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Reaction Chemistry of Transition Metal Clusters

Research Project

Project/Area Number 18105002
Research Category

Grant-in-Aid for Scientific Research (S)

Allocation TypeSingle-year Grants
Research Field Inorganic chemistry
Research InstitutionTokyo Institute of Technology

Principal Investigator

SUZUKI Hiroharu  Tokyo Institute of Technology, 大学院・理工学研究科, 教授 (30106629)

Co-Investigator(Kenkyū-buntansha) 高尾 俊郎  東京工業大学, 大学院・理工学研究科, 准教授 (00313346)
大石 理貴  東京工業大学, 大学院・理工学研究科, 助教 (20376940)
Co-Investigator(Renkei-kenkyūsha) 高尾 俊郎  東京工業大学, 大学院・理工学研究科, 准教授 (00313346)
大石 理貴  東京工業大学, 大学院・理工学研究科, 助教 (20376940)
Project Period (FY) 2006 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥114,530,000 (Direct Cost: ¥88,100,000、Indirect Cost: ¥26,430,000)
Fiscal Year 2010: ¥15,600,000 (Direct Cost: ¥12,000,000、Indirect Cost: ¥3,600,000)
Fiscal Year 2009: ¥15,600,000 (Direct Cost: ¥12,000,000、Indirect Cost: ¥3,600,000)
Fiscal Year 2008: ¥15,600,000 (Direct Cost: ¥12,000,000、Indirect Cost: ¥3,600,000)
Fiscal Year 2007: ¥15,600,000 (Direct Cost: ¥12,000,000、Indirect Cost: ¥3,600,000)
Fiscal Year 2006: ¥52,130,000 (Direct Cost: ¥40,100,000、Indirect Cost: ¥12,030,000)
Keywords金属クラスター / 多核クラスター / 多電子移動 / 多点相互作用 / 小分子活性化 / 混合金属クラスター / 異種金属クラスター / 異種金属効果 / 平行四辺形型クラスター / 混合配位子クラスター / ベンザイン錯体 / アルキルベンゼン / ルテニウム / ヒドリド錯体 / 多点配位 / クラスター錯体 / 五核クラスター / 六核クラスター / ポリヒドリド / クラスター触媒 / ピリジン脱水素カップリング / ビピリジン / アルカン / ピリジン二量化
Research Abstract

We have systematically studied on the reaction chemistry of the transition metal polyhydride clusters for these five years in the quest to develop new and effective organic transformations achieved by the synergetic effect of the adjacent metal centers. And we have successfully achieved main subjects such as 1) synthesis of homo- and heterometallic clusters with higher nuclearity, 2) modification of the electronic and steric environment of the reaction site, 3) elucidation of the mechanism of the cluster reaction, and 4) development of new reactions catalyzed by the cluster complexes.

Report

(7 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • 2008 Annual Research Report   Self-evaluation Report ( PDF )
  • 2007 Annual Research Report
  • 2006 Annual Research Report
  • Research Products

    (75 results)

All 2010 2009 2008 2007 2006 Other

All Journal Article (43 results) (of which Peer Reviewed: 23 results) Presentation (25 results) Book (1 results) Remarks (5 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Rational Construction of Oligomec Polymetallic Ensambles Consisting of Ru2H4 Subunits Interconnected by Flexible Carbon Chains2010

    • Author(s)
      T.Yanagi, H.Suzuki
    • Journal Title

      Organometallics 29

      Pages: 2357-2366

    • Related Report
      2010 Final Research Report
  • [Journal Article] Synthesis and Structure of a Novel Ruthenium Hydrido Bis(dihydrogen) Complex with1, 4, 7-Trimethyl-1, 4, 7-triazacyclononane Ligand : A Useful Precursor for Synthesis of Heterometallic Complexes2010

    • Author(s)
      T.Shima, K.Namura, H.Kameo, S.Kakuta, H.Suzuki
    • Journal Title

      Organometallics 29

      Pages: 337-346

    • Related Report
      2010 Final Research Report
  • [Journal Article] Synthesis of Ruthenium Polyhydride Clusters with 1, 4, 7-Triazacyclononane-Type Ligands : Stereo and Electronic Effects of Ancillary Ligands2010

    • Author(s)
      K.Namura, S.Kakuta, H.Suzuki
    • Journal Title

      Organometallics 29

      Pages: 4305-4311

    • Related Report
      2010 Final Research Report
  • [Journal Article] Metathesis Reaction of Hydrocarbyl Ligands across the Triruthenium Plane2010

    • Author(s)
      A.Tahara, m.Kajigaya, M.Moriya, T.Takao, H.Suzuki
    • Journal Title

      Angew.Chem.Int.Ed. 49

      Pages: 5898-5901

    • Related Report
      2010 Final Research Report
  • [Journal Article] Rational Construction of Oligomeric Polymetallic Ensembles Consisting of Ru2H5 Subunit Interconnected…2010

    • Author(s)
      柳貴子・鈴木寛治
    • Journal Title

      Organometallics

      Volume: 29 Pages: 2357-2366

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Structure of a Novel Ruthenium Hydrido Bis(dihydrogen) Complex with 1, 4, 7-Trimethyl-1, 4, 7-Triazacyclononane Ligand : A Useful Precursor for Synthesis of Heterometallic Complexes2010

    • Author(s)
      島隆則・名村響・亀尾肇・角田聡・鈴木寛治
    • Journal Title

      Organometallics

      Volume: 29 Pages: 337-346

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Ruthenium Polyhydride Clusters with 1, 4, 7-Triazacyclononane-Type Ligands : Stereo and2010

    • Author(s)
      名村響・角田聡・鈴木寛治
    • Journal Title

      Organometallics

      Volume: 29 Pages: 4305-4311

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Direct Arylation of a Cluster-Bound Alkyne Ligand with Benzene2010

    • Author(s)
      高尾俊郎・守谷誠・梶ヶ谷真奈・鈴木寛治
    • Journal Title

      Organometallics

      Volume: 29 Pages: 4770-4773

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Metathesis Reaction of Hydrocarbyl Ligands across the Triruthenium Plane2010

    • Author(s)
      田原淳士・梶ヶ谷真奈・守谷誠・高尾俊郎・鈴木寛治
    • Journal Title

      Angew.Chem.Int.Ed.

      Volume: 49 Pages: 5898-5901

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Heterometallic Trinuclear Polyhydrido Clusters Containing Ruthenium and Osmium and Their Elctronic and Structural Deviation from Homometallic Systems2009

    • Author(s)
      H.Kameo, T.Shima, Y.Nakajima, H.Suzuki
    • Journal Title

      Organometallics 28

      Pages: 2535-2545

    • Related Report
      2010 Final Research Report
  • [Journal Article] Zirconocene-Iridium Hydrido Complexes : Arene Carbon-Hydrogen Bond Activation and Formation of a Planar Square Zr2Ir2 Complex2009

    • Author(s)
      M.Oishi, H.Suzuki
    • Journal Title

      Inorg.Chem. 48

      Pages: 2349-2351

    • Related Report
      2010 Final Research Report
  • [Journal Article] Arylation of a Hydrocarbyl Ligand Formed from n-Alkane via C-H Bond Activation of Benzene using a Triruthenium Cluster2009

    • Author(s)
      守谷誠、田原淳士、高尾俊郎、鈴木寛治
    • Journal Title

      Eur.J.Inorg.Chem.

      Pages: 3393-3397

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 三核ルテニウムクラスター上での炭化水素配位子の骨格転位2009

    • Author(s)
      高尾俊郎, 鈴木寛治
    • Journal Title

      有機化学合成協会誌 67

      Pages: 475-485

    • NAID

      10024968707

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Structure of a Novel Ruthenium Hydrido Bis(dihydrogen)Complex with 1,4,7-Trimethyl-1,4,7-triazacyclononae Ligand : A Useful Precursor for Synthesis of Heterometallic Complexes2009

    • Author(s)
      島隆則、名村響、亀尾肇、鈴木寛治
    • Journal Title

      Organometallics 29

      Pages: 337-346

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Trinuclear Osmium Polyhydrido Clusters [{(C5Me5)Os}3(μ-H)6]+and{(C5Me5)Os}3(μ-H)5 and Comparison with the Ruthenium Analogues2008

    • Author(s)
      H.Kameo, H.Suzuki
    • Journal Title

      Organometallics 27

      Pages: 4248-4253

    • Related Report
      2010 Final Research Report
  • [Journal Article] Synthesis and Reactivity of Eary-Late Heterobimetallic Hydrides of Group 4 Metals and Iridium Supported by Mono(■5-C5Me5) Ancillary Ligands : Bimetallic Carbon-Hydrogen Bond Activation2008

    • Author(s)
      M.Oishi, T.Kato, M.Nakagawa, H.Suzuki
    • Journal Title

      Organometallics 27

      Pages: 6046-6049

    • Related Report
      2010 Final Research Report
  • [Journal Article] Introduction of a Methoxy Group into a Hydrocarbyl Ligand Derived from a Linear Alkane on a Triruthenium Cluster via Chemical Oxidation2008

    • Author(s)
      高尾俊郎、守谷誠、鈴木寛治
    • Journal Title

      Organometallics 27

      Pages: 18-20

    • Related Report
      2008 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Insertion of Acetylene and Nitriles into a Ru-C Bond of a Dicationic Triruthenium Complex Having a μ_3-η^3-C_3 Ring : Formation of Six-Membered Ruthenacycles on a Triruthenium Core2008

    • Author(s)
      高尾俊郎、守谷誠、鈴木寛治
    • Journal Title

      Organometallics 27

      Pages: 1044-1054

    • Related Report
      2008 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Preparation and Propertities of Diruthenium Hydrido Complexes Having a Brdging Benzoquinone Ligand : Formation of an Alcohol Adduct of a μ-η^2:η^2-Benzoquinone Complex through Hydrogen Bonding2008

    • Author(s)
      高尾俊郎、秋吉一憲、鈴木寛治
    • Journal Title

      Organometallics 27

      Pages: 4199-4206

    • Related Report
      2008 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Reactivity of Early-Late Heterobimetallic Hydrides of Group 4 Metals and Iridium Supported by Mono(η^5-C_5Me_5)Ancillary Ligands : Bimetallic Carbon-Hydrogen Bond Activation2008

    • Author(s)
      大石理貴、加藤剛史、中川麻悠子、鈴木寛治
    • Journal Title

      Organometallics 27

      Pages: 6046-6049

    • Related Report
      2008 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Trinuclear Osmium Polyhydrido Clusters…2008

    • Author(s)
      亀尾肇, 鈴木寛治
    • Journal Title

      Organometallics 27

      Pages: 4248-4253

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Insertion of Acetylene and Nitriles into a Ru-C Bond of…2008

    • Author(s)
      高尾俊郎, 守谷 誠, 鈴木寛治
    • Journal Title

      Organometallics 27

      Pages: 1004-1054

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Introduction of a Methoxy Group into a Hydrocarbyl Ligand Derived from a Linear Alkane on a Triruthenium Cluster via Chemical Oxidation2008

    • Author(s)
      Toshiro Takao, Makoto Moriya, Hiroharu Suzuki
    • Journal Title

      Organometallics 27

      Pages: 18-20

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Insertion of Acetylene and Nitriles into a Ru-C Bond of a Dicationic Triruthenium Complex Having a μ_3-η^3-C_3 Ring: Formation of Six-Membered Ruthenacycles on a Triruthenium Core2008

    • Author(s)
      Toshiro Takao, Makoto Moriya, Hiroharu Suzuki
    • Journal Title

      Organometallics 27

      Pages: 1044-1054

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ruthenium Poluhydrido Clusters Having a Bridging AlkylzincGroup2007

    • Author(s)
      M.Ohashi, K.Matsubara, H.Suzuki
    • Journal Title

      Organometallics 26

      Pages: 2330-2339

    • Related Report
      2010 Final Research Report
  • [Journal Article] Redox-Induced Reversible Rearrangement of a Dimatallaaryl Ligand on the Trinuclear Cluster of Ruthenium.Mechanistic Aspects of Formation of the Face-Capping μ3-C3 Ring on the Triruthrnium Plane2007

    • Author(s)
      T.Takao, M.Moriya, H.Suzuki
    • Journal Title

      Organometallics 26

      Pages: 1349-1360

    • Related Report
      2010 Final Research Report
  • [Journal Article] Synthesis and Structure of Cationic Triruthenium Complexes Containing an Oxametallacycle : Reversible Carbon-Carbon Bond Formation and Scission on an Electron-Deficient Triruthrnium Plane2007

    • Author(s)
      M.Moriya, T.Takao, H.Suzuki
    • Journal Title

      Organometallics 26

      Pages: 1650-1657

    • Related Report
      2010 Final Research Report
  • [Journal Article] Dehydrogenative Coupling of 4-Substituted Pyridines Catalyzed by Diruthenium Complexes2007

    • Author(s)
      T.Kawashima, T.Takao, H.Suzuki
    • Journal Title

      J.Am.Chem.Soc. 129

      Pages: 11006-11007

    • Related Report
      2010 Final Research Report
  • [Journal Article] Dehydrogenetive Coupling of 4-Substituted Pyridines Catalyzed…2007

    • Author(s)
      川島敬史, 高尾俊郎, 鈴木寛治
    • Journal Title

      J. Am. Chem. Soc. 129

      Pages: 11006-11007

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Redox-induced Reversible Rearrangement of a Dimetalloallyl Ligand on the Trinuclear Cluster of Ruthenium. Mechanistic Aspects of Formation of the Face-capping μ_3-C_3 Ring on the Triruthenium Plane2007

    • Author(s)
      Toshiro Takao, Makoto Moriya, Hiroharu Suzuki
    • Journal Title

      Organometallics 26

      Pages: 1349-1360

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Structure of Cationic Triruthenium Complexes Containing an Oxametallacycle; Reversible Carbon-Oxygen Bond Formation and Scission on an Electron-Deficient Triruthenium Plane2007

    • Author(s)
      Makoto Moriya, Toshiro Takao, Hiroharu Suzuki
    • Journal Title

      Organometallics 26

      Pages: 1650-1657

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ruthenium Polyhydrido Clusters Having a Bridging Alkylzinc Group, [(η^5-C_5Me_5)Ru(μ-H)]_3(μ_3-ZnR)_n(μ_3-H)_<2-n> and [(η^5-C_5Me_5)Ru]_2(μ-ZnR)_n(μ-H)_<4-n> (R = Me and Et; n = 1 and 2)2007

    • Author(s)
      Masato Ohashi, Kouki Matsubara, Hiroharu Suzuki,
    • Journal Title

      Organometallics 26

      Pages: 2330-2339

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hydrogenation of a Trinuclear μ_3-Imido Complex of Ruthenium: Homolytic or Heterolytic H-H Bond Cleavage?2007

    • Author(s)
      Hajime Kameo, Yumiko Nakajima, Hiroharu Suzuki
    • Journal Title

      Eur. J. Inorg. Chem.

      Pages: 1793-1798

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dehydrogenative Coupling of 4-Substituted Pyridines Catalyzed by Diruthenium Complexes2007

    • Author(s)
      Takashi Kawashima, Toshiro Takao, Hiroharu Suzuki
    • Journal Title

      J. Am. Chem. Soc. 129

      Pages: 11006-11007

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Reaction of a Heterobimetallic Polyhydrido Cluster, [Cp*Ru(μ-H)_4OsCp*](Cp*=η^5-C_5Me_5), with Diphenylacetylene. Regioselective C-H Bond Activation at the Osmium Center2007

    • Author(s)
      Takanori Shima, Toshiaki Ichikawa, Hiroharu Suzuki
    • Journal Title

      Organometallics 26

      Pages: 6329-6337

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Redox-induced Reversible Rearrangement of a Dimetalloally Ligand on the Trinuclear Cluster of Ruthenium. Mechanistic Aspects of Formation of the Face-capping μ_3-C_3 Ring on the Triruthenium Plane2007

    • Author(s)
      Toshiro Takao, Makoto Moriya, Hiroharu Suzuki
    • Journal Title

      Organometallics 26・6

      Pages: 1349-1360

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Synthesis and Structure of Cationic Trirutheenium Complexes Containing an Oxametallacycle; Reversible Carbon-Oxygen Bond Formation and Scissin on an Electron-Deficient Triruthenium Plane2007

    • Author(s)
      Makoto Moriya, Toshiro Takao, Hiroharu Suzuki
    • Journal Title

      Organometallics 26・7

      Pages: 1650-1657

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Trinuclear Ru/Os Clusters : Compounds with Hydrocarbon Ligands (Cyclopentadienyls)2007

    • Author(s)
      Hiroharu Suzuki, Toshiro Takao
    • Journal Title

      Comprehensive Organometallic Chemistry III, 6

      Pages: 797-821

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Synthesis of Group8-Group 6 Heterotrimetallic Polyhydrido Complexes Habing Only a C5Me5 Group as Auxiliary Ligand2006

    • Author(s)
      J.Ito, T.Shima, H.Suzuki
    • Journal Title

      Organometallics 25

      Pages: 1333-1336

    • Related Report
      2010 Final Research Report
  • [Journal Article] Cleavage of the CN Triple Bond on a Triruthenium Cluster : Synthesis and Structure of a Triruthenium Complex Containinf a μ3-Nitrido Ligand2006

    • Author(s)
      T.Kawashima, T.Takao, H.Suzuki
    • Journal Title

      Angew.Chem.Int.Ed. 45

      Pages: 485-488

    • Related Report
      2010 Final Research Report
  • [Journal Article] Cleavage of Nitrogen-Hydrogen Bonds of Ammonia Induced by Triruthenium Polyhydrido Clusters2006

    • Author(s)
      Y.Nakajima, H.Kameo, H.Suzuki
    • Journal Title

      Angew.Chem.Int.Ed. 45

      Pages: 950-952

    • Related Report
      2010 Final Research Report
  • [Journal Article] Hydrogenation of a Trinuclear m3-Imido Complex of Ruthenium Homolytic or Heterolytic H-H Bond Cleavage?

    • Author(s)
      Hajime Kameo, Yumiko Nakajima, Hiroharu Suzuki
    • Journal Title

      Eur.J.Inorg.Chem in press.

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Ruthenium Polyhydrido Clusters Having a Bridging Alkylzinc Group,[(η^5-C_5Me_5)Ru(μ-H)]_3(μ_3-ZnR)_n(μ_3-H)_2-n and [(η^5-C_5Me_5)Ru]_2(μ-ZnR)_n(μ-H)_4-n (R=Me and Et; n=1 and 2)

    • Author(s)
      Masato Ohashi, Kouki Matsubara, Hiroharu Suzuki
    • Journal Title

      Organometallics, in press.

    • Related Report
      2006 Annual Research Report
  • [Presentation] Simplest Atom but Complicated Chemistry of Transition Metal Polyhydrido Clusters2010

    • Author(s)
      H.Suzuki
    • Organizer
      24^<th> International Conference on Organometallic Chemistry
    • Place of Presentation
      Taipei
    • Year and Date
      2010-07-19
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Presentation] 遷移金属クラスター反応場の構築とクラスター反応の開発(特別講演)2009

    • Author(s)
      鈴木寛治
    • Organizer
      第104回 触媒討論会
    • Place of Presentation
      長崎大学
    • Year and Date
      2009-09-30
    • Related Report
      2009 Annual Research Report
  • [Presentation] C-H Activation of Arene Substrates Mediated by Coodinative Unsaturation of Group 4 Metallocene-Iridium ELHB Hydrides2008

    • Author(s)
      大石理貴、塩谷泰介、鈴木寛治
    • Organizer
      有機金属化学討論会
    • Place of Presentation
      大阪
    • Year and Date
      2008-09-30
    • Related Report
      2008 Self-evaluation Report
  • [Presentation] ジアミドアミン配位子を有する4族及びCp系9族ユニットを含む新規ELHBヒドリド錯体の合成(4E4-27)2008

    • Author(s)
      堀内新之介, 加藤剛史, 大石理貴, 鈴木寛治
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      立教大学
    • Year and Date
      2008-03-29
    • Related Report
      2007 Annual Research Report
  • [Presentation] シクロペンタジエニル配位子を有するタンタル-イリジウム二核錯体の反応性:タンタル上の置換基による効果(4E4-28)2008

    • Author(s)
      笹生雅之, 大石理貴, 鈴木寛治
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      立教大学
    • Year and Date
      2008-03-29
    • Related Report
      2007 Annual Research Report
  • [Presentation] Ru_5M骨格を有する六核ポリヒドリドクラスターの合成と構造(3E8-08)2008

    • Author(s)
      望月信介, 高尾俊郎, 鈴木寛治
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      立教大学
    • Year and Date
      2008-03-28
    • Related Report
      2007 Annual Research Report
  • [Presentation] ルテニウムとオスミウムを含む二核テトラヒドリド錯体と三級ボスフィンとの反応における異種金属効果(2E8-49)2008

    • Author(s)
      亀尾肇, 鈴木寛治
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      立教大学
    • Year and Date
      2008-03-27
    • Related Report
      2007 Annual Research Report
  • [Presentation] ルテニウムポリヒドリドクラスターとイミン類との反応(2E8-47)2008

    • Author(s)
      神田英行, 川島敬史, 高尾俊郎, 鈴木寛治
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      立教大学
    • Year and Date
      2008-03-27
    • Related Report
      2007 Annual Research Report
  • [Presentation] 三重架橋ルテナシクロペンタジエン骨格を有する新規三核錯体の合成と構造(2E8-51)2008

    • Author(s)
      田原淳士, 高尾俊郎, 鈴木寛治
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      立教大学
    • Year and Date
      2008-03-27
    • Related Report
      2007 Annual Research Report
  • [Presentation] 二核ルテニウム錯体を用いたピリジン類の脱水素カップリング反応2008

    • Author(s)
      高尾俊郎
    • Organizer
      名古屋大学G-COE第1回物質化学フロンティアセミナー
    • Place of Presentation
      名古屋大学
    • Year and Date
      2008-01-11
    • Related Report
      2007 Annual Research Report
  • [Presentation] Reaction of Ru-Os Heterobimetallic Complex (C_5Me_5)Os(μ-H)_4 Ru(C_5Me_5)…2008

    • Author(s)
      亀尾 肇, 鈴木寛治
    • Organizer
      国際有機金属会議
    • Place of Presentation
      フランス、レンヌ
    • Related Report
      2008 Annual Research Report
  • [Presentation] Control over the Reactivity of a Polyhydrido Cluster via Subtle Interaction with Alcohol (PA-238)2007

    • Author(s)
      Toshiro Takao, Tomomi Suzuki, Kazunori Akiyoshi, Hiroharu Suzuki
    • Organizer
      第54回 有機金属化学討論会
    • Place of Presentation
      広島大学
    • Year and Date
      2007-10-28
    • Related Report
      2007 Annual Research Report
  • [Presentation] Reaction of Tetra-Nuclear Polyhydrido Complexes of Ruthenium with Molecular Oxygen: Mono- or Dioxygenation? (PA-234)2007

    • Author(s)
      Hajime Kameo, Yasuhiro Ohki, Hiroharu Suzuki
    • Organizer
      第54回 有機金属化学討論会
    • Place of Presentation
      広島大学
    • Year and Date
      2007-10-28
    • Related Report
      2007 Annual Research Report
  • [Presentation] 三核ルテニウムクラスター上でのニトリルの分子変換反応(2B5-50)2007

    • Author(s)
      高尾俊郎, 川島敬史, 鈴木寛治
    • Organizer
      日本化学会第1回関東支部大会
    • Place of Presentation
      首都大学東京
    • Year and Date
      2007-09-28
    • Related Report
      2007 Annual Research Report
  • [Presentation] ヒドリド架橋4族メタロセンー9族金属からなる異種金属錯体:新規平面四核錯体の生成(2B5-37)2007

    • Author(s)
      大石理貴, 鈴木寛治
    • Organizer
      日本化学会第1回関東支部大会
    • Place of Presentation
      首都大学東京
    • Year and Date
      2007-09-28
    • Related Report
      2007 Annual Research Report
  • [Presentation] ルテニウムおよびオスミウムから成る三核ポリヒドリド錯体の合成-それらのμ_3-オキソ誘導体とアンモニアとの反応(2B5-35)2007

    • Author(s)
      亀尾肇, 島隆則, 鈴木寛治
    • Organizer
      日本化学会第1回関東支部大会
    • Place of Presentation
      首都大学東京
    • Year and Date
      2007-09-28
    • Related Report
      2007 Annual Research Report
  • [Presentation] 二核ルテニウム架橋ベンゾキノン錯体の合成とその性質(2D-07)2007

    • Author(s)
      秋吉一憲, 高尾俊郎, 鈴木寛治
    • Organizer
      第57回 錯体化学討論会
    • Place of Presentation
      名古屋工業大学
    • Year and Date
      2007-09-26
    • Related Report
      2007 Annual Research Report
  • [Presentation] 架橋ヒドリド配位子を含むルテニウム-タングステン系クラスターによる触媒的ラジカル反応(2D-08)2007

    • Author(s)
      松宮史宜, 大石理貴, 鈴木寛治
    • Organizer
      第57回 錯体化学討論会
    • Place of Presentation
      名古屋工業大学
    • Year and Date
      2007-09-26
    • Related Report
      2007 Annual Research Report
  • [Presentation] 四核ルテニウムポリヒドリドクラスターとアルキンとの反応-Ru-Ru結合の切断、形成を伴うクラスター骨格の変換-(2D-06)2007

    • Author(s)
      望月信介, 上原直樹, 高尾俊郎, 鈴木寛治
    • Organizer
      第57回 錯体化学討論会
    • Place of Presentation
      名古屋工業大学
    • Year and Date
      2007-09-26
    • Related Report
      2007 Annual Research Report
  • [Presentation] 三核ルテニウムクラスター上でのイミンの炭素-窒素結合切断(1PD-013)2007

    • Author(s)
      神田英行, 川島敬史, 高尾俊郎, 鈴木寛治
    • Organizer
      第57回 錯体化学討論会
    • Place of Presentation
      名古屋工業大学
    • Year and Date
      2007-09-25
    • Related Report
      2007 Annual Research Report
  • [Presentation] シクロペンタジエニル配位子を有する新規タンタル-イリジウム二核錯体の合成と反応(1PD-015)2007

    • Author(s)
      笹生雅之, 大石理貴, 鈴木寛治
    • Organizer
      第57回 錯体化学討論会
    • Place of Presentation
      名古屋工業大学
    • Year and Date
      2007-09-25
    • Related Report
      2007 Annual Research Report
  • [Presentation] 架橋ヒドリド配位子を有するCp系4族-9族を含む二核錯体の合成と反応性(4J04)2007

    • Author(s)
      大石理貴, 加藤剛史, 原麻悠子, 鈴木寛治
    • Organizer
      第100回 触媒討論会
    • Place of Presentation
      北海道大学
    • Year and Date
      2007-09-20
    • Related Report
      2007 Annual Research Report
  • [Presentation] 6族遷移金属とルテニウムを含む異種金属クラスター上での炭化水素配位子への官能基導入(3J31)2007

    • Author(s)
      市川利明, 伊藤淳一, 鈴木寛治
    • Organizer
      第100回触媒討論会
    • Place of Presentation
      北海道大学
    • Year and Date
      2007-09-19
    • Related Report
      2007 Annual Research Report
  • [Presentation] Dehydrogenative Coupling of 4-Substituted Pyridines Catalyzed by the Di-and Trinuclear Ruthenium Complexes(P-384)2007

    • Author(s)
      Toshiro Takao, Takashi Kawashima, Hiroharu Suzuki
    • Organizer
      14th IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis (OMCOS14)
    • Place of Presentation
      Nara Centennial Hall
    • Year and Date
      2007-08-05
    • Related Report
      2007 Annual Research Report
  • [Presentation] Cleavaga of N-H Bonds of Ammonia Induced by Polyhydrido Clusters (P-103)2007

    • Author(s)
      Hajime Kameo, Yumiko Nakajima, Hiroharu Suzuki
    • Organizer
      14th IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis (OMCOS14)
    • Place of Presentation
      Nara Centennial Hall
    • Year and Date
      2007-08-03
    • Related Report
      2007 Annual Research Report
  • [Book] Comprehensive Organometallic Chemistry III("Trinuclear Ruthenium Clusters with Cyclopentadienyl Ligands")(D.M.P.Mingos and R.H.Crabtree, Eds)2007

    • Author(s)
      H.Suzuki, T.Takao
    • Publisher
      Elsevier
    • Related Report
      2010 Final Research Report
  • [Remarks] ホームページ等

    • URL

      http://www.apc.titech.ac.jp/~hsuzuki/index.html

    • Related Report
      2010 Final Research Report
  • [Remarks]

    • Related Report
      2010 Annual Research Report
  • [Remarks]

    • URL

      http://www.apc.titech.ac.jp/~hsuzuki/index.html

    • Related Report
      2009 Annual Research Report
  • [Remarks]

    • URL

      http://www.apc.titech.ac.jp/~hsuzuki/index.html

    • Related Report
      2008 Self-evaluation Report
  • [Remarks]

    • URL

      http://www.titech.ac.jp/whoswho/Profiles/0026/0000169/profile.html

    • Related Report
      2007 Annual Research Report
  • [Patent(Industrial Property Rights)] 2,2'-ビビリジン類の製造方法2006

    • Inventor(s)
      鈴木 寛治, 高尾 俊郎, 川島 敬史
    • Industrial Property Rights Holder
      長尾 雅昭, 相澤 益男
    • Industrial Property Number
      2006-225951
    • Filing Date
      2006-08-23
    • Related Report
      2006 Annual Research Report

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Published: 2006-04-01   Modified: 2016-04-21  

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