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Synergetic effects of dual metal group interaction for catalysis

Research Project

Project/Area Number 18064014
Research Category

Grant-in-Aid for Scientific Research on Priority Areas

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionKyushu University

Principal Investigator

NAGASHIMA Hideo  Kyushu University, 先導物質化学研究所, 教授 (50159076)

Co-Investigator(Kenkyū-buntansha) MOTOYAMA Yukihiro  九州大学, 先導物質化学研究所, 准教授 (20283492)
SUNADA Yusuke  九州大学, 先導物質化学研究所, 助教 (70403988)
Project Period (FY) 2006 – 2009
Project Status Completed (Fiscal Year 2009)
Budget Amount *help
¥73,600,000 (Direct Cost: ¥73,600,000)
Fiscal Year 2009: ¥9,900,000 (Direct Cost: ¥9,900,000)
Fiscal Year 2008: ¥9,900,000 (Direct Cost: ¥9,900,000)
Fiscal Year 2007: ¥9,900,000 (Direct Cost: ¥9,900,000)
Fiscal Year 2006: ¥43,900,000 (Direct Cost: ¥43,900,000)
Keywords分子触媒 / クラスター / ヒドロシラン / シリコーンゲル / 固定化触媒 / 還元反応 / 脱水反応 / 鉄触媒反応 / 反応機構 / 遷移金属 / 触媒 / ナノ粒子 / ルテニウム / 重合 / アミド / 白金 / ヘテロバイメタリック錯体
Research Abstract

Studies on the multinuclear transition metal complexes and silicon-transition metal clusters revealed their unique structures and reactivity, leading to discovery of unique catalysis based on synergetic effects of the element and element in these complexes. Proximity effect of dual Si-H bonds in ruthenium, iron, platinum, and iridium catalyzed hydrosilane reduction of carbonyl compounds provides practical process to access amines, enamines, and other organic molecules. An intriguing discovery is metallic species encapsulated in silicone gel, which behaves reusable catalysts in organic synthesis.

Report

(6 results)
  • 2009 Annual Research Report   Final Research Report ( PDF )
  • 2008 Annual Research Report   Self-evaluation Report ( PDF )
  • 2007 Annual Research Report
  • 2006 Annual Research Report
  • Research Products

    (117 results)

All 2011 2010 2009 2008 2007 2006 Other

All Journal Article (48 results) (of which Peer Reviewed: 38 results) Presentation (59 results) Book (1 results) Remarks (2 results) Patent(Industrial Property Rights) (7 results)

  • [Journal Article] Catalytic atom-transfer radical cyclization by copper/bipyridine species encapsulated in polysiloxane gel2010

    • Author(s)
      Motoyama, Y. ; Kamo, K. ; Yuasa, A. ; Nagashima, H.
    • Journal Title

      Chem.Commun.

      Pages: 2256-2258

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Hydrosilanes Are Not Always Reducing Agents for Carbonyl Compounds, II : Ruthenium-Catalyzed Deprotection of tert-Butyl Groups in Carbamates.2010

    • Author(s)
      Hanada, S ; Yuasa, A ; Kuroiwa, H ; Motoyama, Y ; Nagashima, H.
    • Journal Title

      Eur.J.Org.Chem.

      Pages: 1021-1025

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Catalytic atom-transfer radical cyclization by copper/bipyridine species encapsulated in polysiloxange gel.2010

    • Author(s)
      Motoyama, Y. ; Kamo, K. ; Yuasa, A. ; Nagashima, H.
    • Journal Title

      Chem.Commun.

      Pages: 2256-2258

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Catalytic atom-transfer radical cyclization by copper/bipyridine species encapsulated in polysiloxange gel2010

    • Author(s)
      H.Nagashima, et al
    • Journal Title

      Chemical Communications

      Volume: 46 Pages: 2256-2258

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hydrosilanes Are Not Always Reducing Agents for Carbonyl Compounds, II : Ruthenium-Catalyzed Deprotection of tert-Butyl Groups in Carbamates2010

    • Author(s)
      H.Nagashima, et al
    • Journal Title

      European Journal of Organic Chemistry

      Pages: 1021-1025

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Practical access to amines by platinum-catalyzed reduction of carboxamides with hydrosilanes : Synergy of dual Si-H groups leads to high efficiency and selectivity.2009

    • Author(s)
      Hanada, S ; Tsutsumi, E ; Motoyama, Y ; Nagashima, H.
    • Journal Title

      J.Am.Chem.Soc. 131

      Pages: 15032-15040

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Hydrosilane Reduction of Tertiary Carboxamides by Iron Carbonyl Catalysts.2009

    • Author(s)
      Sunada, Y ; Kawakami, H ; Imaoka, T ; Motoyama, Y ; Nagashima, H.
    • Journal Title

      Angew.Chem.Int.Ed. 48

      Pages: 9511-9514

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Hydrosilane Reduction of Tertiary Carboxamides by Iron Carbonyl Catalysts2009

    • Author(s)
      H.Nagashima, et al
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 48 Pages: 9511-9514

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mono- and bimetallic ethylene polymerization catalysts having an azanickellacyclo pentene skeleton2009

    • Author(s)
      H.Nagashima, et al
    • Journal Title

      Polyhedron

      Volume: 28 Pages: 3935-3944

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] New Iron(II) Complexes for Atom-Transfer Radical Polymerization : The Ligand Design for Triazacyclononane Results in High Reactivity and Catalyst Performance2009

    • Author(s)
      H.Nagashima, et al
    • Journal Title

      Advanced Synthesis and Catalysis

      Volume: 351 Pages: 2086-2091

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Practical access to amines by platinum-catalyzed reduction of carboxamides with hydrosilanes : Synergy of dual Si-H groups leads to high efficiency and selectivity2009

    • Author(s)
      H.Nagashima, et al
    • Journal Title

      Journal of the American Chemical Society

      Volume: 131 Pages: 15032-15040

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of TMEDA on Iron-Catalyzed Coupling Reactions of ArMgX with Alkyl Halides2009

    • Author(s)
      H.Nagashima, et al
    • Journal Title

      Journal of the American Chemical Society

      Volume: 131 Pages: 6078-6079

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rhodium Nanoparticles Supported on Carbon Nanofibers as an Arene Hydrogenation Catalyst Highly Tolerant to a Coexisting Epoxido Group.2009

    • Author(s)
      H.Nagashima, et al
    • Journal Title

      Organic Letters

      Volume: 11 Pages: 5042-5045

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of TMEDA on Iron-Catalyzed Coupling Reaction of ArMgX with Alkyl Halides2009

    • Author(s)
      Noda, D.; Sunada, Y.; Hatakeyama, T.; Nakamura, M.; Nagashima, H
    • Journal Title

      J. Am. Chem. Soc. 131

      Pages: 6078-6079

    • Related Report
      2008 Self-evaluation Report
  • [Journal Article] Catalysis in Polysiloxane Gels: Platinum-Catalyzed Hydrosilylation of Polymethylhydrosiloxane (PMHS) Leading to Reusable Catalysts for Reduction of Nitroarenes2009

    • Author(s)
      Motoyama, Y.; Kamo, K.; Nagashima, H.
    • Journal Title

      Org. Lett . 11

      Pages: 1345-1348

    • Related Report
      2008 Self-evaluation Report
  • [Journal Article] Highly Efficient Synthesis of Aldenamines from Carboxamides to Enamines by Iridium-Catalyzed Silane-Reduction/Dehydration under Mild Conditions2009

    • Author(s)
      Y.Motoyama, M.Aoki, N.Takaoka, R.Aoto, H.Nagashima
    • Journal Title

      Chem.Commun.

      Pages: 1574-1576

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Catalysis in Polysiloxane Gels : Platinum-Catalyzed Hydrosilylation of Polymethylhydrosiloxane (PMHS) Leading to Reusable Catalysts for Reduction of Nitroarenes2009

    • Author(s)
      Y.Motoyama, K.Kamo, H.Nagashima, Hideo
    • Journal Title

      Org.Lett. 11

      Pages: 1345-1348

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Two coordination modes of TCNE in the ruthenium amidinates : The first example providing experimental evidence for □^1-N to □^2-C rearrangement2009

    • Author(s)
      H.Kondo, T.Sue, A.Kageyama.; Y.Yamaguchi, Y.Sunada, H.Nagashima, Hideo.
    • Journal Title

      J.Organomet.Chem. 694

      Pages: 795-800

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] (η^3-Allyl)Ni(II), Pd(II), and Pt(II) Complexes Bearing a Bidentate Titanium(IV) Phosphinoamide Ligand : a Ti←M_2 Dative Bond Enhances the Electrophilicity of the π-Allyl Moiety2009

    • Author(s)
      H.Tsutsumi, Y.Sunada, Y.Shiota, K.Yoshizawa, H.Nagashima.
    • Journal Title

      Organometallics 28

      Pages: 1988-1991

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Catalytic reduction of amides using hydrosilanes having multiple Si-H groups.Synergistic effect of elements for chemistry of silicon and transition metals.2008

    • Author(s)
      Nagashima, H.
    • Journal Title

      Organometallic News 1

      Pages: 14-19

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Hydrosilanes are not always reducing agents for carbonyl compounds but can also induce dehydration : a ruthenium-catalyzed conversion of primary amides to nitriles.2008

    • Author(s)
      Hanada, S. ; Motoyama, Y. ; Nagashima, H.
    • Journal Title

      Eur.J.Org.Chem.

      Pages: 4097-4100

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synergistic Effects of Two Si-H Groups and a Metal Center" in Transition Metal-Catalyzed Hydrosilylation of Unsaturated Molecules : A Mechanistic Study of the RhCl(PPh3)3-Catalyzed Hydrosilylation of Ketones with 1,2-Bis(dimethylsilyl)benzene.2008

    • Author(s)
      Sunada, Y. ; Fujimura, Y. ; Nagashima, H.
    • Journal Title

      Organometallics 27

      Pages: 3502-3513

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Encapsulated molecular catalysts in polysiloxane gels: ruthenium cluster-catalyzed isomerization of alkenes.2008

    • Author(s)
      Motoyama, Y. ; Abe, M. ; Kamo, K. ; Kosako, Y. ; Nagashima, H.
    • Journal Title

      Chem.Commun.

      Pages: 5321-5323

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Catalysis in Polysiloxane Gels : Platinum-Catalyzed Hydrosilylation of Polymethylhydrosiloxane Leading to Reusable Catalysts for Reduction of Nitroarenes.2008

    • Author(s)
      Motoyama, Y. ; Kamo, K. ; Nagashima, H.
    • Journal Title

      Org.Lett. 11

      Pages: 1345-1348

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Highly efficient synthesis of aldenamines from carboxamides by iridium-catalyzed silane-reduction/dehydration under mild conditions.2008

    • Author(s)
      Motoyama, Y. ; Aoki, M. ; Takaoka, N. ; Aoto, R. ; Nagashima, H.
    • Journal Title

      Chem.Commun.

      Pages: 1574-1576

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] synergistic effects of two Si-H groups and a metal center2008

    • Author(s)
      Sunada, Y.; Fujimura, Y.; Nagashima, H. The
    • Journal Title

      transition metal catalyzed hydrosilylation of unsaturated molecules: A mechanistic study of the RhCl(PPh_3)_3-catalyzed hydrosilylation of ketones with 1,2-bis(dimethylsilyl)benzene (Organometallics) 27

      Pages: 3502-3513

    • Related Report
      2008 Self-evaluation Report
  • [Journal Article] The "synergistic effects of two Si-H groups and a metal center" in transition metal catalyzed hydrosilylation of unsaturated molecules : A mechanistic study of the RhCl(PPh_3)_3-catalyzed hydrosilylation of ketones with 1,2-bis(dimethylsilyl)benzene2008

    • Author(s)
      Y.Sunada, Y.Fujimura, H.Nagashima
    • Journal Title

      Organometallics 27

      Pages: 3502-3513

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Experimental and theoretical aspects of the haptotropic Rearrangement of diiron and diruthenium carbonyl complexes bound to 4,6,8-trimethylazulene2008

    • Author(s)
      K.Tsuchiya, K.Ideta, K.Mogi, Y.Sunada, H.Nagashima
    • Journal Title

      Dalton Transaction

      Pages: 2708-2716

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hydrosilanes are not Always Reducing Agents for Carbonyl Compounds but can Also Induce Dehydration : A Ruthenium-Catalyzed Conversion of Primary Amides to Nitriles2008

    • Author(s)
      S.Hanada, Y.Motoyama, H.Nagashima, Hideo
    • Journal Title

      Eur.J.Org.Chem

      Pages: 4097-4100

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Encapsulated Molecular Catalysts in Polysiloxane Gels : Ruthenium Cluster-Catalyzed Isomerization of Alkenes2008

    • Author(s)
      Y.Motoyama, M.Abe, K.Kamo, Y.Kosako, Yusuke ; Nagashima, Hideo
    • Journal Title

      Chem.Commun.

      Pages: 5321-5323

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chemoselective Hydrogenation of Nitroarenes with Carbon Nanofiber-Supported Platinum and Palladium Nanoparticles2008

    • Author(s)
      H. Nagashima, et al
    • Journal Title

      Organic Letters 10

      Pages: 1601-1604

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Experimental and theoretical aspects of the haptotropic rearrangement of diiron and diruthenium carbonyl complexes bound to 4,6,8-trimethylazulene2008

    • Author(s)
      H. Nagashima, et al
    • Journal Title

      Dalton Transaction

      Pages: 2708-2716

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] The Ruthenium-Catalyzed Reduction and Reductive N-Alkylation of Secondary Amides with Hydrosilanes : Practical Synthesis of Secondary and Tertiary Amines by Judicious Choice of Hydrosilanes.2007

    • Author(s)
      Hanada, S. ; Ishida, T. ; Motoyama, Y. ; Nagashima, H.
    • Journal Title

      J.Org.Chem. 72

      Pages: 7551-7559

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Functional Group-Selective Poisoning of Molecular Catalysts : A Ruthenium Cluster-Catalyzed Highly Amide-Selective Silane Reduction That does not Affect Ketones or Esters.2007

    • Author(s)
      Sasakuma, H. ; Motoyama, Y. ; Nagashima, H.
    • Journal Title

      Chem.Commun.

      Pages: 4916-4918

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Functional Group-Selective Poisoning of Molecular Catalysts: A Ruthenium Cluster-Catalyzed Highly Amide-Selective Silane Reduction That does not Affect Ketones or Esters2007

    • Author(s)
      Sasakuma, H.; Motoyama, Y.; Nagashima, H.
    • Journal Title

      Chem. Commun

      Pages: 4916-4918

    • Related Report
      2008 Self-evaluation Report
  • [Journal Article] 5,5',6,6',7,7',8,8'-Octahydro-1,1'-bi-2-naphthol and -naphthylamine Derivatives by Partial Hydrogenation of 1,1'-Binaphthyls with Carbon Nanofiber Supported Ruthenium Nanoparticles2007

    • Author(s)
      H. Nagashima, et al
    • Journal Title

      Journal of Organic Chemistry 72

      Pages: 10291-10293

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A bis-[C(trimethylsilyl)-N-arylimino]dimethylsilane, Me_3Si(C=NAr)SiMe_2(C=NAr)SiMe_3 (Ar=2,6-xylyl), as a New β-Diimine Ligand2007

    • Author(s)
      H. Nagashima, et al
    • Journal Title

      Organometallics 26

      Pages: 6055-6058

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Functional Group-Selective Poisoning of Molecular Catalysts : A Ruthenium Cluster-Catalyzed Highly Amide-Selective Silane Reduction That does not Affect Ketones or Esters2007

    • Author(s)
      H. Nagashima, et al
    • Journal Title

      Chemical Communication

      Pages: 4916-4918

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ruthenium Nanoparticles on Nano-Level-Controlled Carbon Supports as Highly Effective Catalysts for Arene Hydrogenation2007

    • Author(s)
      H. Nagashima, et al
    • Journal Title

      Chemistry, an Asian journal 2

      Pages: 1524-1533

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] The Ruthenium-Catalyzed Reduction and Reductive N-Alkylation of Secondary Amides with Hydrosilanes : Practical Synthesis of Secondary and Tertiary Amines by Judicious Choice of Hydrosilanes2007

    • Author(s)
      H. Nagashima, et al
    • Journal Title

      Journal of Organic Chemistry 72

      Pages: 7551-7559

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Zirconium(IV) Tris(phosphinoamide) Complexes as the Tripod-type Metallolig and : A Novel Route to Zr-M (M=Cu, Mo, Pt) Heterobimetallic Complexes2007

    • Author(s)
      H. Nagashima, et al
    • Journal Title

      European Journal of Inorganic Chemistry 18

      Pages: 2897-2908

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Reusable and environmentally friendly ionic trinuclear iron complex catalyst for atom transfer radical polymerization2007

    • Author(s)
      S.Niibayashi, H.Hayakawa, R.- H.Jin, H.Nagashima
    • Journal Title

      Chemical Communications (In press)

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Ring Expansion of a Platinacyclopropane to a Platinacyclopentane by Double Insertion of Isocyanides into Pt-C Bonds2007

    • Author(s)
      K.Tsuchiya, H.Kondo, H.Nagashima
    • Journal Title

      Organometallics 26

      Pages: 1044-1051

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Dual Si-H effects in platinum-catalyzed silane reduction of carboxamides leading to a practical synthetic process of tertiary amines involving self-encapsulation of the catalyst species into the insoluble silicone resin formed.2006

    • Author(s)
      Hanada, S. ; Motoyama, Y. ; Nagashima, H.
    • Journal Title

      Tetrahedron Lett. 47

      Pages: 6173-6177

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Dual Si-H effects in platinum-catalyzed silane reduction of carboxamides leading to a practical synthetic process of tertiary amines involving self-encapsulation of the catalyst species into the insoluble silicone resin formed2006

    • Author(s)
      S.Hanada, Y.Motoyama, H.Nagashima
    • Journal Title

      Tetrahedron Letters 47

      Pages: 6173-6177

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Dynamic Titanium Phosphinoamides as Unique Bidentate Phosphorus Ligands for Platinum2006

    • Author(s)
      H.Nagashima, T.Sue, T.Oda, A.Kanemitsu, T.Matsumoto, Y.Motoyama, Y.Sunada
    • Journal Title

      Organometallics 25

      Pages: 1987-1994

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Titanium(IV) phosphinoamide as a unique bidentate ligand for late transition metals II : Ti-Ru heterobimetallics bearing a bridging chlorine atom2006

    • Author(s)
      Y.Sunada, T.Sue, T.Matsumoto, H.Nagashima
    • Journal Title

      Journal of Organometallic Chemistry 691

      Pages: 3176-3182

    • Related Report
      2006 Annual Research Report
  • [Journal Article] A coordinatively unsaturated ruthenium methoxide as a highly effective catalyst for the halogen atom-transfer radical cyclization of N-allyl dichloroacetamides and related reactions2006

    • Author(s)
      Y.Motoyama, S.Hanada, K.Shimamoto, H.Nagashima
    • Journal Title

      Tetrahedron 62

      Pages: 2779-2788

    • Related Report
      2006 Annual Research Report
  • [Presentation] ジシラメタラサイクル骨格を有する新しいハーフサンドイッチ型鉄錯体の合成と反応2010

    • Author(s)
      砂田祐輔、今岡剛、永島英夫
    • Organizer
      日本化学会 第90春季年会
    • Place of Presentation
      大阪
    • Year and Date
      2010-03-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] Ir-Vaska型触媒とTMDSによるエナミン合成プロセスにおけるホスフィン配位子の反応性に与える効果2010

    • Author(s)
      宮本保光、砂田祐輔、永島英夫
    • Organizer
      日本化学会 第90春季年会
    • Place of Presentation
      大阪
    • Year and Date
      2010-03-27
    • Related Report
      2009 Annual Research Report
  • [Presentation] ジシラプラチナ骨格を鍵中間体とするヒドロシリル化反応の反応機構研究2010

    • Author(s)
      堤大典、砂田祐輔、永島英夫
    • Organizer
      日本化学会 第90春季年会
    • Place of Presentation
      大阪
    • Year and Date
      2010-03-26
    • Related Report
      2009 Annual Research Report
  • [Presentation] Disilaplatinacycle complex as a key intermediate for hydrosilylation reaction2009

    • Author(s)
      Hironori Tsutsumi, Yusuke Sunada, Hideo Nagashima
    • Organizer
      The Fourth International Symposium on Novel Carbon Resource Sciences : Environmental Science and Technology
    • Place of Presentation
      上海、中国
    • Year and Date
      2009-12-12
    • Related Report
      2009 Annual Research Report
  • [Presentation] Reusable Reverse ATRP catalyst : Controll Radical Polymerization of Styrene and MMA2009

    • Author(s)
      Hideo Nagashima, Hidetomo Kai, Yusuke Sunada, Mitsunobu Kawamura, Masataka Watanabe, Nobuyuki Koike, Akane Hamada, Hitoshi Hayakawa, Ren-Hua Jin
    • Organizer
      The 11th International Kyoto Conference on New Aspects of Organic Chemistry
    • Place of Presentation
      京都
    • Year and Date
      2009-11-12
    • Related Report
      2009 Annual Research Report
  • [Presentation] Carbon Nanofiber-Supported Rhodium Nanoparticles as Efficient Reusable Catalysts for Arene Hydrogenation2009

    • Author(s)
      Yukihiro Motoyama, Mikihiro Takasaki, Seong-Ho Yoon, Isao Mochida, Hideo Nagashima
    • Organizer
      The 11th International Kyoto Conference on New Aspects of Organic Chemistry
    • Place of Presentation
      京都
    • Year and Date
      2009-11-12
    • Related Report
      2009 Annual Research Report
  • [Presentation] Capsulated Molecular Catalysis in Polysiloxane Gels : Copper/Bipyridine-Catalyzed Atom-Transfer Radical Cyclization2009

    • Author(s)
      Akihiro Yuasa, Kazuyuki Kamo, Yukihiro Motoyama, Hideo Nagashima
    • Organizer
      The 11th International Kyoto Conference on New Aspects of Organic Chemistry
    • Place of Presentation
      京都
    • Year and Date
      2009-11-12
    • Related Report
      2009 Annual Research Report
  • [Presentation] Iron Catalyzed Reduction of Carboxamides woth Hydrosilanes2009

    • Author(s)
      Yusuke Sunada, Hiroko Kawakami, Tsuyoshi Imaoka, Hideo Nagashima
    • Organizer
      The 11th International Kyoto Conference on New Aspects of Organic Chemistry
    • Place of Presentation
      京都
    • Year and Date
      2009-11-12
    • Related Report
      2009 Annual Research Report
  • [Presentation] Silane-Induced Polymerization of Functionalized Oxetanes Catalyzed by a Triruthenium Carbonyl Cluster2009

    • Author(s)
      Nariaki Harada, Jyushiro Yasuhara, Yukihiro Motoyama, Hideo Nagashima
    • Organizer
      The Third International Symposium on Novel Carbon Resource Sciences : Advanced Materials, Processes and Systems toward C02 Mitigation
    • Place of Presentation
      福岡
    • Year and Date
      2009-11-03
    • Related Report
      2009 Annual Research Report
  • [Presentation] 鉄カルボニル触媒を用いたアミド化合物の還元とニトロ基選択的還元反応の開発2009

    • Author(s)
      今岡剛、川上弘子、砂田祐輔、本山幸弘、永島英夫
    • Organizer
      第13回ケイ素化学協会シンポジウム
    • Place of Presentation
      佐賀
    • Year and Date
      2009-10-30
    • Related Report
      2009 Annual Research Report
  • [Presentation] イリジウムVaska型触媒とTMDSによるアミド化合物からのエナミン合成プロセスにおけるホスフィンの効果2009

    • Author(s)
      宮本保光、砂田祐輔、永島英夫
    • Organizer
      第13回ケイ素化学協会シンポジウム
    • Place of Presentation
      佐賀
    • Year and Date
      2009-10-30
    • Related Report
      2009 Annual Research Report
  • [Presentation] ジシラプラチナサイクル構造を鍵中間体とするヒドロシリル化反応の反応機構研究2009

    • Author(s)
      堤大典、砂田祐輔、永島英夫
    • Organizer
      第13回ケイ素化学協会シンポジウム
    • Place of Presentation
      佐賀
    • Year and Date
      2009-10-30
    • Related Report
      2009 Annual Research Report
  • [Presentation] New Fe(II)-complexes for Atom Transfer Radical Polymerization : The Ligand Design for TACN Results in High Reactivity and Catalyst Performance2009

    • Author(s)
      Yusuke Sunada, Mitsunobu Kawamura, Hidetomo Kai, Nobuyuki Koike, Akane Hamada, Hitoshi Hayakawa, Ren-Hua Jin, Hideo Nagashima
    • Organizer
      The 1st FAPS Polymer Congress
    • Place of Presentation
      愛知
    • Year and Date
      2009-10-23
    • Related Report
      2009 Annual Research Report
  • [Presentation] 金属内包シリコーンゲルの有機合成2009

    • Author(s)
      永島英夫
    • Organizer
      第26回有機合成化学セミナー
    • Place of Presentation
      群馬
    • Year and Date
      2009-09-17
    • Related Report
      2009 Annual Research Report 2009 Final Research Report
  • [Presentation] 金属触媒内包ポリシロキサンゲル:銅触媒によるα-アセトアミド類の原子移動型ラジカル環化反応2009

    • Author(s)
      湯浅章弘、加茂和幸、本山幸弘、永島英夫
    • Organizer
      近畿化学会第56回有機金属化学討論会
    • Place of Presentation
      京都
    • Year and Date
      2009-09-11
    • Related Report
      2009 Annual Research Report
  • [Presentation] 様々な置換TACNを持つ鉄錯体:設計、合成、 ATRP触媒機能2009

    • Author(s)
      砂田祐輔、甲斐英知、河村充展、渡辺正敬、小池展行、濱田茜、早川均、金仁華、永島英夫
    • Organizer
      近畿化学会第56回有機金属化学討論会
    • Place of Presentation
      京都
    • Year and Date
      2009-09-10
    • Related Report
      2009 Annual Research Report
  • [Presentation] ジシラメタラサイクル骨格を有する鉄(II)錯体の合成と反応2009

    • Author(s)
      永島英夫、砂田祐輔
    • Organizer
      近畿化学会第56回有機金属化学討論会
    • Place of Presentation
      京都
    • Year and Date
      2009-09-10
    • Related Report
      2009 Annual Research Report
  • [Presentation] 遷移金属とケイ素の相乗効果が開く新しい触媒的有機合成の化学2009

    • Author(s)
      永島英夫
    • Organizer
      第19回万有福岡シンポジウム
    • Place of Presentation
      福岡
    • Year and Date
      2009-05-23
    • Related Report
      2009 Annual Research Report 2009 Final Research Report
  • [Presentation] Ru3核クラスター錯体とヒドロシランを開始剤として用いたオキセタン重合における置換基効果と共重合特性に関する研究2009

    • Author(s)
      高崎幹大、本山幸弘、東賢志、尹聖昊、持田勲、永島英夫
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      千葉
    • Year and Date
      2009-03-29
    • Related Report
      2008 Annual Research Report
  • [Presentation] 窒素含有炭素ナノ繊維担持白金ナノ粒子触媒によるニトロ基選択的還元反応2009

    • Author(s)
      辻啓太、李榮振、本山幸弘、尹聖昊、持田勲、永島英夫
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      千葉
    • Year and Date
      2009-03-29
    • Related Report
      2008 Annual Research Report
  • [Presentation] 光もしくは熱により活性化された鉄カルボニル錯体によるアミド化合物の還元2009

    • Author(s)
      砂田祐輔、川上弘子、永島英夫
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      千葉
    • Year and Date
      2009-03-28
    • Related Report
      2008 Annual Research Report
  • [Presentation] Nitro-Selective Hydrogenation of Functionalized Nitroarenes to Aniline Derivatives with Carbon Nanofiber-Supported Platinum and Palladium Nanoparticles2009

    • Author(s)
      Motoyama, Y.; Takasaki, M.; Tsuji. K.; Yoon, S.-H.; Mochida, I.; Nagashima, H.
    • Organizer
      元素相乗系化合物の化学 第4回公開シンポジウム
    • Place of Presentation
      広島
    • Year and Date
      2009-01-10
    • Related Report
      2008 Annual Research Report
  • [Presentation] Nitro-Selective Hydrogenation of Functionalized Nitroarenes to Aniline Derivatives with Carbon Nanofiber-Supported Platinum and Palladium Nanoparticles2008

    • Author(s)
      Motoyama, Y.; Takasaki, M.; Tsuji. K.; Yoon, S.-H.; Mochida, I.; Nagashima, H.
    • Organizer
      6th Asian Forum on Carbon Materials to Save the Earth
    • Place of Presentation
      Jeonju
    • Year and Date
      2008-11-12
    • Related Report
      2008 Annual Research Report
  • [Presentation] Highly Chemo- and Stereoselective Conversion of Carboxamides to Enamines by Iridium-Catalyzed Silane-Reduction/Dehydration under Mild Conditions2008

    • Author(s)
      Motoyama, Y.; Aoki, M.; Takaoka, N.; Aoto, R.; Nagashima, H.
    • Organizer
      2008 Workshop on Organometallic Chemistry
    • Place of Presentation
      Peking, China
    • Year and Date
      2008-10-09
    • Related Report
      2008 Annual Research Report
  • [Presentation] Fe触媒によるグリニャールカップリングの反応機構研究2008

    • Author(s)
      野田大輔、畠山琢次、砂田祐輔、中村正治、永島英夫
    • Organizer
      第55回有機金属化学討論会
    • Place of Presentation
      大阪
    • Year and Date
      2008-09-30
    • Related Report
      2008 Annual Research Report
  • [Presentation] 分子内Dative Bondを有するTi-10族二核錯体の合成と反応2008

    • Author(s)
      砂田祐輔、堤大典、塩田淑仁、吉澤一成、永島英夫
    • Organizer
      第55回有機金属化学討論会
    • Place of Presentation
      大阪
    • Year and Date
      2008-09-29
    • Related Report
      2008 Annual Research Report
  • [Presentation] 金属触媒内包シロキサンゲル:白金触媒によるニトロ化合物の官能基選択的還元反応2008

    • Author(s)
      加茂和幸、本山幸弘、永島英夫
    • Organizer
      第55回有機金属化学討論
    • Place of Presentation
      大阪
    • Year and Date
      2008-09-29
    • Related Report
      2008 Annual Research Report
  • [Presentation] かさ高い置換基を有する配位不飽和ルテニウムアミジナートへのTCNEの配位挙動2008

    • Author(s)
      砂田祐輔、末隆志、近藤英夫、影山明、永島英夫
    • Organizer
      第58回錯体化学討論会
    • Place of Presentation
      金沢
    • Year and Date
      2008-09-21
    • Related Report
      2008 Annual Research Report
  • [Presentation] Fe触媒によるグリニャールカップリングの反応機構研究2008

    • Author(s)
      野田大輔, 畠山琢次, 砂田祐輔, 中村正治, 永島英夫
    • Organizer
      第25回有機合成セミナー
    • Place of Presentation
      熊本
    • Year and Date
      2008-09-08
    • Related Report
      2008 Annual Research Report
  • [Presentation] 単核配位不飽和鉄触媒の合成とATRPへの応用2008

    • Author(s)
      河村充展、砂田祐輔、甲斐英知、小池展行、濱田茜、早川均、永島英夫
    • Organizer
      第25回有機合成セミナー
    • Place of Presentation
      熊本
    • Year and Date
      2008-09-08
    • Related Report
      2008 Annual Research Report
  • [Presentation] 炭素ナノ繊維担持金属ナノ粒子触媒による水素化反応2008

    • Author(s)
      高崎幹大、東賢志、本山幸弘、永島英夫
    • Organizer
      第25回有機合成セミナー
    • Place of Presentation
      熊本
    • Year and Date
      2008-09-08
    • Related Report
      2008 Annual Research Report
  • [Presentation] 白金触媒とヒドロシランによる効率的なアミドの還元反応2008

    • Author(s)
      花田汐理、堤絵美、本山幸弘、永島英夫
    • Organizer
      第25回有機合成セミナー
    • Place of Presentation
      熊本
    • Year and Date
      2008-09-08
    • Related Report
      2008 Annual Research Report
  • [Presentation] Catalytic Reduction of Carboxamides by Hydrosilanes2008

    • Author(s)
      Nagashima, H.; Sasakuma, H.; Harada, N.; Tsutsumi, H.; Motoyama, Y
    • Organizer
      The First International Symposium on Process Chemistry [ISPC 08]
    • Place of Presentation
      京都
    • Year and Date
      2008-07-30
    • Related Report
      2008 Annual Research Report
  • [Presentation] Carbon Nanofiber-Supported Metal Nanoparticles as Efficient Catalysts for Hydrogenation Reactions2008

    • Author(s)
      Motoyama, Y.; Takasaki, M.; Higashi, K.; Tsuji, K.; Nagashima, H
    • Organizer
      The First International Symposium on Process Chemistry [ISPC 08] 2008, 2P-16.
    • Place of Presentation
      京都
    • Year and Date
      2008-07-30
    • Related Report
      2008 Annual Research Report
  • [Presentation] Silane-induced Polymerization of functionalized oxetanes catalyzed by a triruthenium carbonyl cluster2008

    • Author(s)
      Harada, N, Yasuhara, J.; Motoyama, Y.; Nagashima, H
    • Organizer
      The 15^<th> International Symposium on Organosilicon Chemistry, 2008.
    • Place of Presentation
      Jeju, Korea
    • Year and Date
      2008-06-03
    • Related Report
      2008 Annual Research Report
  • [Presentation] Platinum-Catalyzed Practical Reduction of Carboxamides2008

    • Author(s)
      Hanada, S.; Tsutsumi, E.; Motoyama, Y.; Nagashima, H.
    • Organizer
      The 15^<th> International Symposium on Organosilicon Chemistry, 2008.
    • Place of Presentation
      Jeju, Korea
    • Year and Date
      2008-06-03
    • Related Report
      2008 Annual Research Report
  • [Presentation] Functional Group Selective Reduction of Carboxamides by a Triruthenium Carbonyl Cluster2008

    • Author(s)
      Sasakuma, H.; Motoyama, Y.; Sunada, Y.; Nagashima, H.
    • Organizer
      The 15^<th> International Symposium on Organosilicon Chemistry (Jeju) 2008.
    • Place of Presentation
      Jeju, Korea
    • Year and Date
      2008-06-03
    • Related Report
      2008 Annual Research Report
  • [Presentation] ルテニウム触媒を用いるヒドロシランとアミドの反応2008

    • Author(s)
      花田汐理、本山幸弘、永島英夫
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      東京
    • Year and Date
      2008-03-29
    • Related Report
      2007 Annual Research Report
  • [Presentation] 炭素ナノ繊維担持白金ナノ粒子触媒による芳香族ニトロ化合物の官能基選択的還元反応2008

    • Author(s)
      高崎幹大、本山幸弘、東賢志、尹聖昊、持田勲、永島英夫
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      東京
    • Year and Date
      2008-03-26
    • Related Report
      2007 Annual Research Report
  • [Presentation] Catalytic Reduction of Carboxamides by Hydrosilanes2008

    • Author(s)
      H.Nagashima ; H.Sasakuma ; N.Harada ; H.Tsutsumi ; Y.Motoyama
    • Organizer
      The First International Symposium on Process Chemistry [ISPC 08]
    • Related Report
      2009 Final Research Report
  • [Presentation] Silane-induced polymerization reactions catalyzed by a triruthenium cluster2007

    • Author(s)
      H.Nagashima
    • Organizer
      The Third International Symposium on Development of Silicon-based Functional Materials
    • Place of Presentation
      Kiryu, Japan
    • Year and Date
      2007-11-30
    • Related Report
      2009 Final Research Report
  • [Presentation] Silane-induced polymerization reactions catalyzed by a triruthenium cluster2007

    • Author(s)
      永島英夫
    • Organizer
      The Third International Symposium on Development of Silicon-based Functional Materials
    • Place of Presentation
      桐生、群馬
    • Year and Date
      2007-11-30
    • Related Report
      2007 Annual Research Report
  • [Presentation] ケイ素と遷移金属の元素相乗系アミド還元反応2007

    • Author(s)
      永島英夫
    • Organizer
      近畿化学協会 有機金属部会第3回例会
    • Place of Presentation
      札幌
    • Year and Date
      2007-11-22
    • Related Report
      2009 Final Research Report
  • [Presentation] ケイ素と遷移金属の元素相乗系アミド還元反応2007

    • Author(s)
      永島英夫
    • Organizer
      近畿化学協会 有機金属部会第3回例会
    • Place of Presentation
      札幌、北海道
    • Year and Date
      2007-11-22
    • Related Report
      2007 Annual Research Report
  • [Presentation] Synergetic Effects of Dual Si-H Groups in Transition Metal Catalyzed Silane Reduction of Carboxamides2007

    • Author(s)
      永島英夫
    • Organizer
      The 1st International Symposium on Synergy of Elements
    • Place of Presentation
      東京
    • Year and Date
      2007-11-12
    • Related Report
      2007 Annual Research Report
  • [Presentation] Catalysts for greenchemistry Carbon Saves the Earth 20072007

    • Author(s)
      H.Nagashima
    • Place of Presentation
      Beppu, Japan
    • Year and Date
      2007-11-06
    • Related Report
      2009 Final Research Report
  • [Presentation] Catalysts for green chemistry2007

    • Author(s)
      永島英夫
    • Organizer
      Carbon Saves the Earth 2007
    • Place of Presentation
      別府、大分
    • Year and Date
      2007-11-06
    • Related Report
      2007 Annual Research Report
  • [Presentation] Iridium-Catalyzed Reduction/Dehydration of Tertiary Amides with Hydrosiloxanes : Highly Selective Synthesis of Aldehyde Enamines2007

    • Author(s)
      M. Aoki, N. Takaoka, Y. Motoyams, H. Nagashima
    • Organizer
      The First Asian Silicon Symposium
    • Place of Presentation
      蔵王、宮城
    • Year and Date
      2007-11-01
    • Related Report
      2007 Annual Research Report
  • [Presentation] Hydrosilanes as Dehydration Reagents -Ruthenium catalyzed Dehydration of Primary amides to Nitriles2007

    • Author(s)
      S. Hanada, Y. Motoyama, H. Nagashima
    • Organizer
      The First Asian Silicon Symposium
    • Place of Presentation
      蔵王、宮城
    • Year and Date
      2007-11-01
    • Related Report
      2007 Annual Research Report
  • [Presentation] Silane-Induced Polymerization of Oxetane and Cyclohexeneoxide Catalyzed by a Triruthenium Cluster2007

    • Author(s)
      N. Harada, J. Yasuhara, Y. Motoyama, H. Nagashima
    • Organizer
      The First Asian Silicon Symposium
    • Place of Presentation
      蔵王、宮城
    • Year and Date
      2007-11-01
    • Related Report
      2007 Annual Research Report
  • [Presentation] Synthesis of Rh(III) Complexes Having a Disilacyclic Skeleton, and Catalytic Hydrosilylation of Ketones2007

    • Author(s)
      Y. Sunada, Y. Fujimura, H. Nagashima
    • Organizer
      The First Asian Silicon Symposium
    • Place of Presentation
      蔵王、宮城
    • Year and Date
      2007-11-01
    • Related Report
      2007 Annual Research Report
  • [Presentation] Platinum-Catalyzed Reduction of Tertiary Amides with Hydrosilanes : Practical and Scalable Synthesis of Tertiary Amines2007

    • Author(s)
      E. Tsutsumi, S. Hanada, Y. Motoyama, H. Nagashima
    • Organizer
      The First Asian Silicon Symposium
    • Place of Presentation
      蔵王、宮城
    • Year and Date
      2007-11-01
    • Related Report
      2007 Annual Research Report
  • [Presentation] Environmentally Benign Silane Reduction of Carboxamides : Self-encapsulation of Catalytically Active Species Leading to Facile Separation of Products from Metal and Silane Residues2007

    • Author(s)
      永島英夫
    • Organizer
      IMRAM Tohoku University -England-IMCE Kyushu University- 1st Joint Workshop
    • Place of Presentation
      福岡
    • Year and Date
      2007-10-30
    • Related Report
      2007 Annual Research Report
  • [Presentation] ジシラメタラサイクル骨格を有するRh(III)錯体の合成とケトンの触媒的ヒドロシリル化反応2007

    • Author(s)
      藤村佳樹、砂田祐輔、永島英夫
    • Organizer
      第54回有機金属化学討論会
    • Place of Presentation
      東広島、広島
    • Year and Date
      2007-10-28
    • Related Report
      2007 Annual Research Report
  • [Presentation] ヒドロシランを還元剤に用いたアミドからの触媒的エナミン合成2007

    • Author(s)
      本山幸弘・青木正治・高岡直樹、花田汐理、永島英夫
    • Organizer
      第54回有機金属化学討論会
    • Place of Presentation
      東広島、広島
    • Year and Date
      2007-10-27
    • Related Report
      2007 Annual Research Report
  • [Presentation] ナノ炭素を担体とする金属ナノ粒子触媒 : 光学活性ビナフチル誘導体の効率合成2007

    • Author(s)
      高崎幹大、本山幸弘、尹聖昊、持田勲、永島英夫
    • Organizer
      第54回有機金属化学討論会
    • Place of Presentation
      東広島、広島
    • Year and Date
      2007-10-27
    • Related Report
      2007 Annual Research Report
  • [Presentation] Ti-ホスフィノアミド錯体をメタロリガンドとして有する新規10族遷移金属錯体の開発2007

    • Author(s)
      堤大典、末隆志、砂田祐輔、永島英夫
    • Organizer
      第57回錯体化学討論会
    • Place of Presentation
      名古屋、愛知
    • Year and Date
      2007-09-26
    • Related Report
      2007 Annual Research Report
  • [Presentation] 遷移金属錯体によるラジカル種の発生 : 有機合成と高分子合成の視点から2007

    • Author(s)
      永島英夫
    • Organizer
      第56回高分子討論会
    • Place of Presentation
      名古屋、愛知
    • Year and Date
      2007-09-19
    • Related Report
      2007 Annual Research Report
  • [Presentation] ルテニウム3核クラスター触媒の実用的な合成法の開発とアミド官能基の選択的還元反応2007

    • Author(s)
      永島英夫、笹熊英博、原田斉明、堤大典、本山幸弘
    • Organizer
      日本プロセス化学会2007サマーシンポジウム
    • Place of Presentation
      東京
    • Year and Date
      2007-08-03
    • Related Report
      2007 Annual Research Report
  • [Book] 有機金属化学の最前線多様な元素を使いこなす2011

    • Author(s)
      永島英夫、砂田祐輔
    • Publisher
      東京化学同人
    • Related Report
      2009 Final Research Report
  • [Remarks] ホームページ等

    • URL

      http://www.cm.kyushu-u.ac.jp/dv04/dv04j.html

    • Related Report
      2009 Final Research Report
  • [Remarks] 鉄触媒を用いた精密高分子合成に関する研究について、日本経済新聞(2008 年12 月22日、12 面)に掲載

    • Related Report
      2008 Self-evaluation Report
  • [Patent(Industrial Property Rights)] 鉄錯体の回収方法2008

    • Inventor(s)
      永島英夫、砂田祐輔、甲斐英知
    • Industrial Property Rights Holder
      九州大学, 大日本インキ化学工業
    • Industrial Property Number
      2008-267387
    • Filing Date
      2008-10-16
    • Related Report
      2009 Final Research Report
  • [Patent(Industrial Property Rights)] 鉄錯体を触媒とする重合体の製造方法2008

    • Inventor(s)
      永島英夫、甲斐英知、濱田茜、小池展行、早川均
    • Industrial Property Rights Holder
      九州大学, 大日本インキ化学工業
    • Industrial Property Number
      2008-267386
    • Filing Date
      2008-10-16
    • Related Report
      2009 Final Research Report
  • [Patent(Industrial Property Rights)] ビナフチル化合物の還元によるH8-ビナフチル誘導体の合成法2007

    • Inventor(s)
      本山幸弘、永島英夫、高崎幹大、越山智樹、岩村泰一郎, 真見博司
    • Industrial Property Rights Holder
      九州大学, 新日本理化株式会社
    • Industrial Property Number
      2007-214115
    • Filing Date
      2007-08-20
    • Related Report
      2009 Final Research Report
  • [Patent(Industrial Property Rights)] 脂環族系ポリマーの製造方法2007

    • Inventor(s)
      本山幸弘、永島英夫、高崎幹大、越山智樹、岩村泰一郎, 真見博司
    • Industrial Property Rights Holder
      九州大学, 新日本理化株式会社
    • Industrial Property Number
      2007-174580
    • Filing Date
      2007-07-02
    • Related Report
      2009 Final Research Report
  • [Patent(Industrial Property Rights)] 金属ナノ微粒子担持炭素ナノ繊維の製造法2006

    • Inventor(s)
      本山幸弘、永島英夫、高崎幹大、東賢志、尹聖昊、持田勲
    • Industrial Property Rights Holder
      科学技術振興機構
    • Industrial Property Number
      2006-301076
    • Filing Date
      2006-11-07
    • Related Report
      2009 Final Research Report
  • [Patent(Industrial Property Rights)] 鉄錯体及び該鉄錯体を触媒とする重合体の製造方法

    • Inventor(s)
      永島英夫、砂田祐輔、渡辺正敬、野田大輔、河村充展、甲斐英知、濱田茜、早川均、小池展行
    • Industrial Property Rights Holder
      永島英夫、砂田祐輔、渡辺正敬、野田大輔、河村充展、甲斐英知、濱田茜、早川均、小池展行
    • Related Report
      2008 Self-evaluation Report
  • [Patent(Industrial Property Rights)] 鉄錯体を触媒とする重合体の製造方法

    • Inventor(s)
      永島英夫、新林昭太、金仁華、早川均
    • Industrial Property Rights Holder
      永島英夫、新林昭太、金仁華、早川均
    • Related Report
      2008 Self-evaluation Report

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Published: 2006-04-01   Modified: 2018-03-28  

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