| Project/Area Number |
18065006
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| Research Category |
Grant-in-Aid for Scientific Research on Priority Areas
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| Allocation Type | Single-year Grants |
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| Review Section |
Science and Engineering
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| Research Institution | Tokyo University of Agriculture and Technology |
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Principal Investigator |
KOMIYA Sanshiro Tokyo University of Agriculture and Technology, 大学院・共生科学技術研究院, 教授 (00111667)
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| Co-Investigator(Kenkyū-buntansha) |
平野 雅文 東京農工大学, 大学院・共生科学技術研究院, 准教授 (70251585)
小峰 伸之 東京農工大学, 大学院・共生科学技術研究院, 助教 (90302918)
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| Co-Investigator(Renkei-kenkyūsha) |
HIRANO Masafumi 東京農工大学, 大学院・共生科学技術研究院, 准教授 (70251585)
KOMINE Nobuyuki 東京農工大学, 大学院・共生科学技術研究院, 助教 (90302918)
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| Project Period (FY) |
2006 – 2009
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| Project Status |
Completed (Fiscal Year 2009)
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| Budget Amount *help |
¥69,600,000 (Direct Cost: ¥69,600,000)
Fiscal Year 2009: ¥10,400,000 (Direct Cost: ¥10,400,000)
Fiscal Year 2008: ¥10,400,000 (Direct Cost: ¥10,400,000)
Fiscal Year 2007: ¥10,400,000 (Direct Cost: ¥10,400,000)
Fiscal Year 2006: ¥38,400,000 (Direct Cost: ¥38,400,000)
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| Keywords | 遷移金属錯体 / 協同効果 / 錯体触媒 / 挿入反応 / カルベン / ヘテロ二核錯体 / 架橋型アルケニル錯体 / 共同効果 / 触媒反応 / 二核錯体 / μ-η_1:η_2-アリル / 還元的脱離 / 白金-マンガン二核錯体 / μ-η^1 : η^2-アリル / μ-η^1:η^2-アリル / 白金-コバルト二核錯体 / 酸化的付加 / アリル基移動 / パラジウム-コバルト二核錯体 / アジリジン / 一酸化炭素 / 共重合反応 / 白金-パラジウム二核錯体 / η^1,η^2-アリル基 |
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| Research Abstract |
Series of Heterodinulcear organo(or hydrido, allyl, carbene)platinum(or palladium) complexesd were prepared. Palladium(0)-catalyzed Markovnikov-type olefin insertion into insertion-inactive transition metal hydride complexes MHL´n were achieved, whose activity highly depends on steric factors of tertiary phosphine ligand employed. (E)-Isomer-selective intramolecular fluxional behavior and facile olefin induced reductive elimination of heterodinuclear allyplatinum-cobalt complexes are observed. These unusual reactivities are considered to be arisen from thermodynamic stability of the resulting allyltransition metal complexes.
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