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Creation of nanofiber with ion recognition and reduction functions and development of innovative separation method

Research Project

Project/Area Number 17K20067
Research Category

Grant-in-Aid for Challenging Research (Exploratory)

Allocation TypeMulti-year Fund
Research Field Environmental conservation measure and related fields
Research InstitutionUniversity of Miyazaki

Principal Investigator

Baba Yoshinari  宮崎大学, 工学部, 特任教授 (20039291)

Co-Investigator(Kenkyū-buntansha) 大榮 薫  宮崎大学, 工学部, 准教授 (00315350)
岩熊 美奈子  都城工業高等専門学校, 物質工学科, 教授 (00342593)
Project Period (FY) 2017-06-30 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥6,500,000 (Direct Cost: ¥5,000,000、Indirect Cost: ¥1,500,000)
Fiscal Year 2019: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2018: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Fiscal Year 2017: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Keywordsナイロンファイバー / 濃縮・還元機能 / スペーサー / 金・パラジウムの回収 / セルロースナノファイバー / 金ナノ粒子 / パラジウムナノ粒子 / バイオマス / キトサンナノファイバー / 金の回収 / 金イオン / 反応・分離工学 / 廃棄物再資源化 / 省エネプロセス / 環境保全 / 分子認識
Outline of Final Research Achievements

The aim of this research is to recycle precious metals from industrial wastes as nanoparticles. In this study, high specific surface area Nylon nanofibers and cellulose nanofibers are used as substrates, coated with self-assembling polymers with high adhesiveness, and then "concentration/reduction/desorption" is applied to the microspace on the fibers. We created an unprecedented reaction field that integrates these three functions. Precious metal ions such as gold (III), palladium (II) and platinum (IV) were targeted, and their adsorption (concentration), reduction and desorption experiments were carried out by the batch method. We have constructed a highly selective precious metal recycling system that can recover these "ions as solid nanoparticles" with high energy efficiency.

Academic Significance and Societal Importance of the Research Achievements

本研究は安定確保が困難である希少金属の中の貴金属を産業廃棄物からリサイクルすることで、環境保全および資源の有効利用を目指すものである。環境・資源の観点から社会的に意義があり、資源循環システムの構築による持続可能な社会づくりへの貢献が期待できる。さらに、回収した貴金属をナノ材料として再資源化することは学術的にも価値も高く、センシング、医療、フォトニクス材料などへの応用が期待される。

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Research-status Report
  • 2017 Research-status Report
  • Research Products

    (38 results)

All 2020 2019 2018 2017

All Journal Article (12 results) (of which Peer Reviewed: 12 results,  Open Access: 3 results) Presentation (25 results) (of which Int'l Joint Research: 13 results,  Invited: 1 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Synthesis of Citric Acid-Immobilized Chitosan Derivative and Its Selective Separation and Recovery of In(III) and Ga(III) from Model Waste of Solar Panels2020

    • Author(s)
      日高 栞、伊藤 崇裕、金丸 慎太郎、馬場 由成
    • Journal Title

      KAGAKU KOGAKU RONBUNSHU

      Volume: 46 Issue: 2 Pages: 13-17

    • DOI

      10.1252/kakoronbunshu.46.13

    • NAID

      130007812303

    • ISSN
      0386-216X, 1349-9203
    • Year and Date
      2020-03-20
    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Selective Extraction of In(Ⅲ) and Ga(Ⅲ) Using N-Lauroylsarcosine(NLS)2020

    • Author(s)
      T.Ito, S.Kanemaru, T.Shiragami and Y.Baba
    • Journal Title

      Solvent Extraction Research and Development, Japan

      Volume: in press

    • NAID

      130007953718

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Gold Ion Adsorption on Chitosan Membrane and Separation and Recovery from the Membrane as Gold Nanoparticles2019

    • Author(s)
      鹿屋 京平,馬場 由成
    • Journal Title

      KAGAKU KOGAKU RONBUNSHU

      Volume: 45 Issue: 3 Pages: 123-126

    • DOI

      10.1252/kakoronbunshu.45.123

    • NAID

      130007651441

    • ISSN
      0386-216X, 1349-9203
    • Year and Date
      2019-05-20
    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] High Capacity Adsorption of Metals using a Novel Iminodiacetic Acid Chelate Adsorbent Based on Crosslinked Polyvinylamine Resin2019

    • Author(s)
      大榮 薫, 大島 達也, 小畑佑介,金丸慎太郎,本多剛,臨護
    • Journal Title

      KAGAKU KOGAKU RONBUNSHU

      Volume: 45 Issue: 2 Pages: 66-71

    • DOI

      10.1252/kakoronbunshu.45.66

    • NAID

      130007616616

    • ISSN
      0386-216X, 1349-9203
    • Year and Date
      2019-03-20
    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of structure of aromatic ethers on their extraction of Au(III) from acidic chloride media2019

    • Author(s)
      Oshima T., Horiuchi T., Matsuzaki K., Ohe K.
    • Journal Title

      Hydrometallurgy

      Volume: 183 Pages: 207-212

    • DOI

      10.1016/j.hydromet.2018.12.017

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Extraction Behavior of Metal Cations Using 8-Quinolinol as an Extractant in Cyclopentyl Methyl Ether2019

    • Author(s)
      T.Oshima, T.Koyama, K.Ohe, N.Otsuki
    • Journal Title

      Solvent Extraction Research and Development, Japan

      Volume: 26 Issue: 1 Pages: 1-10

    • DOI

      10.15261/serdj.26.1

    • NAID

      130007662552

    • ISSN
      1341-7215, 2188-4765
    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 酸化水酸化鉄微粒子を内包したポリアクリルアミドクライオゲルによるヒ素(V)のカラム連続吸着特性2019

    • Author(s)
      市川大稀,塩盛弘一郎,大榮 薫
    • Journal Title

      科学・技術研究

      Volume: 8 Pages: 23-29

    • NAID

      130007687551

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Extraction Behavior of Arsenic, Selenium, and Antimony Using Cyclopentyl Methyl Ether from Acidic Chloride Media2019

    • Author(s)
      MATSUO Naoki, OSHIMA Tatsuya, OHE Kaoru, OTSUKI Noriyasu
    • Journal Title

      Solvent Extraction Research and Development, Japan

      Volume: 26 Issue: 2 Pages: 81-89

    • DOI

      10.15261/serdj.26.81

    • NAID

      130007662533

    • ISSN
      1341-7215, 2188-4765
    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Extraction Behavior of Precious Metals in Hydrochloric-acid Media Using a Novel Amine Extractant Bearing a Furan Group2019

    • Author(s)
      T.Oshima, S.Iwao, N.Matsuo, K.Ohe
    • Journal Title

      Solvent Extraction Research and Development, Japan

      Volume: 26 Issue: 2 Pages: 69-80

    • DOI

      10.15261/serdj.26.69

    • NAID

      130007662535

    • ISSN
      1341-7215, 2188-4765
    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Aminophosphonic Acid Extractants and the Effect of the Alkyl Chain on Their Extraction Selectivities for Indium(III), Gallium(III), and Zinc(II)2018

    • Author(s)
      Yuji SASAKI,Tatsuya OSHIMA,Yoshinari BABA
    • Journal Title

      Solvent Extraction Research and Development, Japan

      Volume: 25 Issue: 1 Pages: 11-21

    • DOI

      10.15261/serdj.25.11

    • NAID

      130006733836

    • ISSN
      1341-7215, 2188-4765
    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] A Comprehensive Extraction Study Using a Mono-alkylated Diglycolamic Acid Extractant: Comparison Between a Secondary Amide Group and a Tertiary Amide Group2017

    • Author(s)
      Tsuyoshi Sugita, Iori Fujiwara, Hiroyuki Okamura, Tatsuya Oshima, Yoshinari Baba, Hirochika Naganawa, Kojiro Shimojo
    • Journal Title

      Solvent Extraction Research and Development, Japan

      Volume: 24 Issue: 2 Pages: 61-69

    • DOI

      10.15261/serdj.24.61

    • NAID

      130005689402

    • ISSN
      1341-7215, 2188-4765
    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Extraction of Gold(III) Using Cyclopentyl Methyl Ether in Hydrochloric Acid Media2017

    • Author(s)
      Tatsuya OSHIMA, Naoki OHKUBO, Iori FUJIWARA, Takashi HORIUCHI, Takao KOYAMA, Kaoru OHE, Yoshinari BABA
    • Journal Title

      Solvent Extraction Research and Development, Japan

      Volume: 24 Issue: 2 Pages: 89-96

    • DOI

      10.15261/serdj.24.89

    • NAID

      130005689410

    • ISSN
      1341-7215, 2188-4765
    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Presentation] Highly selective separation of In(III) and Ga(III) with N-lauroylsarcosine and its application to PIMs2019

    • Author(s)
      Takahiro Ito, Tsutomu Shiragami, Yoshinari Baba, M. Ines G.S.Almeida, Spas D. Kolev
    • Organizer
      JTK2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] アルキルアミドサルコシンを用いたIn(III)、Ga(III)の選択的抽出とPIMsへの応用2019

    • Author(s)
      Takahiro Ito, Tsutomu Shiragami, Yoshinari Baba, Spas D. Kolev
    • Organizer
      第38回溶媒抽出討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] N-n-ドデシル-2-ピロリドンによる金の高選択的抽出2019

    • Author(s)
      Shintaro Kanemaru, Takahiro Ito, Tsutomu Shiragami, Yoshinari Baba, Spas D. Kolev
    • Organizer
      第38回溶媒抽出討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Selective Separation of In(III) , Ga(III) from Zn(II) using Polymer Inclusion Membranes2019

    • Author(s)
      Takahiro Ito, Tsutomu Shiragami, Yoshinari Baba, M. Ines G.S.Almeida, Spas D. Kolev
    • Organizer
      第56回化学関連支部合同九州大会・外国人研究者交流国際シンポジウム
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Selective Solvent Extraction of In(Ⅲ), Ga(Ⅲ) over Zn(Ⅱ) from Wastes of Sollar Panels2019

    • Author(s)
      Takahiro Ito, Shintaro Kanemaru, Yukie O'bryan, M. Ines G.S.Almeida, Spas D. Kolev, Yoshinari Baba
    • Organizer
      APPChE2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Development of highly selective extractant of Cd(Ⅱ) over Zn(Ⅱ) and its application to the CTA membrane transport2019

    • Author(s)
      Shintaro Kanemaru, Takahiro Ito, Spas D. Kollev, Yoshinari Baba
    • Organizer
      APPChE2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Selective extraction of In(Ⅲ) and Ga(Ⅲ) over Zn(Ⅱ) with thiol-containing extractants and its application to membrane separation2019

    • Author(s)
      Shintaro Kanemaru, Takahiro Ito, Yoshinari Baba
    • Organizer
      APPChE2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Selective membrane separation of In(III) , Ga(III) over Zn(II) from wastes of solar panel using PIMs2019

    • Author(s)
      Takahiro Ito, Shintaro Kanemaru, Yoshinari Baba, Yukie O'bryan, M. Ines G.S.Almeida, Spas D. Kolev
    • Organizer
      APPChE2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Solvent extraction of amino acid esters using a calix[6]arene carboxylic acid derivative in aromatic ethers2019

    • Author(s)
      Tokiya ASANO, Tatsuya OSHIMA, Kaoru OHE, Keisuke OHTO
    • Organizer
      APPChE2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 芳香族エーテルを用いたイオン溶媒和に基づく塩酸系からの金属イオンの抽出2019

    • Author(s)
      松崎 喜代治,大島 達也, 大榮 薫
    • Organizer
      第38回溶媒抽出討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] カリックスアレーン誘導体の溶媒となるエーテル化合物の開発と抽出特性の評価2019

    • Author(s)
      浅野迅矢, 大島達也, 大榮薫, 大渡啓介
    • Organizer
      第56回化学関連支部合同九州大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 活性炭への化学修飾による高機能性吸着材の開発と有機化合物および金属吸着能の評価2018

    • Author(s)
      鹿屋 京平,塚﨑 孝規,大島 達也,馬場 由成
    • Organizer
      化学工学会 第50回秋季大会
    • Related Report
      2018 Research-status Report
  • [Presentation] 高専での研究活動~貴金属回収技術をテーマとして2018

    • Author(s)
      岩熊美奈子
    • Organizer
      化学工学会第83年会
    • Related Report
      2017 Research-status Report
    • Invited
  • [Presentation] N, Oを配位原子とする新規抽出剤による貴金属イオンの選択的分離2017

    • Author(s)
      鹿屋京平,大島達也,馬場由成
    • Organizer
      化学関連支部合同九州大会
    • Related Report
      2017 Research-status Report
  • [Presentation] 活性炭表面の化学修飾による高機能性吸着剤の開発と水環境浄化への応用2017

    • Author(s)
      鹿屋 京平,大島 達也, 馬場 由成
    • Organizer
      化学工学会 第49回秋季大会
    • Related Report
      2017 Research-status Report
  • [Presentation] キチンを原料としたポリオールキトサン誘導体の合成とAs, SeおよびSbの吸着特性2017

    • Author(s)
      愛甲 尚正,大島 達也,馬場 由成,大榮 薫
    • Organizer
      化学工学会 第49回秋季大会
    • Related Report
      2017 Research-status Report
  • [Presentation] 硫黄原子と窒素原子を配位子とする2座高分子型抽出剤の新規合成と金(III)の抽出平衡2017

    • Author(s)
      花田 隆文,岩熊 美奈子,馬場 由成
    • Organizer
      化学工学会 第49回秋季大会
    • Related Report
      2017 Research-status Report
  • [Presentation] 水酸基を導入したキトサン誘導体による半金属元素の吸着特性2017

    • Author(s)
      愛甲尚正 杉本匡弥 大島達也 馬場由成
    • Organizer
      平成29年度繊維学会秋季研究発表会
    • Related Report
      2017 Research-status Report
  • [Presentation] キトサン膜の生成と金ナノ粒子化への応用2017

    • Author(s)
      鹿屋京平 馬場由成
    • Organizer
      平成29年度繊維学会秋季研究発表会
    • Related Report
      2017 Research-status Report
  • [Presentation] Selective Extraction Separation of Indium and Gallium with Thiol Derivative2017

    • Author(s)
      Shintaro Kanemaru, Rieko Miura, Megumi Tokumaru, Tatsuya Oshima, Yoshinari Baba
    • Organizer
      The 21st International Solvent Extraction Conference
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Extraction Behavior of Precious Metals from Hydrochloric Acid with 8-Dodecoxyquinoline2017

    • Author(s)
      Kyohei Kanoya, Tatsuya Oshima, Yoshinari Baba
    • Organizer
      The 21st International Solvent Extraction Conference
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Synthesis of Methylacrylate-Styrene Copolymer Containing A Sulfur Atom and Extraction Equilibrium of Gold(III) from Hydrochloric Acid2017

    • Author(s)
      Minako Iwakuma, Takafumi Hanada, Yoshinari Baba
    • Organizer
      The 21st International Solvent Extraction Conference
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Extraction of Arsenic and Antimony Using Cyclopentyl Methyl Ether in Hydrochloric Acid Media2017

    • Author(s)
      Naoki Matsuo, Tatsuya Oshima, Yoshinari Baba, Noriyasu Otsuki
    • Organizer
      The 21st International Solvent Extraction Conference
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Selective Extraction of Antimony and Arsenic with Alkylated Piperazine Derivative2017

    • Author(s)
      Rieko Miura, Tatsuya Oshima, Yoshinari Baba
    • Organizer
      The 21st International Solvent Extraction Conference
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Anion Exchangeof Arsenic Oxyanions by Ni-Zn Hydroxide Double Salts2017

    • Author(s)
      Kaoru Ohe, Ryosuke Tabuchi, Tatsuya Oshima, Yoshinari Baba, Takayoshi Hara, Shogo Shimazu
    • Organizer
      The 21st International Solvent Extraction Conference
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Patent(Industrial Property Rights)] 貴金属の分離回収方法及びその方法によって回収される貴金属微粒子2019

    • Inventor(s)
      馬場由成
    • Industrial Property Rights Holder
      馬場由成
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2019-039583
    • Filing Date
      2019
    • Related Report
      2019 Annual Research Report

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Published: 2017-07-21   Modified: 2021-02-19  

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