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Atomic force microscopy characterization of hydrogen bonding at the single atomic level

Research Project

Project/Area Number 17K19024
Research Category

Grant-in-Aid for Challenging Research (Exploratory)

Allocation TypeMulti-year Fund
Research Field Nano/Micro science and related fields
Research InstitutionThe University of Tokyo

Principal Investigator

Shiotari Akitoshi  東京大学, 大学院新領域創成科学研究科, 助教 (50755717)

Research Collaborator SUGIMOTO YOSHIAKI  
Project Period (FY) 2017-06-30 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥6,500,000 (Direct Cost: ¥5,000,000、Indirect Cost: ¥1,500,000)
Fiscal Year 2018: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Fiscal Year 2017: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Keywords原子間力顕微鏡 / 走査トンネル顕微鏡 / 水素結合 / パウリ斥力 / 金属表面 / 表面・界面物性 / 単原子力学計測 / 走査プローブ顕微鏡 / 単分子化学
Outline of Final Research Achievements

We aimed at quantitative measurement of the spatial distribution of individual hydrogen-bonding force at the single atomic level using non-contact atomic force microscopy.
Some molecular species at the tip apex reacted readily with target molecules, which prevented us from evaluating a large hydrogen bond in a non-destructive manner.
In contrast, we successfully evaluated an interatomic Pauli repulsive force that induces a configurational change of a nitric oxide molecule on a copper surface. The single molecule behaves as a tiny toggle switch that can be turned on by repulsive torque from the tip, which provides microscopic insights into the effects of external force to molecules for the development of molecular mechanical engineering.

Academic Significance and Societal Importance of the Research Achievements

本研究によって、2原子間に働く微小な力を空間的に計測し、分子ダイナミクスを解明できることを実証した。この知見から、今後、水素結合を含む様々な化学結合力の単原子レベル定量計測による結合状態の評価や元素同定、さらに、そのような原子間力を活用した単分子マシン・単分子デバイスの開発が進むことが期待できる。

Report

(3 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Research-status Report
  • Research Products

    (34 results)

All 2019 2018 2017 Other

All Journal Article (6 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 6 results,  Open Access: 1 results) Presentation (22 results) (of which Int'l Joint Research: 5 results,  Invited: 3 results) Book (4 results) Remarks (2 results)

  • [Journal Article] Atomic-scale study of formation of sodium-water complexes on Cu (110)2018

    • Author(s)
      A Shiotari, H Okuyama, S Hatta, T Aruga, I Hamada
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: 20 Issue: 17 Pages: 12210-12216

    • DOI

      10.1039/c8cp01237g

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Water-NO Complex Formation and Chain Growth on Cu(111)2018

    • Author(s)
      Koshida Hiroyuki、Hatta Shinichiro、Okuyama Hiroshi、Shiotari Akitoshi、Sugimoto Yoshiaki、Aruga Tetsuya
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 122 Issue: 16 Pages: 8894-8900

    • DOI

      10.1021/acs.jpcc.7b12447

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enhanced resolution imaging of ultrathin ZnO layers on Ag(111) by multiple hydrogen molecules in a scanning tunneling microscope junction2018

    • Author(s)
      Liu Shuyi、Shiotari Akitoshi、Baugh Delroy、Wolf Martin、Kumagai Takashi
    • Journal Title

      Physical Review B

      Volume: 97 Issue: 19

    • DOI

      10.1103/physrevb.97.195417

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Torque-Induced Change in Configuration of a Single NO Molecule on Cu(110)2018

    • Author(s)
      Shiotari Akitoshi、Odani Takafumi、Sugimoto Yoshiaki
    • Journal Title

      Physical Review Letters

      Volume: 121 Issue: 11 Pages: 1161011-6

    • DOI

      10.1103/physrevlett.121.116101

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chiral Discrimination and Manipulation of Individual Heptahelicene Molecules on Cu(001) by Noncontact Atomic Force Microscopy2018

    • Author(s)
      Shiotari Akitoshi, Tanaka Koichi, Nakae Takahiro, Mori Shigeki, Okujima Tetsuo, Uno Hidemitsu, Sakaguchi Hiroshi, Sugimoto Yoshiaki
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 122 Issue: 9 Pages: 4997-5003

    • DOI

      10.1021/acs.jpcc.8b00487

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Strain-induced skeletal rearrangement of a polycyclic aromatic hydrocarbon on a copper surface2017

    • Author(s)
      Shiotari Akitoshi, Nakae Takahiro, Iwata Kota, Mori Shigeki, Okujima Tetsuo, Uno Hidemitsu, Sakaguchi Hiroshi, Sugimoto Yoshiaki
    • Journal Title

      Nature Communications

      Volume: 8 Issue: 1 Pages: 16089-16089

    • DOI

      10.1038/ncomms16089

    • NAID

      120006329156

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Open Access
  • [Presentation] Reconstruction of Crystalline Ice Surface Revealed by Atomic Force Microscopy2019

    • Author(s)
      N. Kawakami, A. Shiotari, and Y. Sugimoto
    • Organizer
      2019 Annual Meeting of the Physical Society of Taiwan
    • Related Report
      2018 Annual Research Report
  • [Presentation] 単分子トグルスイッチ:NO/Cu(110)の配向変化の観測と制御2019

    • Author(s)
      塩足亮隼
    • Organizer
      日本顕微鏡学会走査型プローブ顕微鏡分科会「超高空間分解能SPMの最前線」
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] NO 修飾探針の作製とSTM 像シミュレーション2019

    • Author(s)
      尾谷卓史、塩足亮隼、杉本宜昭
    • Organizer
      第66回応用物理学会春季学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 斥力誘起による銅表面上の一酸化窒素単分子の配向変化制御2019

    • Author(s)
      塩足亮隼、尾谷卓史、杉本宜昭
    • Organizer
      第66回応用物理学会春季学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] STM/AFMおよびIRASによるCu(111)表面上のギ酸の吸着構造解明2019

    • Author(s)
      塩足亮隼、塩澤佑一郎、杉本宜昭、吉信淳
    • Organizer
      日本物理学会第74回年次大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 原子間力顕微鏡を用いた氷表面の原子分解能観察2018

    • Author(s)
      川上直也、塩足亮隼、杉本宜昭
    • Organizer
      日本物理学会2018年秋季大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 原子間力顕微鏡によるCu(110)表面上のNO単分子のトグルスイッチ制御2018

    • Author(s)
      塩足亮隼、尾谷卓史、杉本宜昭
    • Organizer
      日本物理学会2018年秋季大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Cu(111)表面上に吸着したギ酸のナノスケール構造解明2018

    • Author(s)
      塩足亮隼、塩澤佑一郎、杉本宜昭、吉信淳
    • Organizer
      第79回応用物理学会秋季学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 原子間力顕微鏡を用いた氷表面の高分解能観察2018

    • Author(s)
      川上直也、塩足亮隼、杉本宜昭
    • Organizer
      第79回応用物理学会秋季学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Ultrahigh-resolution imaging of water networks on a Cu surface by atomic force microscopy2018

    • Author(s)
      A. Shiotari、Y. Sugimoto
    • Organizer
      14th International Conference on Atomically Controlled Surfaces, Interfaces and Nanostructures (ACSIN-14)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 原子間力顕微鏡による氷表面の構造評価2018

    • Author(s)
      川上直也、塩足亮隼、杉本宜昭
    • Organizer
      2018年日本表面真空学会学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 原子間力顕微鏡による銅表面上の一酸化窒素単分子のトグルスイッチ制御2018

    • Author(s)
      塩足亮隼、尾谷卓史、杉本宜昭
    • Organizer
      2018年日本表面真空学会学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Cu(111) 表面における水-NO 複合体の形成とその鎖状成長2018

    • Author(s)
      越田裕之、奥山弘、八田振一郎、塩足亮隼、杉本宜昭、有賀哲也
    • Organizer
      表面・界面スペクトロスコピー2018
    • Related Report
      2018 Annual Research Report
  • [Presentation] 超高分解能原子間力顕微鏡による表面吸着分子の構造評価2018

    • Author(s)
      塩足亮隼
    • Organizer
      日本物理学会第73回年次大会
    • Related Report
      2017 Research-status Report
    • Invited
  • [Presentation] 原子間力顕微鏡による水素結合した吸着分子系の高分解能観察2018

    • Author(s)
      塩足亮隼
    • Organizer
      第13回日本表面科学会放射光表面科学研究部会・SPring-8ユーザー協同体顕微ナノ材料科学研究会合同シンポジウム
    • Related Report
      2017 Research-status Report
    • Invited
  • [Presentation] 原子間力顕微鏡による水分子ネットワークの高分解能観察2017

    • Author(s)
      塩足亮隼、杉本宜昭
    • Organizer
      第37回表面科学学術講演会
    • Related Report
      2017 Research-status Report
  • [Presentation] 原子間力顕微鏡によるCu(110)表面上の水単分子層の高分解能観察2017

    • Author(s)
      塩足亮隼、杉本宜昭
    • Organizer
      日本物理学会2017年秋季大会
    • Related Report
      2017 Research-status Report
  • [Presentation] 原子間力顕微鏡によるIn/Si(111)-4×1表面の相転移前後の測定2017

    • Author(s)
      岩田孝太、山崎詩郎、塩足亮隼、杉本宜昭
    • Organizer
      日本物理学会2017年秋季大会
    • Related Report
      2017 Research-status Report
  • [Presentation] Ultrahigh-resolution imaging of water networks on a copper surface by atomic force microscopy2017

    • Author(s)
      A. Shiotari, Y. Sugimoto
    • Organizer
      20th International Conference on Non-Contact Atomic Force Microscopy (NCAFM2017)
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Ultrahigh-resolution imaging of water networks on a metal surface by atomic force microscopy2017

    • Author(s)
      A. Shiotari, Y. Sugimoto
    • Organizer
      8th International Symposium on Surface Science (ISSS-8)
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] AFM/STM observation of strain-induced skeletal rearrangement of a polycyclic aromatic hydrocarbon on Cu(001)2017

    • Author(s)
      A. Shiotari T. Nakae, K. Iwata, S. Mori, T. Okujima, H. Uno, H. Sakaguchi, Y. Sugimoto
    • Organizer
      8th International Symposium on Surface Science (ISSS-8)
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Ultrahigh-resolution imaging of water networks on Cu(110) by atomic force microscopy2017

    • Author(s)
      A. Shiotari and Y. Sugimoto
    • Organizer
      5th Ito International Research Center Conference (IIRC5)
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Book] 原子間力顕微鏡による水ネットワークの超高分解能観察(Journal of surface science and vacuum、61巻、215頁)2018

    • Author(s)
      塩足亮隼、杉本宜昭
    • Total Pages
      6
    • Publisher
      日本表面真空学会
    • Related Report
      2018 Annual Research Report
  • [Book] 分子力学計測(日本化学会 編「分子アーキテクトニクス(CSJ:31)」Part II, Chapter 6)2018

    • Author(s)
      杉本宜昭、塩足亮隼
    • Total Pages
      4
    • Publisher
      化学同人
    • ISBN
      9784759813913
    • Related Report
      2018 Annual Research Report
  • [Book] Inelastic Electron Tunneling Spectroscopy. In: The Surface Science Society of Japan (eds), Compendium of Surface and Interface Analysis2018

    • Author(s)
      Akitoshi Shiotari
    • Total Pages
      5
    • Publisher
      Springer
    • ISBN
      9789811061554
    • Related Report
      2017 Research-status Report
  • [Book] Reactivity of Nitric Oxide on Copper Surfaces: Elucidated by Direct Observation of Valence Orbitals2017

    • Author(s)
      Akitoshi Shiotari
    • Total Pages
      129
    • Publisher
      Springer
    • ISBN
      9789811045813
    • Related Report
      2017 Research-status Report
  • [Remarks] 東京大学プレスリリース「分子1個でできた世界最小のレバー型スイッチをON!」

    • URL

      http://www.k.u-tokyo.ac.jp/info/entry/22_entry672/

    • Related Report
      2018 Annual Research Report
  • [Remarks] 金属表面で分子を曲げて骨格を変える新・有機合成法を開発

    • URL

      http://www.k.u-tokyo.ac.jp/info/entry/22_entry588/

    • Related Report
      2017 Research-status Report

URL: 

Published: 2017-07-21   Modified: 2020-03-30  

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