| Budget Amount *help |
¥31,600,000 (Direct Cost: ¥31,600,000)
Fiscal Year 2009: ¥7,900,000 (Direct Cost: ¥7,900,000)
Fiscal Year 2008: ¥7,900,000 (Direct Cost: ¥7,900,000)
Fiscal Year 2007: ¥7,900,000 (Direct Cost: ¥7,900,000)
Fiscal Year 2006: ¥7,900,000 (Direct Cost: ¥7,900,000)
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| Research Abstract |
A series of ligands containing C=N and P=O moieties were created. These ligands displayed hemi-labile behaviors in palladium complexes due to interaction with oxygen of the P=O moiety and relatively high performance in ethylene oligomerization and Heck reaction. On the other hand, the foregoing observations suggested that the interaction of the oxygen in RC(O) and R2P(O) moieties with acidic promoters would enhance the reactivity. On the basis of the assumption, we were able to develop efficient addition reactions of acid chlorides or HP(O)R2 compounds with alkynes.
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