| Budget Amount *help |
¥6,500,000 (Direct Cost: ¥5,000,000、Indirect Cost: ¥1,500,000)
Fiscal Year 2019: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2018: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2017: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
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| Outline of Final Research Achievements |
Upon adsorption of molecules on a surface, most molecular systems show chirality. This project aims at the precise control over the molecular chirality on surfaces and tuning their chiral recognition ability by means of scanning tunneling microscopy with molecular-level resolution. A systematic investigation of organic molecules that produce chiral porous honeycomb structures based on modifications of the structure and functionality of the alkyl side-chain of the molecules revealed several factors involved in the control of their chirality. In addition, to investigate molecular recognition in the vacancies of these chiral honeycomb structures, we developed functionalized pores comprising sites that recognize guest molecules depending on the polarity and steric environment of the functional groups.
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