 分子性物質 / 分子ダイナミクス / 水素結合ネットワーク / 酸塩基性 / プロトン伝導体 / 無水有機物質 / 弱酸ー弱塩基
Outline of Final Research Achievements

Proton conducting materials that can work without humidification and in the medium temperature range of 100-300℃ have been highly desired for future fuel cells, and thus the materials design towards high-performance anhydrous organic proton conductors based upon conduction mechanism and the development of novel anhydrous proton conductors are pivotal issues. In this study, we have investigated structure and property relationship by synthesizing single crystals of anhydrous organic proton conductors, successfully proposed materials design strategy, and developed novel anhydrous proton conductors focused upon construction of the hydrogen-bond network and utilizing molecular dynamics of constituent molecules on the proton conductivity.

Academic Significance and Societal Importance of the Research Achievements

プロトン伝導体は、プロトン (H+) がキャリアとなるイオン伝導体であり、燃料電池の電解質候補として近年注目され、基礎から応用まで幅広い研究分野において精力的に研究されている。従来は含水系のプロトン伝導体が主流であり、加湿機構が必要かつ0~100 ℃ でしか使えないという問題があった。したがって、中温域で用いるためには、無水でプロトン伝導性を示す物質開発が重要である。本研究では、燃料電池の電解質、あるいはプロトンセンサーに用いる良導性無水有機プロトン伝導体の開発設計指針を構築し、新規伝導体を開発し、環境・エネルギー課題解決の一助となる研究に貢献した。

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Research-status Report
  • 2017 Research-status Report
  • Research Products

    (98 results)

All 2020 2019 2018 2017 Other

All Journal Article (26 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 26 results,  Open Access: 9 results,  Acknowledgement Compliant: 1 results) Presentation (68 results) (of which Int'l Joint Research: 20 results,  Invited: 17 results) Remarks (3 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] A computational examination of the electric-field-induced proton transfer along the interface hydrogen bond between proton donating and accepting self-assembled monolayers2020

    • Author(s)
      Kanematsu Yusuke、Kato Hiroyuki S.、Yoshimoto Shinya、Ueda Akira、Yamamoto Susumu、Mori Hatsumi、Yoshinobu Jun、Matsuda Iwao、Tachikawa Masanori
    • Journal Title

      Chemical Physics Letters

      Volume: 741 Pages: 137091-137091

    • DOI

      10.1016/j.cplett.2020.137091

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Anhydrous Purely Organic Solid-State Proton Conductors: Effects of Molecular Dynamics on the Proton Conductivity of Imidazolium Hydrogen Dicarboxylates2020

    • Author(s)
      Sunairi Yoshiya、Dekura Shun、Ueda Akira、Ida Tomonori、Mizuno Motohiro、Mori Hatsumi
    • Journal Title

      Journal of the Physical Society of Japan

      Volume: 89 Issue: 5 Pages: 051008-051008

    • DOI

      10.7566/jpsj.89.051008

    • NAID

      210000158129

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Direct Evidence of Interfacial Hydrogen Bonding in Proton-Electron Concerted 2D Organic Bilayer on Au Substrate2019

    • Author(s)
      Yamamoto Susumu、Kato Hiroyuki S.、Ueda Akira、Yoshimoto Shinya、Hirata Yasuyuki、Miyawaki Jun、Yamamoto Kohei、Harada Yoshihisa、Wadati Hiroki、Mori Hatsumi、Yoshinobu Jun、Matsuda Iwao
    • Journal Title

      e-Journal of Surface Science and Nanotechnology

      Volume: 17 Issue: 0 Pages: 49-55

    • DOI

      10.1380/ejssnt.2019.49

    • NAID

      130007638859

    • ISSN
      1348-0391
    • Year and Date
      2019-04-27
    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Construction of three-dimensional anionic molecular frameworks based on hydrogen-bonded metal dithiolene complexes and the crystal solvent effect2019

    • Author(s)
      S. Yokomori,A. Ueda, T. Higashino, R. Kumai, Y. Murakami, and H. Mori
    • Journal Title

      CrystEngCommun

      Volume: 21 Issue: 18 Pages: 2940-2948

    • DOI

      10.1039/c9ce00364a

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Pressure-induced hydrogen localization coupled to a semiconductor?insulator transition in a hydrogen-bonded molecular conductor2019

    • Author(s)
      Ueda Akira、Kishimoto Kouki、Isono Takayuki、Yamada Shota、Kamo Hiromichi、Kobayashi Kensuke、Kumai Reiji、Murakami Youichi、Gouchi Jun、Uwatoko Yoshiya、Nishio Yutaka、Mori Hatsumi
    • Journal Title

      RSC Advances

      Volume: 9 Issue: 32 Pages: 18353-18358

    • DOI

      10.1039/c9ra02833a

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Di- and tetramethoxy benzothienobenzothiophenes: substitution position effects on the intermolecular interactions, crystal packing and transistor properties2019

    • Author(s)
      Toshiki Higashino, Akira Ueda and Hatsumi Mori
    • Journal Title

      New Journal of Chemistry

      Volume: 43 Issue: 2 Pages: 884-892

    • DOI

      10.1039/c8nj04251a

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Charge Order and Poor Glass-forming Ability of an Anisotropic Triangular-lattice System, θ-(BEDT-TTF)2TlCo(SCN)4, Investigated by NMR2019

    • Author(s)
      K. Miyagawa, T. Sato, H. Hashimoto, M. Kodama, K. Ohnoh, A. Ueda, H. Mori, and K. Kanoda
    • Journal Title

      Jouranal of Physical Society of Japan

      Volume: 88 Issue: 3 Pages: 034705-034705

    • DOI

      10.7566/jpsj.88.034705

    • NAID

      210000135132

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Hysteretic Current-Voltage Characteristics in the Deuterium-Dynamics- Triggered Charge-Ordered Phase of κ-D3(Cat-EDT-TTF)22019

    • Author(s)
      A. Ueda, K. Kishimoto, Y. Sunairi, J. Yoshida, H. Yamakawa, T. Miyamoto, T. Terashige, H. Okamoto and H. Mori
    • Journal Title

      J. Phys. Soc. Jpn.

      Volume: 88 Issue: 3 Pages: 034710-034710

    • DOI

      10.7566/jpsj.88.034710

    • NAID

      210000135137

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Strange metal from a frustration-driven charge order instability2019

    • Author(s)
      T. Sato, K. Kitai, K. Miyagawa, M. Tamura, A. Ueda, H. Mori and K. Kanoda
    • Journal Title

      Nature Materials

      Volume: 18 Issue: 3 Pages: 229-233

    • DOI

      10.1038/s41563-019-0284-9

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] High-Temperature Cooperative Spin Crossover Transitions and Single-Crystal Reflection Spectra of [FeIII(qsal)2](CH3OSO3) and Related Compounds2019

    • Author(s)
      Takahashi Kazuyuki、Yamamoto Kaoru、Yamamoto Takashi、Einaga Yasuaki、Shiota Yoshihito、Yoshizawa Kazunari、Mori Hatsumi
    • Journal Title

      Crystals

      Volume: 9 Issue: 2 Pages: 81-81

    • DOI

      10.3390/cryst9020081

    • NAID

      120006599239

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Dynamics of Water Molecules in a 3-Fold Interpenetrated Hydrogen-Bonded Organic Framework Based on Tetrakis(4-pyridyl)methane2019

    • Author(s)
      D. Inokuchi, Y. Hirao, K. Takahashi, K. Matsumoto, H. Mori, and T Kubo
    • Journal Title

      J. Phys. Chem. C

      Volume: 123 Issue: 11 Pages: 6599-6606

    • DOI

      10.1021/acs.jpcc.8b12421

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] 有機結晶を舞台としたπ電子-プロトンカップリング物性 の新展開2019

    • Author(s)
      森 初果
    • Journal Title

      日本物理学会誌

      Volume: 74 Pages: 82-92

    • NAID

      130007687129

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Anisotropic Proton Conductivity Arising from Hydrogen-Bond Patterns in Anhydrous Organic Single Crystals, Imidazolium Carboxylates2018

    • Author(s)
      Y. Sunairi, A. Ueda, J. Yoshida, K. Suzuki and H. Mori
    • Journal Title

      J. Phys. Chem. C

      Volume: 122 Issue: 22 Pages: 11623-11632

    • DOI

      10.1021/acs.jpcc.8b00814

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] The thermoelectric power of band-filling controlled organic conductors, beta'-(BEDT-TTF)3(CoCl4)2-x(GaCl4)x2018

    • Author(s)
      清田泰裕、川本正、他
    • Journal Title

      J. Mater. Chem. A

      Volume: 6 Issue: 5 Pages: 2004-2010

    • DOI

      10.1039/c7ta06987a

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Strong Hydrogen Bonds at the Interface between Proton-Donating and -Accepting Self-Assembled Monolayers on Au(111)2018

    • Author(s)
      Kato Hiroyuki S.、Yoshimoto Shinya、Ueda Akira、Yamamoto Susumu、Kanematsu Yusuke、Tachikawa Masanori、Mori Hatsumi、Yoshinobu Jun、Matsuda Iwao
    • Journal Title

      Langmuir

      Volume: 34 Issue: 5 Pages: 2189-2197

    • DOI

      10.1021/acs.langmuir.7b03451

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] A phenol-fused tetrathiafulvalene: modulation of hydrogen-bond patterns and electrical conductivity in the charge-transfer salt2018

    • Author(s)
      Ueda Akira、Mori Hatsumi
    • Journal Title

      Materials Chemistry Frontiers

      Volume: 2 Issue: 3 Pages: 566-572

    • DOI

      10.1039/c7qm00574a

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Size effects on supercooling phenomena in strongly correlated electron systems: IrTe2 and θ-(BEDT-TTF)2RbZn(SCN)42018

    • Author(s)
      Oike H.、Suda M.、Kamitani M.、Ueda A.、Mori H.、Tokura Y.、Yamamoto H. M.、Kagawa F.
    • Journal Title

      Physical Review B

      Volume: 97 Issue: 8 Pages: 085102-085102

    • DOI

      10.1103/physrevb.97.085102

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Thermodynamics of the quantum spin liquid state of the single-component dimer Mott system k-H3(Cat-EDT-TTF)2.2017

    • Author(s)
      Satoshi Yamashita, Yasuhiro Nakazawa, Akira Ueda, Hatsumi Mori
    • Journal Title

      Physical Review B

      Volume: 95 Issue: 18

    • DOI

      10.1103/physrevb.95.184425

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Visualization of a nonlinear conducting path in an organic molecular ferroelectric by using emission of terahertz radiation2017

    • Author(s)
      Sotome M.、Kida N.、Kinoshita Y.、Yamakawa H.、Miyamoto T.、Mori H.、Okamoto H.
    • Journal Title

      Physical Review B

      Volume: 95 Issue: 24 Pages: 241102-241102

    • DOI

      10.1103/physrevb.95.241102

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Spin-Singlet Transition in the Magnetic Hybrid Compound from a Spin-Crossover Fe(III) Cation and π-Radical Anion2017

    • Author(s)
      Takahashi Kazuyuki、Sakurai Takahiro、Zhang Wei-Min、Okubo Susumu、Ohta Hitoshi、Yamamoto Takashi、Einaga Yasuaki、Mori Hatsumi
    • Journal Title

      Inorganics

      Volume: 5 Issue: 3 Pages: 54-54

    • DOI

      10.3390/inorganics5030054

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Crystallization and vitrification of electrons in a glass-forming charge liquid2017

    • Author(s)
      Sasaki S.、Hashimoto K.、Kobayashi R.、Itoh K.、Iguchi S.、Nishio Y.、Ikemoto Y.、Moriwaki T.、Yoneyama N.、Watanabe M.、Ueda A.、Mori H.、Kobayashi K.、Kumai R.、Murakami Y.、M?ller J.、Sasaki T.
    • Journal Title

      Science

      Volume: 357 Issue: 6358 Pages: 1381-1385

    • DOI

      10.1126/science.aal3120

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Development of Novel Functional Organic Crystals by Utilizing Proton- and π-Electron-Donating/Accepting Abilities2017

    • Author(s)
      Ueda Akira
    • Journal Title

      Bulletin of the Chemical Society of Japan

      Volume: 90 Issue: 11 Pages: 1181-1188

    • DOI

      10.1246/bcsj.20170239

    • NAID

      130006201452

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Quantum-disordered state of magnetic and electric dipoles in an organic Mott system2017

    • Author(s)
      Shimozawa M.、Hashimoto K.、Ueda A.、Suzuki Y.、Sugii K.、Yamada S.、Imai Y.、Kobayashi R.、Itoh K.、Iguchi S.、Naka M.、Ishihara S.、Mori H.、Sasaki T.、Yamashita M.
    • Journal Title

      Nature Communications

      Volume: 8 Issue: 1 Pages: 1-6

    • DOI

      10.1038/s41467-017-01849-x

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Antiferromagnetic Ordering in Organic Conductor λ-(BEDT-TTF)2GaCl4 probed by 13C NMR.2017

    • Author(s)
      Saito, Y., Fukuoka, S., Kobayashi, T., Kawamoto, A., and Mori, H.
    • Journal Title

      Journal of the Physical Society of Japan

      Volume: 87 Issue: 1 Pages: 013707-013707

    • DOI

      10.7566/jpsj.87.013707

    • NAID

      210000134657

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Multicomponent DFT study of geometrical H/D isotope effect on hydrogen-bonded organic conductor, κ-H3(Cat-EDT-ST)22017

    • Author(s)
      K. Yamamoto, Y. Kanematsu, U. Nagashima, A. Ueda, H. Mori, M. Tachikawa
    • Journal Title

      Chem. Phys. Lett.

      Volume: 674 Pages: 168-172

    • DOI

      10.1016/j.cplett.2017.02.073

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Development of Novel Functional Molecular Crystals by Utilizing Dynamic Hydrogen Bonds2017

    • Author(s)
      Ueda Akira、Yoshida Junya、Takahashi Kazuyuki、Mori Hatsumi
    • Journal Title

      Journal of Synthetic Organic Chemistry, Japan

      Volume: 75 Issue: 10 Pages: 1045-1054

    • DOI

      10.5059/yukigoseikyokaishi.75.1045

    • NAID

      130006156692

    • ISSN
      0037-9980, 1883-6526
    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Presentation] 一軸性圧縮下におけるβ’-[H3(Cat-EDO-TTF)2]BF4の電気抵抗測定2020

    • Author(s)
      菅井祐太、出倉 駿、上田 顕、吉田順哉、郷地 順、上床美也、浅井晋一郎、益田隆嗣、今城周作、金道浩一、森 初果
    • Organizer
      日本物理学会第75回年次大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 水素と電子のカップリングによる物性制御2020

    • Author(s)
      森 初果
    • Organizer
      日本物理学会第75回年次大会
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] 新規Znジチオレン錯体結晶の構造とベイポクロミック特性2020

    • Author(s)
      横森 創、出倉 駿、藤野 智子、尾崎 泰助、森 初果
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Structures and physical properties of EDOT (3,4-ethylenedioxy- thiophene) dimer-based molecular crystals2020

    • Author(s)
      R. Kameyama, S. Dekura, T. Fujino, H. Mori
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Syntheses and Field-Effect Transistor Characteristics of Novel Nickel-Dithiolene Complexes2020

    • Author(s)
      L. Zhang, T. Fujino, S. Yokomori, D. Zhang, S. Dekura, M. Lippmaa, H. Mori
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Structure and Anhydrous Proton Conductivity of an Imidazolium Dihydrogen Phosphate Crystal2020

    • Author(s)
      S. Dekura, Y. Sunairi, H. Mori
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] ジカルボン酸とイミダゾールからなる酸-塩基型有機結晶の無水プロトン伝導性: 水素結合様式と分子運動の効果2019

    • Author(s)
      砂入允哉、出倉 駿、上田 顕、井田智友、水野元博、森 初果
    • Organizer
      第22回超イオン導伝体物性研究会(第73回イオニクス研究会)
    • Related Report
      2019 Annual Research Report
  • [Presentation] 分子性イミダゾリウム塩結晶における無水プロトン伝導性2019

    • Author(s)
      出倉 駿、砂入允哉、森 初果
    • Organizer
      ハイドロジェノミクス第4回若手育成スクール
    • Related Report
      2019 Annual Research Report
  • [Presentation] イミダゾール-リン酸塩における新規結晶構造及びその無水プロトン伝導性2019

    • Author(s)
      出倉 駿、砂入 允哉、横森 創、森 初果
    • Organizer
      日本物理学会2019年秋季大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] ジカルボン酸-イミダゾール塩の無水プロトン伝導性に対する分子ダイナミクス効果 II2019

    • Author(s)
      砂入允哉、出倉駿、上田 顕、森 初果
    • Organizer
      日本物理学会2019年秋季大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] ジカルボン酸とイミダゾールからなる酸-塩基型有機結晶の水素結合様式と分子運動および無水プロトン伝導性2019

    • Author(s)
      砂入允哉、出倉 駿、上田 顕、森 初果
    • Organizer
      第13回分子科学討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 新規チオフェン系オリゴマーの合成およびその電荷移動錯体の伝導度測定2019

    • Author(s)
      亀山亮平、出倉 駿、藤野智子、森 初果
    • Organizer
      第13回分子科学討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 新規結晶構造を有するイミダゾール-リン酸塩における無水プロトン伝導性2019

    • Author(s)
      出倉 駿、砂入允哉、横森 創、森 初果
    • Organizer
      第13回分子科学討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 水素結合型有機伝導体beta’-[H3(Cat-EDO-TTF)2A] (A = BF4 , ClO4)の圧力下電気抵抗測定2019

    • Author(s)
      菅井 祐太、上田 顕、吉田 順哉、 横森 創、出倉 駿、 郷地 順、上床 美也、浅井 晋一郎、益田 隆嗣、森 初果
    • Organizer
      第13回分子科学討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 水酸基を有するNiジチオレン錯体を用いた新規水素結合型分子性結晶の構造及び物性2019

    • Author(s)
      横森 創、上田 顕、出倉 駿、熊井 玲児、村上 洋一、森 初果
    • Organizer
      第13回分子科学討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Syntheses and Field-Effect Transistor Characteristics of Novel Nickel-Dithiolene Complexes with Methoxybenzene Moieties(メトキシベンゼン部位を有する新規ニッケルジチオレン錯体の合成及びFET特性2019

    • Author(s)
      L. Zhang, S. Yokomori, D. Zhang, T. Fujino, S. Dekura, H. Mori
    • Organizer
      第13回分子科学討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Novel Molecular Functional Materials Utilizing Proton Dynamics2019

    • Author(s)
      H. Mori
    • Organizer
      The 13th International Symposium on Crystalline Organic Metals, Superconductors and Magnets (ISCOM2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Syntheses, Structures, and Properties of Novel Molecular Crystals with Hydrogen-bonded Framework based on Metal-dithiolene Complexes2019

    • Author(s)
      S. Yokomori, A. Ueda, S. Dekura, R. Kumai, Y. Murakami, and H. Mori
    • Organizer
      The 13th International Symposium on Crystalline Organic Metals, Superconductors and Magnets (ISCOM2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Anhydrous Proton Conductivity in Imidazolium Hydrogen Carboxylates: Effects of Hydrogen-Bond Manners and Molecular Motions2019

    • Author(s)
      Y. Sunairi, S. Dekura, A. Ueda, and H. Mori
    • Organizer
      The 13th International Symposium on Crystalline Organic Metals, Superconductors and Magnets (ISCOM2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Anhydrous Proton Conductivity of Novel Imidazolium Dihydrogen Phosphate2019

    • Author(s)
      S. Dekura, Y. Sunairi, S. Yokomori, Hatsumi Mori
    • Organizer
      The 13th International Symposium on Crystalline Organic Metals, Superconductors and Magnets (ISCOM2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Novel Functional Molecular Materials by Utilizing Molecular Degrees of Freedom2019

    • Author(s)
      H. Mori
    • Organizer
      The 14th Asia-Pacific Physics Conference (APPC14)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Proton-dynamics Coupled Quantum Spin Liquid State and Magnetic Switching in Organic Mott System2019

    • Author(s)
      H. Mori
    • Organizer
      Topological Phases and Functionality of Correlated Electron Systems 2019
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Quantum liquid of magnetic and electric dipoles in a proton-electron coupled molecular crystal2019

    • Author(s)
      H. Mori
    • Organizer
      日本化学会 第99春季年会 (2019)
    • Related Report
      2018 Research-status Report
    • Invited
  • [Presentation] イミダゾール‐ジカルボン酸塩のプロトン伝導性に対する分子ダイナミクス効果”、砂入允哉2019

    • Author(s)
      砂入允哉
    • Organizer
      日本物理学会第74回年次大会
    • Related Report
      2018 Research-status Report
  • [Presentation] カチオン-アニオン間に水素結合を導入した水素結合性有機リン酸結晶における無水プロトン伝導特性2019

    • Author(s)
      出倉 駿
    • Organizer
      日本物理学会第74回年次大会
    • Related Report
      2018 Research-status Report
  • [Presentation] π電子-プロトン相関型Cat-TTF系電荷移動塩の圧力下電気抵抗測定2019

    • Author(s)
      菅井 祐太
    • Organizer
      日本物理学会第74回年次大会
    • Related Report
      2018 Research-status Report
  • [Presentation] カテコール縮環型金属ジチオレン錯体の構造と物性における中心金属置換効果2019

    • Author(s)
      横森 創
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Research-status Report
  • [Presentation] ジメトキシベンゼンが縮環した中性の金属ジチオレン錯体の合成、構造、性質ならびに電界効果トランジスタ特性2019

    • Author(s)
      横森 創
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Research-status Report
  • [Presentation] Recent Advances in Molecular Conductors: Materials Development2018

    • Author(s)
      H. Mori
    • Organizer
      International conference for coordination chemistry 2018
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Novel Molecular Functional Materials Using Dynamic H-bond and Polarization2018

    • Author(s)
      H. Mori
    • Organizer
      The 2018 Gordon Research Conference on Conductivity and Magnetism in Molecular Materials Emergent Materials and Phenomena as Foundation for Future Molecule-Based Devices
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Development of a New Type of Molecular Conductors with Dynamic Hydrogen Bonds2018

    • Author(s)
      A. Ueda
    • Organizer
      豊田理研国際ワークショップ”organic semiconductors, conductors, electronics”
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] 新規カテコール縮環型金属ジチオレン錯体の合成と水素結合フレームワーク構造2018

    • Author(s)
      横森 創
    • Organizer
      錯体化学会 第68回討論会
    • Related Report
      2018 Research-status Report
  • [Presentation] イミダゾール‐ジカルボン酸共結晶のプロトン伝導性に対するジカルボン酸分子修飾効果 II2018

    • Author(s)
      砂入允哉
    • Organizer
      日本物理学会2018年秋季大会
    • Related Report
      2018 Research-status Report
  • [Presentation] 電気抵抗測定でみたπ電子-プロトン相関型Cat-TTF系有機伝導体に対する静水圧力ならびに元素置換効果2018

    • Author(s)
      高倉 知将
    • Organizer
      日本物理学会2018年秋季大会
    • Related Report
      2018 Research-status Report
  • [Presentation] 有機カチオン分子とリン酸アニオンからなる水素結合性結晶の構造、プロトン伝導性ならびに誘電性2018

    • Author(s)
      武井 史
    • Organizer
      日本物理学会2018年秋季大会
    • Related Report
      2018 Research-status Report
  • [Presentation] 半導体-絶縁体転移を示す新規カテコール-TTF系水素結合型電荷移動塩の合成と構造、物性2018

    • Author(s)
      上田 顕
    • Organizer
      第12回分子科学討論会
    • Related Report
      2018 Research-status Report
  • [Presentation] カテコール縮環型金属ジチオレン錯体: 水素結合による多様な集積構造と中心金属置換効果2018

    • Author(s)
      横森 創
    • Organizer
      第12回分子科学討論会
    • Related Report
      2018 Research-status Report
  • [Presentation] エチレンジオキシ基を有するカテコール縮環型TTF誘導体を用いた水素結合型の新規電荷移動塩の合成と構造、物性2018

    • Author(s)
      池田 潤
    • Organizer
      第12回分子科学討論会
    • Related Report
      2018 Research-status Report
  • [Presentation] A Strategy for Developing Isotropic Charge Transport Mobility in Anthracene Derivatives with Multi-functions2018

    • Author(s)
      D. Zhang
    • Organizer
      The 8th TOYOTA RIKEN International Workshop “Organic Semiconductors, Conductors, and Electronics”
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Syntheses, Structures and Physical Properties of Novel Metal-dithiolene Complexes with Hydrogen bonds2018

    • Author(s)
      S. Yokomori
    • Organizer
      The 8th TOYOTA RIKEN International Workshop “Organic Semiconductors, Conductors, and Electronics”
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Anhydrous Proton Conductivity in Imidazolium Hydrogen Carboxylates: Effects of Hydrogen Bonds and Molecular Motions2018

    • Author(s)
      Y. Sunairi
    • Organizer
      The 8th TOYOTA RIKEN International Workshop “Organic Semiconductors, Conductors, and Electronics”
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] モノとヒトの多様性~有機伝導体および磁性体の化学と物理から2018

    • Author(s)
      森 初果
    • Organizer
      女性研究者サミット
    • Related Report
      2018 Research-status Report
    • Invited
  • [Presentation] 水素と電子のカップリングによる新機能材料・デバイスの開発2018

    • Author(s)
      森 初果
    • Organizer
      ポスト「京」重点課題(7)第4回シンポジウム
    • Related Report
      2018 Research-status Report
    • Invited
  • [Presentation] カテコール部位を有する金属ジチオレン錯体を用いた多様な水素結合型結晶の合成と構造2018

    • Author(s)
      横森 創、上田 顕、熊井 玲児、村上 洋一、森 初果
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Research-status Report
  • [Presentation] カテコール縮環TTFと各種アニル酸誘導体からなる水素結合型電荷移動錯体の構造と物性2018

    • Author(s)
      土居 諒平、上田 顕、熊井 玲児、村上 洋一、森 初果
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Research-status Report
  • [Presentation] TTF-o-ベンゾキノン骨格を有する新規ドナー・アクセプター型有機分子の合成と置換基効果の調査2018

    • Author(s)
      寺岡 なつみ、上田 顕、横森 創、榎本 真哉、森 初果
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Research-status Report
  • [Presentation] イミダゾール‐ジカルボン酸共結晶のプロトン伝導性に対するジカルボン酸分子修飾効果2018

    • Author(s)
      砂入允哉、上田 顕、吉田順哉、森 初果
    • Organizer
      日本物理学会第73回年次大会
    • Related Report
      2017 Research-status Report
  • [Presentation] π電子-プロトン相関型Cat-TTF系有機伝導体における非線形伝導現象とその元素置換効果2018

    • Author(s)
      岸本幸樹, 上田 顕, 砂入允哉, 吉田順哉,山川大路, 宮本辰也, 岡本 博, 森 初果
    • Organizer
      日本物理学会第73回年次大会
    • Related Report
      2017 Research-status Report
  • [Presentation] 有機結晶における動的水素と相関した電子機能物性2017

    • Author(s)
      森 初果
    • Organizer
      日本真空学会関西支部&日本表面科学会関西支部合同セミナー「水素の挙動と物質科学 -最近の展開-」
    • Related Report
      2017 Research-status Report
    • Invited
  • [Presentation] 「モノとヒトの多様性」~強相関系有機導体の化学と物理から~2017

    • Author(s)
      森 初果
    • Organizer
      第62回物性若手夏の学校 集中ゼミ
    • Related Report
      2017 Research-status Report
    • Invited
  • [Presentation] 水素-π電子相関系有機伝導体 κ-X3(Cat-EDT-TTF)2 [X = H, D] における圧力効果:電気抵抗とX線回折2017

    • Author(s)
      上田 顕、岸本幸樹、山田翔太、磯野貴之、森 初果、小林賢介、熊井玲児、村上洋一
    • Organizer
      第11回分子科学討論会
    • Related Report
      2017 Research-status Report
  • [Presentation] ビスインドリルメチリウム塩の構造相転移と誘電応答2017

    • Author(s)
      吉田順哉、森 初果
    • Organizer
      第11回分子科学討論会
    • Related Report
      2017 Research-status Report
  • [Presentation] カテコール部位を有するジチオレン配位子を用いた新規な水素結合型金属錯体の合成、構造および物性2017

    • Author(s)
      横森 創、上田 顕、東野寿樹、森 初果
    • Organizer
      第11回分子科学討論会
    • Related Report
      2017 Research-status Report
  • [Presentation] カテコール縮環TTFとジヒドロキシベンゾキノンからなる新規水素結合型電荷移動錯体の合成と構造、物性2017

    • Author(s)
      土居 諒平、上田 顕、熊井 玲児、村上 洋一、森 初果、
    • Organizer
      第11回分子科学討論会
    • Related Report
      2017 Research-status Report
  • [Presentation] 二次元水素結合系イミダゾール‐シュウ酸共結晶におけるプロトン伝導性と結晶構造の相関2017

    • Author(s)
      砂入允哉、上田 顕、吉田順哉、森 初果
    • Organizer
      日本物理学会秋季大会
    • Related Report
      2017 Research-status Report
  • [Presentation] π電子-プロトン相関型有機伝導体κ-X3(Cat-EDT-TTF)2 [X = H, D]における電場および圧力効果2017

    • Author(s)
      岸本幸樹, 上田 顕, 磯野貴之, 砂入允哉, 吉田順哉、熊井玲児, 小林賢介, 村上洋一,森 初果
    • Organizer
      日本物理学会秋季大会
    • Related Report
      2017 Research-status Report
  • [Presentation] Development of a New Class of Molecular Conductors with Hydrogen-Bond Dynamics: Chemical Modification of Catechol-Fused TTF System2017

    • Author(s)
      A. Ueda, H. Mori
    • Organizer
      The 12th International Symposium on Crystalline Organic Metals, Superconductors and Magnets (ISCOM2017)
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Methoxy-substituted BTBT derivatives: Synthesis and substitution position effect on the solid-state structures and transistor properties2017

    • Author(s)
      T. Higashino, A. Ueda, H. Mori
    • Organizer
      The 12th International Symposium on Crystalline Organic Metals, Superconductors and Magnets (ISCOM2017)
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Proton Conductivity and Hydrogen-Bond Network of Anhydrous Organic Crystals, Imidazolium Dicarboxylate2017

    • Author(s)
      Y. Sunairi, A. Ueda, J. Yoshida, H. Mori
    • Organizer
      The 12th International Symposium on Crystalline Organic Metals, Superconductors and Magnets (ISCOM2017)
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Nonlinear Conduction in κ-X3(Cat-EDT-TTF)2 [X=H, D]2017

    • Author(s)
      K. Kishimoto, A. Ueda, Y. Sunairi, J. Yoshida, D. Ueta, H. Yoshizawa, and H. Mori
    • Organizer
      The 12th International Symposium on Crystalline Organic Metals, Superconductors and Magnets (ISCOM2017)
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Development of Metal-dithiolene Complexes Having Hydrogen-bonding Ability2017

    • Author(s)
      S. Yokomori, A. Ueda, T. Higashino, and H. Mori
    • Organizer
      The 12th International Symposium on Crystalline Organic Metals, Superconductors and Magnets (ISCOM2017)
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Synthesis, Structures, and Physical Properties of Novel Hydrogen-bonded Charge-transfer Complexes based on Catechol-fused TTF2017

    • Author(s)
      R. Doi, A. Ueda, R. Kumai, Y. Murakami, and H. Mori
    • Organizer
      The 12th International Symposium on Crystalline Organic Metals, Superconductors and Magnets (ISCOM2017)
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Hydrogen-related Functional Molecular Materials2017

    • Author(s)
      Hatsumi Mori
    • Organizer
      New Frontier of Molecular Materials (NFMM)
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Self-doped purely organic conductors by deprotonation and oxidation of proton/electron donors, catechol-fused TTF family2017

    • Author(s)
      H. Mori
    • Organizer
      Materials Research Society (MRS) fall meeting (EM01 Organic conductors - Surface, Interface, Bulk Doping and Charge Transport
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] 水素ー電子相関系における機能性物質開拓2017

    • Author(s)
      森 初果
    • Organizer
      東北大学金属材料研究所共同利用・共同研究ワークショップ「多自由度・多階層性が協奏する物質材料システムの科学」
    • Related Report
      2017 Research-status Report
    • Invited
  • [Presentation] Development of pai-electron functional materials utilizing molecular degrees of freedom2017

    • Author(s)
      Hatsumi Mori
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Research-status Report
    • Invited
  • [Presentation] フェノールを縮環させたTTF誘導体の合成とその電荷移動塩の構造・物性2017

    • Author(s)
      上田 顕、森 初果
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Research-status Report
  • [Presentation] ビスインドリルメチリウム塩の強誘電性相転移2017

    • Author(s)
      吉田 順哉、堀内 佐智雄、森 初果
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Research-status Report
  • [Remarks] 森研究室HP 実績

    • URL

      https://hmori.issp.u-tokyo.ac.jp/

    • Related Report
      2019 Annual Research Report
  • [Remarks] 東京大学物性研究所森研究室研究業績

    • URL

      https://hmori.issp.u-tokyo.ac.jp/publications.html

    • Related Report
      2018 Research-status Report
  • [Remarks] 森研究室HP 業績

    • URL

      http://hmori.issp.u-tokyo.ac.jp/

    • Related Report
      2017 Research-status Report
  • [Patent(Industrial Property Rights)] 導電性オリゴマー、導電性組成物、導電助剤、前記導電性組成物を用いて形成された、コンデンサ用電極、透明電極、電池用電極、又はキャパシタ用電極2019

    • Inventor(s)
      森 初果、出倉 駿、亀山亮平、中村浩昭、清野美勝
    • Industrial Property Rights Holder
      森 初果、出倉 駿、亀山亮平、中村浩昭、清野美勝
    • Industrial Property Rights Type
      特許
    • Filing Date
      2019
    • Related Report
      2019 Annual Research Report

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Published: 2017-07-21   Modified: 2021-02-19  

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