Development of Bio-inspired Catalytic Reactions in Water
Project/Area Number |
18065017
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Research Category |
Grant-in-Aid for Scientific Research on Priority Areas
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Allocation Type | Single-year Grants |
Review Section |
Science and Engineering
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Research Institution | Kyushu University |
Principal Investigator |
SEIJI Ogo (OGO Seiji) Kyushu University, 大学院・工学研究院, 教授 (60290904)
|
Project Period (FY) |
2006 – 2009
|
Project Status |
Completed (Fiscal Year 2009)
|
Budget Amount *help |
¥65,600,000 (Direct Cost: ¥65,600,000)
Fiscal Year 2009: ¥10,400,000 (Direct Cost: ¥10,400,000)
Fiscal Year 2008: ¥10,400,000 (Direct Cost: ¥10,400,000)
Fiscal Year 2007: ¥10,400,000 (Direct Cost: ¥10,400,000)
Fiscal Year 2006: ¥34,400,000 (Direct Cost: ¥34,400,000)
|
Keywords | 水中 / 水素 / 電子 / 錯体 / 触媒 / 触媒・化学プロセス / 酵素反応 / モデル化 / 合成化学 |
Research Abstract |
The catalytic mimic of hydrogenase has been a long-standing challenge in the study of activation of hydrogen gas. The NiRu model complexes mimic the major features of hydrogenase, that is : heterolytic hydrogen activation, electron extraction, and simultaneous isotope exchange. The key mechanistic aspects are the proton-like character of the hydride intermediate, the activation of a second molecule of hydrogen gas during each cycle, and the possibility of positive ion exchange, which produces simultaneous, not sequential isotope exchange.
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Report
(6 results)
Research Products
(64 results)
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[Journal Article] A Dinuclear Ni(μ-H)Ru Complex Derived from H2.2007
Author(s)
Ogo, Seiji;* Kabe, Ryota; Uehara, Keiji; Kure, Bunsho; Nishimura, Takashi; Menon, Saija C.; Harada, Ryosuke; Fukuzumi, Shunichi; Higuchi, Yoshiki; Ohhara, Takashi; Tamada, Taro; Kuroki, Ryota.
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Journal Title
Science 316(5824)
Pages: 585-587
Related Report
Peer Reviewed
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[Journal Article] A Dinuclear Ni(μ-H)Ru Complex Derived from H_22007
Author(s)
Ogo, Seiji; Kabe, Ryota; Uehara, Keiji; Kure, Bunsho; Nishimura, Takashi; Menon, Saija C.; Harada, Ryosuke; Fukuzumi, Shunichi; Higuchi, Yoshiki; Ohhara, Takashi; Tamada, Taro; Kuroki, Ryota
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Journal Title
Science 316(5824)
Pages: 585-587
Related Report
Peer Reviewed
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