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Nano-structured thermoelectric materials investigated through electrochemical interface

Research Project

Project/Area Number 17K19060
Research Category

Grant-in-Aid for Challenging Research (Exploratory)

Allocation TypeMulti-year Fund
Research Field Applied condensed matter physics and related fields
Research InstitutionInstitute of Physical and Chemical Research

Principal Investigator

Shimizu Sunao  国立研究開発法人理化学研究所, 創発物性科学研究センター, 研究員 (60595932)

Project Period (FY) 2017-06-30 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥6,370,000 (Direct Cost: ¥4,900,000、Indirect Cost: ¥1,470,000)
Fiscal Year 2018: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Fiscal Year 2017: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Keywords物性実験 / 電界効果 / 電気化学 / 熱電効果
Outline of Final Research Achievements

In this research subject, we have developed a thermoelectric measurement system, in which the thickness of samples is controlled by electrochemical reaction. If we can measure the thermoelectric properties with changing the thickness of materials, the investigation of the nano-sclae thermoelectics would become possible in variety of material systems. In the fiscal year 2017, we established the method to measure the Seebeck coefficient with reducing the thickness of materials through the electrochemical etching. In the fiscal year 2018, we applied the established approach to thermoelectric materials and realized the temperature-thickness mapping of a single sample. The method established in this study would be applied to other materials, enabling us to investigate nano-scale thermoelectrics and to find novel thermoelectric.

Academic Significance and Societal Importance of the Research Achievements

近年、コンピュータだけではなく、全ての“モノ”をインターネットにつなぐ、いわゆる IoT 社会へ向けた取り組みが着実に進んできている。その中で、エネルギーハーベスティングによ るエネルギー創出が必須の課題としてあげられ、熱電発電の重要性が再認識されている。本研究課題により、二次元超薄膜の 熱電効果の新しい研究手法を確立し、またそれを様々な物質に適用することで、これまで困難 であった超薄膜領域の熱電効果の研究を飛躍的に推進できると期待される。

Report

(3 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Research-status Report
  • Research Products

    (13 results)

All 2019 2018 2017 Other

All Journal Article (5 results) (of which Peer Reviewed: 5 results,  Open Access: 2 results,  Acknowledgement Compliant: 1 results) Presentation (7 results) (of which Int'l Joint Research: 2 results,  Invited: 3 results) Remarks (1 results)

  • [Journal Article] Giant thermoelectric power factor in ultrathin FeSe superconductor2019

    • Author(s)
      Sunao Shimizu, Junichi Shiogai, Nayuta Takemori, Shiro Sakai, Hiroaki Ikeda, Ryotaro Arita, Tsutomu Nojima, Atsushi Tsukazaki, Yoshihiro Iwasa
    • Journal Title

      Nature Communications

      Volume: 10 Issue: 1

    • DOI

      10.1038/s41467-019-08784-z

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Enhancement of superconducting transition temperature in FeSe electric-double-layer transistor with multivalent ionic liquids2018

    • Author(s)
      Tomoki Miyakawa, Junichi Shiogai, Sunao Shimizu, Michio Matsumoto, Yukihiro Ito, Takayuki Harada, Kohei Fujiwara, Tsutomu Nojima, Yoshimitsu Itoh, Takuzo Aida, Yoshihiro Iwasa, Atsushi Tsukazaki
    • Journal Title

      Phys. Rev. Materials

      Volume: 2 Issue: 3 Pages: 031801-031801

    • DOI

      10.1103/physrevmaterials.2.031801

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Exceptionally High Electric Double Layer Capacitances of Oligomeric Ionic Liquids2017

    • Author(s)
      M. Matsumoto, S. Shimizu, R. Sotoike, M. Watanabe, Y. Iwasa, Y. Itoh, T. Aida
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 139 Issue: 45 Pages: 16072-16075

    • DOI

      10.1021/jacs.7b09156

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Endeavor of Iontronics: From Fundamentals to Applications of Ion-Controlled Electronics2017

    • Author(s)
      S. Z. Bisri, S. Shimizu, M. Nakano, Y. Iwasa
    • Journal Title

      Adv. Mater.

      Volume: 29 Issue: 25

    • DOI

      10.1002/adma.201607054

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Bulk rectification effect in a polar semiconductor2017

    • Author(s)
      T. Ideue, K. Hamamoto, S. Koshikawa, M. Ezawa, S. Shimizu, Y. Kaneko, Y. Tokura, N. Nagaosa and Y. Iwasa
    • Journal Title

      Nature Communications

      Volume: online Issue: 6 Pages: 1-7

    • DOI

      10.1038/nphys4056

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Presentation] Enhanced Seebeck effect in ion-gated FeSe2019

    • Author(s)
      Sunao Shimizu、Junichi Shiogai、Nayuta Takemori、Shiro Sakai、Hiroaki Ikeda、Ryotaro Arita、Tsutomu Nojima、Atsushi Tsukazaki、Yoshihiro Iwasa
    • Organizer
      APS March Meeting 2019
    • Related Report
      2018 Annual Research Report
  • [Presentation] 電気二重層トランジスタと固体物性研究2019

    • Author(s)
      清水直
    • Organizer
      第3回全固体電池研究開発に関する研究会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Electric field control of thermoelectric properties in layered two dimensional materials2018

    • Author(s)
      Sunao Shimizu
    • Organizer
      3rd EU-Japan Workshop on Graphene and Related 2D Materials
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] SrTiO3電場誘起超伝導体における高ドープ領域での面内臨界磁場の増大2018

    • Author(s)
      大内拓, 清水直, 岩佐義宏, 野島勉
    • Organizer
      日本物理学会 第73会年次大会
    • Related Report
      2017 Research-status Report
  • [Presentation] Thermoelectric Effect in Ultrathin FeSe2018

    • Author(s)
      Sunao Shimizu、Shiogai Junichi、Nayuta Takemori、Shiro Sakai、Hiroaki Ikeda、Ryotaro Arita、Tsutomu Nojima、Atsushi Tsukazaki、Yoshihiro Iwasa
    • Organizer
      APS March Meeting 2018
    • Related Report
      2017 Research-status Report
  • [Presentation] Thermoelectric transport in gate-induced two dimensional electrons2017

    • Author(s)
      Sunao Shimizu
    • Organizer
      CEMS Topical Meeting on Emergent 2D Materials 2017
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] FeSe極薄膜の熱電効果2017

    • Author(s)
      清水直、塩貝純一、野島勉、塚﨑敦、岩佐義宏
    • Organizer
      第78回応用物理学会周期学術講演会
    • Related Report
      2017 Research-status Report
  • [Remarks] 2次元物質で高効率の熱電変換を実現

    • URL

      http://www.riken.jp/pr/press/2019/20190305_2/

    • Related Report
      2018 Annual Research Report

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Published: 2017-07-21   Modified: 2020-03-30  

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