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動的錯体による応答性配位空間の創出と機能の多段階制御

Research Project

Project/Area Number 18033005
Research Category

Grant-in-Aid for Scientific Research on Priority Areas

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionUniversity of Tsukuba

Principal Investigator

鍋島 達弥  University of Tsukuba, 大学院・数理物質科学研究科, 教授 (80198374)

Co-Investigator(Kenkyū-buntansha) 秋根 茂久  筑波大学, 大学院・数理物質科学研究科, 講師 (30323265)
池田 忠作  筑波大学, 大学院・数理物質科学研究科, 準研究員 (30378541)
佐藤 総一  首都大学東京, 都市教養学部, 准教授 (90280908)
Project Period (FY) 2006 – 2007
Project Status Completed (Fiscal Year 2007)
Budget Amount *help
¥3,800,000 (Direct Cost: ¥3,800,000)
Fiscal Year 2007: ¥1,900,000 (Direct Cost: ¥1,900,000)
Fiscal Year 2006: ¥1,900,000 (Direct Cost: ¥1,900,000)
Keywords超分子化学 / 分子認識 / 配位結合 / 応答性分子 / 協同効果
Research Abstract

外部因子応答性の機能性分子の研究が近年活発に行われるようになってきたが、多段階の協同性や応答性、これを利用したlogic gateといった動的機能を有する分子は興味深いターゲットであるにもかかわらずその報告例は非常に少ない。そこで本研究では配位結合を利用した自己集積により、柔軟な構造をもつ多元応答性配位空間の構築を行い、分子情報の伝達や機能の変換および増幅を目指した研究を進めた。そこで配位結合による自己組織化・自己集積化による機能場の創成を構築の基本的ストラテジーとした。さらにこの場に、ゲストの添加、酸化還元など外部因子を用いた構造および機能に対する摂動を加えることによって、協同的で動的な機能の多段階制御の実現が可能な配位空間の創出を目指した。
擬クリプタンドによる応答性配位空間の創出として以下の検討を行った。球状配位空間として、正八面体型の鉄一ビピリジン錯体部を構成要素とする擬クリプタンド型アニオンレセプターを設計した。認識場となる空間を包み込むように三つの尿素部位を導入し、効果的なアニオンの包接にふさわしい構造とした。この系においては、認識場の近傍に位置する鉄一ビピリジン錯体部とゲストの静電相互作用の大きさをレドックスにより変化させることで、アニオン認識能を劇的に変化させることに成功した。また我々が開発した新規配位子であるsalamoのC字型誘導体を基本骨格に用い、静的構造および動的性質(配座変換・化学反応)の制御として、「球状配位空間」に取り込まれるイオンの種類に応じた錯林分子の動的な配座変換(らせん反転)速度の制御を実現することができた。

Report

(2 results)
  • 2007 Annual Research Report
  • 2006 Annual Research Report
  • Research Products

    (95 results)

All 2008 2007 2006 Other

All Journal Article (18 results) (of which Peer Reviewed: 7 results) Presentation (75 results) Book (1 results) Remarks (1 results)

  • [Journal Article] Synthesis Stability,and Complexation Behavior of Isolable Salen-Type N^2S^2 and N^2SO Ligands Based on Thiol and Oxime Functionalities2008

    • Author(s)
      Akine, S., Akimoto, A., Shiga, , Oshio, H, Nabeshima, T
    • Journal Title

      Inorg.Chem. 47

      Pages: 875-885

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Self-assembled Cyclic Boron-Dipyrrin Oligomers2008

    • Author(s)
      lkead, C., Nabeshima, T.
    • Journal Title

      Chem.Commun.

      Pages: 721-723

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis,Characterization and Molecular Recognition of a Bis-Platinum Terpyridine Dimer2008

    • Author(s)
      Trokowski, R., Akine, S., Nabeshima, T.
    • Journal Title

      Chem.Commun.

      Pages: 889-890

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Novel Cis-Trans lsomerism Found in a Sulfur-Bridged Pd^2AU^2 Tetranuclear Complex with 「Pd(amine)^2(thiolato)^2」-Type Building2008

    • Author(s)
      Taguchi, M., Sameshima, Y., lgashira-Kamiyama, A., Akine, S., Nabeshima, T., Konno, T.
    • Journal Title

      Chem.Commun. 37

      Pages: 244-245

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Core/Shell Oligometallic Template Synthesis of Macrocyclic Hexaoxime2007

    • Author(s)
      Akine, S., Sunaga, S., Taniguchi, T., Miyazaki, H., Nabeshima
    • Journal Title

      Inorg.Chem 46

      Pages: 2959-2961

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Oligometallic Template Strategy for Ring-Closing Olefin Metathesis:Highly Cis-and Trans-Selective Synthesis of a 32-Membered Macrocyclic Tetraoxime2007

    • Author(s)
      Akine, S., Kagiyama, S., T.Nabeshima
    • Journal Title

      Inorg.Chem 46

      Pages: 9525-9527

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Multi-Step Regulation of Anion Recognition by Redox-Active Pseudocryptand2007

    • Author(s)
      Nabeshima, T., Masubuchi, S., Taguchi, N., Akine, S., Saiki, T., Sato, S.
    • Journal Title

      Tetrahedron Lett. 48

      Pages: 1595-1598

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Multi-metal Complexation and Partially Templated Synthesis of Metal Clusters by Using Triangular Trisaloph Ligands2007

    • Author(s)
      Nabeshima, T., Miyazaki, H., Iwasaki, A., Akine, S., Saiki, T., Ikeda, C.
    • Journal Title

      Tetrahedron 63

      Pages: 3328-3333

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Core/Shell Oligometallic Template Synthesis of Macrocyclic Hexaoxime2007

    • Author(s)
      Akine, S., Sunaga, S., Taniguchi, T., Miyazaki, H., Nabeshima, T.
    • Journal Title

      Inorg.Chem. (in press)

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Tricyclic Pseudocryptand Formed by Reaction of Fe^<II> with Tripodand Bearing Triazacrown Ether2006

    • Author(s)
      Nabeshima, T., Tanaka, Y., Saiki, T., Akine, S., Ikeda, C., Sato, S.
    • Journal Title

      Tetrahedron Lett. 47

      Pages: 3541-3544

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Heterometallic Zn_2La and ZnLu Complexes Formed by Site-selective Transmetalation of a Dimeric Homotrinuclear Zinc(II) Complex2006

    • Author(s)
      Akine, S., Taniguchi, T., Nabeshima, T.
    • Journal Title

      Chem.Lett. 35

      Pages: 604-605

    • NAID

      10019162564

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Octanuclear Zinc(II) and Cobalt(II) Clusters Produced by Cooperative Tetrameric Assembling of Oxime Chelate Ligands2006

    • Author(s)
      Akine, S., Dong, W., Nabeshima, T.
    • Journal Title

      Inorg.Chem. 45

      Pages: 4677-4684

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Isolation and Molecular Structure of the Organo-persulfuranes [12-S-6(C6)]2006

    • Author(s)
      Sato, S., Matsunaga, K., Horn, E., Furukawa, N., Nabeshima, T.
    • Journal Title

      J.Am.Chem.Soc. 128

      Pages: 6778-6779

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Efficient Formation of Homo and Hetero Metal Clusters by Triangular Trisaloph Ligand as a Partial Template2006

    • Author(s)
      Nabeshima, T., Miyazaki, H., Iwasaki, A., Akine, S., Saiki, T., Ikeda, C., Sato, S.
    • Journal Title

      Chem.Lett. 35

      Pages: 1070-1071

    • NAID

      10018063494

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Guest-dependent Inversion Rate of a Tetranuclear Single Metallohelicate2006

    • Author(s)
      Akine, S., Taniguchi, T., Matsumoto, T., Nabeshima, T.
    • Journal Title

      Chem.Commun.

      Pages: 4961-4963

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Chiral Single-stranded Metallohelix : Metal-mediated Folding of Linear Oligooxime Ligand2006

    • Author(s)
      Akine, S., Taniguchi, T., Nabeshima, T.
    • Journal Title

      Tetrahedron Lett. 47

      Pages: 8419-8422

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Helical Metallohost-Guest Complexes via Site-Selective Transmetalation of Homotrinuclear Complexes2006

    • Author(s)
      Akine, S., Taniguchi, T., Nabeshima, T.
    • Journal Title

      J.Am Chem.Soc. 128

      Pages: 15765-15774

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Acyclic Bis(N^2O^2 chelate)Ligand for Trinuclear d-Block Homo-and Heterometal Complexes

    • Author(s)
      Akine, S., Taniguchi, T., Nabeshima, T.
    • Journal Title

      lnorg.Chem (In press)

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Presentation] Design and Synthesis of Helical Oligooxime-Zinc(II)Complexes for lon Recognition2008

    • Author(s)
      S., Akine
    • Organizer
      First International Symposium on Interdisciplinary Materials Science (ISIMS-2008)
    • Place of Presentation
      Tsukuba,Japan
    • Related Report
      2007 Annual Research Report
  • [Presentation] Synthesis of Zinc(II)Dipyrrin Cyclic Assembly by Heteroleptic Coordination2008

    • Author(s)
      S. Ueda, C. Ikeda, T. Nabeshima
    • Organizer
      First International Symposium on Interdisciplinary Materials Science (ISIMS-2008)
    • Place of Presentation
      Tsukuba,Japan
    • Related Report
      2007 Annual Research Report
  • [Presentation] lon Pair Recognition by Multidentate Pyridine Ligand Bearing Urea Moieties2008

    • Author(s)
      H. Tamai, T. Nabeshima
    • Organizer
      First International Symposium on Interdisciplinary Materials Science (ISIMS-2008)
    • Place of Presentation
      Tsukuba,Japan
    • Related Report
      2007 Annual Research Report
  • [Presentation] Selr-assembled Cyclic Boron-Dipyrin Oligomers as a Supramolecular Host2008

    • Author(s)
      C. Ikeda, T. Nabeshima
    • Organizer
      First International Symposium on Interdisciplinary Materials Science (ISIMS-2008)
    • Place of Presentation
      Tsukuba,Japan
    • Related Report
      2007 Annual Research Report
  • [Presentation] SYnthesis and Complexation of Podand with a Catechol Moiety for Responsible Metallohost2008

    • Author(s)
      S. Kijima, Y. Imamura, T. Nabeshima
    • Organizer
      First International Symposium on Interdisciplinary Materials Science (ISIMS-2008)
    • Place of Presentation
      Tsukuba,Japan
    • Related Report
      2007 Annual Research Report
  • [Presentation] One-Synthesis of Hetero and Homo Multi-metal Complexes of Macrocyclic Trisaloph Ligand2008

    • Author(s)
      R. Ebata, T. Nabeshima
    • Organizer
      First International Symposium on Interdisciplinary Materials Science (ISIMS-2008)
    • Place of Presentation
      Tsukuba,Japan
    • Related Report
      2007 Annual Research Report
  • [Presentation] Synthesis of Macrocyclic Hexaoxime Ligand Using Two Different Metal lons2008

    • Author(s)
      S. Sunaga, S. Akine, T. Nabeshima
    • Organizer
      First International Symposium on Interdisciplinary Materials Science (ISIMS-2008)
    • Place of Presentation
      Tsukuba,Japan
    • Related Report
      2007 Annual Research Report
  • [Presentation] Synthesis and Luminescent Properties of Zinc(II)-lanthanide(III)Complexes of Oxime Chelate Ligands2008

    • Author(s)
      F. Utsuno, Y. Morita, S. Akine, T. Nabeshima
    • Organizer
      First International Symposium on Interdisciplinary Materials Science (ISIMS-2008)
    • Place of Presentation
      Tsukuba,Japan
    • Related Report
      2007 Annual Research Report
  • [Presentation] Synthesis, lon Recognition Ability and Luminescence Properties of Novel lridium Complexes with Azacrown Ethers2008

    • Author(s)
      M. Saireji, C. lkeda, T. Nabeshima
    • Organizer
      First lnternational Symposium on lnterdisciplinary Materials Science (lSlMS-2008)
    • Place of Presentation
      Tsukuba, Japan
    • Related Report
      2007 Annual Research Report
  • [Presentation] Synthesis of Novel Macrocyclic Oligo-oxime Ligands by Ring-closing Olefin Metathesis of Helical Metal Complexes2008

    • Author(s)
      T. Tadokoro, S. Skine, T. Nabeshima
    • Organizer
      First lnternational Symposium on lnterdisciplinary Materials Science (lSlMS-2008)
    • Place of Presentation
      Tsukuba, Japan
    • Related Report
      2007 Annual Research Report
  • [Presentation] Synthesis and Guest Recognition Ability of Macrocyclic Oligo-Dipyrrin BF2 Complex2008

    • Author(s)
      N. Sakamoto, C. lkeda, T. Naveshima
    • Organizer
      First lnternational Symposium on lnterdisciplinary Materials Science (lSlMS-2008)
    • Place of Presentation
      Tsukuba, Japan
    • Related Report
      2007 Annual Research Report
  • [Presentation] Platinum-Directed Formation of Terpyridime-Type Cyclic Trimucleat Self-Assembly2008

    • Author(s)
      R. Trokowski, S. Akine, T. N. abeshima
    • Organizer
      First lnternational Symposium on lnterdisciplinary Materials Science (lSlMS-2008)
    • Place of Presentation
      Tsukuba, Japan
    • Related Report
      2007 Annual Research Report
  • [Presentation] Hellical Complexes of Flexible Ligand Based of Two N2O2 Chelate Moieties Connected with Polyether Linker2008

    • Author(s)
      Y. Morita, S. Akine, T. Nabeshima
    • Organizer
      First lnternational Symposium on lnterdisciplinary Materials Science (lSlMS-2008)
    • Place of Presentation
      Tsukuba, Japan
    • Related Report
      2007 Annual Research Report
  • [Presentation] Synthesis and Function of Novel Terpyridine Podand Bearing Several Recognition Sites2008

    • Author(s)
      T. Tadokoro, S. Skine, T. Nabeshima
    • Organizer
      First lnternational Symposium on lnterdisciplinary Materials Science (lSlMS-2008)
    • Place of Presentation
      Tsukuba, Japan
    • Related Report
      2007 Annual Research Report
  • [Presentation] Synthesis of Novel Terpyridine Ligand Bearing Naphalene-diimide Moedties at 6,6"-Positions2008

    • Author(s)
      T. Shimada, C. Ikeda, T. Nabeshima
    • Organizer
      First lnternational Symposium on lnterdisciplinary Materials Science (lSlMS-2008)
    • Place of Presentation
      Tsukuba, Japan
    • Related Report
      2007 Annual Research Report
  • [Presentation] Synthesis and Complexation of Tripodand Having Terminal Catechol Moieties2008

    • Author(s)
      Y. Imamura, T. Nabeshima
    • Organizer
      First lnternational Symposium on lnterdisciplinary Materials Science (lSlMS-2008)
    • Place of Presentation
      Tsukuba, Japan
    • Related Report
      2007 Annual Research Report
  • [Presentation] 2つの四座キレート部位をもつオキシム多座配位子の錯形成によるらせん構造の構築2008

    • Author(s)
      森田陽子・秋根茂久・鍋島達弥
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      東京
    • Related Report
      2007 Annual Research Report
  • [Presentation] N2O2配位部位を有するジピリンの非遷移金属錯体の合成と性質2008

    • Author(s)
      池田忠作・上田智子・鍋島達弥
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      東京
    • Related Report
      2007 Annual Research Report
  • [Presentation] N2O2配位部位を有するジピリン亜鉛(II)錯体の合成と性質2008

    • Author(s)
      上田智子・池田忠作・鍋島達弥
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      東京
    • Related Report
      2007 Annual Research Report
  • [Presentation] 白金(II)テルピリジン錯体部位を含む環状自己集合体の構築と認識能2008

    • Author(s)
      トロコウスキーロバート・鍋島達弥
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      東京
    • Related Report
      2007 Annual Research Report
  • [Presentation] テルピリジン白金(II)錯体部位を有するジアザクラウンホストの合成と分子認識能2008

    • Author(s)
      木村望・池田忠作・鍋島達弥
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      東京
    • Related Report
      2007 Annual Research Report
  • [Presentation] 鎖に3つのアミド基を有する鉄(II)擬クリプタンドの合成と機能2008

    • Author(s)
      古川裕理・鍋島達弥
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      東京
    • Related Report
      2007 Annual Research Report
  • [Presentation] 閉環メタセシスによるオリゴオキシム配位子の錯形成能の制御2008

    • Author(s)
      秋根茂久・鍵山聡子・鍋島達弥
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      東京
    • Related Report
      2007 Annual Research Report
  • [Presentation] オキシムキレート配位子を持つ亜鉛(II)ーランタニド(II)錯体の合成とその発光特性2008

    • Author(s)
      宇津野文彦・森田陽子・秋根茂久・鍋島達弥
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      東京
    • Related Report
      2007 Annual Research Report
  • [Presentation] 大環状ジピリンオリゴマーの合成とゲスト認識能2008

    • Author(s)
      坂本直也・池田忠作・鍋島達弥
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      東京
    • Related Report
      2007 Annual Research Report
  • [Presentation] Trisaloph配位子を用いたホモ多核錯体の合成とそのイオン認識2008

    • Author(s)
      江幡良子・鍋島達弥
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      東京
    • Related Report
      2007 Annual Research Report
  • [Presentation] 擬クリプタンド型トリカテコラートホストの合成とその性質2008

    • Author(s)
      今村友紀・鍋島達弥
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      東京
    • Related Report
      2007 Annual Research Report
  • [Presentation] アザクラウンエーテルをもつ新規イリジウム錯体の合成および金属イオン認識能と発光特性2008

    • Author(s)
      西連地雅樹・池田忠作・鍋島達弥
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      東京
    • Related Report
      2007 Annual Research Report
  • [Presentation] 複数の金属イオンをテンプレートとするオリゴオキシム配位子の合成2008

    • Author(s)
      須永修一・秋根茂久・鍋島達弥
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      東京
    • Related Report
      2007 Annual Research Report
  • [Presentation] 尿素部位を有する新規オリゴピリジン配位子のイオン対認識2008

    • Author(s)
      玉井大史・鍋島達弥
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      東京
    • Related Report
      2007 Annual Research Report
  • [Presentation] アニオン認識場として尿素部位を有するテルピリジンポダンドの合成と機能2008

    • Author(s)
      巻口琢郎・鍋島達弥
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      東京
    • Related Report
      2007 Annual Research Report
  • [Presentation] 集積型らせんメタロホ入トのための含カテコールポダンドの合成と錯形成2008

    • Author(s)
      木嶋志穂・今村友紀・鍋島達弥
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      東京
    • Related Report
      2007 Annual Research Report
  • [Presentation] 6,6"位に認識部位を有する新規なテルピリジン配位子の合成と機能2008

    • Author(s)
      嶋田敏彦・池田忠作・鍋島達弥
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      東京
    • Related Report
      2007 Annual Research Report
  • [Presentation] らせん型金属錯体のオレフインメタセシス反応による新規な大環状オリゴオキシム配位子の合成2008

    • Author(s)
      田所利雄・秋根茂久・鍋島達弥
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      東京
    • Related Report
      2007 Annual Research Report
  • [Presentation] 複数の疎水性側鎖を有するTrisaloph-へテロ多核錯体の合成2008

    • Author(s)
      佐々木正男・今村友紀・江幡良子・鍋島達弥
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      東京
    • Related Report
      2007 Annual Research Report
  • [Presentation] らせん型テトラオキシム三核錯体のアニオン認識能2008

    • Author(s)
      保立さやか・秋根茂久・鍋島達弥
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      東京
    • Related Report
      2007 Annual Research Report
  • [Presentation] pybox骨格をもつ新規メタロホストの合成と機能2008

    • Author(s)
      三宅惇哉・今村友紀・池田忠作・鍋島達弥
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      東京
    • Related Report
      2007 Annual Research Report
  • [Presentation] Functional Molecular Systems Responding to External Stimulus2007

    • Author(s)
      T., Nabeshima
    • Organizer
      International Symposium on Nanoscience and Photoscience (Pre-symposium of ISNA-12 in
    • Place of Presentation
      Ikoma, Japan
    • Year and Date
      2007-07-21
    • Related Report
      2007 Annual Research Report
  • [Presentation] Synthesi of a Macrocyclic Hexaoxime Using a Zn3La Heterometallic Template2007

    • Author(s)
      S. Akine, S. Sunaga, T. Nabeshima
    • Organizer
      International Symposium on Nanoscience and Photoscience (Pre-symposium of ISNA-12 in Nara)
    • Place of Presentation
      Ikoma, Japan
    • Year and Date
      2007-07-21
    • Related Report
      2007 Annual Research Report
  • [Presentation] Synthesis of Macrocyclic Dipyrrin Oligomers as a Supramolecular Host2007

    • Author(s)
      C. Ikeda, N. Sakamoto, T. Nabeshima
    • Organizer
      International Symposium on Nanoscience and Photoscience (Pre-symposium of ISNA-12 in Nara)
    • Place of Presentation
      Ikoma, Japan
    • Year and Date
      2007-07-21
    • Related Report
      2007 Annual Research Report
  • [Presentation] Pseudocryptand-Type Tris-Catecholate Ti(IV) Host:Synthesis,Structure・Amine Recognition2007

    • Author(s)
      Y. Imamura, K. Fukushima, S. Akine, T. Nabeshima
    • Organizer
      International Symposium on Nanoscience and Photoscience (Pre-symposium of ISNA-12 in Nara)
    • Place of Presentation
      Ikoma, Japan
    • Year and Date
      2007-07-21
    • Related Report
      2007 Annual Research Report
  • [Presentation] Cooperative and Responding lon Recognition of Metallomacrocycles2007

    • Author(s)
      T., Nabeshima
    • Organizer
      12th International Symposium on Novel Aromatic Compounds
    • Place of Presentation
      Awaji,Japan
    • Related Report
      2007 Annual Research Report
  • [Presentation] Synthesis of a 36-Membered Hexaoxime Macrocycle Using a Zn3La Tetrametallic Template2007

    • Author(s)
      S. Akine, S. Sunaga, T. Nabeshima
    • Organizer
      12th International Symposium on Novel Aromatic Compounds
    • Place of Presentation
      Awaji,Japan
    • Related Report
      2007 Annual Research Report
  • [Presentation] Synthesis of Novel cyclic Assemblies Containing Dipyrrin Framework2007

    • Author(s)
      C. Ikeda, N. Sakamoto, T. Nabeshima
    • Organizer
      12th International Symposium on Novel Aromatic Compounds
    • Place of Presentation
      Awaji,Japan
    • Related Report
      2007 Annual Research Report
  • [Presentation] Amine Recognition by Pseudocryptand-Type Ti(IV)-Catecholate Host:Binding Mode and Selectivity2007

    • Author(s)
      Y. Imamura, K. Fukushima, S. Akine, T. Nabeshima
    • Organizer
      12th International Symposium on Novel Aromatic Compounds
    • Place of Presentation
      Awaji,Japan
    • Related Report
      2007 Annual Research Report
  • [Presentation] Synthesis and Functions of Novel Boron-Dipyrrin Cyclic Assemblis2007

    • Author(s)
      C. Ikeda, T. Nabeshima
    • Organizer
      2nd International Symposium on Atomic Technology
    • Place of Presentation
      Awaji,Japan
    • Related Report
      2007 Annual Research Report
  • [Presentation] Synthesis of Molecular Metalloclefts Bearing Terpyidine-Pt Moieties and Recognition of Electron-rich Aromatic Guests2007

    • Author(s)
      N. Kimura, M. Hasegawa, S. Akine, T. Nabeshima
    • Organizer
      2nd International Symposium on Atomic Technology
    • Place of Presentation
      Awaji,Japan
    • Related Report
      2007 Annual Research Report
  • [Presentation] Synthesis of Zinc(II)Dipyrrin Cyclic Assembly by Heteroleptic Coordination2007

    • Author(s)
      S. Ueda, C. Ikeda, T. Nabeshima
    • Organizer
      2nd International Symposium on Atomic Technology
    • Place of Presentation
      Awaji,Japan
    • Related Report
      2007 Annual Research Report
  • [Presentation] Synthesis and of Macrocyclic Oligo-Dipyrrins Bearing Guest Recognition Sites2007

    • Author(s)
      N. Sakamoto, C. Ikeda, T. Nabeshima
    • Organizer
      2nd International Symposium on Atomic Technology
    • Place of Presentation
      Awaji,Japan
    • Related Report
      2007 Annual Research Report
  • [Presentation] Cooperative Control of lon Recognition by Using Metal lons as an Effector2007

    • Author(s)
      T., Nabeshima
    • Organizer
      The 2nd BK21 International Symposium on Molecular Materials and Nanochemistry
    • Place of Presentation
      Jinju,S.Korea
    • Related Report
      2007 Annual Research Report
  • [Presentation] Synthesis and Guest Recognition of Metallo-Cleft and Box Containing Platnum-terpyridine Units2007

    • Author(s)
      T., Nabeshima
    • Organizer
      Third International Symposium on Chemistry of Coordination Space
    • Place of Presentation
      Awaji,Japan
    • Related Report
      2007 Annual Research Report
  • [Presentation] Synthesis of Macrocyclic Hexaoxime Ligand via Hetero-tetranuclear Complex Precursor2007

    • Author(s)
      S. Akine, S. Sunaga, T. Nabeshima
    • Organizer
      Third International Symposium on Chemistry of Coordination Space
    • Place of Presentation
      Awaji,Japan
    • Related Report
      2007 Annual Research Report
  • [Presentation] 多重の錯形成を利用したらせん型ランタニド(lll)-亜鉛(ll)多核錯体の合成2007

    • Author(s)
      秋根茂久・谷口貴紀・松本崇・鍋島達弥
    • Organizer
      第24回希土類討論会
    • Place of Presentation
      福岡
    • Related Report
      2007 Annual Research Report
  • [Presentation] 応答性メタロホストによる認識能の変換2007

    • Author(s)
      鍋島達弥
    • Organizer
      第2回ホスト・ゲスト化学シンポジウム
    • Place of Presentation
      大阪
    • Related Report
      2007 Annual Research Report
  • [Presentation] ヘテロな金属をテンプレートとする大環状オキシム配位子の合成2007

    • Author(s)
      須永修一・秋根茂久・鍋島達弥
    • Organizer
      第2回ホスト・ゲスト化学シンポジウム
    • Place of Presentation
      大阪
    • Related Report
      2007 Annual Research Report
  • [Presentation] アニオン認識部位をもつ集積型一ルテニウム(ll)ホストの合成と機能2007

    • Author(s)
      木村望・鍋島達弥
    • Organizer
      第2回ホスト・ゲスト化学シンポジウム
    • Place of Presentation
      大阪
    • Related Report
      2007 Annual Research Report
  • [Presentation] 多核テンプレートを用いた閉環メタセシスによる大環状配位子の合成とその錯形成2007

    • Author(s)
      秋根茂久・鍵山聡子・鍋島達弥
    • Organizer
      第57回錯体化学討論会
    • Place of Presentation
      名古屋
    • Related Report
      2007 Annual Research Report
  • [Presentation] 多核テンプレートを用いる大環状へキサオキシム配位子の合成と錯形成2007

    • Author(s)
      須永修一・秋根茂久・鍋島達弥
    • Organizer
      第57回錯体化学討論会
    • Place of Presentation
      名古屋
    • Related Report
      2007 Annual Research Report
  • [Presentation] Recognition-directed Supramolecular Assemblies of Terpyridine Derived Platinum Complexes2007

    • Author(s)
      Robert Trokowski, Tatsuya Nabeshima
    • Organizer
      第57回錯体化学討論会
    • Place of Presentation
      名古屋
    • Related Report
      2007 Annual Research Report
  • [Presentation] ポリエーテル部位をもつオキシム多座配位子の錯形成による二重らせん構造の構築2007

    • Author(s)
      森田陽子・秋根茂久・鍋島達弥
    • Organizer
      第57回錯体化学討論会
    • Place of Presentation
      名古屋
    • Related Report
      2007 Annual Research Report
  • [Presentation] ヘテロレプティックな錯形成を利用した環状β-ジケトナト-ジピリナト3量体錯体の合成2007

    • Author(s)
      上田智子・池田忠作・鍋島達弥
    • Organizer
      日本化学会第1回関東支部大会
    • Place of Presentation
      八王子
    • Related Report
      2007 Annual Research Report
  • [Presentation] 環内部にゲスト認識部位を導入した大環状ジピリンオリゴマーの合成と機能2007

    • Author(s)
      坂本直也・池田忠作・鍋島達弥
    • Organizer
      日本化学会第1回関東支部大会
    • Place of Presentation
      八王子
    • Related Report
      2007 Annual Research Report
  • [Presentation] トライアングル型Trisaloph配位子を用いたホモおよびヘテロ金属クラスター合成2007

    • Author(s)
      江幡良子・宮崎隼人・秋根茂久・鍋島達弥
    • Organizer
      日本化学会第1回関東支部大会
    • Place of Presentation
      八王子
    • Related Report
      2007 Annual Research Report
  • [Presentation] テルピリジン百金(II)錯体部位を有するクレフト型ホストの分子認識有能2007

    • Author(s)
      木村望・長谷川真弓・秋根茂久・鍋島達弥
    • Organizer
      日本化学会第1回関東支部大会
    • Place of Presentation
      八王子
    • Related Report
      2007 Annual Research Report
  • [Presentation] ビナフチル骨格と複数の金属イオン認識部位を有するポダンド類の合成とその機能2007

    • Author(s)
      巻口琢郎・秋根茂久・鍋島達弥
    • Organizer
      日本化学会第1回関東支部大会
    • Place of Presentation
      八王子
    • Related Report
      2007 Annual Research Report
  • [Presentation] 擬クリプタンド型Ru錯体のアニオン認識能とエナンチオ選択的認識へのアプローチ2007

    • Author(s)
      今村友紀・増測小百合・秋根茂久・鍋島達弥
    • Organizer
      日本化学会第1回関東支部大会
    • Place of Presentation
      八王子
    • Related Report
      2007 Annual Research Report
  • [Presentation] 新規な機能性多座配位子としてのジピリジルビピリミジンの合成と錯形成による構造制御2007

    • Author(s)
      玉井大史・鍋島達弥
    • Organizer
      日本化学会第1回関東支部大会
    • Place of Presentation
      八王子
    • Related Report
      2007 Annual Research Report
  • [Presentation] 新規な大環状ジピリンオリゴマーホストの合成と機能2007

    • Author(s)
      池田忠作・坂本直也・鍋島達弥
    • Organizer
      第22回生体機能関連化学シンポジウム
    • Place of Presentation
      仙台
    • Related Report
      2007 Annual Research Report
  • [Presentation] 3つのサロフ部位を有する大環状多核錯体のワンポット合成2007

    • Author(s)
      江幡良子・宮崎隼人・秋根茂久・鍋島達弥
    • Organizer
      第37回複素環化学討論会
    • Place of Presentation
      長野
    • Related Report
      2007 Annual Research Report
  • [Presentation] 新規メタロホストとしての環拡張p-べンジポルフィリンの合成と機有旨2007

    • Author(s)
      坂本直也・池田忠作・鍋島達弥
    • Organizer
      第37回構造有機化学討論会
    • Place of Presentation
      札幌
    • Related Report
      2007 Annual Research Report
  • [Presentation] 尿素部位を有する新規オリゴピリジン配位子の合成と認識能2007

    • Author(s)
      玉井大史・鍋島達弥
    • Organizer
      第37回構造有機化学討論会
    • Place of Presentation
      札幌
    • Related Report
      2007 Annual Research Report
  • [Presentation] 協同的・応答的機能のための超分子システムの設計と合成2007

    • Author(s)
      鍋島達弥
    • Organizer
      第34回有機典型元素化学討論会
    • Place of Presentation
      吹田
    • Related Report
      2007 Annual Research Report
  • [Presentation] 大環状トリスジピグンホウ素錯体の合成とイオン認識能2007

    • Author(s)
      坂本直也・池田忠作・鍋島達弥
    • Organizer
      第34回有機典型元素化学討論会
    • Place of Presentation
      吹田
    • Related Report
      2007 Annual Research Report
  • [Presentation] N2O2配位部位を有するジピリンの13族元素錯体の合成2007

    • Author(s)
      池田忠作・上田智子・鍋島達弥
    • Organizer
      第34回有機典型元素化学討論会
    • Place of Presentation
      吹田
    • Related Report
      2007 Annual Research Report
  • [Presentation] 集積型メタロホストのための含カテコールポダンドの合成と籍房蔵2007

    • Author(s)
      木嶋志穂・今村友紀・鍋島達弥
    • Organizer
      第34回有機典型元素化学討論会
    • Place of Presentation
      吹田
    • Related Report
      2007 Annual Research Report
  • [Book] "Metal-Incorporated Hosts for Cooperative and Responsive Recognition to External Stimulus" in Redox Systems Under Nano-Space Control (Hirao, T., Ed.)2006

    • Author(s)
      Nabeshima, T., AKine, S.
    • Total Pages
      295
    • Publisher
      Springer
    • Related Report
      2006 Annual Research Report
  • [Remarks]

    • URL

      http://www.chem.tsukuba.ac.jp/nabesima/research/research.html

    • Related Report
      2007 Annual Research Report

URL: 

Published: 2006-04-01   Modified: 2018-03-28  

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