Functional Transition Metal Complexes with Heavier Element Ligands
| Project/Area Number |
18064010
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| Research Category |
Grant-in-Aid for Scientific Research on Priority Areas
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| Allocation Type | Single-year Grants |
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| Review Section |
Science and Engineering
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| Research Institution | Kyoto University |
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Principal Investigator |
OZAWA Fumiyuki Kyoto University, 化学研究所, 教授 (40134837)
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| Co-Investigator(Kenkyū-buntansha) |
OKAZAKI Masaaki 弘前大学, 大学院・理工学研究科, 教授 (20292203)
TAKITA Ryo 京都大学, 化学研究所, 助教 (50452321)
NAKAJIMA Yumiko 京都大学, 化学研究所, 助教 (80462711)
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| Project Period (FY) |
2006 – 2009
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| Project Status |
Completed (Fiscal Year 2009)
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| Budget Amount *help |
¥79,000,000 (Direct Cost: ¥79,000,000)
Fiscal Year 2009: ¥10,200,000 (Direct Cost: ¥10,200,000)
Fiscal Year 2008: ¥10,200,000 (Direct Cost: ¥10,200,000)
Fiscal Year 2007: ¥10,200,000 (Direct Cost: ¥10,200,000)
Fiscal Year 2006: ¥48,400,000 (Direct Cost: ¥48,400,000)
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| Keywords | 元素相乗系錯体 / 低配位リン配位子 / 拡張π共役系錯体 / dπ-pπ相互作用 / ヒドロシリル化 / σ結合メタセシス / P-C還元的脱離 / 遷移金属 / 低配位リン相乗系 / ホスファアルケン配位子 / 配位子特性 / π(d-p)相互作用 / 混合原子価錯体 / トランスメタル化 / 直接重縮合反応 / ジホスフィニデンシクロブテン / π共役系遷移金属錯体 / ホモカップリング / ヒドロシラン / ヒドロキシ錯体 / 水の活性化 |
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| Research Abstract |
It has been recognized that heavier main-group elements have fundamental difference in electronic properties from their lighter congeners. This viewpoint should be true for coordination chemistry using heavier element ligands as well. In this study, we examined structures and reactivities of group 8-10 metal complexes bearing heavier element ligands. A particular interest has been focused on applications of low-coordinate phosphorus ligands to catalytic reactions and functional molecule synthesis.
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Report
(6 results)
Research Products
(78 results)
