| Budget Amount *help |
¥32,400,000 (Direct Cost: ¥32,400,000)
Fiscal Year 2009: ¥8,100,000 (Direct Cost: ¥8,100,000)
Fiscal Year 2008: ¥8,100,000 (Direct Cost: ¥8,100,000)
Fiscal Year 2007: ¥8,100,000 (Direct Cost: ¥8,100,000)
Fiscal Year 2006: ¥8,100,000 (Direct Cost: ¥8,100,000)
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| Research Abstract |
On the basis of Concerto Catalysis, new types of tridentate nitrogen-based ligands have been developed to show high catalytic activities in the combination of rhodium and ruthenium atoms. The catalysts exhibited high efficiencies in product and optical yields for reduction- or C-H bond activation based asymmetric carbon bond formations such as reductive aldol couplings, asymmetric hydrogenation, asymmetric transfer hydrogenation, asymmetric cyclopropanation, asymmetric direct aldol reaction.
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