Surface-Mediated Catalyst Design for Selective Oxidation Catalysis

• Project/Area Number: 18065003
• Research Category: Grant-in-Aid for Scientific Research on Priority Areas
• Allocation Type: Single-year Grants
• Review Section: Science and Engineering
• Research Institution: Institute for Molecular Science (2008-2009); The University of Tokyo (2006-2007)
• Principal Investigator: TADA Mizuki Institute for Molecular Science, 物質分子科学研究領域, 准教授 (70396810)
• Co-Investigator(Kenkyū-buntansha): SASAKI Takehiko 東京大学, 大学院・新領域創成科学研究科, 准教授 (90242099)
• Project Period (FY): 2006 – 2009
• Project Status: Completed (Fiscal Year 2009)
• Budget Amount: ¥32,000,000 (Direct Cost: ¥32,000,000); Fiscal Year 2009: ¥8,000,000 (Direct Cost: ¥8,000,000); Fiscal Year 2008: ¥8,000,000 (Direct Cost: ¥8,000,000); Fiscal Year 2007: ¥8,000,000 (Direct Cost: ¥8,000,000); Fiscal Year 2006: ¥8,000,000 (Direct Cost: ¥8,000,000)
• Keywords: 固定化金属錯体 / 固体触媒 / 触媒構造解析 / 選択酸化 / 触媒反応機構 / 協奏機能触媒 / 反応機構 / 触媒表面 / 時間分解XAFS / ルテニウム / モレキュラーインプリンティング / 触媒 / 表面 / XAFS / in-situ解析 / 協奏機能 / 活性構造 / レニウム / ゼオライト

Research Abstract

Novel unique metal catalysts were designed and prepared on oxide surfaces by metal-complex attaching and selective structural transformation at the surfaces and we have found concerto catalysis for selective oxidation on these surface-mediated metal-complex catalysts. Dynamic structural changes of catalytically active species in the concerto catalysis were investigated by in-situ time-resolved XAFS technique and the reaction mechanism and structural kinetics of the concerto catalysis were demonstrated.

Research Products

• [Journal Article] Alternative Selective Oxidation Pathways for Aldehyde Oxidation and Alkene Epoxidation on a SiO2-Supported Ru-Monomer Complex Catalyst (2010)
  • Author(s): M. Tada, S. Muratsugu, M. Kinoshita, T. Sasaki, Y. Iwasawa
  • Journal Title: J. Am. Chem. Soc 132 Pages: 713-724
  • Peer Reviewed
• [Journal Article] Alternative Selective Oxidation Pathways for Aldehyde Oxidation and Alkene Epoxidation on a SiO2-Supported Ru-Monomer Complex Catalyst (2010)
  • Author(s): M.Tada, S.Muratsugu, M.Kinoshita, T.Sasaki, Y.Iwasawa
  • Journal Title: J.Am.Chem.Soc. 132 Pages: 713-724
  • Peer Reviewed
• [Journal Article] Layered Materials with Coexisting Acidic and Basic Sites for Catalytic One-Pot Reaction Sequences (2009)
  • Author(s): K. Motokura, M. Tada, Y. Iwasawa
  • Journal Title: J. Am. Chem. Soc 131 Pages: 7944-7945
  • Peer Reviewed
• [Journal Article] Bifunctional Heterogeneous Catalysis of Silica-Alumina-Supported Tertiary Amines with Controlled Acid-Base Interactions for Efficient 1, 4-Addition Reactions (2009)
  • Author(s): K. Motokura, S. Tanaka, M. Tada, Y. Iwasawa
  • Journal Title: Chem. Eur. J 15 Pages: 10871-10879
  • Peer Reviewed
• [Journal Article] Layered Materials with Coexisting Acidic and Basic sites for Catalytic One-Pot Reaction Sequences (2009)
  • Author(s): K.Motokura, M.Tada, Y.Iwasawa
  • Journal Title: J.Am.Chem.Soc. 131 Pages: 7944-7945
  • Peer Reviewed
• [Journal Article] Bifunctional Heterogeneous Catalysis of Silica-Alumina-Supported Tertiary Amines with Controlled Acid-Base Interactions for Efficient 1,4-Addition Reactions (2009)
  • Author(s): K.Motokura, S.Tanaka, M.Tada, Y.Iwasawa
  • Journal Title: Chem.Eur.J. 15 Pages: 10871-10879
  • Peer Reviewed
• [Journal Article] 時間分解XAFS法による触媒表面の動的構造解析と触媒構造速度論 (2009)
  • Author(s): 唯美津木
  • Journal Title: 表面科学 30 Pages: 75-83
  • NAID: 10024945165
• [Journal Article] 担持Re触媒を用いたベンゼンと酸素からのフェノール直接合成反応 (2009)
  • Author(s): 唯美津木, 岩澤康裕
  • Journal Title: 有機合成化学会誌 67 Pages: 643-650
  • Peer Reviewed
• [Journal Article] Conceptual Integration of Homogeneous and Heterogeneous Catalyses (2008)
  • Author(s): M. Tada, K. Motokura, Y. Iwasawa
  • Journal Title: Topic Catal 48 Pages: 32-40
  • Peer Reviewed
• [Journal Article] Cooperative Catalysis of Primary and Tertiary Amines Immobilized on Oxide Surface for One-Pot C-C Bond Forming Reaction (2008)
  • Author(s): K. Motokura, M. Tada, Y. Iwasawa
  • Journal Title: Angew. Chem. Int. Ed 47 Pages: 9230-9235
  • Peer Reviewed
• [Journal Article] Photoinduced Reversible Structural Transformation and Selective Oxidation Catalysis of Unsaturated Ruthenium Complexes Supported on SiO2 (2008)
  • Author(s): M. Tada, Y. Akatsuka, Y. Yang, T. Sasaki, M. Kinoshita, K. Motokura, Y. Iwasawa
  • Journal Title: Angew. Chem. Int. Ed. 47 Pages: 9252-9255
  • Peer Reviewed
• [Journal Article] Photoinduced Reversible Structural Transformation and Selective Oxidation Catalysis of Unsaturated Ruthenium Complexes Supported on SiO_2 (2008)
  • Author(s): M. Tada, Y. Akatsuka, Y. Yang, T. Sasaki, M. Kinoshita, K. Motokura, Y. Iwasawa
  • Journal Title: Angew. Chem. Int. E 47 Pages: 9252-9255
  • Peer Reviewed
• [Journal Article] Conceptual Integration of Homogeneous and Heterogeneous Catalyses (2008)
  • Author(s): M. Tada, K. Motokura, Y. Iwasawa
  • Journal Title: Topics in Catalysis 48 Pages: 32-40
  • Peer Reviewed
• [Journal Article] Cooperative Catalysis of Primary and Tertiary Amines Immobilized on Oxide Surface for One-Pot C-C Bond Forming Reactions (2008)
  • Author(s): K. Motokura, M. Tada, Y. Iwasawa
  • Journal Title: Angew. Chem. Int. Ed. 47 Pages: 9230-9235
  • Peer Reviewed
• [Journal Article] Photoinduced Reversible Structural Transformation and Selective Oxidation Catalysis of Unsaturated Ruthenium Complexes Supported on SiO_2 (2008)
  • Author(s): M. Tada, Y. Akatsuka, Y. Yang, T. Sasaki, M. Kinoshita, K. Motokura. Y. Iwasawa
  • Journal Title: Angew. Chem. Int. Ed. 47 Pages: 9252-9255
  • Peer Reviewed
• [Journal Article] Hydroamination : Direct Addition of Amines to Alkenes and Alkynes (2008)
  • Author(s): T. E. Muller, K. Hultzsch, M. Yu, F. Foubelo, M. Tada
  • Journal Title: Chem. Rev. 108 Pages: 3795-3892
  • Peer Reviewed
• [Journal Article] 金属錯体を用いた表面上の3次元活性構造の構築と触媒作用 (2008)
  • Author(s): 唯美津木, 岩澤康裕
  • Journal Title: 表面 33 Pages: 267-283
  • NAID: 40016102767
  • Peer Reviewed
• [Journal Article] Enantioselectivity Promotion by Achiral Surface Functionalization on SiO2-Supported Cu-bis(oxazoline) Catalysts for Asymmetric Diels-Alder Reactions (2007)
  • Author(s): T.E. Mueller, K. Hultzsch, M. Yus, F. Foubelo, M. Tada
  • Journal Title: J. Catal. 245 Pages: 173-183
  • Peer Reviewed
• [Journal Article] In-situ Time-Resolved Dynamic Surface Events on the Pt/C Cathode in a Fuel Cell under Operando Conditions (2007)
  • Author(s): M. Tada, S. Murata, T. Asaoka, K. Hiroshima, K. Okumura, H. Tanida, T. Uruga, H. Nakanishi, S. Matsumoto, Y. Inada, M. Nomura, Y. Iwasawa
  • Journal Title: Angew. Chem. Int. Ed 46 Pages: 4310-4315
  • Peer Reviewed
• [Journal Article] A New Aspect of Heterogeneous Catalysis: Highly Reactive cis-(NO)2 Dimer and Eley-Rideal Mechanism for NO-CO Reactions on a Co-Dimer/γ-Alumina Catalyst (2007)
  • Author(s): T. Taniike, M. Tada, R. Coquet, Y. Morikawa, T. Sasaki, Y. Iwasawa
  • Journal Title: Chem. Phys. Lett. 443 Pages: 66-70
  • Peer Reviewed
• [Journal Article] Selective Formation of a Coordinatively Unsaturated Metal Complex at a Surface: A SiO2-Immobilized, Three-Coordinate Ruthenium Catalyst for Alkene Epoxidation (2007)
  • Author(s): M. Tada, R. Coquet, J. Yoshida, M. Kinoshita, Y. Iwasawa
  • Journal Title: Angew. Chem. Int. Ed. 46 Pages: 7220-7223
  • Peer Reviewed
• [Journal Article] Novel Re-Cluster/HZSM-5 Catalyst for Highly Selective Phenol Synthesis from Benzene and O2: Performance and Reaction Mechanism (2007)
  • Author(s): M. Tada, R. Bal, T. Sasaki, Y. Uemura, Y. Inada, S. Tanaka, M. Nomura, Y. Iwasawa
  • Journal Title: J. Phys. Chem. C 111 Pages: 10095-10104
  • Peer Reviewed
• [Journal Article] Understanding of Novel Surface Events on a Supported Co2+-Ensemble Catalyst Promoted by Gas-Phase Molecules: Increases in the Amount and Reactivity of Adsorbed NO by CO Undetectable at the Catalyst Surface (2007)
  • Author(s): M. Tada, T. Taniike, Y. Iwasawa
  • Journal Title: J. Phys. Chem. C 111 Pages: 11663-11675
  • Peer Reviewed
• [Journal Article] Low-Temperature PROX (Preferential Oxidation) on Novel CeO2-Supported Cu-Cluster Catalysts under Fuel-Cell Operating Conditions (2007)
  • Author(s): M. Tada, R. Bal, X. Mu, R. Coquet, S. Namba, Y. Iwasawa
  • Journal Title: Chem. Commun. Pages: 689-4691
  • Peer Reviewed
• [Journal Article] Energy-Gaining Formation and Catalytic Behavior of Active Structures in a SiO2-Supported Unsaturated Ru Complex Catalyst for Alkene Epoxidation by DFT Calculations (2007)
  • Author(s): R. Coquet, M. Tada, Y. Iwasawa
  • Journal Title: Phys. Chem. Chem. Phys. 9 Pages: 6040-6046
  • Peer Reviewed
• [Journal Article] Origin and Dynamics of Oxygen Storage/Release in a Pt/Ordered CeO2-ZrO2 Catalyst Studied by Time-Resolved XAFS Analysis (2007)
  • Author(s): T. Yamamoto, A. Suzuki, Y. Nagai, T. Tanabe, F. Dong, Y. Inada, M. Nomura, M. Tada, Y. Iwasawa
  • Journal Title: Angew. Chem. Int. Ed. 46 Pages: 9253-9256
  • Peer Reviewed
• [Journal Article] Advanced Design of Catalytically Active Reaction Space at Surfaces for Selective Catalysis (2007)
  • Author(s): M. Tada, Y. Iwasawa
  • Journal Title: Coord. Chem. Rev. 251 Pages: 2702-2716
  • Peer Reviewed
• [Journal Article] Enantioselectivity Promotion by Achiral Surface Functionalization on SiO_2-Supported Cu-BOX Catalysts for Asymmetric Diels-Alder Reactions (2007)
  • Author(s): S. Tanaka, M. Tada, Y. Iwasawa
  • Journal Title: J. Catal 245 Pages: 173-183
  • Peer Reviewed
• [Journal Article] In-Situ Time-Resolved Dynamic Surface Events on the Pt/C Cathode in a Fuel Cell under Operando Conditions (2007)
  • Author(s): M. Tada, S. Murata, T. Asaoka, K. Hiroshima, K. Okumura, H. Tanida, T. Uruga, H. Nakanishi, S. Matsumoto, Y. Inada, M. Nomura, Y. Iwasawa
  • Journal Title: Angew. Chem. Int. Ed 46 Pages: 4310-4315
  • Peer Reviewed
• [Journal Article] Novel Re-Cluster/HZSM-5 Catalyst for Highly Selective Phenol Synthesis from Benzene and O_2 : Performance and Reaction Mechanism (2007)
  • Author(s): M. Tada, R. Bal, T. Sasaki, Y. Uemura, Y. Inada, S. Tanaka, M. Nomura, Y. Iwasawa
  • Journal Title: J. Phys. Chem C111 Pages: 10095-10104
  • Peer Reviewed
• [Journal Article] Understanding of Novel Surface Events on a Supported Co^<2+>-Ensemble Catalyst Promoted by Gas-Phase Molecules : Increases in the Amount and Reactivity of Adsorbed NO by CO Undetectable at the Catalyst Surface (2007)
  • Author(s): M. Tada, T. Taniike, Y. Iwasawa
  • Journal Title: J. Phys. Chem C111 Pages: 11663-11675
  • Peer Reviewed
• [Journal Article] Selective Formation of A Coordinatively Unsaturated Metal Complex at a Surface : A SiO_2-Immobilized, Three-Coordinate Ruthenium Catalyst for Alkene Epoxidation (2007)
  • Author(s): M. Tada, R. Coquet, J. Yoshida, M. Kinoshita, Y. Iwasawa
  • Journal Title: Angew. Chem. Int. Ed 46 Pages: 7220-7223
  • Peer Reviewed
• [Journal Article] Low-Temperature PROX (Preferential Oxidation) on Novel CeO_2-Supported Cu-Cluster Catalysts under Fuel-Cell Operating Conditions (2007)
  • Author(s): M. Tada, R. Bal, X. Mu, R. Coquet, S. Namba, Y. Iwasawa
  • Journal Title: Chem. Commun Pages: 4689-4691
  • Peer Reviewed
• [Journal Article] Origin and Dynamics of Oxygen Storage/Release in a Pt/Ordered CeO_2-ZrO_2 Catalyst Studied by Time-Resolved XAFS Analysis (2007)
  • Author(s): T. Yamamoto, A. Suzuki, Y. Nagai, T. Tanabe, F. Dong, Y. Inada, M. Nomura, M. Tada, Y. Iwasawa
  • Journal Title: Angew. Chem. Int. Ed 46 Pages: 9253-9256
  • Peer Reviewed
• [Journal Article] In-situ Time-resolved Dynamic Surface Events on the Pt/C Cathode ina Fuel Cell under Operando Conditions (2007)
  • Author(s): M. Tada, S. Murata, T. Asaoka, K. Hiroshima, K. Okumura, H. Tanida, T. Uruga, H. Nakanishi, S. Matsumoto, Y. Inada, M. Nomura, Y. Iwasawa
  • Journal Title: Angew. Chem. Int. Ed. 46 Pages: 4310-4315
  • Peer Reviewed
• [Journal Article] Novel Re-Cluster/HZSM-5 Catalyst for Highly Selective Phenol Synthesis from Benzene and O2: Performance and Reaction Mechanism (2007)
  • Author(s): M. Tada, R. Bal, T.Sasaki, Y. Uemura, Y. Inada, S. Tanaka, M. Nomura, and Y. Iwasawa
  • Journal Title: J. Phys. Chem. C 111 Pages: 10095-10104
  • Peer Reviewed
• [Journal Article] Understanding of Novel Surface Events on a Supported Co2+Ensemble Catalyst Promoted by Gas-phase Molecules Increases in the Amount and Reactivity of Adsorbed NO by CO Undetectable at the Catalyst Surface (2007)
  • Author(s): M. Tada, T. Taniike, Y. Iwasawa
  • Journal Title: J. Phys. Chem. C 111 Pages: 11663-11675
  • Peer Reviewed
• [Journal Article] Selective Formation of A Coordinatively Unsaturated Metal Complex ata Surface: A SiO2-Immobilized, Three-Coordinate Ruthenium Catalyst for Alkene Epoxidation (2007)
  • Author(s): M. Tada, R. Coquet, J. Yoshida, M. Kinoshita, Y. Iwasawa
  • Journal Title: Angew. Chem. Int. Ed. 46 Pages: 7220-7223
  • Peer Reviewed
• [Journal Article] Low-Temperature PROX on Novel CeO2-Supported Cu-Cluster Catalysts under Fuel-Cell Operating Conditions (2007)
  • Author(s): M. Tada, R. Bal, X. Mu, R. Coquet, S. Namba, Y. Iwasawa
  • Journal Title: Chem. Commun. Pages: 4689-4691
  • Peer Reviewed
• [Journal Article] NH_3-Promoted Direct Phenol Synthesis from Benzene with Molecular Oxygen on N-Interstitial Re_<10>-cluster/Zeolite Catalysts (2007)
  • Author(s): M. Tada, R. Bal, T. Sasaki, and Y. Iwasawa
  • Journal Title: Stud. Surf. Sci. Catal. 172 Pages: 381-384
• [Journal Article] A Novel Re-Cluster/HZSM-5 Catalyst for Highly Selective Phenol Synthesis from Benzene and O_2:Performance and Reaction Mechanism (2007)
  • Author(s): M. Tada, R. Bal, T. Sasaki, Y. Uemura, Y. Inada, S. Tanaka, M. Nomura, and Y. Iwasawa
  • Journal Title: J. Phys. Chem. C. 111 Pages: 10095-10104
• [Journal Article] Direct Phenol Synthesis by Selective Oxidation of Benzene with Molecular Oxygen on an Interstitial-N/Re Cluster/Zeolite Catalyst (2006)
  • Author(s): R. Bal, M. Tada, T. Sasaki, Y. Iwasawa
  • Journal Title: Angew. Chem. Int. Ed 45 Pages: 448-452
  • Peer Reviewed
• [Journal Article] Density Functional Theoretical Calculations for a Co2/γ-Al2O3 Model Catalyst: Structures of the γ-Al2O3 Bulk and Surface and Attachment Sites for Co2+ Ions (2006)
  • Author(s): T. Taniike, M. Tada, Y. Morikawa, T. Sasaki, Y. Iwasawa
  • Journal Title: J. Phys. Chem. B 110 Pages: 4929-4936
  • Peer Reviewed
• [Journal Article] Advanced Chemical Design with Supported Metal Complexes for Selective Catalysis (2006)
  • Author(s): M. Tada, Y. Iwasawa
  • Journal Title: Chem. Commun 2833-2844
  • Peer Reviewed
• [Presentation] Design of Molecularly-Imprinted Ru-Complex Catalysts on SiO2 (2010)
  • Author(s): M.Tada
  • Organizer: 第90回日本化学会 Asian International Confarence
  • Place of Presentation: 大阪(近畿大学)
  • Year and Date: 2010-03-28
• [Presentation] In-situ 時間分解XAFSによる固体触媒の動的構造解析 (2010)
  • Author(s): 唯美津木
  • Organizer: 日本セラミックス協会年会
  • Place of Presentation: 東京(東京農工大)
  • Year and Date: 2010-03-22
• [Presentation] 選択反応制御のための分子レベル触媒表面設計とリアル系触媒の動的構造解析 (2010)
  • Author(s): 唯美津木
  • Organizer: 理化学研究所ナノサイエンス研究施設交流会
  • Place of Presentation: 和光(理化学研究所)
  • Year and Date: 2010-03-01
• [Presentation] リモネン末端C=C結合位置選択的エポキシ化モレキュラーインプリンティングRu触媒の設計 (2010)
  • Author(s): 唯美津木, 邨次智, 木下睦雄, 楊勇, 岩澤康裕
  • Organizer: 第105回触媒討論会
  • Place of Presentation: 京都
• [Presentation] リモネン末端C=C結合位置選択的エポキシ化モレキュラーインプリンティングRu触媒の設計 (2010)
  • Author(s): 唯美津木, 邨次智, 木下睦雄, 楊勇, 岩澤康裕
  • Organizer: 第105回触媒討論会
  • Place of Presentation: 京都(京都テルサ)
• [Presentation] モレキュラーインプリンティングRu触媒の表面設計とリモネンエポキシ化位置選択性制御 (2010)
  • Author(s): 邨次智, 楊勇, 唯美津木
  • Organizer: 第90回日本化学会春季年会
  • Place of Presentation: 大阪(近畿大学)
• [Presentation] 水中で働く表面モレキュラーインプリンティングRu触媒の調製 (2010)
  • Author(s): 翁志換, 邨次智, 岩澤康裕, 唯美津木
  • Organizer: 第90回日本化学会春季年会
  • Place of Presentation: 大阪(近畿大学)
• [Presentation] 人工酵素触媒表面を自在に設計する-モレキュラーインプリンティング触媒の展開- (2009)
  • Author(s): 唯美津木
  • Organizer: 化学技術戦略推進機構討論会
  • Place of Presentation: 東京(JCII)
  • Year and Date: 2009-11-09
• [Presentation] In-situ 時分割XAFSによる触媒構造のリアルタイム解析 (2009)
  • Author(s): 唯美津木
  • Organizer: 第38回未踏化学を探る会(電気化学会関東支部)
  • Place of Presentation: 東京(東京理科大)
  • Year and Date: 2009-10-02
• [Presentation] Advanced Catalyst Design and In-situ Time-resolved Characterization of Metal-complex Catalysts at Surface (2009)
  • Author(s): M.Tada
  • Organizer: Surface Science and Catalysis Seminar at UC Berkeley
  • Place of Presentation: 米国、バークレー
  • Year and Date: 2009-09-10
• [Presentation] 高機能実触媒反応時のリアルタイム構造解析 (2009)
  • Author(s): 唯美津木
  • Organizer: 第1回レーザー学会専門委員会
  • Place of Presentation: 岡崎(分子研)
  • Year and Date: 2009-04-22
• [Presentation] 学術から実用へつながる新触媒の開発へ!!-固体表面の分子レベル設計と実触媒のXAFS解析 (2009)
  • Author(s): 唯美津木
  • Organizer: 化学技術戦略推進機構講演会
  • Place of Presentation: 東京(JCII)
  • Year and Date: 2009-04-16
• [Presentation] Design of a Surface Molecular-Imprinted Chiral Ru-Complex Catalyst for Asymmetric Hydrogenation of Ketones (2009)
  • Author(s): 楊勇, 唯美津木, 岩澤康裕
  • Organizer: 第89回日本化学会春季年会
  • Place of Presentation: 日本大学(船橋)
  • Year and Date: 2009-03-29
• [Presentation] 固定化Ru3核クラスターモレキュラーインプリンティング触媒の設計と選択的ニトリル水素化反応 (2009)
  • Author(s): 石黒志, 唯美津木, 岩澤康裕
  • Organizer: 第89回日本化学会春季年会
  • Place of Presentation: 日本大学(船橋)
  • Year and Date: 2009-03-29
• [Presentation] 表面モレキュラーインプリンティングRu錯体の設計とリモネンの位置選択的エポキシ化反応 (2009)
  • Author(s): 唯美津木, 木下睦雄, 佐々木岳彦, 岩澤康裕
  • Organizer: 第89回日本化学会春季年会
  • Place of Presentation: 日本大学(船橋)
  • Year and Date: 2009-03-29
• [Presentation] 表面上の触媒活性構造の解析法と機能創出 (2009)
  • Author(s): 唯美津木
  • Organizer: 第89回日本化学会春季年会
  • Place of Presentation: 日本大学(船橋)
  • Year and Date: 2009-03-27
• [Presentation] Design of Novel Molecular-Imprinted Ru-Complex Catalyst for Regioselective Epoxidation (2009)
  • Author(s): M. Tada, Y. Yang, M. Kinoshita, Y. Iwasawa
  • Organizer: 238th ACS National Meeting
  • Place of Presentation: Washington D.C., USA
• [Presentation] Advanced Design of Oxide-Supported Metal Complexes for Selective Catalysis (2009)
  • Author(s): M. Tada
  • Organizer: The 2nd Asian Conference on Coordination Chemistry
  • Place of Presentation: Nanjing, China
• [Presentation] Design of Molecular-Imprinted Metal-Complex Catalysts for Shape-Selective Catalysis (2009)
  • Author(s): M. Tada
  • Organizer: Japan-Canada Coordination Space Symposium
  • Place of Presentation: Banff, Canada
• [Presentation] 表面上の触媒活性構造の解析法と機能創出 (2009)
  • Author(s): 唯美津木
  • Organizer: 第89回日本化学会春季年会ATP講演
  • Place of Presentation: 千葉
• [Presentation] Novel Molecularly- Organized Catalysts for Selective Oxidation and Reforming (2009)
  • Author(s): M. Tada
  • Organizer: 237th ACS National Meeting
  • Place of Presentation: Salt Lake City, US
• [Presentation] Design of Molecular-Imprinted Metal-Complex Catalysts for Shape-Selective Catalysis (2009)
  • Author(s): M.Tada
  • Organizer: Japan-Canada Coordination Space Symposium
  • Place of Presentation: カナダ、バンフ
• [Presentation] 分子機能のリアルタイム構造解析 (2009)
  • Author(s): 唯美津木
  • Organizer: 第59回錯体化学討論会
  • Place of Presentation: 長崎(長崎大学)
• [Presentation] Advanced Design of Oxide-Supported Metal Complexes for Selective Catalysis (2009)
  • Author(s): M.Tada
  • Organizer: The 2nd Asian Conference on Coordination Chemistry
  • Place of Presentation: 中国、南京
• [Presentation] Design of Novel Molecular-Imprinted Ru-Complex Catalyst for Regioselective Epoxidation (2009)
  • Author(s): M.Tada, Y.Yang, M.Kinoshita, Y.Iwasawa
  • Organizer: 238th ACS National Meeting
  • Place of Presentation: 米国、ワシントンDC
• [Presentation] モレキュラーインプリンティングRu触媒の設計と位置選択的エポキシ化反応制御 (2009)
  • Author(s): 邨次智, 唯美津木, 木下睦雄, 岩澤康裕
  • Organizer: 第59回錯体化学討論会
  • Place of Presentation: 長崎(長崎大学)
• [Presentation] 強固なIr-Ir二重結合を有する二核Ir錯体を用いた新規表面固定化錯体触媒の設計 (2009)
  • Author(s): 邨次智, 串田祐子, 中井英隆, 磯辺清, 佐々木岳彦, 唯美津木
  • Organizer: 第104回触媒討論会
  • Place of Presentation: 宮崎(宮崎大学)
• [Presentation] 水中で働く表面モレキュラーインプリンティング固定化Ru錯体触媒の設計 (2009)
  • Author(s): 翁志換, 邨次智, 岩澤康裕, 唯美津木
  • Organizer: 第104回触媒討論会
  • Place of Presentation: 宮崎(宮崎大学)
• [Presentation] Novel Molecularly-Organized Catalysts for Selective Oxidation and Reforming (2009)
  • Author(s): M. Tada
  • Organizer: 237th ACS National Meeting
  • Place of Presentation: USA
• [Presentation] 表面を媒体とした新規高活性Ru錯体の創出とその触媒機能 (2008)
  • Author(s): 唯美津木
  • Organizer: 第5回特定領域研究「協奏機能触媒」公開シンポジウム
  • Place of Presentation: 大阪大学(吹田)
  • Year and Date: 2008-12-03
• [Presentation] ゼオライト担持Re触媒によるベンゼン酸化によるフェノール直接合成 (2008)
  • Author(s): 唯美津木, 岩澤康裕
  • Organizer: 第41回酸化反応討論会
  • Place of Presentation: 九州大学(福岡)
  • Year and Date: 2008-11-28
• [Presentation] SiO_2-Supported Coordinatively-Unsaturated Ru-Complex Catalysts Highly Active for Selective Oxidation Using O_2 (2008)
  • Author(s): M. Tada
  • Organizer: 7^<th> China-Japan Joint Symposium on Metal Cluster Compounds
  • Place of Presentation: 北海道大学(札幌)
  • Year and Date: 2008-10-21
• [Presentation] 表面固定化Ruクラスターを用いた選択的にトリル水素化反応 (2008)
  • Author(s): 石黒志, 唯美津木, 岩澤康裕
  • Organizer: 第102回触媒討論会
  • Place of Presentation: 名古屋大学(名古屋)
  • Year and Date: 2008-09-25
• [Presentation] モレキュラーインプリンティングRu単核錯体の表面設計と形状選択的エポキシ化反応制御 (2008)
  • Author(s): 木下睦雄, 唯美津木, 佐々木岳彦, 岩澤康裕
  • Organizer: 第102回触媒討論会
  • Place of Presentation: 名古屋大学(名古屋)
  • Year and Date: 2008-09-25
• [Presentation] Design and Asymmetric Hydrogenation Performance of a Molecular Imprinting Chiral Ru Complex Catalyst on a Silica Surface (2008)
  • Author(s): 楊勇, 唯美津木, 岩澤康裕
  • Organizer: 第102回触媒討論会
  • Place of Presentation: 名古屋大学(名古屋)
  • Year and Date: 2008-09-25
• [Presentation] 担持Re触媒によるベンゼンからのフェノール直接合成 (2008)
  • Author(s): 唯美津木
  • Organizer: 第102回触媒討論会
  • Place of Presentation: 名古屋大学(名古屋)
  • Year and Date: 2008-09-23
• [Presentation] Novel Molecularly-Organized Materials for O_2 Activation in Catalysis (2008)
  • Author(s): M. Tada
  • Organizer: 2008 Gordon Research Conference on Catalysis
  • Place of Presentation: New London (USA)
  • Year and Date: 2008-06-23
• [Presentation] 表面を媒体とした新規高活性Ru錯体の創出とその触媒機能 (2008)
  • Author(s): 唯美津木
  • Organizer: 第5回特定領域研究協奏機能触媒公開シンポジウム
  • Place of Presentation: 大阪
• [Presentation] Active Structure and Dynamic Mechanism for Direct Phenol Synthesis from Benzene and O2 on a Novel Re10(N)2-Cluster/HZSM-5 Catalyst (2008)
  • Author(s): M. Tada
  • Organizer: 14th International Congress on Catalysis
  • Place of Presentation: Seoul, Korea
• [Presentation] Novel Molecularly-Organized Materials for O2 Activation in Catalysis (2008)
  • Author(s): M. Tada
  • Organizer: 2008 Gordon Research Conference on Catalysis
  • Place of Presentation: New London, USA
• [Presentation] Reaction Mechanism of Direct Phenol Synthesis from Benzene and Molecular Oxygen on Re10N2-Cluster/HZSM-5 Catalysts (2008)
  • Author(s): M. Tada
  • Organizer: 235th ACS National Meeting
  • Place of Presentation: New Orleans, USC
• [Presentation] 選択触媒機能創出を目指した表面を媒体とする高活性金属錯体の構築と反応機構解明 (2008)
  • Author(s): 唯美津木
  • Organizer: 第88回日本化学会春季年会
  • Place of Presentation: 東京
• [Presentation] Active Structure and Dynamic Mechanism for Direct Phenol Synthesis from Benzene and O_2 on a Novel Re_<10>(N)_2-Cluster/HZSM-5 Catalyst (2008)
  • Author(s): M. Tada
  • Organizer: 14th International Congress on Catalysis
  • Place of Presentation: Korea
• [Presentation] Novel Molecularly-Organized Materials for O_2 Activation in Catalysis (2008)
  • Author(s): M. Tada
  • Organizer: 2008 Gordon Research Conference on Catalysis
  • Place of Presentation: USA
• [Presentation] Reaction Mechanism of Direct Phenol Synthesis from Benzene and O_2 on Re_<10>N_2- Cluster/HZSM-5 Catalysts (2008)
  • Author(s): M. Tada
  • Organizer: 235th ACS National Meeting
  • Place of Presentation: USA
• [Presentation] Active Structure and Reaction Mechanism for Direct Phenol Synthesis from Benzene and O2 on a Highly Selective N-Interstitial Re-Cluster/HZSM-5 Catalyst (2007)
  • Author(s): M. Tada, R. Bal, Y. Iwasawa
  • Organizer: 13th International Symposium on Relations between Homogeneous and Heterogeneous Catalysis
  • Place of Presentation: Berkeley, USA
• [Presentation] Direct Phenol Synthesis from Benzene with Molecular Oxygen on a Novel N-Interstitial Re Cluster/Zeolite Catalyst (2007)
  • Author(s): M. Tada, R. Bal, Y. Iwasawa
  • Organizer: 20th North American Catalysis Society Meeting
  • Place of Presentation: Houston, USA
• [Presentation] Surface-Mediated Asymmetric Catalysis by Supported Metal Complexes (2007)
  • Author(s): M. Tada
  • Organizer: Workshop in Catalysis and Fine Chemicals 2007
  • Place of Presentation: Singapore
• [Presentation] 表面を媒体とした活性構造制御と選択酸化触媒能の創出 (2007)
  • Author(s): 唯美津木
  • Organizer: 第100回触媒討論会「協奏機能触媒」セッション
  • Place of Presentation: 札幌
• [Presentation] Zeolite-Supported Re-Cluster Catalysts for Direct Phenol Synthesis (2007)
  • Author(s): M. Tada, R. Bal, T. Sasaki, Y. Iwasawa
  • Organizer: China-Japan Symposium on Selective Oxidation Catalysis
  • Place of Presentation: Xiamen, China
• [Presentation] 表面を媒体とした活性構造制御と選択酸化触媒能の創出 (2007)
  • Author(s): 唯美津木
  • Organizer: 第100回触媒討論会
  • Place of Presentation: 札幌
• [Presentation] 表面を用いた触媒協奏機能の設計・創出と高度反応制御 (2006)
  • Author(s): 唯美津木
  • Organizer: 特定領域研究「協奏機能触媒」第1回公開シンポジウム
  • Place of Presentation: 吹田
• [Presentation] Advanced Design of Supported Metal-Complex Catalysts on surfaces for Selective Catalysis (2006)
  • Author(s): M. Tada, Y. Iwasawa
  • Organizer: 6th China-Japan Joint Symposium on Metal Cluster Compounds
  • Place of Presentation: Huangshan, China
• [Book] ナノ空間材料の創製と応用展開 (2009)
  • Author(s): 唯美津木
  • Publisher: フロンティア出版
• [Book] 超分子金属錯体 (2009)
  • Author(s): 唯美津木, 岩澤康裕
  • Publisher: 三共出版
• [Book] Modern Surface Organometallic Chemistry (2009)
  • Author(s): M. Tada, Y. Iwasawa
• [Book] Modern Heterogeneous Oxidation Catalysis (2009)
  • Author(s): M. Tada, Y. Iwasawa
• [Book] Modern Heterogeneous Oxidation Catalysis (2009)
  • Author(s): M.Tada, Y.Iwasawa
  • Total Pages: 33
  • Publisher: Wiley-VCH
• [Book] Modern Surface Organometallic Chemistry Vol.2 (2009)
  • Author(s): M.Tada, Y.Iwasawa
  • Total Pages: 40
  • Publisher: Wiley-VCH
• [Book] Handbook of Heterogeneous Catalysis 2nd Ed (2007)
  • Author(s): M. Tada, Y. Iwasawa
• [Book] 固定化触媒のルネッサンス (2007)
  • Author(s): 唯美津木, 岩澤康裕
  • Publisher: 株式会社シーエムシー出版
• [Book] 設計表面の触媒反応 (2007)
  • Author(s): 唯美津木, 岩澤康裕
• [Book] Surface and Nanomolecular Catalysis (2006)
  • Author(s): M. Tada, Y. Iwasawa
• [Book] Model Systems in Catalysis: From Single Crystals and Size Selected Clusters to Supported Enzyme Mimics
  • Author(s): M. Tada, Y. Iwasawa
  • Publisher: Springer(in press)
• [Book] Modern Surface Organometallic Chemistry Vol. 2
  • Author(s): M. Tada, Y. Iwasawa (Eds. J. M. Basset, R. Psaro, and R. Ugo)
  • Publisher: Wiley-VCH (in press)
• [Book] Recent Development in Heterogeneous Oxidation Catalysis
  • Author(s): M. Tada, Y. Iwasawa (Ed. N. Mizuno)
  • Publisher: Wiley-VCH (in press)
• [Book] Model Systems in Catalysis : From Single Crystals and Size Selected Clusters to Supported Enzyme Mimics
  • Author(s): M. Tada, Y. Iwasawa
  • Publisher: Springer(印刷中)
• [Book] Modern Surface Organometallic Chemistry
  • Author(s): M. Tada, Y. Iwasawa
  • Publisher: Wiley-VCH(印刷中)
• [Patent(Industrial Property Rights)] フェノール製造用触媒の製造方法および該触媒を用いたフェノールの製造方法 (2009)
  • Inventor(s): 唯美津木, 岩澤康裕, 王林勝, 及川隆
  • Industrial Property Rights Holder: 唯美津木, 岩澤康裕, 王林勝, 及川隆
  • Filing Date: 2009-03-15
• [Patent(Industrial Property Rights)] フェノール製造用触媒の製造方法および該触媒を用いたフェノールの製造方法 (2009)
  • Inventor(s): 唯美津木, 岩澤康裕, 王林勝, 及川隆
  • Industrial Property Rights Holder: 唯美津木, 岩澤康裕, 王林勝, 及川隆
  • Filing Date: 2009-03-15
• [Patent(Industrial Property Rights)] ベンゼンの直接酸化によるフェノールの製造方法 (2008)
  • Inventor(s): 岩澤康裕, 唯美津木, 王林勝, 及川隆
  • Industrial Property Rights Holder: 岩澤康裕, 唯美津木, 王林勝, 及川隆
  • Filing Date: 2008-04-04
• [Patent(Industrial Property Rights)] ベンゼンの直接酸化によるフェノールの製造方法 (2008)
  • Inventor(s): 岩澤康裕, 唯美津木, 王林勝, 及川隆
  • Industrial Property Rights Holder: 岩澤康裕, 唯美津木, 王林勝, 及川隆
  • Filing Date: 2008-04-04