| Project/Area Number |
18064014
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| Research Category |
Grant-in-Aid for Scientific Research on Priority Areas
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| Allocation Type | Single-year Grants |
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| Review Section |
Science and Engineering
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| Research Institution | Kyushu University |
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Principal Investigator |
NAGASHIMA Hideo Kyushu University, 先導物質化学研究所, 教授 (50159076)
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| Co-Investigator(Kenkyū-buntansha) |
MOTOYAMA Yukihiro 九州大学, 先導物質化学研究所, 准教授 (20283492)
SUNADA Yusuke 九州大学, 先導物質化学研究所, 助教 (70403988)
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| Project Period (FY) |
2006 – 2009
|
| Project Status |
Completed (Fiscal Year 2009)
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| Budget Amount *help |
¥73,600,000 (Direct Cost: ¥73,600,000)
Fiscal Year 2009: ¥9,900,000 (Direct Cost: ¥9,900,000)
Fiscal Year 2008: ¥9,900,000 (Direct Cost: ¥9,900,000)
Fiscal Year 2007: ¥9,900,000 (Direct Cost: ¥9,900,000)
Fiscal Year 2006: ¥43,900,000 (Direct Cost: ¥43,900,000)
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| Keywords | 分子触媒 / クラスター / ヒドロシラン / シリコーンゲル / 固定化触媒 / 還元反応 / 脱水反応 / 鉄触媒反応 / 反応機構 / 遷移金属 / 触媒 / ナノ粒子 / ルテニウム / 重合 / アミド / 白金 / ヘテロバイメタリック錯体 |
|---|
| Research Abstract |
Studies on the multinuclear transition metal complexes and silicon-transition metal clusters revealed their unique structures and reactivity, leading to discovery of unique catalysis based on synergetic effects of the element and element in these complexes. Proximity effect of dual Si-H bonds in ruthenium, iron, platinum, and iridium catalyzed hydrosilane reduction of carbonyl compounds provides practical process to access amines, enamines, and other organic molecules. An intriguing discovery is metallic species encapsulated in silicone gel, which behaves reusable catalysts in organic synthesis.
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