Metal-Catalyzed Reaction of Main Group Elements
| Project/Area Number |
18064001
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| Research Category |
Grant-in-Aid for Scientific Research on Priority Areas
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| Allocation Type | Single-year Grants |
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| Review Section |
Science and Engineering
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| Research Institution | Hokkaido University |
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Principal Investigator |
MIYAURA Norio Hokkaido University, 大学院・工学研究科, 教授 (10002049)
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| Co-Investigator(Kenkyū-buntansha) |
山本 靖典 北海道大学, 大学院・工学研究科, 助教 (30271646)
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| Project Period (FY) |
2006 – 2009
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| Project Status |
Completed (Fiscal Year 2009)
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| Budget Amount *help |
¥94,900,000 (Direct Cost: ¥94,900,000)
Fiscal Year 2009: ¥13,800,000 (Direct Cost: ¥13,800,000)
Fiscal Year 2008: ¥14,500,000 (Direct Cost: ¥14,500,000)
Fiscal Year 2007: ¥13,800,000 (Direct Cost: ¥13,800,000)
Fiscal Year 2006: ¥52,800,000 (Direct Cost: ¥52,800,000)
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| Keywords | ホウ素化学 / 合成化学 / 触媒・化学プロセス / 構造・機能化学 / 構造・機能材料 |
|---|
| Research Abstract |
We studied B-C bond-forming reactions including borylation of C-H bonds of arenes and alkenes with iridium catalysts. A novel triolborate salts were developed for catalyzed cross-coupling or addition reactions. We developed new bidentate chiral phosphoramidites (Me-BIPAM, N-Me-BIPAM). These ligands were found to be effective for rhodium- and ruthenium-catalyzed asymmetric addition reactions of arylboronic acids to α,β-unsaturated carbonyl compounds, aldehydes and imines.
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Report
(6 results)
Research Products
(215 results)
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[Journal Article] Iridium-Catalyzed C-H Borylation of Arenes and Heteroarenes: 1-Chloro-3-iodo-5-(4, 4, 5, 5-tetramethyl-1, 3, 2-dioxabo rolan-2-yl)benzen and 2-(4, 4, 5, 5-Tetramethyl-1, 3, 2- dioxaborolan-2-yl)indole2009
Author(s)
Ishiyama, T., Takagi, J., Nobuta, Y., Miyaura, N.
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Journal Title
Organic Synthesis Vol.11
Pages: 1007-1014
NAID
Related Report
Peer Reviewed
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[Journal Article] Iridiumu-catalyzed C-H borylation of arenes and heteroarenes : 1-chloro-3-iodo-5-(4,4,5,5-tetramethyl-1,3,2-dioxabororan-2-yl)benzene and 2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)indole2009
Author(s)
Ishiyama, T., Takagi, J., Nobuta, Y., Miyaura, N.
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Journal Title
Organic Synthesis 11
Pages: 1007-1014
Related Report
Peer Reviewed
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[Journal Article] 1, 4-Addition of Arylboronic Acids to β-Aryl-α, β-unsaturated Ketones and Esters Catalyzed by Rhodium(I)-Chiraphos Complex for Catalytic Enantioselective Synthesis of Selective Endothelin A Receptor Antagonists2006
Author(s)
Itoh, T.; Mase, T.; Nishikata, T.; Iyama, T.; Tchikawa, H.; Kobayashi, Y.; Yamamoto, Y.; Miyaura, N.
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Journal Title
Tetrahedron 62
Pages: 9610-9621
Related Report
Peer Reviewed
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