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Study on the relaxation mechanism of valley polarization in atomically-thin transition metal dichalcogenides

Research Project

Project/Area Number 17K19055
Research Category

Grant-in-Aid for Challenging Research (Exploratory)

Allocation TypeMulti-year Fund
Research Field Applied condensed matter physics and related fields
Research InstitutionKyoto University

Principal Investigator

MIYAUCHI Yuhei  京都大学, エネルギー理工学研究所, 准教授 (10451791)

Project Period (FY) 2017-06-30 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥6,500,000 (Direct Cost: ¥5,000,000、Indirect Cost: ¥1,500,000)
Fiscal Year 2018: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Fiscal Year 2017: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Keywords遷移金属ダイカルコゲナイド / バレー / 励起子 / 原子層 / 半導体 / バレートロニクス / バレー緩和
Outline of Final Research Achievements

We studied the relaxation mechanism of exciton valley polarization in a single layer of tungsten diselenide WSe2, one of the typical transition metal dichalcogenide layered semiconductors. We found that the exciton valley relaxation observed in the experiments can be comprehensively understood, predicted, and controlled by taking into account the coupling between the two valley states through electron-hole exchange interactions with the screening effect by the doped carriers. We have also developed a new method to predict the valley polarization at low temperatures with high accuracy based on the characteristics of the emission spectra at room temperature using a machine learning algorism.

Academic Significance and Societal Importance of the Research Achievements

本研究では、代表的な遷移金属ダイカルコゲナイドWSe2の単層膜をモデルケースとして、円偏光によって生成された励起子のバレー分極情報が失われる機構を突き止めた。さらに、機構の理解に基づいて材料に工夫を施すことで、バレー状態をより長く保つことができることを見出した。本研究の成果は、2次元原子層半導体の基礎的かつ重要な光物性の1つが明らかになったという意義に加え、バレー自由度を情報キャリアとして用いる将来の高速・省エネルギー光情報デバイス実現に向けた材料設計の工学的指針を与えるものである。

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Research-status Report
  • 2017 Research-status Report
  • Research Products

    (46 results)

All 2020 2019 2018 2017 Other

All Int'l Joint Research (3 results) Journal Article (20 results) (of which Int'l Joint Research: 8 results,  Peer Reviewed: 20 results,  Open Access: 4 results) Presentation (21 results) (of which Int'l Joint Research: 8 results,  Invited: 9 results) Remarks (2 results)

  • [Int'l Joint Research] National University of Singapore(シンガポール)

    • Related Report
      2018 Research-status Report
  • [Int'l Joint Research] National University of Singapore(Singapore)

    • Related Report
      2017 Research-status Report
  • [Int'l Joint Research] Rice University(米国)

    • Related Report
      2017 Research-status Report
  • [Journal Article] Bright and highly valley polarized trions in chemically doped monolayer MoS22020

    • Author(s)
      Zhang Wenjin、Tanaka Kenya、Hasegawa Yusuke、Shinokita Keisuke、Matsuda Kazunari、Miyauchi Yuhei
    • Journal Title

      Applied Physics Express

      Volume: 13 Issue: 3 Pages: 035002-035002

    • DOI

      10.35848/1882-0786/ab7485

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Planar Perovskite Solar Cells with High Efficiency and Fill Factor Obtained Using Two-Step Growth Process2019

    • Author(s)
      Yang Fengjiu、Liu Jiewei、Wang Xiaofan、Tanaka Kenya、Shinokita Keisuke、Miyauchi Yuhei、Wakamiya Atsushi、Matsuda Kazunari
    • Journal Title

      ACS Applied Materials & Interfaces

      Volume: 11 Issue: 17 Pages: 15680-15687

    • DOI

      10.1021/acsami.9b02948

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Continuous Control and Enhancement of Excitonic Valley Polarization in Monolayer WSe 2 by Electrostatic Doping2019

    • Author(s)
      Shinokita Keisuke、Wang Xiaofan、Miyauchi Yuhei、Watanabe Kenji、Taniguchi Takashi、Matsuda Kazunari
    • Journal Title

      Advanced Functional Materials

      Volume: - Issue: 26 Pages: 1900260-1900260

    • DOI

      10.1002/adfm.201900260

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Photostability of Monolayer Transition-Metal Dichalcogenides in Ambient Air and Acidic/Basic Aqueous Solutions2019

    • Author(s)
      Zhang Wenjin、Matsuda Kazunari、Miyauchi Yuhei
    • Journal Title

      ACS Omega

      Volume: 4 Issue: 6 Pages: 10322-10327

    • DOI

      10.1021/acsomega.9b01067

    • NAID

      120006649580

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Ultrafast dynamics of bright and dark positive trions for valley polarization in monolayer WSe22019

    • Author(s)
      Shinokita Keisuke、Wang Xiaofan、Miyauchi Yuhei、Watanabe Kenji、Taniguchi Takashi、Konabe Satoru、Matsuda Kazunari
    • Journal Title

      Physical Review B

      Volume: 99 Issue: 24 Pages: 245307-245307

    • DOI

      10.1103/physrevb.99.245307

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Restoring the intrinsic optical properties of CVD-grown MoS2 monolayers and their heterostructures2019

    • Author(s)
      Kojima Kana、Lim Hong En、Liu Zheng、Zhang Wenjin、Saito Tetsuki、Nakanishi Yusuke、Endo Takahiko、Kobayashi Yu、Watanabe Kenji、Taniguchi Takashi、Matsuda Kazunari、Maniwa Yutaka、Miyauchi Yuhei、Miyata Yasumitsu
    • Journal Title

      Nanoscale

      Volume: 11 Issue: 27 Pages: 12798-12803

    • DOI

      10.1039/c9nr01481k

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Experimental Evidence of Anisotropic and Stable Charged Excitons (Trions) in Atomically Thin 2D ReS22019

    • Author(s)
      Wang Xiaofan、Shinokita Keisuke、Miyauchi Yuhei、Cuong Nguyen Thanh、Okada Susumu、Matsuda Kazunari
    • Journal Title

      Advanced Functional Materials

      Volume: 29 Issue: 51 Pages: 1905961-1905961

    • DOI

      10.1002/adfm.201905961

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Machine-Learning Analysis to Predict the Exciton Valley Polarization Landscape of 2D Semiconductors2019

    • Author(s)
      Tanaka Kenya、Hachiya Kengo、Zhang Wenjin、Matsuda Kazunari、Miyauchi Yuhei
    • Journal Title

      ACS Nano

      Volume: 13 Issue: 11 Pages: 12687-12693

    • DOI

      10.1021/acsnano.9b04220

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Phonon-mediated intervalley relaxation of positive trions in monolayer WSe22019

    • Author(s)
      Shinokita Keisuke、Wang Xiaofan、Miyauchi Yuhei、Watanabe Kenji、Taniguchi Takashi、Konabe Satoru、Matsuda Kazunari
    • Journal Title

      Physical Review B

      Volume: 100 Issue: 16 Pages: 161304-161304

    • DOI

      10.1103/physrevb.100.161304

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Self-Aligned and Scalable Growth of Monolayer WSe2-MoS2 lateral heterojunctions2018

    • Author(s)
      M-Y. Li, J. Pu, J-K. Huang, Y. Miyauchi, K. Matsuda, T. Takenobu, and L-J Li
    • Journal Title

      Advanced Functional Materials

      Volume: 28 Issue: 17 Pages: 1706860-1706860

    • DOI

      10.1002/adfm.201706860

    • Related Report
      2018 Research-status Report 2017 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Carrier Transport and Photoresponse in GeSe/MoS2 Heterojunction p-n Diodes2018

    • Author(s)
      Tan Dezhi、Wang Xiaofan、Zhang Wenjin、Lim Hong En、Shinokita Keisuke、Miyauchi Yuhei、Maruyama Mina、Okada Susumu、Matsuda Kazunari
    • Journal Title

      Small

      Volume: - Issue: 22 Pages: 1704559-1704559

    • DOI

      10.1002/smll.201704559

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Evidence for line width and carrier screening effects on excitonic valley relaxation in 2D semiconductors2018

    • Author(s)
      Y. Miyauchi, S. Konabe, F. Wang, W. Zhang, A. Hwang, Y. Hasegawa, L. Zhou, S. Mouri, M. Toh, G. Eda, K. Matsuda
    • Journal Title

      Nature Communications

      Volume: 9 Issue: 1 Pages: 2598-2598

    • DOI

      10.1038/s41467-018-04988-x

    • NAID

      120006488629

    • Related Report
      2018 Research-status Report 2017 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] pH-Dependent Photoluminescence Properties of Monolayer Transition-Metal Dichalcogenides Immersed in an Aqueous Solution2018

    • Author(s)
      W. Zhang, K. Matsuda, Y. Miyauchi
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 122 Issue: 24 Pages: 13175-13181

    • DOI

      10.1021/acs.jpcc.8b03427

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Efficient Photocarrier Transfer and Effective Photoluminescence Enhancement in Type I Monolayer MoTe2/WSe2 Heterostructure2018

    • Author(s)
      T. Yamaoka, H-E. Lim, S. Koirala, K. Shinokita, M. Maruyama, S. Okada, Y. Miyauchi, K. Matsuda
    • Journal Title

      Advanced Functional Materials

      Volume: 28 Issue: 35 Pages: 1801021-1801021

    • DOI

      10.1002/adfm.201801021

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] High Bending Durability of Efficient Flexible Perovskite Solar Cells Using Metal Oxide Electron Transport Layer2018

    • Author(s)
      F. Yang, J. Liu, H-E. Lim, Y. Ishikura, K. Shinokita, Y. Miyauchi, A. Wakamiya, Y. Murata, K. Matsuda
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 122 Issue: 30 Pages: 17088-17095

    • DOI

      10.1021/acs.jpcc.8b05008

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Photoluminescence quantum yields for atomically thin-layered ReS2: Identification of indirect-bandgap semiconductors2018

    • Author(s)
      N. B. Mohamed, K. Shinokita, X. Wang, H-E. Lim, D. Tan, Y. Miyauchi, K. Matsuda
    • Journal Title

      Applied Physics Letters

      Volume: 113 Issue: 12 Pages: 121112-121112

    • DOI

      10.1063/1.5037116

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Direct and Indirect Exciton Dynamics in Few‐Layered ReS2 Revealed by Photoluminescence and Pump‐Probe Spectroscopy2018

    • Author(s)
      X. Wang, K. Shinokita, H.E. Lim, N. B. Mohamed, Y. Miyauchi, N.T. Cuong, S. Okada, K. Matsuda
    • Journal Title

      Advanced Functional Materials

      Volume: 29 Issue: 6 Pages: 1806169-1806169

    • DOI

      10.1002/adfm.201806169

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Long radiative lifetimes of excitons in monolayer transition-metal dichalcogenides MX2 (M = Mo, W; X = S, Se)2018

    • Author(s)
      N. B. Mohamed, H. E. Lim, F. Wang, S. Koirala, S. Mouri, K. Shinokita, Y. Miyauchi, and K. Matsuda
    • Journal Title

      Applied Physics Express

      Volume: 11 Issue: 1 Pages: 015201-015201

    • DOI

      10.7567/apex.11.015201

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Polarization-sensitive and broadband germanium sulfide photodetectors with excellent high-temperature performance2017

    • Author(s)
      D. Tan, W. Zhang, X. Wang, K. Sandhaya, Y. Miyauchi, and K. Matsuda
    • Journal Title

      Nanoscale

      Volume: 9 Issue: 34 Pages: 12425-12431

    • DOI

      10.1039/c7nr03040a

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Thermal dissociation of inter-layer excitons in MoS2/MoSe2 hetero-bilayers2017

    • Author(s)
      S. Mouri, W. Zhang, D. Kozawa, Y. Miyauchi, G. Eda and K. Matsuda
    • Journal Title

      Nanoscale

      Volume: 9 Issue: 20 Pages: 6674-6679

    • DOI

      10.1039/c7nr01598d

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] Novel excitonic phenomena in one-and two-dimensional semiconducting nanomaterials and their applications2019

    • Author(s)
      Yuhei Miyauchi
    • Organizer
      20th International Conference on Dynamical Processes in Excited States of Solids (New Zealand)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 単層カーボンナノチューブ・原子層半導体の新物性と応用開拓2019

    • Author(s)
      宮内 雄平
    • Organizer
      第80回応用物理学会秋季学術講演会(北海道大学)
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] Exploring Novel Physical Properties of Single-Walled Carbon Nanotubes and Atomically Thin Semiconductors Toward Energy Applications2019

    • Author(s)
      Yuhei Miyauchi
    • Organizer
      第338回GMSI公開セミナー(東京大学)
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] Directional Exciton Transport in a Monolayer WS2-WSe2 Lateral Heterostructure with a Wide Alloy Region2019

    • Author(s)
      Masafumi Shimasaki, Naoki Wada, Yasumitsu Miyata, Keisuke Shinokita, Taishi Nishihara1, Kazunari Matsuda1, Yuhei Miyauchi
    • Organizer
      2019 MRS Fall Meeting (USA)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 機械学習による原子層バレー光物性の解析・予測手法の開拓2019

    • Author(s)
      田中 絢也, 八谷 健吾, 張 文金, 松田 一成, 宮内 雄平
    • Organizer
      第80回応用物理学会秋季学術講演会(北海道大学)
    • Related Report
      2019 Annual Research Report
  • [Presentation] Exciton Dynamics in a Monolayer WS2-WSe2 Lateral Heterostructure with Wide Alloy Region2019

    • Author(s)
      Masafumi Shimasaki, Naoki Wada, Yasumitsu Miyata, Keisuke Shinokita, Taishi Nishihara, Kazunari Matsuda, Yuhei Miyauchi
    • Organizer
      Recent Progress in Grapheren and 2D Materials Research (RPGR) 2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Prediction of low temperature valley polarization characteristics in 2D semiconductors using machine-learning approach2019

    • Author(s)
      Kenya Tanaka, Kengo Hachiya, Wenjin Zhang, Kazunari Matsuda, Yuhei Miyauchi
    • Organizer
      20th International Conference on the Science and Application of Nanotubes and Low-Dimensional Materials (NT19)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Carrier screening effects on the exciton valley relaxation in monolayer transition metal dichalcogenide2019

    • Author(s)
      Y. Miyauchi
    • Organizer
      Nanophotonics of 2D Materials
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] キャリアドーピングによる単層WSe2における励起子バレー分極の増大2019

    • Author(s)
      篠北啓介,王暁凡,宮内雄平,渡邊賢司,谷口尚,松田一成
    • Organizer
      第56回フラーレン・ナノチューブ・グラフェン総合シンポジウム
    • Related Report
      2018 Research-status Report
  • [Presentation] Stability of monolayer WSe2 and MoS2 in an aqueous solution under light irradiation2019

    • Author(s)
      W. Zhang, K. Matsuda, Y. Miyauchi
    • Organizer
      第66回応用物理学会春季学術講演会
    • Related Report
      2018 Research-status Report
  • [Presentation] 単層WS2-WSe2面内ヘテロ構造の発光特性2019

    • Author(s)
      島崎 雅史,和田 尚樹, 宮田 耕充, 松田 一成, 宮内雄平
    • Organizer
      第66回応用物理学会春季学術講演会
    • Related Report
      2018 Research-status Report
  • [Presentation] 原子層半導体とそのヘテロ構造の光物性2019

    • Author(s)
      宮内雄平
    • Organizer
      日本物理学会第74回年次大会
    • Related Report
      2018 Research-status Report
    • Invited
  • [Presentation] Photoluminescence properties of monolayer transition metal dichalcogenides in aqueous solutions2019

    • Author(s)
      W. Zhang, K. Matsuda, Y. Miyauchi
    • Organizer
      Graphene Korea 2019 International Conference
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Optical properties of two-dimensional lateral hetero structure WS2/MoS22018

    • Author(s)
      M. Shimasaki, T. Saito, Y. Miyata, Y. Miyauchi, K. Matsuda
    • Organizer
      第55回フラーレン・ナノチューブ・グラフェン総合シンポジウム
    • Related Report
      2018 Research-status Report
  • [Presentation] Photoluminescence properties of monolayer MoS2 in an aqueous solution2018

    • Author(s)
      W. Zhang, K. Matsuda, Y. Miyauchi
    • Organizer
      APS March Meeting 2018
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Photoluminescence properties of twisted bilayer transition metal dichalcogenides2018

    • Author(s)
      M. Shimasaki, W. Zhang, X. Wang, T. Taniguchi, K. Watanabe, K. Matsuda, Y. Miyauchi
    • Organizer
      第54回フラーレン・ナノチューブ・グラフェン総合シンポジウム
    • Related Report
      2017 Research-status Report
  • [Presentation] 低次元ナノ物質の光物性工学とその応用2017

    • Author(s)
      宮内雄平
    • Organizer
      第24回京都大学宇治キャンパス産学交流会
    • Related Report
      2017 Research-status Report
    • Invited
  • [Presentation] 原子層物質のバレー励起子光物性2017

    • Author(s)
      宮内雄平
    • Organizer
      応用電子物性分科会 研究例会-二次元層状物質研究の最前線-
    • Related Report
      2017 Research-status Report
    • Invited
  • [Presentation] Linewidth and carrier screening effects on exciton valley relaxation in monolayer transition metal dichalcogenides2017

    • Author(s)
      Y. Miyauchi
    • Organizer
      The 3rd International Conference on 2D Materials and Technology
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] 原子層物質の励起子バレー緩和2017

    • Author(s)
      宮内雄平
    • Organizer
      CUPALワークショップ トポロジカル物質・原子層物質の新規物性
    • Related Report
      2017 Research-status Report
    • Invited
  • [Presentation] Substrate and sample dependent exciton transport properties in monolayer transition metal dichalcogenides2017

    • Author(s)
      W. Zhang, A. Hwang, T. Saito, Y. Kobayashi, T. Taniguchi, K. Watanabe, Y. Miyata, K. Matsuda, Y. Miyauchi
    • Organizer
      第53回フラーレン・ナノチューブ・グラフェン総合シンポジウム
    • Related Report
      2017 Research-status Report
  • [Remarks]

    • URL

      http://www.iae.kyoto-u.ac.jp/conv/miyauchi/indexj.html

    • Related Report
      2019 Annual Research Report
  • [Remarks] 京都大学プレスリリース

    • URL

      http://www.kyoto-u.ac.jp/ja/research/research_results/2018/180703_2.html

    • Related Report
      2018 Research-status Report

URL: 

Published: 2017-07-21   Modified: 2022-02-21  

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