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Reaction dynamics of transition metal atoms

Research Project

Project/Area Number 18066014
Research Category

Grant-in-Aid for Scientific Research on Priority Areas

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionUniversity of Hyogo

Principal Investigator

HONMA Kenji  University of Hyogo, 大学院・物質理学研究科, 教授 (30150288)

Co-Investigator(Kenkyū-buntansha) GEJO Tatsuo  兵庫県立大学, 大学院・物質理学研究科, 准教授 (20290900)
MATSUMOTO Yoshiteru  兵庫県立大学, 大学院・物質理学研究科, 助教 (30360051)
Project Period (FY) 2006 – 2009
Project Status Completed (Fiscal Year 2009)
Budget Amount *help
¥20,300,000 (Direct Cost: ¥20,300,000)
Fiscal Year 2009: ¥3,700,000 (Direct Cost: ¥3,700,000)
Fiscal Year 2008: ¥6,000,000 (Direct Cost: ¥6,000,000)
Fiscal Year 2007: ¥6,000,000 (Direct Cost: ¥6,000,000)
Fiscal Year 2006: ¥4,600,000 (Direct Cost: ¥4,600,000)
Keywords化学反応動力学 / 反応ダイナミクス / 気相遷移金属原子 / 交差分子線 / 反応動力学 / 遷移金属原子 / 気相反応ダイナミクス / 酸化反応
Research Abstract

Transition metal atoms(TM) play important roles in various catalytic reactions. In this research project, the collisions and reactions of the TM atoms with molecules were studied experimentally to clarify the mechanism of the catalytic abilities of TM. One characteristics of the TM atoms is the electronic structure. It can be easily mediated by the presence of other molecules, reactants. Here, a crossed-beam technique was used to study the collision of TM with O_2 under single collision condition and velocity/angular distributions of products were determined. These information were useful to clarify the interaction between TM and O_2 and the presence of intermediates.

Report

(6 results)
  • 2009 Annual Research Report   Final Research Report ( PDF )
  • 2008 Annual Research Report   Self-evaluation Report ( PDF )
  • 2007 Annual Research Report
  • 2006 Annual Research Report
  • Research Products

    (46 results)

All 2011 2010 2009 2008 2007 2006 Other

All Journal Article (24 results) (of which Peer Reviewed: 17 results) Presentation (16 results) Book (4 results) Remarks (2 results)

  • [Journal Article] Time-sliced velocity imaging study of reaction Y + O_2 → YO + O2011

    • Author(s)
      Kenji Honma, Yoshiteru Matsumoto
    • Journal Title

      Phys.Chem.Chem.Phys. 13

      Pages: 8236-8244

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Time-sliced velocity imaging study of reaction Y + O_2 YO + O.2011

    • Author(s)
      Kenji Honma, Yoshiteru Matsumoto
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: 13 Pages: 8236-8244

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Crystalline structures in large ammonia clusters studied by IR cavity ringdown spectroscopy and density functional theory calculation.2010

    • Author(s)
      Yoshiteru Matsumoto, Kenji Honma
    • Journal Title

      Chem.Phys.Lett.

      Volume: 490 Pages: 9-13

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hydrogen-bonded structures of the pyrrole-solvent clusters : Infrared cavity ringdown spectroscopy and quantum chemical calculations2009

    • Author(s)
      Yoshiteru Matsumoto, Kenji Honma
    • Journal Title

      J.Chem.Phys. 130

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Excited state reaction dynamics of Ti(a^5F_J) + O_2 → TiO(A,B) + O studied by a crossed-beam technique2009

    • Author(s)
      Ryo Yamashiro, Yoshiteru Matsumoto, Kenji Honma
    • Journal Title

      J.Chem.Phys. 131

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Excited state reaction dynamics of Ti(a^5F_J) + O_2 TiO(A, B) + O studied by a crossed-beam technique.2009

    • Author(s)
      Ryo Yamashiro, Yoshiteru Matsumoto, Kenji Honma
    • Journal Title

      J.Chem.Phys.

      Volume: 131

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hydrogen-bonded structures of the pyrrole-solvent clusters: Infrared cavity ringdown spectroscopy and quantum chemical calculations2009

    • Author(s)
      Yoshiteru Matsumoto and Kenji Honma
    • Journal Title

      J. Chem. Phys. 130

    • Related Report
      2008 Self-evaluation Report
  • [Journal Article] Hydrogen-borlded structures of the pyrrole-solvent clusters : Infrared cavity ringdovvn spectroscopy and quantum chemical calctilatious2009

    • Author(s)
      Yoshiteru Matsumoto and Kenji Honma
    • Journal Title

      The Journal of Chemical Physics 130

      Pages: 11-11

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hydrogen bonding in methanol clusters probed by inner-shell photoabsorption spectroscopy in the carbon and oxygen K-edge regions2008

    • Author(s)
      Y.Tamenori, K.Okada, O.Takahashi, S.Arakawa, K.Tabayashi, A.Hiraya, T.Gejo, K.Honma
    • Journal Title

      J.Chem.Phys. 128

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Dynamics of reaction Si + O_2 → SiO + O studied by the crossed beam LIF technique2008

    • Author(s)
      R.Yamashiro, Y.Matsumoto, Kenji Honma
    • Journal Title

      J.Chem.Phys. 128

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Hydrogen bonding in methanol clusters probed by inner-shell photoabsorption spectroscopy in the carbon and oxygen K-edge regions2008

    • Author(s)
      Y. Tamenori, K. Okada, O. Takahashi, S. Arakawa, K. Tabayashi, A. Hiraya, T. Gejo, and K. Honma
    • Journal Title

      J. Chem. Phys. 128

    • Related Report
      2008 Self-evaluation Report
  • [Journal Article] Dynamics of reaction Si + O2 → SiO + O studied by the crossed-beam LIF technique2008

    • Author(s)
      R. Yamashiro, Y. Matsumoto, and Kenji Honma
    • Journal Title

      J. Chem. Phys. 128

    • Related Report
      2008 Self-evaluation Report
  • [Journal Article] Hydrogen bonding in methanol clusters probed by inner-shell photoab sorption spectroscopy in the, carbon and oxygen K-edge regions2008

    • Author(s)
      Y. Tamenori, et.al.
    • Journal Title

      The Journal of Chemical Physics 128

      Pages: 8-8

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Specific fragmentation of [(CH_3)_2CO]Arn heteroclusters induced by the Ar L_<23>-and O K-shell excitation2008

    • Author(s)
      Y. Tamenori, K. Okada, K. Tab ayashi, T. Gejo, and K. Honma
    • Journal Title

      Chemical Physics Letters 462

      Pages: 40-44

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dynamics of reaction Si +O_2→SiO+O studied by the crossed-beam LIF technique2008

    • Author(s)
      R.Yamaahiro, Y.Matsumoto, K.Honma
    • Journal Title

      The Journal of Chemical Physics 128

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] NH stretching vibrations of pyrrole clusters studied by infrared cavity reigdown spectroscopy2008

    • Author(s)
      Yoshiteru Matsumoto and Kenji Honma
    • Journal Title

      The Journal of Chemical Physics 128

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] NH Stretching vibrations of pyrrole clusters studied by infrared cavity ringdown spectroscopy2007

    • Author(s)
      Yoshiteru Matsumoto, Kenji Honma
    • Journal Title

      J.Chem.Phys. 127

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Core-valence multiply excited states in N_2 probed by detecting metastable fragments2007

    • Author(s)
      Y Hitosaka, T.Gejo, T.Tamura, K.Honma, Y.Tamenori, and E.Shigemasa
    • Journal Title

      Journal of Physics B 40

      Pages: 2091-2097

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Reaction dynamics of V(a^4FJ)+NO → laser-induced fluorescence technique2006

    • Author(s)
      M.Ishida, R.Yamashiro, Y.Matsumoto, Kenji Honma
    • Journal Title

      J.Chem.Phys. 124

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Inner-shell excitation spectroscopy and fragmentation of small hydrogen-bonded clusters of formic acid after core-excitations at the oxygen K-edge2006

    • Author(s)
      K.Tabayashi, K.Yamaoto, O.Takahashi, Y.Tamenori, J.Harris, T.Gejo, M.Iseda, T.Tamura, K.Honma, I.H.Suzuki, S.Nagaoka, T.Ibuki
    • Journal Title

      J.Chem.Phys. 125

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Reaction dynamics of V(a4FJ)+NO → VO(X4S-)+N studied by a crossed-beam laser -induced fluorescence technique2006

    • Author(s)
      M. Ishida, R. Yamashiro, Y. Matsumoto, and Kenji Honma
    • Journal Title

      J. Chem. Phys. 124

    • Related Report
      2008 Self-evaluation Report
  • [Journal Article] Reaction dynamics of V(a^4F_J)+NO → VO(X^4Σ)+N studied by a crossed-beam laser-induced fluorescence technique.2006

    • Author(s)
      M.Ishida, R.Yamashiro, Y.Matsumoto, Kenji Honma
    • Journal Title

      The Journal of Chemical Physics 125

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Inner-shell excitation spectroscopy, and fragmentation of small hydrogen-bonded clusters of formic acid after core-excitations at the oxygen K-edge2006

    • Author(s)
      K.Tabayashi, K.Yamaoto, O.Takahashi, Y.Tamenori, J.Harris, T.Gejo, M.Iseda, T.Tamura, K.Honma, 他
    • Journal Title

      The Journal of Chemical Physics 125

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Formation of H_3O^+ by the soft X-ray ionization of ethanol clusters2006

    • Author(s)
      Y.Tamenori, K.Okada, K.Tabayashi, A.Hiraya, T.Gejo, K.Honma
    • Journal Title

      Chemical Physics Letters 433

      Pages: 43-47

    • Related Report
      2006 Annual Research Report
  • [Presentation] 電子状態と反応性-遷移金属原子の反応ダイナミクス2010

    • Author(s)
      本間健二
    • Organizer
      化学反応のポテンシャル曲面とダイナミクス-加藤重樹先生の足跡をたどって
    • Place of Presentation
      京都大学理学研究科セミナーハウス
    • Year and Date
      2010-06-19
    • Related Report
      2009 Final Research Report
  • [Presentation] Reaction dynamics of gas-phase transition metal atoms2010

    • Author(s)
      Kenji Honma
    • Organizer
      Pacifichem 2010, Symposium on "Frontiers in State-to-State Dynamics"
    • Place of Presentation
      Honolulu, Hawaii
    • Related Report
      2009 Final Research Report
  • [Presentation] Reaction dynamics of transition metal atoms studied by a crossed-beam technique2010

    • Author(s)
      Kenji Honma
    • Organizer
      The 69th Okazaki Conference
    • Place of Presentation
      Okazaki Conference Center
    • Related Report
      2009 Final Research Report
  • [Presentation] Reaction dynamics of gas-phase transition metal atoms.2010

    • Author(s)
      Kenji Honma
    • Organizer
      Pacifichem 2010
    • Place of Presentation
      Hawaii, U.S.A.
    • Related Report
      2009 Annual Research Report
  • [Presentation] Reaction dynamics of transition metal atoms studied by a crossed-beam technique.2010

    • Author(s)
      Kenji Honma
    • Organizer
      The 69th Okazaki Conference
    • Place of Presentation
      愛知県岡崎市岡崎コンファレンスセンター
    • Related Report
      2009 Annual Research Report
  • [Presentation] Reaction dynamics of transition metal atoms studied by crossed beam techniaue2009

    • Author(s)
      Kenji Honma
    • Organizer
      The 13th East Asian Workshop on Chemical Reactions
    • Place of Presentation
      Taipei, Taiwan
    • Year and Date
      2009-03-19
    • Related Report
      2008 Annual Research Report
  • [Presentation] Reaction dynamics of transition metal atoms studied by crossed beam technique2009

    • Author(s)
      Kenji Honma
    • Organizer
      XXIII International Symposium on Molecular Beams
    • Place of Presentation
      Dalian
    • Related Report
      2009 Final Research Report
  • [Presentation] Reaction Dynamics of Transition Metal Atoms Studied by Crossed Beam Technique2009

    • Author(s)
      Kenji Honma
    • Organizer
      The 13th East Asian Workshop on Chemical Reactions
    • Place of Presentation
      Taipei, Taiwan
    • Related Report
      2009 Final Research Report
  • [Presentation] Reaction dynamics of transition metal atoms studied by crossed beam technique2009

    • Author(s)
      Kenji Honma
    • Organizer
      The 13th East Asian Workshop on Chemical Reactions
    • Place of Presentation
      Taipei
    • Related Report
      2008 Self-evaluation Report
  • [Presentation] Reaction dynamics of transition metal atoms studied by crossed beam techniaue2008

    • Author(s)
      Kenji Honma
    • Organizer
      The 8the Asian International Seminar on Atomic and Molecular Physics
    • Place of Presentation
      Perth, Australia
    • Year and Date
      2008-11-27
    • Related Report
      2008 Annual Research Report
  • [Presentation] Reaction dynamics studied by crossed-beam LIF techique:Si+O_2→SiO+O2008

    • Author(s)
      Kenji Honma
    • Organizer
      The 12th East Asian Workshop on Chemical Reaction.
    • Place of Presentation
      Seoul
    • Year and Date
      2008-03-21
    • Related Report
      2007 Annual Research Report
  • [Presentation] Reaction dynamics of transition metal atoms studied by crossed beam technique2008

    • Author(s)
      Kenji Honma
    • Organizer
      The 8the Asian International Seminar on Atomic and Molecular Physics
    • Place of Presentation
      University of Western Australia, Perth
    • Related Report
      2009 Final Research Report
  • [Presentation] Reaction dynamics studied by crossed-beam LIF technique : Si + O_2 → SiO + O2008

    • Author(s)
      Kenji Honma
    • Organizer
      The 12th East Asian Workshop on Chemical Reactions
    • Place of Presentation
      Korea University, Seoul
    • Related Report
      2009 Final Research Report
  • [Presentation] Reaction dynamics studied by crossed-beam LIF technique: Si + O2 → SiO + O2008

    • Author(s)
      Kenji Honma
    • Organizer
      The 12th East Asian Workshop on Chemical Reactions
    • Place of Presentation
      Seoul
    • Related Report
      2008 Self-evaluation Report
  • [Presentation] Reaction dynamics of transition metal atoms studied by crossed beam technique2008

    • Author(s)
      Kenji Honma and Ryo Yamashiro
    • Organizer
      The 8the Asian International Seminar on Atomic and Molecular Physics
    • Place of Presentation
      Perth
    • Related Report
      2008 Self-evaluation Report
  • [Presentation] Reaction dynamics studied by crossed-beam LIF techniques: Si + O2 SiO + O2007

    • Author(s)
      R. Yamashiro, Y. Matsumoto, and Kenji Honma
    • Organizer
      XXII International Symposium on Moecular Beams
    • Place of Presentation
      Freiburg
    • Related Report
      2008 Self-evaluation Report
  • [Book] 物質科学の世界(第12章「化学反応を分子レベルから眺める」)2010

    • Author(s)
      本間健二
    • Publisher
      共立出版
    • Related Report
      2009 Final Research Report
  • [Book] Dynamics of oxidation reactions of gas-phase metal atoms studied by a crossed-beam LIF technique(Ed. By K. C. Lin and Paul Kleiber)2008

    • Author(s)
      Kenji Honma
    • Total Pages
      38
    • Publisher
      Transword Research Network
    • Related Report
      2008 Self-evaluation Report
  • [Book] Dynamics of oxidation reactions of gas-phase metal atoms studied by a crossed-beam LIF technique(in Gas Phase Molecular Reaction and Photodissociation Dynamics)(Ed.By K.C.Lin, Paul Kleiber)2007

    • Author(s)
      Kenji Honma
    • Publisher
      Transworld Research Network
    • Related Report
      2009 Final Research Report
  • [Book] Dynamics of oxidation reactions of gas-phase metal atoms studied by a crossed-beam LIF technique.2007

    • Author(s)
      Kenji Honma
    • Publisher
      Transworld Research Network
    • Related Report
      2007 Annual Research Report
  • [Remarks] ホームページ等

    • Related Report
      2009 Final Research Report
  • [Remarks]

    • URL

      http://www.sci.u-hyogo.ac.jp/material/reactionl/index-j.html

    • Related Report
      2009 Annual Research Report

URL: 

Published: 2006-04-01   Modified: 2018-03-28  

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