Controlled Dynamic Behavior of Interlocked Molecules with Metal Template Motifs
Project/Area Number |
18064008
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Research Category |
Grant-in-Aid for Scientific Research on Priority Areas
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Allocation Type | Single-year Grants |
Review Section |
Science and Engineering
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Research Institution | Tokyo Institute of Technology |
Principal Investigator |
TAKATA Toshikazu Tokyo Institute of Technology, 大学院・理工学研究科, 教授 (40179445)
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Co-Investigator(Kenkyū-buntansha) |
KOYAMA Yasuhito 東京工業大学, 大学院・理工学研究科, 助教 (10456262)
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Project Period (FY) |
2006 – 2009
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Project Status |
Completed (Fiscal Year 2009)
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Budget Amount *help |
¥28,400,000 (Direct Cost: ¥28,400,000)
Fiscal Year 2009: ¥7,100,000 (Direct Cost: ¥7,100,000)
Fiscal Year 2008: ¥7,100,000 (Direct Cost: ¥7,100,000)
Fiscal Year 2007: ¥7,100,000 (Direct Cost: ¥7,100,000)
Fiscal Year 2006: ¥7,100,000 (Direct Cost: ¥7,100,000)
|
Keywords | ロタキサン / パラジウム / 触媒 / 相互作用 / 空間結合 |
Research Abstract |
Rotaxanes possessing catalytic functions have attracted much attention due to their unique structures consisting of mechanically linked components and their properties. The use of the rotaxane-based molecules as a reaction template enables the amplification of weak interactions by a proximity effect between the components, providing an ideal scaffold to evaluate the inherence of interaction between the elements. This study is focused on an evaluation of synergy effect generated between a transition metal and typical elements. On the basis of these results, we developed a new rotaxane catalyst and linear molecular motor including the rotaxane skeleton as a key unit.
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Report
(6 results)
Research Products
(118 results)
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[Journal Article] Catalytic Asymmetric Synthesis and Optical Resolution of Planar Chiral Rotaxane2007
Author(s)
Makita, Y.: Kihara, N, ; Nakakoji, N, ; Takata, T.; Inagaki, S, ; Yamamoto, C.; Okamoto, Y.
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Journal Title
Chemistry Letters 36
Pages: 102-103
NAID
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Peer Reviewed
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[Journal Article] Prolongation of the Lifetime of the Charge-Separated State at Low Temperatures in a Photoinduced Electron-Transfer System of [60]Fullerene and Ferrocene Moieties Tethered by Rotaxane Structures2006
Author(s)
Rajkumar, G.A., Sandanayaka, A.S.D., Ikeshita, K., Araki, Y., Furusho, Y., Takata, T., Ito, O.
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Journal Title
Journal of Physical Chemistry, B 110
Pages: 6516-6525
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[Journal Article] Photoinduced Electron Transfer Processes in Rotaxanes Containing [60]Fullerene and Ferrocene; Effect of Charge of Axle on Light Induced Molecular Mortion2006
Author(s)
Sandanayaka, A.S.D., Sasabe, H., Araki, Y., Kihara, N., Furusho, Y., Takata, T., Ito, O.
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Journal Title
Australian Journal of Chemistry 59
Pages: 186-186
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[Presentation] Synthesis2008
Author(s)
Toshikazu Takata
Organizer
Properties and Application of Rotaxanes Formed by Utilizing Dynamic Covalent Bond
Place of Presentation
Universidad Autonoma de Madrid, Madrid.
Year and Date
2008-07-10
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