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Nanoscale Electrochemical Operand Measurement System with Raman Spectroscopy

Research Project

Project/Area Number 17K19135
Research Category

Grant-in-Aid for Challenging Research (Exploratory)

Allocation TypeMulti-year Fund
Research Field Inorganic/Coordination chemistry, Analytical chemistry, and related fields
Research InstitutionTohoku University

Principal Investigator

Kumatani Akichika  東北大学, 材料科学高等研究所, 准教授 (50568433)

Project Period (FY) 2017-06-30 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥6,500,000 (Direct Cost: ¥5,000,000、Indirect Cost: ¥1,500,000)
Fiscal Year 2018: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2017: ¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Keywordsリチウムイオン電池 / 電気化学 / ラマン分光法 / 走査型プローブ顕微鏡 / 分析化学 / 走査プローブ顕微鏡 / 表面・界面物性 / 分析科学
Outline of Final Research Achievements

In this research, nanoscale electrochemical operand measurement system with Raman spectroscopy was developed. The system is based on a nanopipette used in electrochemical microscopy. The system can measure lithium-ion (de)intercalation process on the electrode of lithium-ion batteries with cyclic voltammogram and Raman spectrum at the same time during the (de) intercalation process as operand measurement. It was demonstrated by on edge/basal plane of HOPG substrate.

Academic Significance and Societal Importance of the Research Achievements

本計測機構を開発することにより、リチウムイオン電池内で起こるイオンの脱挿入反応を電気化学反応と光学特性(ラマン散乱光)の同時計測が可能となった。また、ナノピペットを用いることにより、通常計測が困難であったナノスケール領域での電極内の反応性の変化を追うことが可能となった。今後は電気化学顕微鏡などの走査機構を持つ計測技術に融合することで、電極内における反応性の分布と構造変化や析出物などの同時計測および可視化が可能となることが期待される。

Report

(3 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Research-status Report
  • Research Products

    (42 results)

All 2019 2018 2017 Other

All Int'l Joint Research (2 results) Journal Article (2 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 2 results,  Open Access: 2 results) Presentation (38 results) (of which Int'l Joint Research: 15 results,  Invited: 15 results)

  • [Int'l Joint Research] University College London(英国)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] National Taiwan University/Taipei Medical University(その他の国・地域)

    • Related Report
      2018 Annual Research Report
  • [Journal Article] Chemical dopants on edge of holey graphene accelerate electrochemical hydrogen evolution reaction2019

    • Author(s)
      A. Kumatani, C. Miura, H. Kuramochi, T. Ohto, M. Wakisaka, Y. Nagata, H. Ida, Y. Takahashi, K. Hu, S. Jeong, J. Fujita, T. Matsue, Y. Ito,
    • Journal Title

      Adv. Sci.

      Volume: - Issue: 10 Pages: 1900119-1900119

    • DOI

      10.1002/advs.201900119

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Scanning electrochemical cell microscopy for visualization and local electrochemical activities of lithium‐ion (de) intercalation process in lithium‐ion batteries electrodes2019

    • Author(s)
      Akichika Kumatani, Yasufumi Takahashi, Chiho Miura, Hiroki Ida, Hirotaka Inomata, Hitoshi Shiku, Hirokazu Munakata, Kiyoshi Kanamura, Tomokazu Matsue
    • Journal Title

      Surface and Interface Analysis

      Volume: 51 Issue: 1 Pages: 27-30

    • DOI

      10.1002/sia.6538

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Presentation] 単層/二層WS2における水素発生反応のナノスケール電気化学イメージング2019

    • Author(s)
      小川 寛人、熊谷 明哉、遠藤 尚彦、小林 佑、井田 大貴、高橋 康史、末永 智一 、宮田 耕充 、珠玖 仁
    • Organizer
      第66回応用物理学会春季学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] ナノ電気化学セルを用いたリチウムイオン電池負極の規定構造領域における SEI形成過程の検証2019

    • Author(s)
      熊谷明哉, 佐藤悠人, 高橋康史, 珠玖仁, 末永智一
    • Organizer
      第66回応用物理学会春季学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Nanoscale electrochemical imaging for hydrogen evolution reaction on WS2 mono-/bilayers2019

    • Author(s)
      Hiroto Ogawa, Akichika Kumatani, Takahiko Endo, Yu Kobayashi, Hiroki Ida, Yasufumi Takahashi, Tomokazu Matsue, Yasumitsu Miyata, Hitoshi Shiku
    • Organizer
      日本化学会99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Nanoscale Electrochemical Imaging for Functional Materials2019

    • Author(s)
      Akichika Kumatani
    • Organizer
      2019 Taiwan-Nippon Workshop on Innovation of Emergent Materials
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Nanoscale Electrochemical Imaging for Energy Functional Materials2019

    • Author(s)
      Akichika Kumatani
    • Organizer
      Japan-Taiwan Workshop on Electrochemistry JTWE 2019
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] SnS2二次元薄膜における水素発生反応のナノスケール電気化学イメージング2018

    • Author(s)
      小川寛人、熊谷明哉、上野啓司、遠藤尚彦、小林佑、宮田耕充、井田大貴、高橋康史、末永智一、珠玖仁
    • Organizer
      日本分析化学会第67年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 水素貯蔵合金表面におけるナノ電気化学イメージング2018

    • Author(s)
      安永幹生、熊谷明哉、田中元基、高橋康史、末永智一、珠玖仁
    • Organizer
      日本分析化学会第67年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] ナノ電気化学セル顕微鏡とToF-SIMSを用いた SEI 生成制御とその評価2018

    • Author(s)
      佐藤悠人、熊谷明哉、渡邊徹弥、珠玖仁、末永智一
    • Organizer
      第49回セミコンファレンス、第31回東北若手の会
    • Related Report
      2018 Annual Research Report
  • [Presentation] ナノ電気化学イメージングによるグラフェン構造欠陥の検証2018

    • Author(s)
      志村実優、熊谷明哉、井田大貴、珠玖仁、Y. P. Chen、末永智一
    • Organizer
      第49回セミコンファレンス、第31回東北若手の会
    • Related Report
      2018 Annual Research Report
  • [Presentation] グラフェンエッジにおける電気化学活性のナノスケール電気化学イメージング2018

    • Author(s)
      熊谷 明哉、三浦 千穂、高橋 康史、井田 大貴、珠玖 仁、末永 智
    • Organizer
      日本分析化学会 第67年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] ナノ電気化学イメージングによる電気化学反応の可視化:二次電池電極から水素貯蔵合金まで2018

    • Author(s)
      熊谷明哉
    • Organizer
      「鉄鋼関連材料の化学状態分析の新しい展開」フォーラム 第2回講演会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Scanning Electrochemical Microscopy for Nanoscale Electrochemical Imaging on Energy Materials2018

    • Author(s)
      Akichika Kumatani, Yasufumi Takahashi, Tomokazu Matsue
    • Organizer
      2019年度化学系学協会東北大会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Nanoscale Electrochemical Imaging by Spatially Resolved Electrochemical Microscopy: From Battery Electrodes to 2D Materials2018

    • Author(s)
      Akichika Kumatani
    • Organizer
      AI-Mat seminar
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Spatially resolved electrochemical imaging on energy materials: From battery electrodes to 2D materials2018

    • Author(s)
      Akichika Kumatani
    • Organizer
      TCECM 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Visualization of Electrochemical Activities on 2D Materials2018

    • Author(s)
      Akichika Kumatani
    • Organizer
      isCEBT2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Nanoscale Electrochemical Imaging of Aligned Semiconducting and Metallic Single-Walled Carbon Nanotube Bundles2018

    • Author(s)
      Akichika Kumatani, Takeru Okada, Takahashi Yasufumi, Miyu Shimura, Hitoshi Shiku, Seiji Samukawa, Tomokazu Matsue
    • Organizer
      AiMES 2018 ECS and SMEQ Joint International Meeting(国際学会)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Spatially Resolved Electrochemical Imaging on Energy Materials2018

    • Author(s)
      Akichika Kumatani
    • Organizer
      nanoHUB
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Nanoscale Electrochemical Imaging on Energy Materials2018

    • Author(s)
      Akichika Kumatani
    • Organizer
      UCL-Tohoku Partnership ‘kick-off’ workshop
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Nanoscale Electrochemical Imaging for Functional Energy Materials2018

    • Author(s)
      A. Kumatani, Y. P. Chen, Y. Takahashi, T. Matsue
    • Organizer
      2018 Sustainable Industrial Processing Summit & Exhibition SIPS
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Nanoscale Electrochemical Imaging by Scanning Electrochemical Microscopies on Energy Materials2018

    • Author(s)
      Akichika Kumatani
    • Organizer
      uTAS2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Nanoscale Electrochemical Imaging for 2D Materials2018

    • Author(s)
      A. Kumatani
    • Organizer
      International Workshop on Frontier and Cutting-edge Technologies over 2D Materials
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] 電気化学イメージングによる金属/半導体カーボンナノチューブの酸化還元反応の検証2018

    • Author(s)
      志村 実優,熊谷 明哉,岡田 健,三浦 千穂,井田 大貴,寒川 誠二,珠玖 仁, 高橋 康史,末永 智一
    • Organizer
      電気化学会第85回大会
    • Related Report
      2017 Research-status Report
  • [Presentation] 酸化還元反応の差異による半導体・金属カーボンナノチューブの検出2018

    • Author(s)
      熊谷 明哉,志村 実優,高橋 康史,三浦 千穂,岡田 健,井田 大貴,珠玖 仁,寒川 誠二,末永 智一
    • Organizer
      第65回応用物理学会春季学術講演会
    • Related Report
      2017 Research-status Report
  • [Presentation] Visualization of Electrochemical Activities on Energy Materials by Scanning Electrochemical Cell Microscopy2017

    • Author(s)
      A. Kumatani
    • Organizer
      The 3rd Tohoku Univ. & GREEN Joint Symposium
    • Related Report
      2017 Research-status Report
    • Invited
  • [Presentation] ナノ電気化学セル顕微鏡を用いたグラフェン/グラファイト表面構造における電気化学活性の評価2017

    • Author(s)
      三浦千穂,熊谷明哉,岡田健,寒川誠二,珠玖仁,高橋康史,末永智一
    • Organizer
      第78回応用物理学会秋季学術講演会
    • Related Report
      2017 Research-status Report
    • Invited
  • [Presentation] グラフェン・グラファイトの表面構造におけるナノ電気化学イメージング2017

    • Author(s)
      熊谷明哉
    • Organizer
      日本分析化学会東北支部:平成29年度東日本若手交流会
    • Related Report
      2017 Research-status Report
    • Invited
  • [Presentation] Scanning Electrochemical Cell Microscopy for Analyzing Local Electrochemical Performance at Lithium-ion Battery Electrodes2017

    • Author(s)
      A. Kumatani, Y. Takahashi, H. Shiku, T. Matsue
    • Organizer
      IWNET-2017
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] ナノ電気化学セル顕微鏡を用いたBCC系合金における水素貯蔵過程の可視化2017

    • Author(s)
      熊谷明哉, 田中元基、近真紀雄、陶山博司、西山博史、中西真二、珠玖仁、高橋康史、射場英紀、末永智一
    • Organizer
      第78回応用物理学会秋季学術講演会
    • Related Report
      2017 Research-status Report
  • [Presentation] ナノ電気化学セル顕微鏡を利用したBCC系合金表面における水素吸蔵反応分布の観察2017

    • Author(s)
      田中元基、熊谷明哉、近真紀雄、陶山博司、西山博史、珠玖仁、高橋康史、射場英紀、末永智一
    • Organizer
      第56回電池討論会
    • Related Report
      2017 Research-status Report
  • [Presentation] Scanning Electrochemical Cell Microscopy for Visualization of Lithium-ion (De)intercalation Process in Lithium-ion Batteries Electrodes2017

    • Author(s)
      A. Kumatani, Y. Takahashi, H. Munakata, H. Shiku, K. Kanamura and T. Matsue
    • Organizer
      ALC’17
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Redox Activities on the Surface/Edge Structures of Graphene/Graphite2017

    • Author(s)
      A. Kumatani, C. Miura, H. Shiku, Y. Takahashi, T. Matsue
    • Organizer
      232th ECS Meeting
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] SECCM Analysis for Investigation of functionalities of Negative Electrodes on Lithium-ion Battery2017

    • Author(s)
      A. Kumatani, Y. Sato, Takahashi, Kubota, H. Shiku, S. Komaba and T. Matsue
    • Organizer
      SECM-9
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] 走査型イオンコンダクタンス顕微鏡によるタンパク質薄膜の電荷マッピング2017

    • Author(s)
      今井俊輔, Fei Li, Peng Yang, 井田大貴, 熊谷明哉, 高橋康史, 伊野浩介, 珠玖仁, 末永智一
    • Organizer
      電気化学東北支部:第30回東北若手の会
    • Related Report
      2017 Research-status Report
  • [Presentation] ナノ電気化学セル顕微鏡を用いたグラフェンの電気化学応答評価2017

    • Author(s)
      三浦千穂、熊谷明哉、岡田健、高橋康史、珠玖仁、寒川誠二、末永智一
    • Organizer
      電気化学東北支部:第30回東北若手の会
    • Related Report
      2017 Research-status Report
  • [Presentation] 金属/半導体単層カーボンナノチューブのナノ電気化学イメージング2017

    • Author(s)
      志村実優、熊谷明哉、岡田健、高橋康史、珠玖仁、寒川誠二、末永智一
    • Organizer
      化学系学協会東北大会
    • Related Report
      2017 Research-status Report
  • [Presentation] Scanning Electrochemical Cell Microscopy for Investigation of Negative Composite Electrodes in Lithium-ion Batteries2017

    • Author(s)
      Y Sato, A. Kumatnai, Y. Takahashi, K. Kubota, S. Shiku, S Komaba, T. Matsue
    • Organizer
      化学系学協会東北大会
    • Related Report
      2017 Research-status Report
  • [Presentation] Redox Activity on Metallic and Semiconducting Single Walled Carbon Nanotubes by Nanoscale Meniscus2017

    • Author(s)
      M. Shimura, A. Kumatnai, T Okada, Y. Takahashi, H. Shiku, S. Samukawa, T. Matsue
    • Organizer
      化学系学協会東北大会
    • Related Report
      2017 Research-status Report
  • [Presentation] ナノ電気化学セル顕微鏡を利用したリチウムイオン電池用Si-黒鉛複合電極表面の電池特性評価2017

    • Author(s)
      佐藤悠人、熊谷明哉、高橋康史、久保田圭、珠玖仁、駒場慎一、末永智一
    • Organizer
      日本分析化学会東北支部:平成29年度東日本若手交流会
    • Related Report
      2017 Research-status Report

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Published: 2017-07-21   Modified: 2020-03-30  

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