Metal-Catalyzed Reaction of Main Group Elements

• Project/Area Number: 18064001
• Research Category: Grant-in-Aid for Scientific Research on Priority Areas
• Allocation Type: Single-year Grants
• Review Section: Science and Engineering
• Research Institution: Hokkaido University
• Principal Investigator: MIYAURA Norio Hokkaido University, 大学院・工学研究科, 教授 (10002049)
• Co-Investigator(Kenkyū-buntansha): 山本 靖典 北海道大学, 大学院・工学研究科, 助教 (30271646)
• Project Period (FY): 2006 – 2009
• Project Status: Completed (Fiscal Year 2009)
• Budget Amount: ¥94,900,000 (Direct Cost: ¥94,900,000); Fiscal Year 2009: ¥13,800,000 (Direct Cost: ¥13,800,000); Fiscal Year 2008: ¥14,500,000 (Direct Cost: ¥14,500,000); Fiscal Year 2007: ¥13,800,000 (Direct Cost: ¥13,800,000); Fiscal Year 2006: ¥52,800,000 (Direct Cost: ¥52,800,000)
• Keywords: ホウ素化学 / 合成化学 / 触媒・化学プロセス / 構造・機能化学 / 構造・機能材料

Research Abstract

We studied B-C bond-forming reactions including borylation of C-H bonds of arenes and alkenes with iridium catalysts. A novel triolborate salts were developed for catalyzed cross-coupling or addition reactions. We developed new bidentate chiral phosphoramidites (Me-BIPAM, N-Me-BIPAM). These ligands were found to be effective for rhodium- and ruthenium-catalyzed asymmetric addition reactions of arylboronic acids to α,β-unsaturated carbonyl compounds, aldehydes and imines.

Research Products

• [Journal Article] Synthesis of Lithium 2-Pyridyltriolborate and its Cross-Coupling Reaction with Aryl Halides (2010)
  • Author(s): Yamamoto, Y.; Sugai, J.; Takizawa, M.; Miyaura, N.
  • Journal Title: Organic Syntheses (in press)
  • Peer Reviewed
• [Journal Article] Palladium-Catalyzed Cross-Coupling Reaction of Heteroaryltriolborates with Aryl Halides for Synthesis of Biaryls (2010)
  • Author(s): Yamamoto, Y.; Takizawa, M.; Yu, X. -Q.; Miyaura, N.
  • Journal Title: Heterocycles 81 Pages: 359-368
  • NAID: 120002834748
  • Peer Reviewed
• [Journal Article] Ortho-C-H Borylation of Benzoate Esters with Bis(pinacolato)diboron Catalyzed by Iridium-phosphine Complexes (2010)
  • Author(s): Ishiyama, T., Isou, H., Kikuchi, T., Miyaura, N.
  • Journal Title: Chem. Commun. 46 Pages: 159-161
  • NAID: 120002695774
  • Peer Reviewed
• [Journal Article] Palladium-catalyzed cross-coupling reaction of heteroaryltriolborates with arylhalides for synthesis of biaryls (2010)
  • Author(s): Yamamoto, Y., Takizawa, M., Yu, X.-Q., Miyaura, N.
  • Journal Title: Heterocycles 80 Pages: 359-368
  • NAID: 120002834748
  • Peer Reviewed
• [Journal Article] Ortho-C-H borylation of benzoate esters with bis(pinacolate)diboron catalyzed by iridium-phosphine complexes (2010)
  • Author(s): Ishiyama, T., Isou, H, Kikuchi, T., Miyaura, N.
  • Journal Title: Chemical Communications 46 Pages: 159-161
  • Peer Reviewed
• [Journal Article] キラル触媒による光学活性化合物の製造 (2009)
  • Author(s): 山本靖典, 宮浦憲夫
  • Journal Title: M&E 2009 36 Pages: 120-127
• [Journal Article] 有機環状トリオールボレート塩を用いる遷移金属触媒反応 (2009)
  • Author(s): 山本靖典, 宮浦憲夫
  • Journal Title: Wako Organic Square No.27 Pages: 2-4
• [Journal Article] Iridium-Catalyzed C-H Borylation of Arenes and Heteroarenes: 1-Chloro-3-iodo-5-(4, 4, 5, 5-tetramethyl-1, 3, 2-dioxabo rolan-2-yl)benzen and 2-(4, 4, 5, 5-Tetramethyl-1, 3, 2- dioxaborolan-2-yl)indole (2009)
  • Author(s): Ishiyama, T., Takagi, J., Nobuta, Y., Miyaura, N.
  • Journal Title: Organic Synthesis Vol.11 Pages: 1007-1014
  • NAID: 120005438250
  • Peer Reviewed
• [Journal Article] Special Account for Celebrating 20 Years of SYNLETT: Palladium(II)-Catalyzed Additions of Arylboronic Acids to Electron-deficient Alkenes, Aldehydes, Imines and Nitriles (2009)
  • Author(s): Miyaura, N.
  • Journal Title: Synlett Pages: 2039-2050
  • Peer Reviewed
• [Journal Article] Chiral N, N-Dimethyl Bisphosphoramidite (Me-BIPAM) for Rh(I)-Catalyzed Asymmetric Hydrogenation (2009)
  • Author(s): Kurihara, K.; Yamamoto, Y. Miyaura, N.
  • Journal Title: Tetrahedron Lett. 50 Pages: 3158-3160
  • Peer Reviewed
• [Journal Article] Me-BIPAM for Enantioselective Ruthenium(II)-Catalyzed Arylation of Aldehydes with Arylboronic Acids (2009)
  • Author(s): Yamamoto, Y.; Kurihara, K.; Miyaura, N.
  • Journal Title: Angew. Chem. Int. Ed. 48 Pages: 4414-4416
  • Peer Reviewed
• [Journal Article] Rhodium-Catalyzed Asymmetric 1, 4-Addition of Cyclic Heteroaryl(triol)borates toα, β-Unsaturated Carbonyl Compounds (2009)
  • Author(s): Yu, X. -Q.; Yamamoto, Y.; Miyaura, N.
  • Journal Title: Synlett Pages: 994-998
  • Peer Reviewed
• [Journal Article] Novel N-Linked Bidentate Phosphoramidite Ligand (N-Me-BIPAM) for Rhodium- Catalyzed Asymmetric Addition of Arylboronic Acids to N-Sulfonyl Arylaldimines (2009)
  • Author(s): Kurihara, K.; Yamamoto, Y.; Miyaura, N.
  • Journal Title: Adv. Synth. Catal. 351 Pages: 260-270
  • Peer Reviewed
• [Journal Article] γ-Selective Cross-Coupling Reactions of Potassium Allyltrifluoroborates with Haloarenes Catalyzed by a Pd(0)/D-t-BPF or Pd(0)/Josiphos ((R, S)-CyPF-t-Bu) Complex: Mechanistic Studies on Transmetalation and Enantioselection (2009)
  • Author(s): Yamamoto, Y.; Takada, S.; Miyaura, N.; Iyama T.; Tachikawa, H.
  • Journal Title: Organometallics 28 Pages: 152-160
• [Journal Article] 有機ボロン酸を用いる触媒的結合形成反応 (2009)
  • Author(s): 山本靖典, 宮浦憲夫
  • Journal Title: 化学工業 60 Pages: 9-14
  • NAID: 10021083022
  • Peer Reviewed
• [Journal Article] Iridiumu-catalyzed C-H borylation of arenes and heteroarenes : 1-chloro-3-iodo-5-(4,4,5,5-tetramethyl-1,3,2-dioxabororan-2-yl)benzene and 2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)indole (2009)
  • Author(s): Ishiyama, T., Takagi, J., Nobuta, Y., Miyaura, N.
  • Journal Title: Organic Synthesis 11 Pages: 1007-1014
  • Peer Reviewed
• [Journal Article] Celebrating 20 years of Synlett-Special account on Palladium(II)-catalyzed additions of arylboronic acids to electron-deficient alkenes, aldehydes, imines, and nitriles (2009)
  • Author(s): Miyaura, N.
  • Journal Title: Synlett Pages: 2039-2050
  • Peer Reviewed
• [Journal Article] Me-bipam for enantioselective ruthenium(II)-catalyzed arylation of aldehydes with arylboronic acids (2009)
  • Author(s): Yamamoto, Y., Kurihara, K., Miyaura, N.
  • Journal Title: Angew.Chem.Int.Ed. 48 Pages: 4414-4416
  • Peer Reviewed
• [Journal Article] A chiral bidentate phosphoramidite(Me-BIPAM))for Rh-catalyzed asymmetric hydrogenation of α-dehydroamino esters, enamides, and dimethyl itaconate (2009)
  • Author(s): Kurihara, K., Yamamoto, Y., Miyaura, N.
  • Journal Title: Tetrahedron Lett. 50 Pages: 3158-3160
  • Peer Reviewed
• [Journal Article] γ-Selective Cross-Coupling Reactions of Potassium Allyltrifluoroborates with Haloarenes Catalyzed by a Pd(0)/D-t-BPF or Pd(0)/Josiphos ((R, S)-CyPF-t-Bu) Complex : Mechanistic Studies on Transmetalation and Enantioselection (2009)
  • Author(s): S. Takada, Y. Yamamoto, N. Miyaura
  • Journal Title: Organometallics 28 Pages: 152-160
  • Peer Reviewed
• [Journal Article] Rhodium-Catalyzed Asymmetric 1, 4-Addition of Heteroaryl Cyclic Triolborate to α, β-Unsaturated Carbonyl Compounds (2009)
  • Author(s): Yu, X.-Q. ; Yamamoto, Y. ; Miyaura, N.
  • Journal Title: Synlett Pages: 994-998
  • Peer Reviewed
• [Journal Article] An N-Linked Bidentate Phosphoramidite Ligand (N-Me-BIPAM) for Rhodium-Catalyzed Asymmetric addition of Arylboronic Acids to N-Sulfonylarylaldimines (2009)
  • Author(s): Kurihara, K. ; Yamamoto, Y. ; Miyaura, N.
  • Journal Title: Adv. Synth. Catal. 351 Pages: 260-270
  • Peer Reviewed
• [Journal Article] γ-Selective Cross-Coupling Reactions of Potassium Allyltrifluoroborates with Haloarenes Catalyzed by a Pd(0)/D-t-BPF or Pd(0)/Josiphos ((R,S)-CyPF-t-Bu)Complex : Mechanistic Studies on Transmetalation and Enantioselection (2009)
  • Author(s): Yamamoto, Y. ; Takada, S. ; Miyaura, N. ; Iyama, T. ; Tachikawa, H.
  • Journal Title: Organometallics 28 Pages: 152-160
  • Peer Reviewed
• [Journal Article] Aryl Triolborates : Novel Reagent for Copper-Catalyzed N Arylation of Amines, Anilines, and Imidazoles (2009)
  • Author(s): Yu, X.-Q. ; Yamamoto, Y ; Miy aura, N.
  • Journal Title: Chem. Asian J. 3 Pages: 1517-1522
  • Peer Reviewed
• [Journal Article] 有機環状トリオールボレート塩を用いる遷移金属触媒反応 (2009)
  • Author(s): 山本靖典, 宮浦憲夫
  • Journal Title: Wako Organic Square Pages: 2-4
• [Journal Article] キラル触媒による光学活性化合物の製造 (2009)
  • Author(s): 山本靖典, 宮浦憲夫
  • Journal Title: M&E 36 Pages: 120-127
• [Journal Article] Air- and Water-Stable Cyclic Triolborates for Metal-Catalyzed Bond-Forming Reactions (2008)
  • Author(s): Yamamoto, Y.; Miyaura, N.
  • Journal Title: Sandwich Chemistry, Pfizer Global Research & Development
• [Journal Article] トリオールボレート塩:金属触媒反応用に開発されたホウ素試薬 (2008)
  • Author(s): 山本靖典, 宮浦憲夫
  • Journal Title: 和光純薬時報 76 Pages: 2-5
• [Journal Article] Metal-Catalyzed Reactions of Organoboronic Acids and Esters (2008)
  • Author(s): Miyaura, N.
  • Journal Title: Bull. Chem. Soc. Jpn. 81 Pages: 1535-1553
  • NAID: 10023986055
  • Peer Reviewed
• [Journal Article] Metal-Catalyzed Reactions of Organoboron Compounds in Organic Syntheses (2008)
  • Author(s): Yammoto Y.; Miyaura, N.
  • Journal Title: J. Synth. Org. Chem. Jpn. 66 Pages: 194-204
  • NAID: 10021173842
  • Peer Reviewed
• [Journal Article] Asymmetric 1, 4-Addition of Arylboronic Acids toα, β-Unsaturated Esters Catalyzed by Dicationic Palladium(II)-chiraphos Complex for Short-step Synthesis of SmithKline Beecham's Endothelin Receptor Antagonist (2008)
  • Author(s): Nishikata, T.; Kiyomura S.; Yamamoto, Y.; Miyaura, N.
  • Journal Title: Synlett Pages: 2487-2490
  • Peer Reviewed
• [Journal Article] A Separate Preparation of H-BN Nano-Tubes, -Bamboos, and -Fibers from Borazine Oligomer using Aluminum Porous Template (2008)
  • Author(s): Wang, Y.; Shimada, S.; Yamamoto, Y.; Miyaura, N.
  • Journal Title: Mater. Res. Bull. 43 Pages: 251-256
  • Peer Reviewed
• [Journal Article] Stepwise Palladium-Catalyzed 1, 4-Addition of Arylboronic Acids to Enones and Regioselective Baeyer-Villiger Oxidation for Enantioselective Syntheses of β-Diaryl Esters and (+)-(R)-Tolterodine (2008)
  • Author(s): Kobayashi, K.; Nishikata, T.; Yamamoto, Y.; Miyaura
  • Journal Title: N. Bull. Chem. Soc. Jpn. 81 Pages: 1019-1025
  • Peer Reviewed
• [Journal Article] Vinylic C-H Borylation of Cyclic Vinyl Ethers with Bis(pinacolato)diboron Catalyzed by an Iridium(I)-dtbpy Complex (2008)
  • Author(s): Kikuchi, T.; Takagi, J.; Isou, H.; Ishiyama, T.; Miyaura, N.
  • Journal Title: Chem. Asian J. 3 Pages: 2082-2090
  • Peer Reviewed
• [Journal Article] Iridium-Catalyzed Vinylic C-H Borylation of Cyclic Vinyl Ethers by Bis(pinacolato)diboron (2008)
  • Author(s): Kikuchi, T.; Takagi, J.; Ishiyama, T. Miyaura, N.
  • Journal Title: Chem. Lett. 37 Pages: 664-665
  • NAID: 10021081657
  • Peer Reviewed
• [Journal Article] Practical Synthesis of Pinacolborane for One-pot Synthesis of Unsymmetrical Biaryls via Aromatic C-H Borylation-Cross-Coupling Sequence (2008)
  • Author(s): Kikuchi, T.; Nobuta, Y.; Umeda, J.; Yamamoto, Y.; Ishiyama, T.; Miyaura, N.
  • Journal Title: Tetrahedron 64 Pages: 4967-4971
  • NAID: 120005438276
  • Peer Reviewed
• [Journal Article] 1, 4-Additions of Arylboron, -silicon, and -bismuth Compounds toα, β-Unsaturated Carbonyl Compounds Catalyzed by Dicationic Palladium(II) Complexes (2008)
  • Author(s): Yamamoto, Y.; Nishikata T.; Miyaura, N.
  • Journal Title: Pure and Appl. Chem. 80 Pages: 807-817
  • Peer Reviewed
• [Journal Article] Aryl(triol)borates: Novel Reagent for Copper-Catalyzed N-Arylation of Amines, Anilines and Imidazoles (2008)
  • Author(s): Yu, X. -Q.; Yamamoto, Y.; Miyaura, N.
  • Journal Title: Chem. Asian J. 3 Pages: 1517-1522
  • Peer Reviewed
• [Journal Article] Cyclic Triolborates: Air- and Water-Stable Ate-Complexes of Organoboronic Acids (2008)
  • Author(s): Yamamoto, Y.; Takizawa, M.; Yu, X. -Q.; Miyaura, N.
  • Journal Title: Angew. Chem. Int. Ed. 47 Pages: 928-931
  • Peer Reviewed
• [Journal Article] Metal-Catalyzed Reactions of Organoboronic acids and Esters (2008)
  • Author(s): N. Miyaura
  • Journal Title: Bull. Chem. Soc. Jpn. 81 Pages: 1535-1553
  • NAID: 10023986055
  • Peer Reviewed
• [Journal Article] Cyclic Triolborates : Air- and Water-Stable Ate Complexes of Organoboronic Acids (2008)
  • Author(s): Y. Yamamoto, M. Takizawa, X. -Q. Yu, N. Miyaura
  • Journal Title: Angew. Chem. Int. Ed. 47 Pages: 928-931
  • Peer Reviewed
• [Journal Article] Vinylic C-H Borylation of Cyclic Vinyl Ethers with Bis(pinacolato)diboron Catalyzed by an Iridium(I)-dtbpy Complex (2008)
  • Author(s): T. Kikuchi, J. Takagi, H. Isou, T. Ishiyama, N. Miyaura
  • Journal Title: Chem. Asian J. 3 Pages: 2082-2090
  • Peer Reviewed
• [Journal Article] 1, 4-Addition of Arylboron, -silicon, and -bismuth Compounds to α, β-Unsaturated Carbonyl Compounds Catalyzed by Dicationic Palladium(II) Complexes (2008)
  • Author(s): Y. Yamamoto, T. Nishikata, N. Miyaura
  • Journal Title: Pure and Appl. Chem. 80 Pages: 807-817
  • Peer Reviewed
• [Journal Article] Vinylic C-H Borylation of Cyclic Vinyl Ethers with Bis(pinacolato)diboron Catalyzed by an Iridium(I)-dtbpy Complex (2008)
  • Author(s): Kikuchi, T. ; Takagi, J. ; Isou, H. ; Ishiyama, T. ; Miyaura, N.
  • Journal Title: Chem. Asian J. 3 Pages: 2082-2090
  • Peer Reviewed
• [Journal Article] Asymmetric 1,4-Addition of Arylboronic Acids to α, β-Unsaturated Esters Catalyzed by Dicationic Palladium(II)-Chiraphos Complex for Short-Step Synthesis of SmithKline Beecham's Endothelin Receptor Antagonist (2008)
  • Author(s): Nishikata, T. ; Kiyomura, S. ; Ya mamoto, Y. ; Miyaura, N.
  • Journal Title: Synlett Pages: 2487-2490
  • Peer Reviewed
• [Journal Article] Stepwise Palladium-Catalyzed 1,4-Addition of Arylboronic Acids to E nones and Regioselective Baeyer-Villiger Oxidation for Enantioselective Synthesis of β-Diaryl Esters and (+)-(R)-Tolterodine (2008)
  • Author(s): Kobayashi, K. ; Nishikata, T. ; Y amamoto, Y. ; Miyaura, N.
  • Journal Title: Bull. Chem. Soc. Jpn. 81 Pages: 1019-1025
  • Peer Reviewed
• [Journal Article] Iridium-Catalyzed Vinylic C-H Borylation of Cyclic Vinyl Ethers by Bis(pinacolato)diboron (2008)
  • Author(s): Kikuchi, T. ; Takagi, J. ; Ishiyam a, T. ; Miyaura, N.
  • Journal Title: Chem. Lett. 37 Pages: 664-665
  • NAID: 10021081657
  • Peer Reviewed
• [Journal Article] Practical Synthesis of Pinacolborane for One-Pot Synthesis of Unsym metrical Biaryls via Aromatic C-H Borylation-Cross-Coupling Sequence (2008)
  • Author(s): Kikuchi, T. ; Nobuta, Y. ; Umeda, J. ; Yamamoto, Y. ; Ishiyama, T. ; Miyaura, N.
  • Journal Title: Tetrahedron 64 Pages: 4967-4971
  • Peer Reviewed
• [Journal Article] 1, 4-Additions of -Arylboron, Silicon, and : -Bismuth Compounds to α, β-Unsaturated Carbonyl Compounds Catalyzed by Dicationic Palladium (II) Complexes (2008)
  • Author(s): Yamamoto, Y. ; Nishikata, T. ; Miyaura, N.
  • Journal Title: Pure Appl. Chem. 80 Pages: 807-817
  • Peer Reviewed
• [Journal Article] Cyclic triol Borates : Air-and Water-Stable Ate Complexes of Organoboronic Acids (2008)
  • Author(s): Yamamoto, Y. ; Takizawa, M. ; Yu, X.-Q. ; Miyaura, N.
  • Journal Title: Angew. Chem. Int. Ed. 47 Pages: 251-256
  • Peer Reviewed
• [Journal Article] Preparation of h-BN Nano-Tubes, -Bamboos, and -Fibers from Borazine Oligomer with Alumina Porous Template (2008)
  • Author(s): Wang, Y.; Shimada, S.; Yamam oto, Y.; Miyaura, N.
  • Journal Title: Mater Res. Bull. 43 Pages: 251-256
  • Peer Reviewed
• [Journal Article] 有機ホウ素化合物の触媒的有機合成化学 (2008)
  • Author(s): 山本靖典, 宮浦憲夫
  • Journal Title: 有機合成化学協会誌 66 Pages: 194-204
  • NAID: 10021173842
  • Peer Reviewed
• [Journal Article] トリオールボレート塩 : 金属触媒反応用に開発されたホウ素試薬 (2008)
  • Author(s): 山本靖典, 宮浦憲夫
  • Journal Title: 初光純薬時報 76 Pages: 2-5
• [Journal Article] Cyclic Triolborates: Air-and Water-Stable Ate Complexes of Organoboronic Acids (2008)
  • Author(s): Y. Yamamoto, M. Takizawa, X.-Q. Yu, N. Miyaura
  • Journal Title: Angew. Chem. Int. Ed. 47 Pages: 928-931
  • Peer Reviewed
• [Journal Article] キラル配位子Me-BIPAMの開発と不斉触媒への応用 (2007)
  • Author(s): 山本靖典、宮浦憲夫
  • Journal Title: WAKO Organic Square 20 Pages: 2-4
• [Journal Article] Asymmetric 1, 4-Addition of Arylboronic Acids toα, β-Unsaturated N-Acylamides Catalyzed by Dicationic Palladium(II)-(S, S)-Chiraphos Complex (2007)
  • Author(s): Nishikata, T.; Yamamoto, Y.; Miyaura, N.
  • Journal Title: Chem. Lett. 36 Pages: 1442-1443
  • Peer Reviewed
• [Journal Article] Tandem Conjugate Addition-Aldol Cyclization to give Optically Active 1-Aryl-1H-indenes via Asymmetric Palladium(2+)-Catalyzed 1, 4-Addition of Arylboronic Acids (2007)
  • Author(s): Nishikata, T.; Kobayashi, Y.; Kobayshi, K.; Yamamoto, Y.; Miyaura, N.
  • Journal Title: Synlett Pages: 3055-3057
  • Peer Reviewed
• [Journal Article] Palladium(II)-Catalyzed 1, 4-Addition of Arylboronic Acids to β-Arylenals for Enantioselective Syntheses of 3, 3-Diarylalkanals: A Shot-steps Synthesis of (+)-(R)-CDP 840 (2007)
  • Author(s): Nishikata, T.; Yamamoto, Y.; Miyaura, N.
  • Journal Title: Tetrahedron Lett. 48 Pages: 4007-4010
  • Peer Reviewed
• [Journal Article] Palladium(II)-Catalyzed 1, 4-Addition of Arylboronic Acids to β-Arylenones for Enantioselective Synthesis of 4-Aryl-4H-chromenes (2007)
  • Author(s): Nishikata, T.; Yamamoto, Y.; Miyaura, N.
  • Journal Title: Adv. Synth. Catal. 349 Pages: 1759-1764
  • Peer Reviewed
• [Journal Article] Cross-Coupling Reactions using Allyltrifluoroborate (2007)
  • Author(s): Miyaura, N.; Yamamoto, Y.
  • Journal Title: Organometallic News Pages: 16-21
• [Journal Article] Asymmetric 1, 4-Addition of arylboronic acids to α, β-unsaturated N-acylamides catalyzed by dicationic palladium (II) - (S, S) -chiraphos complex. (2007)
  • Author(s): T. Nishikata, Y. Yamamoto, N. Miyaura
  • Journal Title: Chem. Lett. 36 Pages: 1442-1443
  • NAID: 10020011763
  • Peer Reviewed
• [Journal Article] Tandem conjugate addition-aldol cyclization to give optically active l-aryl-1H-indenesvia asymmetric Pd2+-catalyzed 1, 4-addition of aryl-boronic acids. (2007)
  • Author(s): T. Nishikata, Y. Kobayashi, K. Kobayshi, Y. Yamamoto, N. Miyaura
  • Journal Title: Synlett Pages: 3055-3057
  • Peer Reviewed
• [Journal Article] Palladium (II) -Catalyzed 1, 4-Additionof Arylboronic Acids to β-Arylenones for Enantioselective Synthesis of 4-Aryl-4H-chromenes (2007)
  • Author(s): T. Nishikata, Y. Yamamoto, N. Miyaura
  • Journal Title: Adv. Synth. Catal. 349 Pages: 1759-1764
  • Peer Reviewed
• [Journal Article] Palladium (II) -catalyzed 1, 4-addition of arylboronic acides to β-arylenals for enantioselective syntheses of 3, 3-diarylalkanals: a short synthesis of (+)-(R)-CDP 840 (2007)
  • Author(s): T. Nishikata, Y. Yamamoto, N. Miyaura
  • Journal Title: Tetrahedron Lett. 48 Pages: 4007-4010
  • NAID: 120000972381
  • Peer Reviewed
• [Journal Article] Enantioselective 1,4-addition of aryboronic acids to α,β-unsaturated carbonyl compounds catalyzed by rhodium(I)-chiral phosphoramidite complexes. (2007)
  • Author(s): K.Kurihara, N.Sugishita, K.Oshita, D.Piao, Y.Yamamoto, N.Miyaura
  • Journal Title: J. Organomet. Chem. 692・1-3 Pages: 428-435
• [Journal Article] Enantioselective 1, 4-Addition of Arylboronic Acids toα, β-Unsaturated Carbonyl Compounds Catalyzed by Rhodium(I)-Chiral Phosphoramidite Complexes (2006)
  • Author(s): Kurihara, K.; Sugishita, N.; Oshita, K.; Piao, D.; Yamamoto, Y.; Miyaura, N.
  • Journal Title: J. Organomet. Chem. 692 Pages: 428-435
  • Peer Reviewed
• [Journal Article] Improvements of Efficiency and Regioselectivity in the Iridium(I)-Catalyzed Aromatic C-H Silylation of Arenes with Fluorodisilanes (2006)
  • Author(s): Saiki, T.; Nishio, Y.; Ishiyama, T.; Miyaura, N.
  • Journal Title: Organometallics 25 Pages: 6068-6073
  • Peer Reviewed
• [Journal Article] Asymmetric Cross-Coupling of Potassium Crotyltrifluoroborates with Aryl and 1-Alkenyl Bromides Catalyzed by a Pd(OAc)2/Josiphos Complex (2006)
  • Author(s): Yamamoto, Y.; Takada, S.; Miyaura, N.
  • Journal Title: Chem. Lett. 35 Pages: 1368-1369
  • Peer Reviewed
• [Journal Article] Rhodium(I)- or Palladium(II)-Catalyzed 1, 4-Additions of Organoboron, -Silicon and -Bismuth Compounds to Electron-deficient Alkenes (2006)
  • Author(s): Yamamoto, Y.; Nishikata, T.; Miyaura, N.
  • Journal Title: J. Synth. Org. Chem. Jpn (Engl. Ed. ) 64 Pages: 1112-1121
  • NAID: 10020608620
  • Peer Reviewed
• [Journal Article] Synthesis of B-Substituted Borazines via the Rhodium-Catalyzed Hydroboration of Alkenes with N-Trimethyl or N-Triethylborazine (2006)
  • Author(s): Yamamoto, Y.; Miyamoto, K.; Umeda, J.; Nakatani, Y.; Yamamoto, T.; Miyaura, N.
  • Journal Title: J. Organomet. Chem. 691 Pages: 4909-4917
  • Peer Reviewed
• [Journal Article] 1, 4-Addition of Arylboronic Acids to β-Aryl-α, β-unsaturated Ketones and Esters Catalyzed by Rhodium(I)-Chiraphos Complex for Catalytic Enantioselective Synthesis of Selective Endothelin A Receptor Antagonists (2006)
  • Author(s): Itoh, T.; Mase, T.; Nishikata, T.; Iyama, T.; Tchikawa, H.; Kobayashi, Y.; Yamamoto, Y.; Miyaura, N.
  • Journal Title: Tetrahedron 62 Pages: 9610-9621
  • Peer Reviewed
• [Journal Article] γ-Selective Cross-Coupling of Potassium Allyltrifluoroborates with Aryl and 1-Alkenyl Bromides Catalyzed by a Pd(OAc)2/D-t-BPF Complex (2006)
  • Author(s): Yamamoto, Y.; Takada S.; Miyaura, N.
  • Journal Title: Chem. Lett. 35 Pages: 704-705
  • Peer Reviewed
• [Journal Article] Iridium-Catalyzed Borylation of Arenes and Heteroarenes via C-H Activation (2006)
  • Author(s): Ishiyama, T.; Miyaura, N.
  • Journal Title: Pure and Appl. Chem. 78 Pages: 1369-1375
  • NAID: 120005438275
  • Peer Reviewed
• [Journal Article] Asymmetric cross-coupling of potassium 2-butenyltrifluoroborates with ary and 1-alkenyl bromides catalyzed by Pd(OAc)_2/josiphos complex. (2006)
  • Author(s): Y.Yamamoto, S.Takada, N.Miyaura
  • Journal Title: Chem. Lett. 35・12 Pages: 1368-1369
• [Journal Article] Improvements of Efficiency and Regioselectivity in the Iridium(I)-Catalyzed Aromatic C-H Silylation of Arenes with Fluorodisilanes. (2006)
  • Author(s): T.Saiki, Y.Nishio, T.Ishiyama, N.Miyaura
  • Journal Title: Organometallics 25・26 Pages: 1112-1121
• [Journal Article] Synthesis of B-trisubstituted borazines via the rhodium-catalyzed hydroboration of alkenes with N,N',N"-trimethyl or N,N',N"-triethylborazine. (2006)
  • Author(s): Y.Yamamoto, K.Miyamoto, J.Umeda, Y.Nakatani, T.Yamamoto, N.Miyaura
  • Journal Title: J. Organomet. Chem. 691・23 Pages: 4909-4917
• [Journal Article] 1,4-Addition of arylboronic acids to β-aryl-α,β-unsaturated ketones and esters catalyzed by a rhodium(I)-chiraphos complex for catalytic and enantioselective synthesis of selective endothelin A receptor antagonists. (2006)
  • Author(s): T.Itoh, T.Mase, T.Nishikata, T.Iyama, H.Tachikawa, Y.Kobayashi, Y.Yamamoto, N.Miyaura
  • Journal Title: Tetrahedron 62・41 Pages: 9610-9621
• [Journal Article] Iridium-catalyzed borylation of arenes and heteroarenes via C-H activation. (2006)
  • Author(s): T.Ishiyama, N.Miyaura
  • Journal Title: Pure and Applied Chemistry 78・7 Pages: 1369-1375
  • NAID: 120005438275
• [Journal Article] γ-Selective cross-coupling of potassium allyltrifluoroborates with aryl and 1-alkenyl bromides catalyzed by a Pd(OAc)_2/D-t-BPF complex. (2006)
  • Author(s): Y.Yamamoto, S.Takada, N.Miyaura
  • Journal Title: Chem. Lett. 35・7 Pages: 704-705
  • NAID: 10017604037
• [Presentation] ヘテロ芳香俗トリオールボレート塩の触媒反応 (2010)
  • Author(s): 山本靖典
  • Organizer: 日本薬学会第130年会
  • Place of Presentation: 岡山
  • Year and Date: 2010-03-28
• [Presentation] ヘテロ芳香族トリオールボレート塩の触媒反応 (2010)
  • Author(s): 山本靖典
  • Organizer: 日本薬学会第130年会
  • Place of Presentation: 岡山大学(岡山)
  • Year and Date: 2010-03-28
• [Presentation] Synthesis of ortho-tetrasubstituted biaryls with aryltriolborates (2010)
  • Author(s): 李高強、山本靖典、宮浦憲夫
  • Organizer: 北海道大学GCOE「触媒が先導する物質科学イノベーション」平成21年度若手研究成果発表会
  • Place of Presentation: 北海道大学(札幌)
  • Year and Date: 2010-02-24
• [Presentation] α-アリールエステルの不斉合成 (2010)
  • Author(s): 小林謙也、山本靖典、宮浦憲夫
  • Organizer: 北海道大学GCOE「触媒が先導する物質科学イノベーション」平成21年度若手研究成果発表会
  • Place of Presentation: 北海道大学(札幌)
  • Year and Date: 2010-02-24
• [Presentation] Metal-Cataliyzed Reaction of Organoboronic Acids (2010)
  • Author(s): 宮浦憲夫
  • Organizer: The Second Symposium on Academic Exchange and Collaborative Research between GSE-HU and MRC-ETHZ
  • Place of Presentation: Sapporo
  • Year and Date: 2010-02-09
• [Presentation] Metal-Catalyzed Reactions of Organoboronic Acids (2010)
  • Author(s): 宮浦憲夫
  • Organizer: The Second Symposium on Academic Exchange and Collaborative Research between GSE-HU and MRC-ETHZ
  • Place of Presentation: 北海道大学(札幌)
  • Year and Date: 2010-02-09
• [Presentation] 有機ボロン酸の触媒化学 (2010)
  • Author(s): 宮浦憲夫
  • Organizer: 第15回精密合成化学セミナー
  • Place of Presentation: 札幌
  • Year and Date: 2010-01-08
• [Presentation] 有機ボロン酸の触媒化学 (2010)
  • Author(s): 宮浦憲夫
  • Organizer: 第15回精密合成科学セミナー
  • Place of Presentation: 北海道大学(札幌)
  • Year and Date: 2010-01-08
• [Presentation] ルテニウム/Me-BIPAM錯体を用いるアリールボロン酸のα-ケトエステルへの不斉付加反応 (2010)
  • Author(s): 白井智彦、栗原一典、山本靖典、宮浦憲夫
  • Organizer: 日本化学会第90春季年会
  • Place of Presentation: 近畿大学(大阪)
• [Presentation] パラジウム/Josiphos 錯体を用いるシリルケテンアセタールの不斉アリール化 (2010)
  • Author(s): 小林謙也、山本靖典、宮浦憲夫
  • Organizer: 日本化学会第90春季年会
  • Place of Presentation: 近畿大学(大阪)
• [Presentation] 有機トリオールボレートを用いたオルト四置換ビアリールの合成 (2010)
  • Author(s): 李高強、山本靖典、宮浦憲夫
  • Organizer: 日本化学会第90春季年会
  • Place of Presentation: 近畿大学(大阪)
• [Presentation] イリジウム触媒を用いたフルオロジシランによるヘテロアレーンの芳香族C-Hシリル化における反応効率の改善 (2010)
  • Author(s): 岩口祐介、石山竜生、宮浦憲夫
  • Organizer: 日本化学会第90春季年会
  • Place of Presentation: 近畿大学(大阪)
• [Presentation] Metal-catalyzed asymmetric addition reaction of organoboron compounds (2009)
  • Author(s): 山本靖典
  • Organizer: 特定領域研究「元素相乗系化合物の化学」第4回若手国際シンポジウム(2009WOMC)
  • Place of Presentation: 福岡
  • Year and Date: 2009-10-29
• [Presentation] 有機ボロン酸の触媒化学 (2009)
  • Author(s): 宮浦憲夫
  • Organizer: 特定領域研究「フォトクロミズムの攻究とメカニカル機能の創出」第4回シンポジウム
  • Year and Date: 2009-09-01
• [Presentation] 有機ボロン酸の触媒化学 (2009)
  • Author(s): 宮浦憲夫
  • Organizer: 特定領域研究「フォトクロミズムの攻究とメカニカル機能の創出」第4回公開シンポジウム
  • Place of Presentation: 北海道大学(札幌)
  • Year and Date: 2009-09-01
• [Presentation] アリールアミノヒドロボランを用いたB-トリアリールボラジンの合成 (2009)
  • Author(s): 田中宏明、山本靖典、宮浦憲夫
  • Organizer: 日本化学会北海道支部2009年夏季研究発表会
  • Place of Presentation: 苫小牧工専(苫小牧)
  • Year and Date: 2009-07-11
• [Presentation] パラジウム触媒を用いたケテンシリルアセタールのアリル化反応 (2009)
  • Author(s): 金本和也、山本靖典、宮浦憲夫
  • Organizer: 日本化学会北海道支部2009年夏季研究発表会
  • Place of Presentation: 苫小牧工専(苫小牧)
  • Year and Date: 2009-07-11
• [Presentation] カチオン性ロジウム触媒を用いる環状トリオールボレート塩の1,4-付加反応 (2009)
  • Author(s): 白井智彦、于暁強、山本靖典、宮浦憲夫
  • Organizer: 日本化学会北海道支部2009年夏季研究発表会
  • Place of Presentation: 苫小牧工専(苫小牧)
  • Year and Date: 2009-07-11
• [Presentation] イリジウム触媒を用いたビス(ピナコラート)ジボロンによる芳香族ケトンのオルト位ホウ素化反応 (2009)
  • Author(s): 伊藤啓司、菊池貴夫、石山竜生、宮浦憲夫
  • Organizer: 日本化学会北海道支部2009年夏季研究発表会
  • Place of Presentation: 苫小牧工専(苫小牧)
  • Year and Date: 2009-07-11
• [Presentation] 有機ボロン酸の触媒化学 (2009)
  • Author(s): 宮浦憲夫
  • Organizer: 北海道大学触媒科学研究センター研究討論会in東京
  • Place of Presentation: 東京
  • Year and Date: 2009-01-22
• [Presentation] カチオン性パラジウム錯体に対するトランスメタル化反応 (2009)
  • Author(s): 宮浦憲夫
  • Organizer: 特定領域研究「元素相乗系化合物の化学」第4回公開シンポジウム
  • Place of Presentation: 宮島グランドホテル(広島)
• [Presentation] Metal-catalyzed asymmetric addition reactions of organoboron compounds (2009)
  • Author(s): 山本靖典
  • Organizer: 特定領域研究「元素相乗系化合物の化学」第4回若手国際シンポジウム(2009WOMC)
  • Place of Presentation: 九州大学先導研(福岡)
• [Presentation] ヘテロ芳香族環状トリオールボレート塩のロジウム触媒不斉1,4-付加反応 (2009)
  • Author(s): 于暁強、白井智彦、山本靖典、宮浦憲夫
  • Organizer: 第56回有機金属化学討論会
  • Place of Presentation: 同志社大学(京都)
• [Presentation] ルテニウム/Me-BIPAM錯体によるアリールボロン酸のアルデヒドへの不斉1,2-付加反応 (2009)
  • Author(s): 山本靖典、栗原一典、宮浦憲夫
  • Organizer: 第56回有機金属化学討論会
  • Place of Presentation: 同志社大学(京都)
• [Presentation] イリジウム触媒を用いたアリールケトンのビス(ピナコラート)ジボロンによるオルト位ホウ素化反応 (2009)
  • Author(s): 伊藤啓司、菊池貴夫、石山竜生、宮浦憲夫
  • Organizer: 第56回有機金属化学討論会
  • Place of Presentation: 同志社大学(京都)
• [Presentation] 有機ボロン酸の触媒化学 (2009)
  • Author(s): 宮浦憲夫
  • Organizer: 北海道大学触媒化学研究センター研究討論会in東京
  • Place of Presentation: 東京・東京工業大学
• [Presentation] パラジウム触媒によるボラジンとハロゲン化アリールのクロスカップリング反応 (2009)
  • Author(s): 長澤勇希、山本靖典、宮浦憲夫
  • Organizer: 日本化学会第89春季年会
  • Place of Presentation: 千葉・日本大学
• [Presentation] ヘテロ芳香族環状トリオールボレート塩のロジウム触媒不斉共役付加反応 (2009)
  • Author(s): 于暁強、山本靖典、宮浦憲夫
  • Organizer: 日本化学会第89春季年会
  • Place of Presentation: 千葉・日本大学
• [Presentation] ロジウム/窒素架橋二座ホスホロアミダイト錯体を用いるアリールボロン酸の不斉共役付加反応 (2009)
  • Author(s): 高橋良徳、栗原一典、山本靖典、宮浦憲夫
  • Organizer: 日本化学会第89春季年会
  • Place of Presentation: 千葉・日本大学
• [Presentation] カチオン性パラジウム/キラボス触媒を用いるα, β-不飽和エステルへの不斉共役付加反応 (2009)
  • Author(s): 清村俊介、西形孝司、山本靖典、宮浦憲夫
  • Organizer: 日本化学会第89春季年会
  • Place of Presentation: 千葉・日本大学
• [Presentation] イリジウム触媒を用いたフルオロジシランよるビニル位C-Hケイ素化反応 (2009)
  • Author(s): 高田瑠美・岸田恵美・石山竜生・宮浦憲夫
  • Organizer: 日本化学会第89春季年会
  • Place of Presentation: 千葉・日本大学
• [Presentation] クロスカップリング反応におけるプロセス化学の新展開 (2008)
  • Author(s): 宮浦憲夫
  • Organizer: 日本プロセス化学会2008ウィンターシンポジウム
  • Place of Presentation: 東京
  • Year and Date: 2008-12-01
• [Presentation] クロスカップリング反応におけるプロセス化学の新展開 (2008)
  • Author(s): 宮浦憲夫
  • Organizer: 日本プロセス化学会2008ウインターシンポジウム
  • Place of Presentation: 東京
  • Year and Date: 2008-12-01
• [Presentation] クロスカップリング反応におけるプロセス化学の新展開 (2008)
  • Author(s): 宮浦憲夫
  • Organizer: 日本プロセス化学会2008ウィンターシンポジウム
  • Place of Presentation: 東京・タワーホール船堀
  • Year and Date: 2008-12-01
• [Presentation] Metal-Catalyzed Reactions of Organoboronic Acids (2008)
  • Author(s): 宮浦憲夫
  • Organizer: Donald S. Matteson Symposium
  • Place of Presentation: Pullman, WA
  • Year and Date: 2008-09-13
• [Presentation] Metal-Catalyzed Reactions of Organoboronic Acids (2008)
  • Author(s): Norio Miyaura
  • Organizer: Donald S. Matteson Symposium
  • Place of Presentation: Pullman, WA, USA・ワシントン州立大学
  • Year and Date: 2008-09-13
• [Presentation] C-C結合形成反応(3) (2008)
  • Author(s): 宮浦憲夫
  • Organizer: 日本化学会実力養成化学スクール:「有機化学」研修コース
  • Place of Presentation: 東京
  • Year and Date: 2008-07-25
• [Presentation] C-C結合形成反応(3) (2008)
  • Author(s): 宮浦憲夫
  • Organizer: 日本化学会実力養成化学スクール : 「有機化学」研修コース
  • Place of Presentation: 東京・化学会館
  • Year and Date: 2008-07-25
• [Presentation] ロジウム/二座ボスホロアミダイト錯体を用いる不斉共役付加反応 (2008)
  • Author(s): 高橋良徳、栗原一典、山本靖典、宮浦憲夫
  • Organizer: 日本化学会北海道支部2008年夏季研究発表会
  • Place of Presentation: 北見・北見工業大学
  • Year and Date: 2008-07-19
• [Presentation] カチオン性パラジウム触媒を用いる不飽和エステルへの不斉共役付加/アルドール縮合反応 (2008)
  • Author(s): 清村俊介、西形孝司、山本靖典、宮浦憲夫
  • Organizer: 日本化学会北海道支部2008夏季研究発表会
  • Place of Presentation: 北見・北見工業大学
  • Year and Date: 2008-07-19
• [Presentation] 二座ホスホロアミダイト配位子を用いる不斉触媒反応 (2008)
  • Author(s): 栗原一典、山本靖典、宮浦憲夫
  • Organizer: 万有福岡シンポジウム
  • Place of Presentation: 福岡・九州大学
  • Year and Date: 2008-05-10
• [Presentation] キラル触媒による光学活性化合物の製造 (2008)
  • Author(s): 宮浦憲夫
  • Organizer: 科学技術週間セミナーin北海道2008
  • Place of Presentation: 札幌
  • Year and Date: 2008-04-16
• [Presentation] キラル触媒による光学活性化合物の製造 (2008)
  • Author(s): 宮浦憲夫
  • Organizer: 科学技術週間セミナーin北海道2008
  • Place of Presentation: 札幌・京王プラザホテル
  • Year and Date: 2008-04-16
• [Presentation] 有機トリオールボレート塩を用いたクロスカップリング反応 (2008)
  • Author(s): 滝沢美穂、山本靖典、宮浦憲夫
  • Organizer: 日本化学会第88春季年会
  • Place of Presentation: 東京・立教大学
  • Year and Date: 2008-03-30
• [Presentation] 有機トリオールボレート塩を用いた銅触媒によるアミン類のN-アリール化反応 (2008)
  • Author(s): 于暁強、山本靖典、宮浦憲夫
  • Organizer: 日本化学会第88春季年会
  • Place of Presentation: 東京・立教大学
  • Year and Date: 2008-03-30
• [Presentation] イリジウム触媒を用いたジボロンよる安息香酸エステルのオルト位ホウ素化反応 (2008)
  • Author(s): 異相宏典、菊池貴夫、石山竜生、宮浦憲夫
  • Organizer: 日本化学会第88春季年会
  • Place of Presentation: 東京・立教大学
  • Year and Date: 2008-03-30
• [Presentation] 有機ボロン酸を用いる触媒的結合形成反応 (2008)
  • Author(s): 宮浦憲夫
  • Organizer: 日本化学会第88春季年会
  • Place of Presentation: 東京
  • Year and Date: 2008-03-27
• [Presentation] 有機ボロン酸を用いる触媒的結合形成反応 (2008)
  • Author(s): 宮浦憲夫
  • Organizer: 日本化学会第88春季年会
  • Place of Presentation: 東京・立教大学
  • Year and Date: 2008-03-27
• [Presentation] ロジウム-2座ホスホロアミダイト触媒を用いたアリールボロン酸のN-トシルイミンへの不斉付加反応 (2008)
  • Author(s): 栗原一典、山本靖典、宮浦憲夫
  • Organizer: 日本化学会第88春季年会
  • Place of Presentation: 東京・立教大学
  • Year and Date: 2008-03-26
• [Presentation] Enantioselective C-C Bond-Forming Reactions of Organoboronic Acids (2008)
  • Author(s): N. Miyaura
  • Organizer: The First Merck Catalysis Symposium in China
  • Place of Presentation: 上海有機化学研究所Shanghai, China
  • Year and Date: 2008-03-24
• [Presentation] Metal-Catalyzed Reactions of Organoboronic Acids for 1, 4-Addition of Arylboronic Acids to α, β-Unsaturated Carbonyl Compounds (2008)
  • Author(s): N. Miyaura
  • Organizer: The 10th SNU and Hokkaido University Joint Symposium On Nano Technology Bio Technology and Catalysis
  • Place of Presentation: Seoul National University, Seoul, Korea
  • Year and Date: 2008-01-25
• [Presentation] Chiral N, N-Dimetyl Bisphosphoramidite (Me-BIPAM)for Transition Metal-Catalyzed Asymmetric Reactions (2008)
  • Author(s): K. Kurihara, Y. Yamamoto, N. Miyaura
  • Organizer: The 10th SNU and Hokkaido University Joint Symposium On Nano Technology, Bio Technology and Catalysis
  • Place of Presentation: Seoul National University, Seoul, Korea
  • Year and Date: 2008-01-25
• [Presentation] Chiral N, N-Dimetyl Bisphosphoramidite (Me-BIPAM)for Transition Metal-Catalyzed Asymmetric Reactions (2008)
  • Author(s): K. Kurihara, Y. Yamamoto, N. Miyaura
  • Organizer: The 1st GCOE International Symposium, Catalysis as The Basis for the Innovation in Materials Science
  • Place of Presentation: Sapporo・北海道大学
  • Year and Date: 2008-01-16
• [Presentation] Enantioselective C-C Bond-Forming Reactions of Organoboronic Acids (2008)
  • Author(s): 宮浦憲夫
  • Organizer: The First Merck Catalysis Symposium in China
  • Place of Presentation: Shanghai, China
• [Presentation] 有機ボロン酸を用いる触媒的結合形成反応 (2008)
  • Author(s): 宮浦憲夫
  • Organizer: 日本化学学会第88春季年会
  • Place of Presentation: 東京
• [Presentation] Metal-Catalyzed Reactions of Organoboronic Acids for 1,4-Addition of Arylboronic Acids to α,β-Unsaturated Carbonyl Compounds (2008)
  • Author(s): 宮浦憲夫
  • Organizer: The 10th SNU and hokkaido University Joint Symposium On Nano Technoloty, Bio Technology and Catalysis
  • Place of Presentation: Seoul, Korea
• [Presentation] Metal-Catalyzed Reactions of Organoboronic Acids for 1,4-Addition of Arylboronic Acids to α, β-Unsaturated Carbonyl Compounds (2008)
  • Author(s): Norio Miyaura
  • Organizer: Taiwan-Japan International Symposium on Organic Chemistry and Molecular Science
  • Place of Presentation: 台北、台湾・National Taipei University of Technology
• [Presentation] Transmetalation and Enantioselection Mechanism of γ-Selective Cross-Coupling Reactions of Potassium Allyltrifluoroborates (2008)
  • Author(s): Y. Yamamoto, S. Takada, T. Iyama, H. Tachikawa, N. Miyaura
  • Organizer: 55th Symposium on Organometallic Chemistry
  • Place of Presentation: 大阪・大阪府立大学
• [Presentation] Enantioselective addition of arylboronic acids to aldimines catalyzed by rhodium-bisphosphoramidite complex (2008)
  • Author(s): K. Kurihara, Y. Takahashi, Y. Yamamoto. N. Mivaura
  • Organizer: 55th Symposium on Organometallic Chemistry
  • Place of Presentation: 大阪・大阪府立大学
• [Presentation] Ortho-Borylation of Berizoate Esters with Diborons Catalyzed by Iridium Complexes (2008)
  • Author(s): T. Kikuchi, H. Iso, T. Ishiyama, N. Miyaura
  • Organizer: 55th Symposium on Organometallic Chemistry
  • Place of Presentation: 大阪・大阪府立大学
• [Presentation] Synthesis and Metal-Catalyzed Reactions of Cyclic Triolborates (2008)
  • Author(s): Y. Yamamoto, M. Takizawa, X. -Q. Yu, N. Miyaura
  • Organizer: IMEBORON XIII
  • Place of Presentation: Palau clEsports i Congressos Platja d'Anq Spain
• [Presentation] Iridium-Catalyzed ortho-Borylation of Benzoate Esters by Dib orons (2008)
  • Author(s): T. Ishiyama, H. Iso, T. Kikuchi , N. Miyaura
  • Organizer: IMEBORON XIII
  • Place of Presentation: Palau clEsports i Congresses Platja d'An Spain
• [Presentation] Enantioselective 1,4-Addition to α, β-Unsaturated Esters Catalyzed by a Dicationic Palladium (2008)
  • Author(s): T. Nishikata, S. Kiyomura, Y. Yamamoto, N. Miyaura
  • Organizer: 23rd International Conference on Organometallic Chemistry
  • Place of Presentation: University of Rennes, Rennes. France
• [Presentation] Chiral N, N-Dimethyl Bisphosphoramidite for Transition Metal-Catalyzed Asymmetric Reactions (2008)
  • Author(s): K. Kurihara, Y. Yamamoto, N. Miyaura
  • Organizer: 23rd International Conference on Organometallic Chemistry
  • Place of Presentation: University of Rennes, Rennes, France
• [Presentation] Iridium-Catalyzed Direct ortho-Borylation of Aromatic Esters (2008)
  • Author(s): H. Iso, T. Kikuchi, T. Ishiyarna, N. Miyaura
  • Organizer: Taiwan-Japan International Symposium on Organic Chemistry and Molecular Science
  • Place of Presentation: 台北、台湾・National Taipei University of Technology
• [Presentation] 有機ボロン酸の触媒化学 (2007)
  • Author(s): 宮浦憲夫
  • Organizer: 触媒学会北海道地区札幌講演会&有機金属研究会Organometallic Seminar XXXV
  • Place of Presentation: 札幌・北海道大学
  • Year and Date: 2007-12-05
• [Presentation] Mechanistic Studies on Transmetallation Involed in γ-Selective Cross-Coupling Reactions of Potassium Allyltrifluoroborates (2007)
  • Author(s): Y. Yamamoto, S. Takada, T. Iyama, H. Tachikawa, N. Miyaura
  • Organizer: The 1st International Symposium on Synergy of Elements
  • Place of Presentation: Tokyo・東京工業大学
  • Year and Date: 2007-11-12
• [Presentation] ホウ素化合物の触媒的有機合成化学 (2007)
  • Author(s): 宮浦憲夫
  • Organizer: 第92回 有機合成シンポジウム
  • Place of Presentation: 東京・早稲田大学
  • Year and Date: 2007-11-09
• [Presentation] Asymmetric Conjugate Addition of Arylboronic acids to α, β-Unsaturated Amides Catalyzed by Cationic Palladium (II) omplexes (2007)
  • Author(s): T. Nishikata, Y. Yamamoto, N. Miyaura
  • Organizer: 54th Symposium on Organometallic Chemistry
  • Place of Presentation: Higashihiroshima・広島大学
  • Year and Date: 2007-10-28
• [Presentation] Synthesis of Organotriolborates for Metal-Catalyzed Reactions (2007)
  • Author(s): M. Takizawa, X. Q. Yu, Y. Yamamoto, N. Miyaura
  • Organizer: 54th Symposium on Organometallic Chemistry
  • Place of Presentation: Higashihiroshima・広島大学
  • Year and Date: 2007-10-28
• [Presentation] Iridium-Catalyzed Direct Silylation of Heteroarenes by 1-Hydrosilatrane (2007)
  • Author(s): R. Takata, E. Kishida, T. Saiki, T. Ishiyama, N. Miyaura
  • Organizer: 54th Symposium on Organometallic Chemistry
  • Place of Presentation: Higashihiroshima・広島大学
  • Year and Date: 2007-10-28
• [Presentation] 有機ボロン酸を用いる触媒的不斉炭素-炭素結合形成機構 (2007)
  • Author(s): 宮浦憲夫
  • Organizer: 第57回有機反応化学討論会
  • Place of Presentation: 広島
  • Year and Date: 2007-09-30
• [Presentation] 有機ボロン酸を用いる触媒的不斉炭素-炭素結合形成機構 (2007)
  • Author(s): 宮浦憲夫
  • Organizer: 第57回有機反応化学討論会
  • Place of Presentation: 東広島・広島大学
  • Year and Date: 2007-09-30
• [Presentation] Arylboron Compounds in Asymmetric 1, 4-Addition reactions catalyzed by Cationic Palladium (II) Complexes (2007)
  • Author(s): T. Nishikata, Y. Yamamoto, N. Miyaura
  • Organizer: EUROBORON4
  • Place of Presentation: Bremen・ブレーメン大学
  • Year and Date: 2007-09-04
• [Presentation] Palladium-Catalyzed γ-Selective Cross-Coupling of Potassium Allyltrifluoroborates with Aryl and 1-Alkenyl Bromides (2007)
  • Author(s): Y. Yamamoto, S. Takada, N. Miyaura
  • Organizer: EUROBORON4
  • Place of Presentation: Bremen・ブレーメン大学
  • Year and Date: 2007-09-04
• [Presentation] Metal-Catalyzed Reactions of Organoboronic Acids and Esters for Organic Synthesis (2007)
  • Author(s): N. Miyaura
  • Organizer: OMCOS 14
  • Place of Presentation: Nara, Japan
  • Year and Date: 2007-08-05
• [Presentation] Metal-Catalyzed Reactions of Organoboronic Acids and Esters for Organic Syntheses (2007)
  • Author(s): N. Miyaura
  • Organizer: The 14th IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis(OMCOS14)
  • Place of Presentation: Nara・なら100年会館
  • Year and Date: 2007-08-05
• [Presentation] Cationic Palladium (II) Catalysts in Asymmetric 1, 4-additions (2007)
  • Author(s): T. Nishikata, Y. Kobayashi, K. Kobayashi, Y. Yamamoto, N. Miyaura
  • Organizer: The 14th IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis(OMCOS 14)
  • Place of Presentation: Nara・なら100年会館
  • Year and Date: 2007-08-03
• [Presentation] Palladium-Catalyzed γ-Selective Cross-Coupling of Potassium Allyltrifluoroborates with Aryl and 1-Alkenyl Bromides (2007)
  • Author(s): Y. Yamamoto, S. Takada, N. Miyaura
  • Organizer: The 14th IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis(OMCOS 14)
  • Place of Presentation: Nara・なら100年会館
  • Year and Date: 2007-08-03
• [Presentation] Chiral N, N-Dimetyl Bisphosphoramidite (Me-BIP AM) for Transition Metal-Catalyzed Asymmetric Reactions (2007)
  • Author(s): K. Kurihara, Y. Yamamoto, N. Miyaura
  • Organizer: The 14th IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis (OMCOS 14)
  • Place of Presentation: Nara・なら100年会館
  • Year and Date: 2007-08-03
• [Presentation] Potassium Aryl (trialkoxy) borates: Novel and Powerful Reagents for Copper (II)-Catalyzed N-Arylation of Amines, Anilines and Imidazoles. (2007)
  • Author(s): X. Q. Yu, Y. Yamamoto, N. Miyaura
  • Organizer: The 14th IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis (OMCOS 14)
  • Place of Presentation: Nara・なら100年会館
  • Year and Date: 2007-08-03
• [Presentation] Iridium-Catalyzed Borylation of Cyclic Vinyl Ethers via vinylic C-H Activation (2007)
  • Author(s): T. Kikuchi, T. Ishiyama, N. Miyaura
  • Organizer: The 14th IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis (OMCOS 14)
  • Place of Presentation: Nara・なら100年会館
  • Year and Date: 2007-08-03
• [Presentation] カチオン性パラジウム(II)触媒を用いるアリールボロン酸の不斉共役付加を利用した(R)-Tolterodineの合成 (2007)
  • Author(s): 西形孝司、小林謙也、山本靖典、宮浦憲夫
  • Organizer: 日本化学会北海道支部2007夏季研究発表会
  • Place of Presentation: 旭川・旭川工業高等専門学校
  • Year and Date: 2007-07-21
• [Presentation] 有機トリオールボレート塩の合成とクロスカップリング反応への応用 (2007)
  • Author(s): 滝沢美穂、山本靖典、宮浦憲夫
  • Organizer: 日本化学会北海道支部2007夏季研究発表会
  • Place of Presentation: 旭川・旭川工業高等専門学校
  • Year and Date: 2007-07-21
• [Presentation] イリジウム触媒を用いた1-ヒドロシラトランによる芳香族C-H結合の直接ケイ素化反応 (2007)
  • Author(s): 高田瑠美、岸田恵美、齋木丈章、石山竜生、宮浦憲夫
  • Organizer: 日本化学会北海道支部2007夏季研究発表会
  • Place of Presentation: 旭川・旭川工業高等専門学校
  • Year and Date: 2007-07-21
• [Presentation] 二座ホスホロアミダイト(Me-BIPAM)配位子を用いる不斉触媒反応 (2007)
  • Author(s): 栗原一典、山本靖典、宮浦憲夫
  • Organizer: 第19回万有札幌シンポジウム
  • Place of Presentation: 札幌・厚生年金会館
  • Year and Date: 2007-07-07
• [Presentation] ロジウムおよびパラジウム触媒を用いる有機ホウ素化合物の1,4-付加反応 (2007)
  • Author(s): 山本靖典
  • Organizer: 特定領域研究「元素相乗系化合物の化学」第1回若手コロキウム
  • Place of Presentation: 福岡
  • Year and Date: 2007-03-08
• [Presentation] 有機ホウ素化合物を用いる遷移金属触媒反応 (2007)
  • Author(s): 山本靖典
  • Organizer: 北海道支部2007年冬季研究発表会
  • Place of Presentation: 札幌
  • Year and Date: 2007-02-06
• [Presentation] 有機ボロン酸の触媒化学 (2007)
  • Author(s): 宮浦憲夫
  • Organizer: 触媒学会北海道地区札幌講演会&有機金属研究会Organometallic SeminarXXXV
  • Place of Presentation: 札幌
• [Presentation] Metal-Catalyzed Reactions of Organoboronic Acids and Esters for Organic Synthese (2007)
  • Author(s): 宮浦憲夫
  • Organizer: The 14th IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis(OMCOS14)
  • Place of Presentation: Nara
• [Presentation] ホウ素化合物の触媒的有機合成化学 (2007)
  • Author(s): 宮浦憲夫
  • Organizer: 第92回有機合成シンポジウム
  • Place of Presentation: 東京
• [Presentation] 有機ボロン酸を用いる触媒的不斉炭素-炭素結合形成機構 (2007)
  • Author(s): 宮浦憲夫
  • Organizer: 第57回有機反応化学討論会
  • Place of Presentation: 九州
• [Presentation] イリジウム触媒を用いるアレーンのホウ素化とケイ素化 (2007)
  • Author(s): 宮浦憲夫
  • Organizer: 日本化学会第87春季年会特別企画C-H結合の活性化を利用した有機合成
  • Place of Presentation: 大阪
• [Presentation] 有機ボロン酸の触媒化学 (2006)
  • Author(s): 宮浦憲夫
  • Organizer: 有機金属部会平成18年度第3回例会
  • Place of Presentation: 九州
• [Presentation] Metal-Catalyzed Reaction s Organoboron Compaunds for C-C and B-C Bond Formation (2006)
  • Author(s): 宮浦憲夫
  • Organizer: IFOC-5
  • Place of Presentation: 東京
• [Presentation] Organoboron Compounds in Organic Synthese and Materials (2006)
  • Author(s): 宮浦憲夫
  • Organizer: 2nd BASF Boron Conference
  • Place of Presentation: 東京
• [Presentation] ホウ素-炭素、ケイ素-炭素結合形成における相乗系イリジウム錯体 (2006)
  • Author(s): 宮浦憲夫
  • Organizer: 第56回錯体化学討論会
  • Place of Presentation: 広島
• [Presentation] 有機ホウ素化合物のクロスカップリング反応 (2006)
  • Author(s): 宮浦憲夫
  • Organizer: 日本化学第86春季年会特別企画・最新のクロスカップリング
  • Place of Presentation: 東京
• [Book] 鈴木カップリングを革新するボロン酸誘導体 (2010)
  • Author(s): 山本靖典、宮浦憲夫
  • Publisher: シーエムシー出版(印刷中)
• [Book] Metal-Catalyzed Borylation of C-H and C-halogen Bonds of Alkanes, Alkenes and Arenes for Synthesis of Boronic Esters, Boronic Acids, ( Ed. by D. Hall) (2010)
  • Author(s): Ishiyama, T.; Miyaura, N.
  • Publisher: Wiley-VCH(in press)
• [Book] アリールボロン酸のSuzuki Couplingにおける遷移金属触媒 (2007)
  • Author(s): 宮浦憲夫
• [Book] Boron Compounds in Organic Synthesis, Comprehensive Organometallics Chemistry III, (Eds. by R.H. Crabtree and M.P. Mingos) (2007)
  • Author(s): Miyaura, N.; Yamamoto, Y.
  • Publisher: Elsevier
• [Book] 触媒年鑑「触媒技術の動向と展望2007」アリールボロン酸のSuzuki couplingにおける遷移金属触媒(pp29-39) (2007)
  • Author(s): 宮浦憲夫
  • Total Pages: 578
  • Publisher: 触媒学会
• [Book] アリルトリフルオロボレートを用いるクロスカップリング反応(Organometallic News No.1) (2007)
  • Author(s): 宮浦憲夫, 山本靖典
  • Publisher: 社団法人近畿化学協会有機金属部会
• [Book] Chapter 9.05 Boron, Comprehensive Organometallic Chemistry III vol. 9 (2006)
  • Author(s): N. Miyaura, Y. Yamamoto
  • Publisher: Elsevier
• [Book] "Chapter 9.05 Boron", Comprehensive Organometallic Chemistry III Vol. 9 (Eds. by R. H. Crabtree, M. P. Mingos) (2006)
  • Author(s): N.Miyaura, Y.Yamamoto
  • Publisher: Elsevier
• [Book] "(2R, 3R)-2,3-Bis(diphenylphosphino)butane", Electronic Encyclopedia of Reagents for Organic Synthesis (2006)
  • Author(s): Y.Yamamoto, N.Miyaura
  • Total Pages: 7
  • Publisher: John Wiley ＆ Sons
• [Book] "Boron Trichloride", Electronic Encyclopedia of Reagents for Organic Synthesis (2006)
  • Author(s): Y.Yamamoto, N.Miyaura
  • Total Pages: 15
  • Publisher: John Wiley ＆ Sons
• [Book] 鈴木カップリング反応との出会い(化学者たちの感動の瞬間-興奮に満ちた51の発見物語) (2006)
  • Author(s): 宮浦憲夫
  • Publisher: 化学同人
• [Book] 人名反応に学ぶ有機合成戦略、富岡清(監訳)(翻訳分担) (2006)
  • Author(s): 宮浦憲夫
  • Total Pages: 20
  • Publisher: 化学同人
• [Remarks] 宮浦憲夫文部科学大臣表彰科学技術賞(平成22年4月13日)
• [Remarks] 日本化学会賞(平成20年3月27日)
• [Remarks] 有機合成化学協会賞(平成19年2月22日)
• [Remarks] 山本靖典日本化学会北海道支部奨励賞(平成19年2月6日)
• [Remarks] SYNFACTS 2009, 885 "Enantioselective Ruthenium(II)- catalyzed Aldehydes Arylations"
• [Remarks] SYNFACTS 2009, 650 "Rhodium-Catalyzed Asymmetric 1, 4-Addition of Heteroaryl Triolborates"
• [Remarks] SYNFACTS 2008, 743 "Biaryls via a One-Pot Borylation- Cross-Coupling Sequence Using Pinacolborane"
• [Patent(Industrial Property Rights)] b-アリールボラジンの製造方法 (2009)
  • Inventor(s): 宮浦憲夫、山本靖典
  • Industrial Property Rights Holder: 日本触媒、北海道大学
  • Industrial Property Number: 2009-137319
  • Filing Date: 2009-06-08
• [Patent(Industrial Property Rights)] ピナコールボランの製造方法 (2009)
  • Inventor(s): 宮浦憲夫、山本靖典
  • Industrial Property Rights Holder: 北海道大学、広栄化学(株)
  • Patent Publication Number: 2009-191025
  • Acquisition Date: 2009-08-27
• [Patent(Industrial Property Rights)] B-アリールボラジンの製造方法 (2009)
  • Inventor(s): 宮浦憲夫、山本靖典
  • Industrial Property Rights Holder: 北海道大学、日本触媒
  • Industrial Property Number: 2009-137319
  • Filing Date: 2009-06-08
• [Patent(Industrial Property Rights)] 有機トリオールボレート塩を含んでなる有機合成用試薬 (2008)
  • Inventor(s): 宮浦憲夫、山本靖典
  • Industrial Property Rights Holder: 北海道大学
  • Acquisition Date: 2008-08-07
• [Patent(Industrial Property Rights)] 光学活性置換インデン類の製造方法 (2008)
  • Inventor(s): 宮浦憲夫、山本靖典、西形孝司
  • Industrial Property Rights Holder: 北海道大学、科学技術振興機構
  • Patent Publication Number: 2008-214313
  • Acquisition Date: 2008-09-18
• [Patent(Industrial Property Rights)] 有機ケイ素化合物の製造方法 (2008)
  • Inventor(s): 宮浦憲夫、石山竜生、齋木丈章
  • Industrial Property Rights Holder: 東レ・ダウコーニング(株)
  • Patent Publication Number: 2008-024607
  • Acquisition Date: 2008-03-27
• [Patent(Industrial Property Rights)] 光学活性化合物の製造方法 (2008)
  • Inventor(s): 宮浦憲夫、山本靖典、西形孝司
  • Industrial Property Rights Holder: 北海道大学、科学技術振興機構
  • Patent Publication Number: 2008-024607
  • Acquisition Date: 2008-02-07
• [Patent(Industrial Property Rights)] β-ジアリール電子求引性基置換化合物の製造方法 (2008)
  • Inventor(s): 宮浦憲夫、山本靖典、西形孝司、伊藤孝浩
  • Industrial Property Rights Holder: 北海道大学、科学技術振興機構、萬有製薬
  • Acquisition Date: 2008-01-24
• [Patent(Industrial Property Rights)] ピナコールボランの製造方法 (2008)
  • Inventor(s): 宮浦憲夫、山本靖典
  • Industrial Property Rights Holder: 北海道大学、広栄化学株式会社
  • Industrial Property Number: 2008-034083
  • Filing Date: 2008-02-15
• [Patent(Industrial Property Rights)] 有機トリオールボレート塩を含んでなる有機合成用試薬 (2008)
  • Inventor(s): 宮浦憲夫、山本靖典
  • Industrial Property Rights Holder: 北海道大学
  • Acquisition Date: 2008-08-07
  • Overseas
• [Patent(Industrial Property Rights)] βジアリール電子求引性基置換化合物の製造方法 (2008)
  • Inventor(s): 宮浦憲夫、山本靖典、西形孝司、伊藤孝浩
  • Industrial Property Rights Holder: 北海道大学、科学技術振興機構、万有製薬
  • Acquisition Date: 2008-01-24
  • Overseas
• [Patent(Industrial Property Rights)] 光学活性置換インデン類の製造方法 (2007)
  • Inventor(s): 宮浦憲夫, 山本靖典, 西形孝司
  • Industrial Property Rights Holder: 北海道大学, 科学技術振興機構
  • Industrial Property Number: 2007-057311
  • Filing Date: 2007-03-07
• [Patent(Industrial Property Rights)] 有機トリオールポレート塩 (2007)
  • Inventor(s): 宮浦憲夫, 山本靖典
  • Industrial Property Rights Holder: 北海道大学
  • Industrial Property Number: 2007-017286
  • Filing Date: 2007-01-29
• [Patent(Industrial Property Rights)] 不斉合成用触媒およびそれに用いる配位子、並びにこれらを用いた不斉合成反応による光学活性化合物の製造方法 (2006)
  • Inventor(s): 宮浦憲夫、山本靖典
  • Industrial Property Rights Holder: 科学技術振興機構
  • Acquisition Date: 2006-08-24
• [Patent(Industrial Property Rights)] ヘキサアルキルボラジンの製造方法 (2006)
  • Inventor(s): 宮浦憲夫、山本靖典、中谷泰隆、山本哲也
  • Industrial Property Rights Holder: 北海道大学、日本触媒
  • Acquisition Date: 2006-05-11
• [Patent(Industrial Property Rights)] 不斉合成用触媒およびそれに用いる配位子、並ひにこれらを用いた不斉合成反応による光学活性化合の製造方法 (2006)
  • Inventor(s): 宮浦憲夫, 山本靖典
  • Industrial Property Rights Holder: 科学技術振興機構
  • Patent Publication Number: 2006-257081
  • Filing Date: 2006
• [Patent(Industrial Property Rights)] βジアリール電子求引性基置換化合物の製造方法 (2006)
  • Inventor(s): 宮浦憲夫, 山本靖典, 西形孝司, 伊藤孝浩
  • Industrial Property Rights Holder: 北海道大学, 科学技術振興機構, 萬有製薬
  • Industrial Property Number: 2006-196491
  • Filing Date: 2006-07-19
• [Patent(Industrial Property Rights)] 光学活性化合物の製造方法 (2006)
  • Inventor(s): 宮浦憲夫, 山本靖典, 西形孝司
  • Industrial Property Rights Holder: 北海道大学, 科学技術振興機構
  • Industrial Property Number: 2006-196477
  • Filing Date: 2006-07-19
• [Patent(Industrial Property Rights)] ヘキサアルキルボラジンの製造方法 (2004)
  • Inventor(s): 宮浦憲夫, 山本靖典, 中谷泰隆, 山本哲也
  • Industrial Property Rights Holder: 北海道大学, 日本触媒
  • Patent Publication Number: 2006-131569
  • Filing Date: 2004-11-08