New Approaches for Creating New Phosphines and Their Applications
| Project/Area Number |
18065014
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| Research Category |
Grant-in-Aid for Scientific Research on Priority Areas
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| Allocation Type | Single-year Grants |
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| Review Section |
Science and Engineering
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| Research Institution | Kyoto University |
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Principal Investigator |
OSHIMA Koichiro Kyoto University, 大学院・工学研究科, 教授 (00111922)
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| Project Period (FY) |
2006 – 2009
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| Project Status |
Completed (Fiscal Year 2009)
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| Budget Amount *help |
¥33,600,000 (Direct Cost: ¥33,600,000)
Fiscal Year 2009: ¥8,400,000 (Direct Cost: ¥8,400,000)
Fiscal Year 2008: ¥8,400,000 (Direct Cost: ¥8,400,000)
Fiscal Year 2007: ¥8,400,000 (Direct Cost: ¥8,400,000)
Fiscal Year 2006: ¥8,400,000 (Direct Cost: ¥8,400,000)
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| Keywords | 選択的合成・反応 / ホスフィン配位子 / 環化付加 / インドール / 立体障害 / 鈴木カップリング / パラジウム触媒 / ホスフィン / 均一系分子触媒 / 配位子 / 協奏機能 / かさ高い配位子 / 交差カップリング反応 / 二座配位子 / ヒドロホスフィン化 / 1-アルキニルホスフィン |
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| Research Abstract |
Due to the importance of organophosphines as ligands for transition metal catalysts, development of efficient methods for the synthesis of new phosphines is very important. We recognized 1-alkynylphosphines and their derivatives as useful precursors for creation of new phosphines. Chemical modifications of the carbon-carbon triple bonds, including nucleophilic addition and cycloaddition, led to a wide range of new useful phosphines that are otherwise difficult to synthesize.
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Report
(6 results)
Research Products
(24 results)
