Design and Development of Multimetallic Reagents and Their Application in Synthetic Reactions
| Project/Area Number |
18064006
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| Research Category |
Grant-in-Aid for Scientific Research on Priority Areas
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| Allocation Type | Single-year Grants |
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| Review Section |
Science and Engineering
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| Research Institution | Kyoto University |
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Principal Investigator |
NAKAMURA Masaharu Kyoto University, 化学研究所, 教授 (00282723)
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| Project Period (FY) |
2006 – 2009
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| Project Status |
Completed (Fiscal Year 2009)
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| Budget Amount *help |
¥35,600,000 (Direct Cost: ¥35,600,000)
Fiscal Year 2009: ¥8,900,000 (Direct Cost: ¥8,900,000)
Fiscal Year 2008: ¥8,900,000 (Direct Cost: ¥8,900,000)
Fiscal Year 2007: ¥8,900,000 (Direct Cost: ¥8,900,000)
Fiscal Year 2006: ¥8,900,000 (Direct Cost: ¥8,900,000)
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| Keywords | 普遍金属 / 化学資源 / 触媒 / 有機合成 / 元素科学 / 金属複合反応剤 / 有機合成反応 / 協働機能触媒 / 鉄触媒 / クロスカップリング / 金属複合系反応剤 / 協奏機能触媒 / ビアリール / 有機マグネシウム化合物 / 炭素-炭素結合 / 後周期 |
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| Research Abstract |
This research program dealt with synergistic effects of various combinations of transition and main group metals on the catalyses for synthetic organic transformations. We focused, in particular, on transition metal/main group metal, or transition metal/transition metal cooperative catalysts upon carbon-carbon bond formation reactions. Herein are described representative results of the research program: iron-catalyzed selective biaryl cross-coupling and iron-catalyzed cross-coupling reaction of haloalkanes with various organometallic reagensts, including organomagnesium, zinc, boron, and aluminum compounds.
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Report
(6 results)
Research Products
(137 results)
