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Functional Transition Metal Complexes with Heavier Element Ligands

Research Project

Project/Area Number 18064010
Research Category

Grant-in-Aid for Scientific Research on Priority Areas

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionKyoto University

Principal Investigator

OZAWA Fumiyuki  Kyoto University, 化学研究所, 教授 (40134837)

Co-Investigator(Kenkyū-buntansha) OKAZAKI Masaaki  弘前大学, 大学院・理工学研究科, 教授 (20292203)
TAKITA Ryo  京都大学, 化学研究所, 助教 (50452321)
NAKAJIMA Yumiko  京都大学, 化学研究所, 助教 (80462711)
Project Period (FY) 2006 – 2009
Project Status Completed (Fiscal Year 2009)
Budget Amount *help
¥79,000,000 (Direct Cost: ¥79,000,000)
Fiscal Year 2009: ¥10,200,000 (Direct Cost: ¥10,200,000)
Fiscal Year 2008: ¥10,200,000 (Direct Cost: ¥10,200,000)
Fiscal Year 2007: ¥10,200,000 (Direct Cost: ¥10,200,000)
Fiscal Year 2006: ¥48,400,000 (Direct Cost: ¥48,400,000)
Keywords元素相乗系錯体 / 低配位リン配位子 / 拡張π共役系錯体 / dπ-pπ相互作用 / ヒドロシリル化 / σ結合メタセシス / P-C還元的脱離 / 遷移金属 / 低配位リン相乗系 / ホスファアルケン配位子 / 配位子特性 / π(d-p)相互作用 / 混合原子価錯体 / トランスメタル化 / 直接重縮合反応 / ジホスフィニデンシクロブテン / π共役系遷移金属錯体 / ホモカップリング / ヒドロシラン / ヒドロキシ錯体 / 水の活性化
Research Abstract

It has been recognized that heavier main-group elements have fundamental difference in electronic properties from their lighter congeners. This viewpoint should be true for coordination chemistry using heavier element ligands as well. In this study, we examined structures and reactivities of group 8-10 metal complexes bearing heavier element ligands. A particular interest has been focused on applications of low-coordinate phosphorus ligands to catalytic reactions and functional molecule synthesis.

Report

(6 results)
  • 2009 Annual Research Report   Final Research Report ( PDF )
  • 2008 Annual Research Report   Self-evaluation Report ( PDF )
  • 2007 Annual Research Report
  • 2006 Annual Research Report
  • Research Products

    (78 results)

All 2010 2009 2008 2007 2006 Other

All Journal Article (41 results) (of which Peer Reviewed: 38 results) Presentation (32 results) Remarks (5 results)

  • [Journal Article] Electronic Structure of Four- coordinate Iron(I)Complex Supported by a Bis(phosphaetheny1)pyridine Ligand2010

    • Author(s)
      中島裕美子, 小澤文幸, 他4名
    • Journal Title

      J. Am. Chem. Soc. 132(accepted)

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Substituent Effects on P-C Reductive Elimination from Styrylpalladium(II)Phosphine Complexes2010

    • Author(s)
      脇岡正幸, 小潭文幸
    • Journal Title

      Organometallics 29(accepted)

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Structures of Platinum Diphenylacetylene and Dithiolate Complexes Bearing Diphos- phinidenecyclobutene ligands (DPCB-Y)2010

    • Author(s)
      中島裕美子, 滝田良, 岡崎雅明, 小潭文幸, 他3名
    • Journal Title

      New J. Chem. 34(accepted)

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Structures of Platinum Diphenylacetylene and Dithiolate Complexes Bearing2010

    • Author(s)
      中島裕美子
    • Journal Title

      New J.Chem. 34

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Highly Selective Catalytic System for the Cross-Coupling of (E)-Styry1 Bromide with Benzeneboronic Acid:Application to the Synthesis of All-trans Poly(arylene-vinylene)s2009

    • Author(s)
      脇岡正幸, 武藤雄一郎, 滝田良, 小潭文幸
    • Journal Title

      Bull. Chem. Soc. Jpn. 82

      Pages: 1292-1298

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Redox-Active Phosphorus Ligands Bearing a [4Fe-4C亅Core SubstitUent2009

    • Author(s)
      岡崎雅明, 吉村健一, 高野正人, 小潭文幸
    • Journal Title

      Organometallics 28

      Pages: 7055-7058

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] ジホスフィニデンシクロブテン錯体の構造と触媒作用2009

    • Author(s)
      小潭文幸
    • Journal Title

      有合化 67

      Pages: 529-539

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Mechanism of C-P Reductive Elimination from trans-[Pd(CH=CHPh)Br(PMePh2)2]2009

    • Author(s)
      脇岡正幸, 中島裕美子, 小潭文幸
    • Journal Title

      Organometallics 28

      Pages: 2527-2534

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Redox- responsive Recombination of Carbon- Carbon Bonds on Flexible Tetrairon Cores2009

    • Author(s)
      岡崎雅明, 高野正人, 小潭文幸
    • Journal Title

      J. Am. Chem. Soc. 131

      Pages: 1684-1685

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis, Structures, and Reactions of Dirhodium Complexes Bearing 1, 2-Dipheny 1-3, 4-diphosphinidene- cyclobutene Ligand2009

    • Author(s)
      岡崎雅明, 林昭人, 小潭文幸, 他2名
    • Journal Title

      Organometallics 28

      Pages: 902-908

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Redox-Active Phosphorus Ligands Bearing a [4Fe-4C] Core Substituent2009

    • Author(s)
      岡崎雅明
    • Journal Title

      Organometallics 28

      Pages: 7055-7058

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] ジホスフィニデンシクロブテン錯体の構造と触媒機能2009

    • Author(s)
      小澤文幸
    • Journal Title

      有機合成化学協会誌 67

      Pages: 529-539

    • NAID

      10024968965

    • Related Report
      2009 Annual Research Report 2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] ジホスフィニデンシクロブテン錯体の構造と触媒機能2009

    • Author(s)
      小澤文幸
    • Journal Title

      有合化 67(印刷中)

    • NAID

      10024968965

    • Related Report
      2008 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] The Mechanism of C-P Reductive Elimination from trans-[Pd (CH=CHPh) Br (PMePh_2)_2]2009

    • Author(s)
      脇岡正幸, 中島裕美子, 小澤文幸
    • Journal Title

      Organometallics 28

      Pages: 2527-2534

    • Related Report
      2008 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Recox-responsive Recombination of Carbon-Carbon Bonds on Flexible Tetrairon Cores2009

    • Author(s)
      岡崎雅明, 高野正人, 小澤文幸
    • Journal Title

      J. Am. Chem. Soc. 131

      Pages: 1684-1685

    • Related Report
      2008 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] The Mechanism of C-P Reductive Elimination from trans-[Pd(CH=CHPh)Br(PMePh2)2]2009

    • Author(s)
      脇岡正幸
    • Journal Title

      Organometallics 28

      Pages: 2527-2534

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Redox-responsive Recombination of Carbon-Carbon Bonds on Flexible Tetrairon Cores2009

    • Author(s)
      岡崎雅明
    • Journal Title

      J. Am. Chem. Soc. 131

      Pages: 1684-1685

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis, Structures, and Reactions of Dirhodium Complexes Bearing 1, 2-Dipheny1-3, 4-diphosphinidenecyclobutene Ligand (DPCB)2009

    • Author(s)
      岡崎雅明
    • Journal Title

      Organometallics 28

      Pages: 902-908

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Ligand Properties of 1-Phosphaetheny1-2-phospha- nylferrocenes2008

    • Author(s)
      滝田良, 高田有子, Rader. S. Jensen, 岡崎雅明, 小潭文幸
    • Journal Title

      Organometallics 27

      Pages: 6279-6285

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Reactions of Diphosphinidenecyclobutene Ruthenium Complexes Relevant to Catalytic Hydrosilylation of Terminal Alkynes2008

    • Author(s)
      林昭人, 吉富隆彦, 梅田和俊, 岡崎雅明, 小潭文幸
    • Journal Title

      Organometallics 27

      Pages: 2321-2327

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and StmctUres of Platinum(0)Alkyne Complexes with Extendedπ-Conjugated Systems2008

    • Author(s)
      林恭平, 中谷充晴, 林昭人, 岡崎雅明, 小潭文幸, 他3名
    • Journal Title

      Organometallics 27

      Pages: 1970-1972

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Reaction of trans-[Pd(styry1)Br(PMePh2)2] with Styryl Bromide Affording 1, 4-Dipheny1- butadiene. An Unexpected Homocoupling Process Induced by P-C Reductive Elimination2008

    • Author(s)
      脇岡正幸, 長尾将人, 小潭文幸
    • Journal Title

      Organometallics 27

      Pages: 602-608

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Reactions of Diphosphinidenecyclobutene Ruthenium Complexes Relevant to Catalytic Hydrosilylation of Terminal Alkynes2008

    • Author(s)
      林昭人, 吉富隆彦, 梅田和俊, 岡崎雅明, 小澤文幸
    • Journal Title

      Organometallics 27

      Pages: 2321-2327

    • Related Report
      2008 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Structures of Platinum (0) Alkyne Complexes with Extended π-Conugated Systems.2008

    • Author(s)
      林恭平, 中谷光晴, 林昭人, 高野正人, 岡崎雅明, 豊田耕三, 吉藤正明, 小澤文幸
    • Journal Title

      Organometallics 27

      Pages: 1970-1972

    • Related Report
      2008 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Ligand Properties of 1-Phosphaetheny1-2- phosphanylferrocenes2008

    • Author(s)
      滝田良
    • Journal Title

      Organometallics 27

      Pages: 6279-6285

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Reaction of trans-Pd (styry1) Br (PMePh_2)_2 with Styryl Bromide Affording 1,4-Diphenylbutadiene. An Unexpected Homocoupling Process Induced by P-C Reductive Elimination2008

    • Author(s)
      脇岡 正幸
    • Journal Title

      Organometallics 27

      Pages: 602-608

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Structures of Platinum (O) Alkyne Complexes with Extended π-Conjugated Systems2008

    • Author(s)
      林 恭平
    • Journal Title

      Organometallics 27

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Reactions of Diphosphinidenecyclobutene Ruthenium Complexes Relevant to Catalytic Hydrosilylation of Terminal Alkynes2008

    • Author(s)
      林 昭人
    • Journal Title

      Organometallics 27

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis, StructUres, and Catalytic Properties of Late-Transition-Metal 2, 6- Bis-(2-phosphaetheny1)pyridine Complexes2007

    • Author(s)
      林昭人, 岡崎雅明, 小澤文幸, 田中里佳
    • Journal Title

      Organometallics 26

      Pages: 5246-5249

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Cationic Iridium(III) Complexes bearing Phosphaalkene and 2-Pyridylphenyl Ligands2007

    • Author(s)
      林昭人, 石山武, 岡崎雅明, 小澤文幸
    • Journal Title

      Organometallics 26

      Pages: 3708-3712

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Catalytic Properties of Cationic Palladium(II) and Rhodium(I)Complexes Bearing Diphosphinidenecyclobutene Ligands2007

    • Author(s)
      RaderS. Jensen, 梅田和俊, 岡崎雅明, 小澤文幸, 吉藤正明
    • Journal Title

      J. Organomet. Chem. 692

      Pages: 286-294

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Cationic Iridium (III) Complexes Bearing Phosphaalkene and 2-Pyridylphenyl Ligands2007

    • Author(s)
      林昭人, 石山武, 岡崎雅明, 小澤文幸
    • Journal Title

      Organometallics 26

      Pages: 3708-3712

    • Related Report
      2008 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Cationic Iridium (III) Complexes Bearing Phosphaalkene and 2-Pyridylpheny1 Ligands2007

    • Author(s)
      林 昭人
    • Journal Title

      Organometallics 26

      Pages: 3708-3712

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis, Structures, and Catalytic Properties of Late-Transition-Metal 2,6-Bis (2-phosphaetheny1) pyridine Complexes2007

    • Author(s)
      林 昭人
    • Journal Title

      Organometallics 26

      Pages: 5246-5249

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Photoisomerization Mechanism of All-Z-Oligo (phenylenevinylene) s2007

    • Author(s)
      池上 和志
    • Journal Title

      Bulletin of the Chemical Society of Japan 80

      Pages: 1833-1835

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Catalytic Properties of Cationic Palladium(II) and Rhodium(I) Complexes Bearing Diphosphinidinecyclobutene Ligands2007

    • Author(s)
      R.S.Jensen
    • Journal Title

      Journal of Organometallic Chemistry 692・1-3

      Pages: 286-294

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Stereoselective Synthesis of cis-and trans-Oligo(phenylenevinylene)s via Palladium-Catalyzed Cross-Coupling Reactions2006

    • Author(s)
      片山博之, 長尾将人, 小澤文幸, 池上和志, 新井達郎
    • Journal Title

      J. Org. Chem. 71

      Pages: 2699-2705

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Cyclodehydration of cis-2-Butene- 1, 41diol with Active Methylene Compounds Catalyzed by a Diphosphi- nidenecyclobutene-coordinated Palladium Complex2006

    • Author(s)
      村上博美, 松井佑紀男, 小潭文幸, 吉藤正明
    • Journal Title

      J. Organomet. Chem. 691

      Pages: 3151-3156

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Catalytic Appli- cations of Transition Metal Complexes Bearing Diphosphinidenecyclobutenes (DPCB)2006

    • Author(s)
      小澤文幸, 吉藤正明
    • Journal Title

      Dalton Trans (Perspectire)

      Pages: 4987-4995

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Catalytic Applications of Transition Metal Complexes Bearing Diphosphini-denecyclobutenes (DPCB)2006

    • Author(s)
      F.Ozawa
    • Journal Title

      Dalton Transactions 2006・42

      Pages: 4987-4995

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Cyclodehydration of cis-2-Butene-1,4-diol with Active Methylene Compounds Catalyzed by a Diphosphinidenecyclobutene-coordinated Palladium Complex2006

    • Author(s)
      H.Murakami
    • Journal Title

      Journal of Organometallic Chemistry 691・14

      Pages: 3151-3156

    • Related Report
      2006 Annual Research Report
  • [Presentation] ビスホスファエテニルピリジン配位子をするコバルト錯体の合成と反応2010

    • Author(s)
      中島裕美子
    • Organizer
      日本化学会第90回春季年会
    • Place of Presentation
      近畿大学本部キャンパス
    • Year and Date
      2010-03-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] ビスホスファエテニルピリジン配位子をする鉄錯体とジアゾメタンの反応2010

    • Author(s)
      関戸雅幸
    • Organizer
      日本化学会第90回春季年会
    • Place of Presentation
      近畿大学本部キャンパス
    • Year and Date
      2010-03-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] バタフライ型四鉄骨格上でのプロモアセチレンと第一級アミンとの反応によるイソニトリルの生成2010

    • Author(s)
      土本貴大
    • Organizer
      日本化学会第90回春季年会
    • Place of Presentation
      近畿大学本部キャンパス
    • Year and Date
      2010-03-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] 四鉄骨格に架橋した非平面形カルボカチオン上でのニトリルの活性化2010

    • Author(s)
      宮城一貴
    • Organizer
      日本化学会第90回春季年会
    • Place of Presentation
      近畿大学本部キャンパス
    • Year and Date
      2010-03-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] ビスホスファエテニルピリジン配位子を有する銅(I)錯体の合成と性質2010

    • Author(s)
      白石悠
    • Organizer
      日本化学会第90回春季年会
    • Place of Presentation
      近畿大学本部キャンパス
    • Year and Date
      2010-03-26
    • Related Report
      2009 Annual Research Report
  • [Presentation] Synthesis, Structures, and Properties of Phosphaalkene Complexes2010

    • Author(s)
      小澤文幸
    • Organizer
      Visiting Scholor Program, The Chinese University of Hong Kong
    • Place of Presentation
      Hong Kong, China
    • Year and Date
      2010-03-19
    • Related Report
      2009 Annual Research Report
  • [Presentation] Synthesis, StmctUres, and Properties of Phosphaalkene Complexes, Visiting Scholar Program2010

    • Author(s)
      小澤文幸
    • Organizer
      香港中文大学
    • Year and Date
      2010-03-18
    • Related Report
      2009 Final Research Report
  • [Presentation] ホスファアルケン配位錯体の構造と機能2010

    • Author(s)
      小澤文幸
    • Organizer
      第15回精密合成化学セミナー
    • Place of Presentation
      北海道大学
    • Year and Date
      2010-01-08
    • Related Report
      2009 Annual Research Report
  • [Presentation] P-C Reductive Elimination from Palladium(II) Phosphine Complexes2009

    • Author(s)
      小澤文幸, 脇岡正幸, 中島裕美子
    • Organizer
      2009 Workshop on Organometallic Chemistry
    • Place of Presentation
      九州大学
    • Year and Date
      2009-10-28
    • Related Report
      2009 Final Research Report
  • [Presentation] Synthesis and Properties of Bis(phosphaetheny1)pyridine Iron Complexes2009

    • Author(s)
      小澤文幸, 中島裕美子
    • Organizer
      The 14th Japan-Korea Joint Symposium on Organometallic and Coordination Chemistry
    • Place of Presentation
      名古屋大学
    • Year and Date
      2009-10-09
    • Related Report
      2009 Final Research Report
  • [Presentation] Synthesis and Properties of Bis (phosphaethenyl) pyridine Iron Complexes2009

    • Author(s)
      小澤文幸
    • Organizer
      The 14th Japan-Korea Joint Symposium on Organometallic and Coordination Chemistry
    • Place of Presentation
      名古屋大学
    • Year and Date
      2009-10-09
    • Related Report
      2009 Annual Research Report
  • [Presentation] 四鉄骨格上での非平面型カルボカチオンの発生と性質2009

    • Author(s)
      岡崎雅明
    • Organizer
      第56回有機金属化学討論会
    • Place of Presentation
      同志社大学今出川キャンパス
    • Year and Date
      2009-09-11
    • Related Report
      2009 Annual Research Report
  • [Presentation] ビス(ホスファエテニル)ピリジン配位子を有する鉄錯体の合成と性質2009

    • Author(s)
      中島裕美子
    • Organizer
      第56回有機金属化学討論会
    • Place of Presentation
      同志社大学今出川キャンパス
    • Year and Date
      2009-09-10
    • Related Report
      2009 Annual Research Report
  • [Presentation] ジホスフィニデンシクロブテン配位子をする拡張π共役系白金錯体の合成と性質2009

    • Author(s)
      白石悠
    • Organizer
      日本化学会第89回春季年会
    • Place of Presentation
      日本大学合橋キャンパス
    • Year and Date
      2009-03-30
    • Related Report
      2008 Annual Research Report
  • [Presentation] π-アリルパラジウム錯体の反応性に及ほすジホスフィニデンシクロブテンの特異な配位子効果2009

    • Author(s)
      中島裕美子
    • Organizer
      日本化学会第89回春季年会
    • Place of Presentation
      日本大学船橋キャンパス
    • Year and Date
      2009-03-29
    • Related Report
      2008 Annual Research Report
  • [Presentation] ジホスファエテニルピリジル配位子を有する鉄錯体の合成とその還元挙動2009

    • Author(s)
      中島裕美子
    • Organizer
      日本化学会第89回春季年会
    • Place of Presentation
      日本大学船橋キャンパス
    • Year and Date
      2009-03-27
    • Related Report
      2008 Annual Research Report
  • [Presentation] P-C Reductive Elimination from [Pd(styry1)Br(PR3)2] Complexes2008

    • Author(s)
      脇岡正幸, 小澤文幸
    • Organizer
      ChinaーJapan Joint Workshop on Organometallic Chemistry
    • Place of Presentation
      北京大学
    • Year and Date
      2008-10-09
    • Related Report
      2009 Final Research Report
  • [Presentation] P-C Reductive Elimination from [Pd(Styryl)Br(PR_3)_2] Complexes2008

    • Author(s)
      脇岡正幸, 小澤文幸
    • Organizer
      China-Japan Joint Workshop on Organometallic Chemistry
    • Place of Presentation
      北京大学
    • Year and Date
      2008-10-09
    • Related Report
      2008 Self-evaluation Report
  • [Presentation] ヘテロ芳香族化合物の直接的アリール化反応と直接的重合反応の開発2008

    • Author(s)
      滝田良
    • Organizer
      第55回有機金属化学討論会
    • Place of Presentation
      大阪府立大学
    • Year and Date
      2008-09-30
    • Related Report
      2008 Annual Research Report
  • [Presentation] ジホスフィニデンシクロブテン配位子(DPCB)を有する低原子価ロジウム錯体の合成と構造2008

    • Author(s)
      岡崎雅明
    • Organizer
      第55回有機金属化学討論会
    • Place of Presentation
      大阪府立大学
    • Year and Date
      2008-09-30
    • Related Report
      2008 Annual Research Report
  • [Presentation] Catalytic Applications of Transition Metal Complexes Bearing Diphosphinedenecyclobutenes (DPCB-Y)2008

    • Author(s)
      小澤文幸
    • Organizer
      International Symposium on Chemistry of Concerto Catalysis Based on Synergy of Elements
    • Place of Presentation
      フランス・レンヌ大学
    • Year and Date
      2008-07-12
    • Related Report
      2009 Final Research Report 2008 Annual Research Report 2008 Self-evaluation Report
  • [Presentation] [RuCl(μ-Cl)(CO)(DPCB-OMe)]2:A Highly Efficient Catalyst for (Z)-Selective Hydrosilylation of Terminal Alkynes2008

    • Author(s)
      小澤文幸
    • Organizer
      The 15th International Symposium on Organosilicon Chemistry
    • Place of Presentation
      韓国・済州島
    • Year and Date
      2008-06-04
    • Related Report
      2009 Final Research Report
  • [Presentation] [RuCl(μ-Cl)(CO)(DPCB-OMe)]_2 : A Highly Efficient Catalyst for (Z)-Selective Hydrosilylation of Terminal Alkynes2008

    • Author(s)
      小澤文幸
    • Organizer
      The 15th International Symposium on Organosilicon Chemistry
    • Place of Presentation
      韓国・済州島
    • Year and Date
      2008-06-04
    • Related Report
      2008 Self-evaluation Report
  • [Presentation] [RuCl(μ-Cl) (CO) (DPCB-OMe)]2 : A Highly Efficient Catalyst for(Z)-Selective Hydrosilylation of Terminal Alkynes2008

    • Author(s)
      小澤文幸
    • Organizer
      The 15th International Symposium on Organosilicon Chemistry
    • Place of Presentation
      韓国・済州島
    • Year and Date
      2008-06-04
    • Related Report
      2008 Annual Research Report
  • [Presentation] ジホスフィニデンシクロブタ[ι]フェナントレンを有する拡張型π共役系白金錯体の合成と性質2008

    • Author(s)
      林 昭人
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      立教大学
    • Year and Date
      2008-03-30
    • Related Report
      2007 Annual Research Report
  • [Presentation] (E)-β-ブロモスチレンとアリールボロン酸の鈴木-宮浦カップリング反応:trans-ポリ(フェニレンビニレン)の立体制御合成への応用2008

    • Author(s)
      脇岡 正幸
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      立教大学
    • Year and Date
      2008-03-29
    • Related Report
      2007 Annual Research Report
  • [Presentation] Platinum (O) Alkyne Complexes with an Extended π-Electron System2007

    • Author(s)
      小澤 文幸
    • Organizer
      The 1st International Symposium on Synergy of Elements
    • Place of Presentation
      東京工業大学
    • Year and Date
      2007-11-12
    • Related Report
      2007 Annual Research Report
  • [Presentation] A Novel Homo-Coupling Process Induced by P-C Reductive Elimination2007

    • Author(s)
      脇岡 正幸
    • Organizer
      2007 Workshop on Organometallic Chemistry
    • Place of Presentation
      理化学研究所
    • Year and Date
      2007-11-08
    • Related Report
      2007 Annual Research Report
  • [Presentation] ジホスフィニデンシクロブテン配位子(DPCB-Y)を有するルテニウム錯体の合成と反応2007

    • Author(s)
      林 昭人
    • Organizer
      第54回有機金属化学討論会
    • Place of Presentation
      広島大学
    • Year and Date
      2007-10-28
    • Related Report
      2007 Annual Research Report
  • [Presentation] C-P還元的脱離により誘起されるβ-ブロモスチレンの特異なホモカップリング反応2007

    • Author(s)
      脇岡 正幸
    • Organizer
      第54回有機金属化学討論会
    • Place of Presentation
      広島大学
    • Year and Date
      2007-10-28
    • Related Report
      2007 Annual Research Report
  • [Presentation] 低配位リン化合物が創る新しい遷移金属錯体反応場2007

    • Author(s)
      小澤文幸
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      関西大学
    • Year and Date
      2007-03-27
    • Related Report
      2009 Final Research Report 2008 Self-evaluation Report
  • [Presentation] Highly Active Catalysts Bearing Diphosphinidenecyclobutene Ligands (DPCB)2006

    • Author(s)
      小澤文幸
    • Organizer
      The Chemistry Research Promotion Center Lectureship
    • Place of Presentation
      国立台湾大学
    • Year and Date
      2006-11-08
    • Related Report
      2009 Final Research Report 2008 Self-evaluation Report
  • [Remarks]

    • URL

      http://om.kuicr.kyoto-u.ac.jp

    • Related Report
      2009 Final Research Report
  • [Remarks]

    • URL

      http://om.kuicr.kyoto-u.ac.jp

    • Related Report
      2009 Annual Research Report
  • [Remarks]

    • URL

      http://om.kuicr.kyoto-u.ac.jp

    • Related Report
      2008 Self-evaluation Report
  • [Remarks]

    • URL

      http://om.kuicr.kyoto-u.ac.jp

    • Related Report
      2008 Annual Research Report
  • [Remarks]

    • URL

      http://om.kuicr.kyoto-u.ac.jp

    • Related Report
      2007 Annual Research Report

URL: 

Published: 2006-04-01   Modified: 2018-03-28  

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