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Understanding the growth mechanism of boron carbon nitride films based on the ion transportation behavior in HiPIMS deischarge

Research Project

Project/Area Number 17KK0136
Research Category

Fund for the Promotion of Joint International Research (Fostering Joint International Research)

Allocation TypeMulti-year Fund
Research Field Material processing/Microstructural control engineering
Research InstitutionTokyo Metropolitan University

Principal Investigator

Shimizu Tetsuhide  東京都立大学, システムデザイン学部, 准教授 (70614543)

Project Period (FY) 2018 – 2020
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥14,170,000 (Direct Cost: ¥10,900,000、Indirect Cost: ¥3,270,000)
Keywordsイオン化物理蒸着 / HiPIMS / 炭窒化ホウ素膜 / イオン質量分析 / イオン流束 / イオンエネルギー分布 / 化学結合状態 / 炭化窒化ホウ素 / t-BN相 / FTIR / XPS / 運動量変換 / エミッシブプローブ / グリッドレスプローブ / イオンエネルギー / プラズマ電位 / イオン化率 / マグネトロン磁場 / グリッドプローブ / 炭化ホウ素 / イオン / イオン輸送 / エネルギアナライザ型質量分析 / パルスプラズマ
Outline of Final Research Achievements

To establish a process design guideline for HiPIMS deposition of highly-toughened boron carbon-nitride (BCN) coatings, this international collaborative research has promoted systematic investigation of ion flux and its energy distribution by using an ion mass spectrometer. As results, influential pulsing process parameters on the ion fluxes incident on the substrate were clarified, leading to the controllability of the momentum transfer per deposited atoms by the selectivity of the incident ionic species. Following BCN depositions and its characterizations revealed a great influence on the nucleation behavior in the several bonding states in BCN film.

Academic Significance and Societal Importance of the Research Achievements

本国際共同研究によりBCN膜成長に対するHiPIMS放電における入射粒子の関連因子の系統的な検証が実現された。これにより基礎原理に基づいた各種HiPIMS入力パラメータの位置づけが明確化され、HiPIMSプロセス設計指針の礎が構築された。これらは我が国におけるHiPIMS技術への産業的な要望を先導するものであり、今後当該技術の国内における産業化に大きく貢献できるものである。また欧州研究機関と盤石な研究交流基盤が築かれたことは、今後アジア諸国における研究者間のネットワークを構築する上でもその社会的意義は大きい。

Report

(4 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Research-status Report
  • 2018 Research-status Report
  • Research Products

    (15 results)

All 2021 2020 2019

All Int'l Joint Research (1 results) Journal Article (6 results) (of which Int'l Joint Research: 3 results,  Peer Reviewed: 5 results,  Open Access: 2 results) Presentation (7 results) (of which Int'l Joint Research: 4 results,  Invited: 3 results) Funded Workshop (1 results)

  • [Int'l Joint Research] Linkoping(リンショーピン)大学(スウェーデン)2019

    • Related Report
      2020 Annual Research Report
  • [Journal Article] Low temperature growth of stress-free single phase α-W films using HiPIMS with synchronized pulsed substrate bias2021

    • Author(s)
      Shimizu Tetsuhide、Takahashi Kazuki、Boyd Robert、Viloan Rommel Paulo、Keraudy Julien、Lundin Daniel、Yang Ming、Helmersson Ulf
    • Journal Title

      Journal of Applied Physics

      Volume: 129 Issue: 15 Pages: 155305-155305

    • DOI

      10.1063/5.0042608

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Experimental verification of deposition rate increase, with maintained high ionized flux fraction, by shortening the HiPIMS pulse2021

    • Author(s)
      Shimizu T、Zanska M、Villoan R P、Brenning N、Helmersson U、Lundin Daniel
    • Journal Title

      Plasma Sources Science and Technology

      Volume: 30 Issue: 4 Pages: 045006-045006

    • DOI

      10.1088/1361-6595/abec27

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Effect of Peak Current Density on Inner-wall Deposition of Ti Films by High-power Impulse Magnetron Sputtering2020

    • Author(s)
      小宮 英敏, 寺西 義一, シャア アナ, 楊 明, 清水 徹英
    • Journal Title

      Vacuum and Surface Science

      Volume: 63 Issue: 8 Pages: 404-412

    • DOI

      10.1380/vss.63.404

    • NAID

      130007886643

    • ISSN
      2433-5835, 2433-5843
    • Year and Date
      2020-08-10
    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] 大電力パルススパッタリング技術とそのパルスパターンの多様性2020

    • Author(s)
      清水徹英
    • Journal Title

      日本材料科学会誌 「材料の科学と工学」

      Volume: 57 Pages: 6-9

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] HiPIMS法によるAlTiN硬質膜の形成と そのプレス金型への適用2020

    • Author(s)
      清水徹英
    • Journal Title

      メカニカル・サーフェス・テック

      Volume: 6月号 Pages: 30-32

    • Related Report
      2020 Annual Research Report
  • [Journal Article] New Advancement of Ionized Physical Vapor Deposition Towards Realization of Highly Durable Forming Die2019

    • Author(s)
      清水 徹英
    • Journal Title

      PLASTOS

      Volume: 2 Issue: 19 Pages: 421-425

    • DOI

      10.32277/plastos.2.19_421

    • NAID

      130007683398

    • ISSN
      2433-8826
    • Related Report
      2019 Research-status Report
    • Peer Reviewed
  • [Presentation] Synthesis of boron carbon nitride coatings using HiPIMS with synchronized substrate bias2021

    • Author(s)
      Tetsuhide Shimizu, Miki Kikuta, Naoto Hayakawa, Ming Yang
    • Organizer
      The 96th IUVSTA Workshop "HiPIMS Today"
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis of semi-coherent Ni/NiO dual-phase nanoparticles using high-power pulsed hollow cathode sputtering2021

    • Author(s)
      Tetsuhide Shimizu, Sebastian Ekeroth, Shuga Ikeda, Shun Watanabe, Robert Boyd, Ming Yang, Ulf Helmersson
    • Organizer
      14th International Conference on Plasma-Nano Technology & Science
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] HiPIMSプラズマの過渡応答特性とその薄膜成長への応用2021

    • Author(s)
      清水徹英
    • Organizer
      日本表面真空学会スパッタリングおよぼプラズマプロセス技術部会 第165回定例研究会
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] HiPIMS法を用いたコーティング技術の開発と工具へのマイクロテクスチャ構造付与の効果2020

    • Author(s)
      清水徹英
    • Organizer
      日本塑性加工学会 金型分科会 第51回セミナー
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] B4Cターゲットを用いた反応性HiPIMS 放電におけるプラズマ特性評価2019

    • Author(s)
      早川直人,小宮英敏,寺西義一,楊明,清水徹英,
    • Organizer
      2019年 日本表面真空学会学術講演会
    • Related Report
      2019 Research-status Report
  • [Presentation] Synthesis of boron carbon nitride films by reactive HiPIMS of B4C in Ar/N2 mixture2019

    • Author(s)
      Naoto Hayakawa, Hidetoshi Komiya, Yoshikazu Teranishi, Ming Yang, Tetsuhide Shimizu
    • Organizer
      ISSP2019 (The 15th International Symposium on Sputtering & Plasma Processes)
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Impact of magnetic field configuration in HiPIMS discharge of W in Ar atmosphere2019

    • Author(s)
      Yuta Yamamura, Yoshikazu Teranishi, Hidetoshi Komiya, Ming Yang, Tetsuhide Shimizu
    • Organizer
      ISSP2019 (The 15th International Symposium on Sputtering & Plasma Processes)
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Funded Workshop] 第96回IUVSTA国際ワークショップ「HiPIMS Today」2021

    • Related Report
      2020 Annual Research Report

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Published: 2018-01-25   Modified: 2022-01-27  

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