| Project/Area Number |
18002011
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| Research Category |
Grant-in-Aid for Specially Promoted Research
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| Allocation Type | Single-year Grants |
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| Review Section |
Science and Engineering
Chemistry
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| Research Institution | Kyushu University |
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Principal Investigator |
KATSUKI Tsutomu Kyushu University, 大学院・理学研究院, 教授 (40037271)
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| Co-Investigator(Kenkyū-buntansha) |
SAKAI Ken 九州大学, 大学院・理学研究院, 教授 (30235105)
UCHIDA Tatsuya 九州大学, 大学院・理学研究院, 助教 (50380564)
IRIE Ryo 九州大学, 大学院・理学研究院, 助教授 (70243889)
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| Co-Investigator(Renkei-kenkyūsha) |
MATSUMOTO Kazuhiro 九州大学, 大学院・理学研究院, 助教 (40512182)
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| Research Collaborator |
KAWABATA Hirotoshi 九州大学, 大学院・理学研究院, 博士研究員
EGAMI Hiromichi 九州大学, 大学院・理学研究院, 学術振興会特別研究員
SUEMATSU Hidehiro 九州大学, 大学院・理学研究院, 学術振興会特別研究員
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| Project Period (FY) |
2006 – 2009
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| Project Status |
Completed (Fiscal Year 2009)
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| Budget Amount *help |
¥331,630,000 (Direct Cost: ¥255,100,000、Indirect Cost: ¥76,530,000)
Fiscal Year 2009: ¥50,700,000 (Direct Cost: ¥39,000,000、Indirect Cost: ¥11,700,000)
Fiscal Year 2008: ¥50,700,000 (Direct Cost: ¥39,000,000、Indirect Cost: ¥11,700,000)
Fiscal Year 2007: ¥50,700,000 (Direct Cost: ¥39,000,000、Indirect Cost: ¥11,700,000)
Fiscal Year 2006: ¥179,530,000 (Direct Cost: ¥138,100,000、Indirect Cost: ¥41,430,000)
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| Keywords | 環境調和 / 多重機能触媒 / 過酸化水素水 / 分子状酸素 / 水素結合 / エポキシ化 / 光分子デバイス / 水素生成触媒 / 光活性化 / 還境調和 |
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| Research Abstract |
Environment and resource conservation is the most urgent issue that human beings face. To address this issue and construct a sustainable society, development of selective, atom-efficient and eco-friendly synthetic reactions is essential. Biological material transformation systems are highly selective and atom-efficient and green, but several enzymes participate in most biological systems that are difficult to be implemented by the current chemical way. To realize equally green and efficient reactions with a catalyst, we designed complexes that can change their structure and exhibit an appropriate catalytic performance along reaction coordinate. With such complexes as catalyst, we could successfully achieve highly enantioselective and atom-efficient oxidation reactions using molecular oxygen or hydrogen peroxide as the terminal oxidant. This research demonstrated the effectiveness of a catalyst that can change its catalytic performance along reaction coordinate, for realizing a green reaction.
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